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YAKEEN 2.0 2023

Complete Organic Chemistry Practice Sheet

1. Arrange the molecules with decreasing order of 4. Arrange the molecules with decreasing order of
acidity? acidity?

(1) 1>3>4>2
(1) 1>3>4>2
(2) 3>2>4>1
(2) 3>2>4>1
(3) 1>3>2>4
(3) 1>3>2>4
(4) 1>4>3>2
(4) 1>4>3>2

5. Arrange the molecules with decreasing order of

2. Arrange the molecules with decreasing order of acidity?
acidity?

(1) 1>3>4>2
(2) 3>2>4>1
(3) 1>3>2>4 (1) 1>2>3>4
(4) 1>4>3>2 (2) 3>1>2>4
(3) 4>1>2>3
3. Arrange the molecules with decreasing order of (4) 4>3>2>1
acidity?
6. The correct order of the stability of carbocation is

(1) P>R>Q>S
(1) 1 > 3 > 4 > 2 (2) 3 > 2 > 4 > 1 (2) S>R>Q>P
(3) 1 > 3 > 2 > 4 (4) 1 > 4 > 3 > 2 (3) S>P>R>Q
(4) S>R>P>Q
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7. Arrange the molecules with decreasing order of 10. Arrange the molecules with decreasing order of
acidity reactivity towards nucleophile?

(1) 2 > 3 > 4 > 1 (2) 2 > 3 > 1 > 4

(3) 3 > 1 > 2 > 4 (4) 4 > 3 > 1 > 2

(1) 1>2>3>4 11. Arrange the molecules with decreasing order of

(2) 3>1>2>4 reactivity toward's nucleophile?
(3) 3>2>1>4
(4) 4>2>1>3

8. The correct order of the reactivity of alkene

towards electrophile

(1) 2 > 3 > 4 > 1 (2) 3 > 1 > 2 > 4

(3) 3 > 2 > 1 > 4 (4) 4 > 3 > 1 > 2

12. Which of the following carbanion is most stable?

(1) (2)
(1) S>R>P>Q
(2) S>P>R>Q
(3) R>S>Q>P (3) (4)
(4) S>R>Q>P

9. The increasing order of reactivity of the following 13. Arrange the stability of following?
compounds towards HNO3/H2SO4 is:

(1) I < II < III (2) II < I < III

(3) I < III < II (4) II < III < I

14. Arrange the decreasing order of the following

cation?

(1) II < I < III < IV

(2) I < II < IV < III
(3) II < I < IV < III (1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1
(4) I < II < III < IV (3) 3 > 4 > 1 > 2 (4) 2 > 1 > 3 > 4
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15. Which is the most stable resonating structure? 20. Arrange the decreasing order of the following
Anion?
(1) (2)

(3) (4)
(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1
(3) 3 > 4 > 2 > 1 (4) 2 > 1 > 3 > 4
16. The correct order of basicity in following
compounds is 21. Basicity order

(1) III > I > II (2) III > II > I

(3) I > III > II > (4) I > II > III
(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 1 > 4
17. Arrange the decreasing order of the following
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
carbocation?

22. Acidity order

(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1

(3) 3 > 4 > 1 > 2 (4) 2 > 1 > 3 > 4 (1) 2 > 1 > 3 > 4 (2) 2 > 3 > 1 > 4
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
18. Acidity order?
23. Arrange the decreasing order of the following
Anion?

(1) 1 > 2 > 3 > 4 (2) 4 > 1 > 3 > 2

(3) 4 > 2 > 1 > 3 (4) 4 > 3 > 2 > 1
(1) 1>2>3>4
19. Basicity order (2) 2>3>4>1
(3) 3>4>2>1
(4) 3>4>1>2

24. Which one of the following groups shows

maximum –I effect?
(1) NH3+
(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 1 > 4
(2) NH2Me+
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
(3) NHMe2+
(4) NMe3+
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25. In which of the following molecule, the resonance 30. Arrange the following electrophiles in the
effect is not present? decreasing order of the electrophilicity?

(1) (2)

(3) (4) (1) 3>1>2

(2) 2>3>1
26. Which of the following order is not the correct (3) 3>2>1
order regarding –I effect of the substituents? (4) 1>2>3
(1) –I < –Cl < –Br < –F
(2) –NR < –O⁺R2 31. Find out the most acidic and basic pair from 1 & 2
(3) –NR < –OR < –F and 3 & 4 respectively
(4) –SR < –OR < –O⁺R2

27. Increasing order of basicity of the following (1)

molecules is,

(2)

(1) I < II < III < IV

(2) II < III < IV < I
(3)
(3) II < I < III < IV
(4) II < I < IV < III

28. Which of the following is the strongest base water? (4)

(1) (2)
32. Circle represents most acidic hydrogen in this
molecule. Which of the following is correct
(3) (4) representation?

(1)
29. Which Hydrogen is the most acidic?

(2)

(1) (I)
(2) (II) (3)
(3) (III)
(4) (IV)
(4) All of these
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33. Find out the most acidic compound? 37. What is the decreasing order of strength of the bases?
OH–, NH2–, H–C≡C– and CH3–CH2–
(1) (2) (1) CH3–CH2– > NH2– > H–C≡C– > OH–
(2) H–C≡C– > CH3–CH2– > NH2– > OH–
(3) OH– > NH2– > NH2– > H–C≡C– > CH3–CH2–
(3) (4) (4) NH2– > H–C≡C– > OH– > CH3–CH2–
38. The correct order of basicities of the following
compounds is
34. Among the following compounds, the most basic
compound is:

(1) (2)
(1) 2 > 1 > 3 > 4 (2) 1 > 3 > 2 > 4
(3) 3 > 1 > 2 > 4 (4) 1 > 2 > 3 > 4
(3) (4) 39. The product A will be

35. Identify most acidic hydrogen in given compound

(1) a (2) b (1)

(3) c (4) d

36. In sets a–d, only one of the set is incorrect

regarding basic strength select it:

(1) (2)

(2)

(3)
(3)

(4)
(4)
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40. The correct acidity order of the following is (3) I > III > IV > II (4) II > III > IV > I
45. The acidity in decreasing order of different acids
is
(1) formic acid > chloroacetic acid > acetic
acid > propanoic acid
(2) formic acid > propanoic acid > chloroacetic
(1) 3 > 4 > 2 > 1 (2) 4 > 3 > 1 > 2 acid > acetic acid
(3) 3 > 2 > 1 > 4 (4) 2 > 3 > 4 > 1 (3) chloroacetic acid > acetic acid > formic
acid > propanoic acid
41. Arrange the following compounds in the order of (4) chloroacetic acid > formic acid > acetic
decreasing acidity acid > propanoic acid

46. Rank the following alcohols in order of increasing

acidity.

(1) 2 > 4 > 1 > 3 (2) 1 > 2 > 3 > 4

(3) 3 > 1 > 2 > 4 (4) 4 > 3 > 1 > 2

42. Arrange the following in the decreasing order of (1) 1 < 2 < 3 < 4 (2) 1 < 2 < 4 < 3
acidity of acidity of the hydrogen indicated in (3) 1 < 3 < 4 < 2 (4) 4 < 1 < 3 < 2
italic
1. CH3COCH3 47. Which of the following has the most stable
2. CH3COCH2COCH3 conjugate acid?
3. CH3OOCCH2COOCH3 (1) (CH3)2NH (2) (CH3)3N
4. CH3COCH2NO2 (3) C6H5NH2 (4) C6H5NHCH3
(1) (ii) > (iii) > (i) > (iv)
(2) (iv) > (ii) > (iii) > (i) 48. The acidity of the protons H in each of the
(3) (iv) > (iii) > (ii) > (i) following is
(4) (ii) > (iv) > (iii) > (i)

43. The correct order of the Ka values for the

conjugate acid’s compounds given below is

(1) i > ii > iii (2) iii > ii > I

(3) i > iii > ii (4) iii > i > ii
(1) 2 > 3 > 1 > 4 (2) 4 > 2 > 3 > 1
(3) 3 > 2 > 4 > 1 (4) 3 > 4 > 2 > 1 49. Arrange the given carbon acids in the increasing
order of acidic strength.
44. Arrange the following in decreasing order of their
acidity?

(1) A < B < D < C

(2) D < C < B < A
(1) I > II > III > IV (2) IV > III > II > I
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(3) C < B < D < A (1) 4 > 2 > 1 > 3 (2) 2 > 1 > 4 > 3
(4) C < A < B < D (3) 2 > 1 > 3 > 4 (4) 1 > 2 > 4 > 3
50. Which among the following carbocations is most 55. Which one of the following anions is most stable
stable? due to the delocalization?

(1) (2)

(1) (2)

(3) (4)

51. Consider the following compounds: (3) (4)

56. Which one of the following anions is most stable

due to the delocalization?

Arrange these compounds in decreasing order of

their basicity:
(1) (2)
(1) 1 > 2 > 3 > 4 (2) 4 > 1 > 3 > 2
(3) 2 > 3 > 4 > 1 (4) 1 > 3 > 2 > 4

52. Which one of the nitrogen containing compounds

is an electrophile? (3) (4)
(1) NH2–NH2 (2) NH2–OH
(3) NF3 (4) NH3

53. In which of the following molecules all the effects

57. Which one of the following ion is not an ambient
namely inductive, mesomeric and hyper-
nucleophile?
conjugation operate
(1) Cyanide ion (2) Ethoxide ion
(1) (2) (3) Nitrite ion (4) Enolate anion

58. Which of the following interaction responsible for

(3) (4) stability of the following carbocation

(1) π to P interaction (2) σ to π interaction

54. Arrange the given compounds in decreasing order
of basicity: Select the correct answer from the (3) π to π interaction (4) σ to P interaction
codes given below:
59. The correct order of decreasing basic strengths of
x, y and z is
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(1) x > y > z (2) x > z > y (3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
(3) y > x > z (4) y > z > x
60. The correct order for the stability among the 64. Acidity order
following compound is:

(1) II > III > IV > I (2) IV > II > III > I
(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1
(3) II > IV > III > I (4) IV > III > II > I
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1

61. The correct order for the stability among the

65. Acidity order
following compound is without rearranging the
carbocation:

(1) 1 > 2 > 3 > 4 (2) 2 > 1 > 3 > 4

(1) I > II > III > IV (2) I > II > IV > I
(3) 2 > 3 > 1 > 4 (4) 4 > 3 > 2 > 1
(3) IV > III > II > I (4) IV > III > I > II
66. Acidity order
62. Acidity order

(1) 1 > 2 > 3 > 4 (2) 2 > 1 > 3 > 4

(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
67. Basicity order
63. Acidity order

(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1 (1) 1 > 2 > 3 > 4 (2) 2 > 1 > 3 > 4
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(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 1 > 2 (4) 4 > 3 > 2 > 1

68. Basicity order 72. Basicity order

(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1 (1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1 (3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1

69. Basicity order 73. Which is/are correct statements?

(a) I is less basic than II (b) II is more basic than I

and III (c) III is more basic than II (d) II is more
basic than III
(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1
(1) a, b and c
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
(2) a, b, c and d
(3) a, b and d
70. Basicity order
(4) only b

74. The most electron rich alkene is

(1)
(2)
(3)
(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1 (4)
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
75. Basicity order
71. Acidity order

(1) 1 > 2 > 3 > 4

(1) 1 > 2 > 3 > 4
(2) 2 > 3 > 4 > 1
(2) 4 > 3 > 2 > 1
(3) 2 > 4 > 3 > 1
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(3) 2 > 4 > 3 > 1 (3) III > I > II > IV (4) IV > III > II > I
(4) 2 > 3 > 4 > 1
76. Acidity order 81. Choose the correct statement regarding the
relative stabilities of the enolates I and II?

(1) I is less stable than II

(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1
(2) II is less stable than I
(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
(3) I and II have same stability
77. Basicity order (4) No comparison of stability can be mad

82. The correct orientation of dipoles in pyrrole and

pyridine is

(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1 (1)

(3) 1 > 2 > 4 > 3 (4) 4 > 3 > 2 > 1
(2)
78. Basicity order

(3)

(4)
(1) 3 > 1 > 2 > 4 (2) 2 > 3 > 4 > 1
(3) 1 > 2 > 4 > 3 (4) 4 > 3 > 2 > 1
83. Basicity order
79. Basicity order

(1) 3 > 1 > 2 > 4 (2) 2 > 3 > 4 > 1 (1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1
(3) 1 > 2 > 4 > 3 (4) 4 > 3 > 2 > 1
(3) 2 > 4 > 3 > 1 (4) 4 > 2 > 3 > 1
80. The correct order of alkene towards reactivity of
electrophile 84. The most stable carbocation is

(1) (2)

(1) III > II > I > IV (2) III > IV > I > II
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(3) (4)

85. Effect present in the molecule

(1) + mesomeric (2) – mesomeric
(3) - Inductive (4) + Inductive

91. Acidity order

(1) + mesomeric (2) – mesomeric
(3) - Inductive (4) + Inductive

86. Effect present in the molecule

(1) 1 > 4 > 2 > 3 (2) 2 > 3 > 4 > 1

(1) + mesomeric (2) – mesomeric (3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
(3) - Inductive (4) + Inductive
92. PKa order
87. Effect present in the molecule

(1) + mesomeric (2) – mesomeric

(3) - Inductive (4) + Inductive (1) 4 > 1 > 2 > 3 (2) 3 > 2 > 4 > 1
(3) 1 > 2 > 4 > 3 (4) 4 > 3 > 2 > 1
88. Effect present in the molecule
93. Acidity order of protons

(1) + mesomeric (2) – mesomeric

(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 4 > 1
(3) - Inductive (4) + Inductive
(3) 2 > 4 > 3 > 1 (4) 3 > 2 > 4 > 1

89. Effect present in the molecule

94. Basicity order of protons

(1) + mesomeric (2) – mesomeric (1) 1 > 4 > 2 > 3 (2) 2 > 3 > 4 > 1
(3) - Inductive (4) + Inductive (3) 2 > 4 > 3 > 1 (4) 3 > 2 > 1 > 4

90. Effect present in the molecule 95. The most stable resonating structure for the
following
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(1) I > III > IV > II (2) III > IV > I > II
(3) III > I > IV > II (4) I > IV > II > III
(1) (2)

99. What is the increasing order of stability of

following carbocations?
(3) (4) (I) Tropyliumcation (II) CH2=CH–CH+
(III) (C6H5)2C+ (IV) CH3+
96. Acidity order (1) III < I < II < IV (2) IV < II < III < I
(3) I < III < II < IV (4) IV < III < II < I

100. Among the following compounds in the increasing

order of the acidity of circled hydrogens

(1) 2 > 1 > 3 > 4 (2) 2 > 3 > 4 > 1

(3) 2 > 4 > 3 > 1 (4) 4 > 3 > 2 > 1
(1) III < II < I (2) II < I < III
97. Effect present in the molecule (3) I < II < III (4) II < III < I

101. Effect presents in the molecule

(1) +I Effect (2) + M Effect

(3) -M Effect (4) –I Effect

98. List the following compounds in order of

decreasing acidity: (1) -I Effect (2) + M Effect
(3) Steric Effect (4) No one above
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Answer Key
1. (3) 27. (1) 53. (2) 79. (1)
2. (1) 28. (2) 54. (2) 80. (3)
3. (2) 29. (1) 55. (2) 81. (2)
4. (4) 30. (1) 56. (4) 82. (1)
5. (2) 31. (1&4) 57. (2) 83. (4)
6. (4) 32. (4) 58. (4) 84. (1)
7. (4) 33. (1) 59. (2) 85. (2)
8. (4) 34. (3) 60. (3) 86. (2)
9. (1) 35. (1) 61. (1) 87. (1)
10. (2) 36. (3) 62. (1) 88. (1)
11. (2) 37. (1) 63. (1) 89. (2)
12. (4) 38. (2) 64. (1) 90. (4)
13. (3) 39. (1) 65. (3) 91. (1)
14. (4) 40. (1) 66. (2) 92. (2)
15. (2) 41. (3) 67. (4) 93. (4)
16. (3) 42. (2) 68. (4) 94. (1)
17. (1) 43. (3) 69. (4) 95. (2)
18. (3) 44. (1) 70. (4) 96. (1)
19. (3) 45. (4) 71. (4) 97. (4)
20. (3) 46. (2) 72. (1) 98. (3)
21. (3) 47. (2) 73. (3) 99. (2)
22. (1) 48. (2) 74. (3) 100. (3)
23. (4) 49. (4) 75. (2) 101. (3)
24. (4) 50. (1) 76. (1)
25. (2) 51. (2) 77. (3)
26. (1) 52. (2) 78. (1)

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