The document describes the production of toluene from n-heptane by dehydrogenation over a Cr2O3 catalyst. N-heptane is heated and fed into a catalytic reactor operating at 800°F where 15% of the n-heptane is converted to toluene and hydrogen. The effluent is cooled and sent to a separator. The flow rates and properties of streams are determined. Toluene is produced with a conversion rate of 15%.
The document describes the production of toluene from n-heptane by dehydrogenation over a Cr2O3 catalyst. N-heptane is heated and fed into a catalytic reactor operating at 800°F where 15% of the n-heptane is converted to toluene and hydrogen. The effluent is cooled and sent to a separator. The flow rates and properties of streams are determined. Toluene is produced with a conversion rate of 15%.
The document describes the production of toluene from n-heptane by dehydrogenation over a Cr2O3 catalyst. N-heptane is heated and fed into a catalytic reactor operating at 800°F where 15% of the n-heptane is converted to toluene and hydrogen. The effluent is cooled and sent to a separator. The flow rates and properties of streams are determined. Toluene is produced with a conversion rate of 15%.
Production of Toluene by Dehydrogenation of Normal Heptane
Rounak Gupta Department of Chemical Engineering, Birsa Institute of Technology, Sindri.
Background & Description:
Toluene is produced from n-heptane by dehydrogenation over a Cr2O3 catalyst, The
reaction for the same is given below:
CH3CH2CH2CH2CH2CH2CH3 C6H5CH3 + 4H2
In this process Toluene is formed along with Hydrogen as shown in the reaction . The process flowsheet shows the conversion of n-heptane to toluene using a catalytic reactor working on the reaction shown above. The toluene production process is started by heating n-heptane from 65 to 800oF in a heater. It is fed to a catalytic reactor, which operates isothermally and converts 15 mol percent of the n- heptane to toluene. Its effluent is cooled to 65oF and fed to a separator (flash). Assuming that all of the units operated at atmospheric pressure, The species flow rate and other properties are determined in every stream.
Flowsheet : Results:
Conclusion:
Toluene is formed with a conversion rate of 15%.
Reference:
1. HYSYS:An Introduction to Chemical Engineering Simulation by
Recent Advances in the Science and Technology of Zeolites and Related Materials: Proceedings of the 14th International Zeolite Conference, Cape Town, South Africa, 25-30th April 2004
Physical Organic Chemistry—Ii: Specially Invited Lectures Presented at the Second IUPAC Conference on Physical Organic Chemistry Held at Noordwijkerhout, Netherlands, 29 April–2 May 1974