4 CHEMISTRY For GCE. Advanced Lovol Examination States of matter Cemanoct QSaab, e6609.... Sais &8OnD (BSc.Engineering(UG).University of Moratuwa) Scanned with CamScannerBerto BOcio Ong qeOd () Hy 2g Bebenam 2x 105Nm~? Boao 0669 4% 10-2m? 08. Og Acbeamed 2 @ @ o o Mm 3X 105Nm~? BOs BO 08 GOGO oman mist, Oe cwandifa amma mdcieo. Qage8 CHaneiOo cemedaddo D8 a8 comona adatn, (2.66) He Oxg Aebeaan 4.2 x 105Nm-? Bdmame O66 dm? 8. OF O68 0.5 m? Om 0 28 BOs0 oss mdsto. Oxged CwddOD emeOadO 088 a8 conden née. (1.68 x 10°Nm=?) egodOo SQoOss M_OHO BVO SF, 08. 20°C 2 on 102.0kPa BOsa adeck 086 ExQha SgeHoHOed 0.100g 0 22.10cm? m OHO quo. Oxge8 gag GQe ecxraeseD. (SF,)(S = 32,F = 19) . NH,HCO, 158g eoOsm sxtnadd ae 127°C enie dob mdm @& C60 aBgtioond® NH3,H,0 ex CO, Beakinn SOs mca ae 0.4988 x 105Pa 8 BOaa ox 0. exceed H590 adre mdakeo. (4000 x 10-5m?) Bq ceioce Mg Al so Cu azn. 68853 0.6g comm NaOH OB eSidrand o8e oGGcn 0Q 89 erAdy Hp 05H 0.6.8. & 336cm? 08. e880 965 On egln edeo aga SMecdeeod ea OA oOinad 8m GHGa mdg 80 ern H, COO 112.cm? 5 80. &g egised 26 gab ogi oGam masks, (Mg = 24,Al = 27,Cu = 635) (AL= 45%, Mg = 20%,Cu = 35%) eb gOeed enoGis BH Ga80 Eoxto. Eng Besom Aro By Gog OD gad Coed qin BA SEES 0.45 x 10°Nm? oo 0.5 x 105Nm? 08. Gow caléndban Og Sgioo CDGa gad 26 0680 2x 10-3? 8. 28 CeanciOed FO 680 0.5 x 10-3} Exie eDad neg a8, @) @8d8a0 Og BOaed Odo BOD Gi) C60 eBad B608s5 og A, 80 moo BHaa (iii) 06810 e8ed3 B608e5 Og B, O anoGa BOna (iv) 20800 cOadd B68 09 H8cin BaD eenaeto. (0.95 x 105Nm~?, 1.8 x 10°Nm7?, 2 x 10°Nm72, 3.8 x 10°Nm=~*) A 388 OrgO 2.00g Sabato endoand me 25°C & o Bla latm cOedd Ge. B axeB EaqO 3.00g 29 encinad® 25°C 8 cung nda ef 280 mdan gE Baa 15atm Oa. Coan miAx® Condens Odes Am B Hxg8e MA/MB ax O90 casi) eamaa cotoena mdeseo.(1/3) Scanned with CamScannerfe tn 69 Ny 0190 0. COBO 15% 10°%9 9 pom 35x 10-%m? Oo endacd a6 pies a : a cs¥ Ba Nya Hs a2 CBOES CERN 6 20) OL gers sxfede 80 ¢ DagOse BLAS. cas oenned Sabie Cito Bone aoe cop rambo oah gaswee econ? 0 £m (i Og By GOO 908 Nz exged Bsa ocx. Gi) Og Bg BOeBst cy 0680 4.5% 10-%m? ends 96 ora. (ii) &g Bgmed I; 6 epoGo BOsa exrasta. (iv) Ong Batoad N, 8 Of wr5a Otome |oCIO. (c03 x 108Nim-2, (2 x 105N, quyo.g x 10°Nm"?,| (woz) ©) 860 aida Exgedd com E AO. Qxgo coABW en envseBede 80 soatodiad @O dst, (0) cdo Og eBghin 8680 om Seles Gn CHlindO 80 BO OAD GOad ¢ ? 08a cage, Krypton © Xenon qdioboo 1.0dm! 9 cO68d co Bead 8x10'Pa Bosaok ev 300K 0 CBéndibam & 2.79gciaaidad C68. og Sganed gras oD dose edna mdaieo. (@ Kr & coeddos iyo class) 83.8 om Xe G cvedas qty dasa 1312 98, Eg Bemed 2 Oxgaies gon Bina odes. (i 02g Spied Kr B moe BOs aOete? (66.985 gmol"*, 93.28%, 6.72%, 7.46 x 10*Nm"*) ay Big Seman own Enged quB and Th Om ea qofia BH cme grated. 0,-8x10* Pa He-24x105Pa Ar—4x10*Pa Ne-4Xx10*Pa @) Org8eme ge Og Oe 08 d gundam 68 a8 Od Od Hoge Og Bo ooo oso ndsia. (i) ©80B ed CHléndO0 127°C 8 Bxess COW aadeoo odesen. ii) 02g Beqsned CHenddOo 427°C enkED gxog Dobe GES ads Ar 2 mol eH aed wad ef. 098 CAiniBod® Brg Sgined ocd Ord Orage Ce roa ose adeko. (iv) exo 127 °C Eni Bgena BBY med w8 G00 oc cS Engel qoGa Bla exnasie. (1.6,4.8,0.8, 0.8/ 665 dm*/ 0.16, 0.48, 0.28, 0.08/ 1.4 x 10°Nm™*) (12) Gem 40 Ox Bede guahss @OorHed! GaGa Qadoakn deb. dnb Org Boe O50 ea 84% oF CHyig) € 10% 8 CaHeiq) €, 3% 8 CoHary 2) 3% B Nr ¢ 085. 02 GO Ogons BBO 2 x 105Nm-? 6 Exacta 300K 8. () Oxg enboeed f Oct bk ExgeD qaoGia BBD eins ade, —— 2 — Scanned with CamScannereect BORD 01g x02 —_——— (i) Brotvedd ge chose omeOine? (i) 29 Setved manida mowing? (1.68 x 105Nm=?, 0.2 x 105Nm™?, 0.06 x 105Nm~2, 0.06 x 10°Nm~2/16.6 gmol~11.46 gmol-1) (13) *5Cl exo *7Cl amg chegiSes @ domBn ODE wOekDBo 8. Clg O89 *Cl*"Chg "Clg & BOmBo gEBarOs Oo oBa eee BES6Es 70, 20 ox 10 8. Bead a6 300K © SOBs teoiSe Og COO 100 oF quo. 088 moO aded Orn qe 0OGe Ege wmdOo 2.36gdm™ eB. cre eogtosd cr odoma mdeten, (35Cl = 35,37Cl = 37) Gi) Bgess 0589 Gi) 77Clacg) BoB BOHD {(1)3000dm?, (11)8.314 x 103Nm™7)} (2004) (14) 2dm? o5 8 encioasd mE 300K & B, O20 ax god OG BOaa 3 x 10°Nm"? e8. C&O emSHa sch 568 nH seaéis e808 exdn exp dGenad o8Os0 nd oxiGed CBexdDo 400K CoD gE BOD C8. Ang + 3B —> 2ABa(q) 088 BEndHa0 gad Hg ESp_hseas9 OBGa ef a8 400K & oeDGa ae GS Boao eoddens most. (16 x 105Nm-?) as) Q ex8c8 EnqeOss 0.1 mol oF C689 5.0 dm? Om Bend ge 27°C w CeéneiOad ceded 098. 100 kPa BAsad cOed 9 400K m CeéoiDacd no H, Eoa® 0.2g nf ©88 edna 60 ened mon Ef exog sxined cdma 0°C end Gf adm Ef. Q so H, cSgbsn cen wxBledn GD ¢, comdono mdse. & a6 exlo grabs oom asa G58 mide. (Hy gO qu@® B90 end mrdao a6 7B BOa0 Gi) Hy a0 qe@® m6 CSérciO0 0°C Eri af] ag 50 F exdac as wd oodd SOc. Gill) Hy gO axp® od CSEndOo 0°C eniO of) ne GO F exina ae QS eGo dao. (iv) extae 26 M8 Bg) 288D00 06 288d Bad ecghad mg 50 dao a6 Hz S 229 mao. (W) 0°C & exOo Bem a6 OH, Bage® gOd med a8 260 Q G qaGo BOs emoos 08 2B qectona add. (4.98 x 10*Nm™2, 9 x 10¢Nm-2, 4.5 x 10*Nm”, 0.2, 4.5 x 10*Nm"?) (16) (a) ©6800 8 x 10-4m? tmnetence 2.5 x 104 Pa BOaam€ 300K & H Eng Gog €6. S680 2 10-+m? exdaam 3 x 10' Pa BOaam & 300K & CH; = CH CH; Oog® axe. 089 Exgs gig trda cpm OBenn0 8AsO ada of Exge Sea gga enraco Bemed csendOo 300K e8. (Hz Onged moGa BOac emoeing ? Scanned with CamScanner x |Og ode anh re = ergo BOn0 diy om 8 x.10-tm? af Oe enctaracd 6 CH2 cH CHs ome eo Gi) Og Based comm Sons emcee oe {()2 x 108 Pa (i)0.6 x 108 Pa (il) 2 6m 800 G8GG00 (b) CH, = CH - CHygg + Hac CHa ~ CH, ~ CHa) 7 Og fp 06 £0 che. Bowed cdenon 200K 08 BqHT.AS dV9 NTR SeeOaDg o8o Bone 28m eba8 excels (exp G88 Eoge0 condoasd 08 odd aden & cophen OB comgons Odea, ab g endode 60 panddvad eat cvestona 50d Be oa006) : Ponyeci-cy = 14% 10"Pa Fi, =O ~ Parca = 0.6 x 10* Pa 2 (17) 008 7.764? Om cxbxo endioasd 6 a8 cio Oded oo CEred Bena God. 280K @ encom ge BODa 1.50% 105Nm™? Bo, 098 endae AE Sead gees 63 e680 oA OxSBEA8 ofacd Ged, 089 SustSE09 Do GS GdD 60 edibud cMghinecedd dmakind S:d8828 com cooaidnn Ba. 089 GAGaes OG 3275K € td 6 8Oe0 0.702 x 105Nm? Bo. () ©2c55208 om ErSBEA8 ScICHO 6 eOdO OOO emia xB e© axB coogosa ROE endian 96 En BGo9 Oe closida vas modi. Gi) sxdeoe gg cxegn GreSBE08 Gxi08H 6 daekd osnos moe. (He = 4,0 = 16,Mg = 24){(0.8g (i)248} (18) 8314dm? 6080 8m Beds cols Ogad ge Gece ao degKed a8 Og Sginad ©. 300K 8 toxtns ag BOma 15x 105Nm-? Ba. 088 Bea GEO 6 OOo QE Og 80 Orad ge Ba8O a me 868¢ emed ehoq 08.08 Cu aA) Sead Q8aSs ens CSéxiOamd oriad Hesiod Oct Send Go ada exe. Sarg Aco GOO cage 60 Cu oq Q NO Ogos COO omen exo sxé 08. shoei MgO emod ao cBqbirenst deraHaO coscrikns © Copper(Ii)chloride coe, @8© gEGare9e3 oy 320K 2 Oem a¢ baa 0.4 x 105Nm- Bo, @ 6G emrms Ora emo on» crowy coeciined COO emagm 68a moda 6 8 Ne Og dado etooe odain, (i) x80 6 exec! Copper (li) chloride Baek edna moa. (Cu = 63:5,Ne = 20,Cl = 35.5){()25g, (15043755) (19) ©5800 V Ox sndoacd a6 1.1347 x 10°Nm™? ade 0°C & Oxides Ea 3.20 Be. 089 saxon aBgbéneasl® ebOae ade EF i COMO V Oa BOs mand a8) odo GR gedog mdm ego 17°C O dos md S ofA BOna 100atm Oacad 28 CaSO X or8r8 OOD ara ado Ef. 08 Oxi ofan f X G daeida 3.00g Oa. 0B Scanned with CamScannerpends BOD Og oe ——— ee ad cde €, OdAda om X Coad Og oem exBadetont . 08, X 6 cnodda amo (0 = 16)(44.12gmol"*) eugr HIIDOE COBO CHNadoo HOM eOedd emOn O89 aw X om Odddles qOd 9pBGmOd BeomOs G6 Comgona miatn. (20) (a) (i) HOmBecd Ga8a Faskn. 088 GaGa eaka wxalond gon mamded o€DGa00 ¢? Gi) PV = 1/3MNC? a a8admensd (dBm md qrOeiHod) Baba Oxdosia moi. (©) Ao» B a BGO ndOod OHH OOO md qn. nosed & mda Oop quo. AG OxgWa N, COS ¢ BE Og8a OBS cOmd qaiatons. Jd Og coo Go eOsee5 extn maisld aden8 608. Bos 8 eae xg V=100m? v= 50m? P=1x10°Nm? P=2x10°Nm? caldera = 127° eseectos = 27°C 80 BOxD BOeOe, BED eceaS goog OxgHe0 OHienn se Acmd ees © nBgbe o@o ¢ Bg 560 gHeca Gre. ed BOe ocd 5 G2 oD 28 asiaboo OraOe Cede. emeOado 88 qdSma yosGO Odd og exe. aBOdd on 28s Bog cOabin Hig een erBeda GOD¢ mowed CHO emmenn axda wh OO ¢ conden 268s ono aged ¢ SI EanOSs asa mdse. G) Md8edk B AG2LAS gag OB CN eoBO Gi) mdBeedz A OgdeaS Hog BOSS Oa OHO coBO Gil) G2 ecenGO mB 92 Hg Ge (iv) B AG220S eB Org Sqived 2 Oxge8 coGo SH00 {(.400.9mol (ii)300.7mol (\ii)701.6mol (iv)1.4 x 10SNm-? (v)8 x 104Nm™*} (2000) X ax6e8 Oogeds 10132 x 10'Nm"? COE 5.01 OD wxdmadd me CNsocdOo 27°C cediod 06 Gof. 1.0132 x 10°Nm"? Boe adecs eo 127°C cedinatOa gO Hy OD 0.2g 089 endo qed aupeds dn @&. exiog exdoed CSMdIHD 0°C EE a8 BOD EE X oo H, dmalin® GSGm omni cand GBGa emda 2 ¢ X ao Hy Babi Og ego exBada @O ¢ CoBdonS md8e EOD ORES J exo adao. @=) (D Hy ©2g© qugd 8690 ed exdno ME GB ODE 6089 GH, Og ened 06, CEB 0°C Ene @BOd qe GOdDOE mndao ae a6 28d0 Bona, (21) Scanned with CamScannerOng @xoe as CDM, Ergb exmed we ewan 0% e300 OO 7H EARNER eHEIDS IB eB XG 000 moo iy exon 90 ne Bag Bonn néBDOD wo Hed Gna ecawNaE BC BO EIIOD ag 6B X 8 QQ S900 22) (i) eBigdatesd oa Bim B80 Eos. CPV = 1/2mNC? om eBadireasd pb 99 exe Bb Eaton aOs>, (ija® 268 So darcy aca con! eardiio ax O68 8 GAD BCE 05H ea a0 28050 G6 Gol, edBoadt 08 ano ocn® 27°C cxtndioed Sebo ead sxxla eo 9¢ WAH BAe 0.70 b Gal, 20 oad aders ogee CES x 10'Na ? 08, qciog® 088 voxia eceard bod clinton 127°C eB o& ood encoce Gedo 0d rene 27°C 8 Cede 08, exdaa 96 a6 HBOS Ege! gma Blac as 235 Od dendg® a6 8 wBEUE ODe com oma mod. (= 57x 10'Pa,127°C Om ge =03mol —-27°C BED aE = O4Mol) Q3) Sdas Gos COHOd qn sndaad 96 H; 90 2 He O290 Gio. O°C E08 encina 6 BODa 0.89 x 105Nm-? Ba. 08 wade EO CHy (methane)0.03 mol 3 qaed a6, (Benda 380K Om ead sadam do ade of 060 enckna ME BOSE 165 x 10!Nm? 38 qang Gass, 089 elcdairs peSwede sxdso a6 H, 6 ano BOaa He ob ecminadd 48 08, cOaiesna gominede edna 96 He OOo mac amas mdsia. 688 ton8d GOscd & Eaqa® oSegdén gga sxBede 20 ¢, sidered C580 ead emda 29 ¢ coadoaa mésin. (A) Bena gBGm eaxnde Ar to Ne Org Egos 100g oS GOGO 66.512dm? Bm oD Bend ge 27°C ceénedOed 15 x 105Nm-? Bmax ced HOci 08. 28 Og Sgsved 200g cf geom tmdnad aoq® m6 celdnciBe -73°C ob Ox ex Ore BAG ade @& 260 Bona 3 x 105Nm™? @8, e89 Og Bgéood, (@ Aro» Ne @80 gamac * Gi) Ar eo Ne das eaenae (27°C & eo -73°C & Ar Oxge® enoSn BOnad osuna mdaio, (ivjOreo aro Oe oBadina 9 Cosbin Hg aBadia mated Og emo ODD ren odide ox o8adead Qgdosta mdako. (v) 08 Ogdiosts me eBadéne qugisd 27°C & Ne gino Osan Oooo acGa adac waeden.(Ar = 40, Ne = 20)(1;3/ 2.3/0.375 x 105Nm™2, 0.75 x 105Nm-2, 9.32 x 10-2) Scanned with CamScannerBix Beko 03g 0 poe ret ne (25) 300K caltoaBOed @ a CeléocdOnse 1.0 x 105Pa BOnam & V Om gO etna OC ned 3.2g Oe Oxide ag enBoead 688, 0680 V On aBgbdend® oOo ate 6¢ BEd GD exiaad 080 mnciand HEBD od ext ecm ge Ox orBdE8O of 100 Gx08. GEGED OBOaKo Oddo CdéniOs 400K ood mob axel). gefow, 20 CBeodOode © BHa 2.0 x 105Pa end ging aBem ade X Oogl a@acida minded 20g mdg Exe. 08 agi GOas Oo X Oxged danke 88g 08, X 6 medde C60 dinsio omona mddio, «89 Eg ecm Sophie em cxBiedn OO ax OO SGeaa cm’ 8Ga emade BD condos adel, (0 = 16)(44gmol™) cow) (26) (2) () @ Pv.= MRT Bog oBadws SSeS qeOanBedt Bada Ogcoakn adele. ) 27°C B 0, Og mBogan Oo Shaane gona (Tz) ext goes omoere ndeio. 08S gang dana omGE qiBe aqo. 088 oxnoede OO Bento oF Como © Medd ¢? (0 = 16) Gi) BG cxda OE GD EDD 300K NHyg) Gt NHS Goq Od quo. 860 280 mine ge BHD 05x 105Pa Oa. 088 Ben 1200K O cdiaefO Oras 80d Beacon oD. 2NH3@q) ——> Naw + 3H) Naa) ——> Nr@ + 2H anges eSgbénoass Beckton Q og 1200K & Aza ag BHaa 45x 105Pa Bo. piBoo Bgived qfoq Og gedisas NzHy gro SGisoad ge ends. (25%) (8) 200°CO eee Ede OEE XO, 68 K70s GD Orget eSeBmeass9 X,03 60 O2 xa 990 Bead 08. 27°C 8 860 axfan, 068) Bes Oras ge 1.08 x 10°Nm™ Boma aOexd 0880 X0, 00 X;05 Org Garkacd 227°C eck colade of e8SE e681 20% Ga OQ grsd BAe 2.375 x 10°Nm"? 2D ecxad. (9 XO, 9 X05 @ Becida 9BGa» Ex eno. (i) edbom Og Sedred XO, 80 X05 Pod CE ENE omars aoe. Gi) XO, 9 X,05 B pon BOs exrasio. (iv) q@am Sge008 X20, 01 07 6 endin BOD osroo ada (1:2,3.6 x 105Pa, 7.2 x 10*Pa, 1.25 x 105Pa, 1.25 x 10*Pa) 01) e860 4.157dm? Q GO Ogos GE CH, 9 CoH, om Enge® Besnard aro. ee 960 02 Sngebed 0.1mol axq® 96 exlndiBa 127°C BOO od BD Of, e880 Oem IE FPS 1.04 x 105Nm-? 80. Bead g8and OB 086 cséncdoo Oe) me 50 CH, CzHe eee 7 Scanned with CamScannerOa exe Btocin BOako WBpbireas9 cms Q Gd C 105Nm-? gee» Ba. O¢90 axep® 98 02 e9e weed 08 ¢ Eea8S, eee Hy 090 fre conc. A oe GH, ae e ae gona -900k}mol™* es —2200Kimol-* og 4 9 CHe ; 18 ct cxida coed 098 cosa Sraed a8 GOD HP ON ON (ii) 08 6g 8—@w000 mxefded ear Org BgHrAO ACIES MOCO Br conde. (0.01 mol 0.02 mol, $3 kl, 0.25 x 10"%gem™*) aarton 1470 ene O08 Ba. e090 SO0a ¢ 126 x ido coma0 O69 Oo GiB ¢ Orges SOehen (28) (@.X 88 &gQoo SOG casio 46g mol”! eB. 127°C cesbocsOod®, 000 4.157 x 105Nm-? tm Bdeed & 088 Oxge8 maaioa exces. (5.75 kgm™*) (ip Schoen B05 06H exdam 27°C B Ar ODO SHO 1 oF ee Br Org OBE 45 geo, txdined Scio 8X00 3 x 105Pa 08. 100°C © 0G ene Caso 8@8 A, om B, exgd 2000 GGGad 968, goo 6498 127°C 0 doime 80 aocln BOaa 32x 105Pa ex By 6 eGo BOsa 1.6 x 105Pa Ba, ae OBO oredy ODO Cea ¢ Sages 8. (@ cxagn 890 AB, eg e0@ aoE NED Bods Bask. (0) X 6 goo wsnaa mdain. (©) AB, 8 Bo BBna osrna 06, comes eniOaie. (2, 1.6 x 10°Pa) 29) Gxo@Bd Bocce (Mn0,) Cdedio eee GLBE0 KCI0, oo BOe8s5 ¢ Somanced & 0, EgO eg om wo. s00) eB KCIO, nBoead od B08 & BOmc 94x 10*Nm™? ex 27°C & dead cAnt: Edthonead éaq adesd 0, xg c6&) 415.70cm? 8a. ©8® 0, Oxg0 127°C BE, 16x 10°Pa BOs ades OG H,S go 8314cm? qe Sead Qed cde e€. (e089 ceéodOece H,S sm 0, eGGan mde aod BGO Gamdto emOs a8c5 agasis.) exiog® Or ge Oxqss 2moldm~* NaOH @Oha0 SOcm? REs ado @& gdog |OKa 16moldm-? HC] Osad oS gatonc ade 6 eszig- 27°C & co@dd Se Ordo Baa 4 x 10°Nm™ (K = 39, Cl = 35.5,0 = 16) go ood G6e8 & C66 clad emda 89 comdsma ndala. gum aged edo erBoecss, @) Bc Bad0 eG oem aoe Go oad Eaxte. (il) Bend 2 0, 082 BoBmO save moan, (ii) eo8em Q KCIO, ena emno8eo ¢? 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(3) 250 cm* (4) 255 cm? (6) 266 cm? (2000) (36) KCI0,12.25g Q8smaxs MnO, Exfedloa qx680 ano Deakioacss ered 0, 6680 0°C E 0 1.0 x 105Nm7? O68 masin Oseasd (K = 39,Cl = 35.5,0 = 16) Q) 4.8 dm? (2) 3.4 dm? (3) 2.0 dm? (@) 5.1 dm? (8) 6.3 dm? G1) 2800 cséndo Bdaed & SoG 1120ml Base 4680 goss © Gob. danke costa rgb ee exBed 08 08 orm mrgBa8 mH eanodso GOss eb? 64g (2) 546g (3) 8.28 @) 288 6) 168 (38) Céxd80 27°C m BHac latm ded 1dm) Oa eguoBs (e886 BOGS) oSsdoacs clnbenecss gone A680 qOes Oo Sciees Og C680, CXoKibe 327°C ao SOac 4atm odes & eave eB? (1 dm? (2) 1.09 dm (3) 2 dm? (4) 5 dm? (5) 8 dm? SS Scanned with CamScannerBtodtn Bost Og oxo G9) So gbe» Oa weBSS Congona Hd8e 298 cumnOD on BOoed & ono OC Heo Org80 COred Goo daxddan s6H0 Esxo8 goo ores ¢? (H=1,C=12,0= 16,F = 19,8 = 32) W) Seeded CoHy (2) @ciGce3 02 (8) Sqedsees F, (4) OB Ode5 egoSH HS (6) Becks CH, (2008) 40) madBa OxQOm wrBOO eoigdién Og weB580 OOnde main Oged com axrosd (y8o OXO Oded ¢? 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