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ORGANIC SPECTROSCOPY
Assignment-1 (IR Spectroscopy)

Attempt as Quiz See Solution

Q1 which of the following spectroscopic techniques will be useful to

distinguish between M-SCN and M-NCS binding modes?
[NET June 2011]
(a) NMR
(b) IR
(c) EPR
(d) Mass
Q2 The order of carbonyl stretching frequency in IR Spectra of
ketone, amide and anhydride is-
[NET June 2011]
(a) anhydride > amide > ketone
(b) ketone > amide > anhydride
(c) amide > anhydride > ketone
(d) anhydride > ketone > amide
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Q3 In the IR spectrum, carbonyl absorption band for the following

compound appears at
[NET Dec 2011]

(a) 1810 cm-1

(b) 1770 cm-1
(c) 1730 cm-1
(d) 1690 cm-1
Q4 In the IR spectrum of p-nitrophenyl acetate, the carbonyl
absorption band appears at
[NET Dec 2012]
(a) 1670 cm-1
(b) 1700 cm-1
(c) 1730 cm-1
(d) 1760 cm-1
Q5 In the IR spectrum, the absorption band due to carbonyl group in
phenyl acetate appears at
[NET June 2013]
(a) 1800 cm-1
(b) 1760 cm-1
(c) 1710 cm-1
(d) 1660 cm-1
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Q6 In the IR spectrum of p-nitrophenyl acetate, the carbonyl

absorption band appears at
[NET Dec 2013]
(a) 1600 cm-1
(b) 1700 cm-1
(c) 1730 cm-1
(d) 1770 cm-1
Q7 Compound that exhibits sharp bands at 3300 cm-1 and 2150 cm-1
in the IR spectrum is
[NET June 2015]
(a) 1-butyne
(b) 2-butyne
(c) butyronitrile
(d) butylamine
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Q8 Correctly matched structure and carbonyl stretching frequency set

is
[NET Dec 2015]

(a) P-Y , Q-Z , R-X

(b) P-Y , Q-X , R-Z
(c) P-Z , Q-Y , R-X
(d) P-X , Q-Z , R-Y
Q9 Among the following, the compound that displays an IR band at
2150 cm-1 is
[NET June 2016]
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Q10 The compound which shows IR frequencies at both 3314 and

2126 cm-1 is
[NET Dec 2016]
(a) CH3(CH2)4CH2SH
(b) CH3(CH2)4CH2C≡N
(c) CH3(CH2)4CH2C≡CH
(d) CH3(CH2)2C≡C(CH2)2CH3

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