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Energy Conversion and Management 243 (2021) 114431

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Energy Conversion and Management


journal homepage: www.elsevier.com/locate/enconman

Experimental and simulation study of multichannel air gap membrane


distillation process with two types of solar collectors
A. Marni Sandid a, M. Bassyouni b, c, Driss Nehari a, Y. Elhenawy d, *
a
Smart Structures Laboratory, University Ain Temouchent Belhadj Bouchaib, 46000 Ain-Temouchent, Algeria
b
Department of Chemical Engineering, Faculty of Engineering, Port Said University, Port Said, 42526, Egypt
c
University of Science and Technology, Materials Science Program, Zewail City of Science and Technology, October Gardens, 6th of October, Giza 12578, Egypt
d
Department of Mechanical Power Engineering, Faculty of Engineering, Port Said University, Port Said, 42526, Egypt

A R T I C L E I N F O A B S T R A C T

Keywords: Solar thermal energy for membrane distillation desalination is a green and safe way for areas where water
Air gap membrane distillation scarcity and solar irradiance are strongly correlated. In this paper, a commercial-scale of desalination plant was
Solar energy installed and tested to study the performance of a multichannel spiral-wound air gap membrane distillation
Solar collectors
module with an area of 14.4 m2. Air gap membrane distillation desalination plant at Port Said university was
Pilot scale analysis
Simulation
powered by solar energy using flat plate and evacuated tube collectors. The model validation was carried out.
Desalination The solar desalination systems were numerically simulated using the program TRNSYS under different weather
conditions throughout the year. The influence of the main operating parameters (feed flow rate and inlet tem­
peratures of evaporator and condenser) was investigated. Regression analysis agreed with experimental data
fitting using a quadratic polynomial model with coefficients of determination (R2) values of 0.997, 0.972, and
0.999 for permeate flux, outlet feed temperature, and outlet coolant temperature, respectively. The results
showed that the permeate flux of the air gap membrane distillation with the evacuated tube collectors was
18.81%–30.44% higher than flat plate collector, and its cost was 22.48% lower. The specific thermal energy
consumption of the air gap membrane distillation system ranged from 158.83 kWh/m3 to 346.55 kWh/m3. The
maximum gain output ratio reaches 4.4 at 52 ◦ C, depending on the feed inlet temperature. The thermal efficiency
of the air gap membrane distillation system is 72%. The proposed air gap membrane distillation system produced
28.78 m3/year of fresh drinking water at a cost of USD 14.73/m3 with remarkable reducing in carbon dioxide
emissions by 7,274.45 kg/year.

commercial MD modules coupled with a static solar collector field and


tested the MD systems [5]. The operating temperature of the MD process
1. Introduction is 50 ◦ C–80 ◦ C, which is the temperature at which solar collectors exhibit
high efficiency. In addition, such membranes withstand fouling and
Due to the rapid demand for high-quality water resources, more than scaling better than reverse osmosis membranes. Intermittent operation
one billion people worldwide cannot use drinking water that meets does not damage the membrane module, and no damage occurs if such
safety standards [1]. Solar thermal collectors can be used to run mem­ membranes dry out.
brane distillation (MD), as collectors exhibit high efficiency and good The Swedish company Scarab Development AB has built and pro­
performance at feed temperatures varying from 60 ◦ C to 90 ◦ C. Sample duced MD modules. Each module has a flat sheet air gap membrane
measurements for clear and cloudy days indicate a high productivity of distillation (AGMD) system with a membrane surface area of 2.8 m2. The
11.2 L/m2∙day for a total solar energy of 7.25 kWh/m2∙day [2]. maximum variation in distillate flux is around 7 L/m2h. The modules
The MD process in a previous study yielded a salt rejection per­ showed a maximum specific distillate flux of 6.5 L/h m2 (65 ◦ C as delta
centage of about 99.5%, process efficiency of approximately 90%, and T, 1 g/L salt solution as a feed), productivity decay of around 14% with
solar collector efficiency of about 50% [3]. Solar-powered MD system increasing salinity (from 1 g/L to 35 g/L). A linear flux increases with
that uses a parabolic solar concentrator with a capacity of 0.5–50 m3/ the delta T across the membrane, with only a slight dependence on the
day was developed [4]. Constructed pilot plant consists of three

* Corresponding author.
E-mail address: dr_yasser@eng.psu.edu.eg (Y. Elhenawy).

https://doi.org/10.1016/j.enconman.2021.114431
Received 2 January 2021; Accepted 15 June 2021
Available online 29 June 2021
0196-8904/© 2021 Elsevier Ltd. All rights reserved.
A. Marni Sandid et al. Energy Conversion and Management 243 (2021) 114431

Nomenclature Subscripts
aux Auxiliary
C Capacity rate, kJ / hr.K c Cold
Cp f Specific heat capacity of solar fluid, kJ/kg.hr d Depth
I Interest rate, % f Feed
J Permeate flow, kg / hr h Hot
m0 Solar fluid mass flow rate, kg / hr hr Hour
N Economic lifetime (year) Htr Heater
Qu Useful heat gain, kW in Inlet
Qe Thermal energy supply, kWh loss Losses
T Temperature, ◦ C max Maximum
T Water average temperature, K min Minimum
Tset Set temperature of heater internal thermostat, K out Outlet
t Time, hr p Permeate
UA Overall loss coefficient between the heater and its
Abbreviations
surroundings during operation, W/ K
AGMD Air-Gap Membrane Distillation
Ub Nominal voltage of the batteries,
CPC Parabolic compound collectors
V Flow rate, kg / hr
ETC Evacuated tube collectors
SFF Sinking Fund Factor
DCMD Direct Contact Membrane Distillation
STEC Specific thermal energy consumption (kWh/m3)
DMV Vacuum Membrane Distillation
Tcooling,out Condenser outlet temperature (◦ C)
FPC Flat Plate Collector
Tfeed,out Evaporator outlet temperature (◦ C)
GOR Gain output ratio
Tfeed,in Evaporator inlet temperature (◦ C)
LCOW levelized cost of water
tlife Economic lifespan
MD Membrane Distillation
Wp Annual running cost of the water pump ($/year)
PTFE Polytetrafluoroethylene
rc Running costs
PVDF Polyvinylidene fluoride
Greek symbols PE Polyethylene
ε Heat exchanger effectiveness SCMD Solar Combined Membrane Distillation
η Efficiency

hot-side absolute temperature. However, the specific fluxes and the in­ The use of solar energy in small- and medium-capacity thermal
fluence of salt concentration on performance and thermal efficiency are desalination systems with low maintenance requirements in terms of the
considerably worse than those from laboratory-scale experiments in the projected cost of water supply was studied [8]. The findings revealed
literature. Although the MD technology of Scarab AB is suitable for that the costs associated with the solar supply are highly dependent on
coupling with solar energy, its thermal efficiency and salt rejection are the actual utilization of thermal energy by the desalination system at
key factors to be improved to enable the application of this technology to different locations. Therefore, the system was simulated (and dimen­
seawater desalination. It was reported that a small device with a 7.2 m2 sioned) for a specific distillate production of 1 m3/day at operation
spiral-wound direct contact membrane distillation (DCMD) module and temperatures between 70 ◦ C and 95 ◦ C. The cost reduction of thermal
a 22.6 m2 flat plate solar thermal collector generates over 140 kg of energy storage (TES) highly depends on the cost of the system (EUR
distillates per day under real weather conditions [6]. This finding is 100/m3 used from a range of EUR 50/m3 to EUR 200/m3). However, for
comparable to a regular rate of distillate output of 19.7 kg/m2 of financial constrains presented (solar field costs of EUR 150/m3 and TES
membranes or 6.3 kg/m2 of solar thermal collectors. The overall thermal costs of EUR 100/m3) in Abu Dhabi (UAE), Almeria (SP), and Cairo
efficiency of the system varies from 0 (early morning and late afternoon) (EGY), the cost reduction of using TES is less significant. Laboratory
to about 0.5 (peak solar radiation). The results showed that DCMD experiments in remote areas of solar-powered stand-alone MD systems
operation under concurrent and countercurrent flow results in two were conducted [9]. In addition, the Fraunhofer Institute for Solar En­
distinctive profiles in water flux, temperature polarization effect, and ergy Systems designed a solar thermal MD system with a capacity range
thermal efficiency along the channel length. A modern solar thermal of 100–500 L/day and larger systems with a capacity up to 10 m3/day.
polygeneration (STP) system for the development of cooling, healthy Simulation computations were conducted for the system design and the
water, and hot domestic water for the United Arab Emirates (UAE) was development of an adapted control strategy for two different pilot
developed and evaluated [7]. Three separate solar collectors were plants. The design capacity for the Aqaba system was up to 1000 L/day
evaluated for STP performance: flat plate collectors (FPCs), evacuated in December, and that for the Gran Canaria system was up to 1600 L/day
tube collectors (ETCs), and parabolic compound collectors (CPCs). The in February. Long-term performance tests in different countries
device was designed and dynamically simulated using TRNSYS. Eco­ demonstrated that a durable operation is possible even with very low
nomic analyses were conducted for all three collector configurations maintenance.
with an inflation rate of 10% and reduction of 5%. The lowest payback To optimize flow by adjusting the flow rate, mean temperature, and
period was 6.75 years, and it was achieved by the STP with an ETC field initial salt concentrations, DCMD and response surface methodology
with a gross area of 216 m2. The STP system offers cumulative savings of (RSM) models were applied [10]. Model predictions on four different
USD 520,000. Economic and environmental benefits are provided by the membranes were evaluated in comparison with experimental results
steady system performance of the absorption chiller (35 kW), membrane obtained using the R2 coefficient of determination. The AGMD method
distiller (80 L/day), and heat recovery system (1.2 m3/h) throughout the used in desalination was developed and optimized [11]. Regression
year. In terms of global warming potential, 109 tons of carbon dioxide models were developed to estimate the output index and the basic
(CO2) emission will be avoided every year. performance index; these models consider energy use as a function of

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A. Marni Sandid et al. Energy Conversion and Management 243 (2021) 114431

different variables. For the performance index, the optimal solution was conducted under different weather conditions throughout the year.
a cooling inlet temperature of 13.9 ◦ C, a feed inlet temperature of 59 ◦ C, A closer look to the literature on AGMD system powered by solar
and a feed flow rate of 205 L/h. A maximum specific performance index energy, however, reveals a number of gaps and shortcomings. The main
of 188.703 kg/kWh was obtained experimentally under these AGMD contribution of current research are as follows:
operating conditions. This index value corresponds to a specific energy
consumption of 5.3 kWh/m3. - To optimize solar-powered AGMD systems and data validation.
Air gap membrane distillation module was evaluated to ascertain the - To evaluate the performance of MD module driven by solar energy
effect of process parameters on distillate flux and thermal efficiency and using the FPC and ETC heating source.
to achieve a distillate flow rate of 1.5–3 kg/h [12]. Factorial design was - To compare different solar energy systems integrating a multi­
conducted for the experiments. In addition, success metrics and response channel spiral-wound AGMD module. To our knowledge, no prior
surface regression (RSM) were used to develop an analytical regression studies have discussed the influence of several solar energy systems
model for the operational parameters of the AGMD framework. They on AGMD performance under different weather conditions.
were tested via variance analysis, and the RSM methodology model was - To develop a technique that covers a wide range of capacities (from
analyzed using ANOVA. 0.13 L/h to 18 L/h); thus, systems can be adapted to any particular
Regression analysis demonstrated compliance with the experimental demand.
knowledge fitted with a second-order polynomial model with coefficient - To evaluate the benefits of the system considering the different
of determination (R2) values of 0.996 and 0.941 for distillate flux and weather conditions, and the related energy markets.
specific performance ratio, respectively. For a desired distillate flux of - To develop a new solar-powered AGMD configuration for higher gain
15 kg/h.m2, the difference between the hot- and cold-side temperatures output ratio (GOR) and lower specific thermal energy consumption
of MD has to be between 40 ◦ C and 45 ◦ C, and the flow rate needs to be (STEC) comparing to conventional methods.
adjusted from 6 L/min to 7 L/min, depending on the season of operation.
In addition, the assessed in accordance with the software TRNSYS. The 2. Methods
dynamic transient device simulation (TRNSYS) method was reported to
model large cassette MD modules to assess the co-production perfor­ Description of AGMD desalination pilot plant including its capacity
mance of a novel solar AGMD system that was designed for the simul­ and units will be discussed in detail. Solar heating system including the
taneous delivery of pure water and hot water to urban households in the main specifications of FPCs and ETCs are demonstrated and discussed
UAE [13]. A solar combined membrane distillation (SCMD) system was showing the flow chart of the considered system. Changing year-round
experimentally tested for the simultaneous production 20 L/day of pure climate conditions including temperature and wind speed will be dis­
water and 250 L/day of hot water for a single household without any cussed in detail.
auxiliary heating device. Distillate productivity was decreased by only
6%, and there was a twofold increase in the domestic hot water in the
SCMD system. 2.1. Air gap membrane distillation system
Testing of commercial scale was performed to study the efficiency of
two multichannel spiral-wound AGMD systems for water desalination Air gap membrane distillation desalination pilot plant was designed,
[14]. The only difference between the two systems was the membrane commissioned, and installed in Port Said City, Egypt (31◦ 20ˊN 32◦ 22ˊE).
surface area (7.2 and 24 m2) and thus the channel length (from 1.5 m to A schematic diagram of the test model and the experimental setup is
5 m, respectively). The results showed that 3.72 m was the optimum shown in Fig. 1. Three main loops are built, namely, feed solution, heat,
channel length needed to simultaneously maximize productivity and and cooling source loops. The permeate is collected in the distillate tank.
thermal efficiency; it produced a permeate flux of 2.44 L/h⋅m2 and An Aquastill multi-envelope spiral wound AGMD membrane module is
specific thermal energy consumption (STEC) of 141.5 kWh/m3. How­ used (one AGMD module with an area of 14.4 m2 (Fig. 2). The main
ever, the optimum values of the three main operating parameters that specifications are given in Tables 1 and 2. In Fig. 2, there are two types of
maximize the flux heat efficiency (80 ◦ C evaporator inlet temperature, jackets. High-temperature water feed channels and the coolant chan­
20 ◦ C condenser inlet temperature, and 560.6 L/h feed flow rate) can nels. Both sides of the cooling channel function as a condenser tray,
decrease productivity. Experiments were conducted on full-scale MD while an air space with a spacer lies between each coolant and hot water
modules spiral-wound with a 5–14 m2 membrane area [15]. Flat plate feed channel; here, the distilled water is collected at the distillate level
collectors (FPCs) and a spiral-wound MD module were tested. All results and expelled from the module. The six membrane envelopes are spiral-
showed a strong influence of the feed flow rate on the module perfor­ wound into a cylindrical shape. The hot water feed and coolant flows are
mance due to the changing bulk temperature difference and hydrody­ countercurrent. The hot water is supplied from the middle of the module
namics. The distillate flux rate was in the range of 10 to 25 kg/h with a and leaves the device, whereas the coolant flow moves in the opposite
specific energy consumption of 130–207 kWh/m3. However, the distil­ direction. Salt concentration in the sea water is 35000 ppm. Saline feed
late output rate decreased with salt by approximately 1 kg/h of distillate water flows from a feed pump through a filter and then into a flat plate
per 10 g/kg of feed water salinity. Solar thermal-driven desalination heat exchanger. Then, it is divided into the AGMD modules using
plant was developed using FPCs and a spiral-wound MD module [16]. It management valve systems and flow meters. Pressure sensors are used to
was aimed to develop systems with a capacity ranging from 0.2 m3/day determine whether the feed water pressure is less than the maximum
to 20 m3/day. The simulation results showed that a simple compact allowable membrane pressure.
system with a collector area less than 6 m2 and without heat storage can
distill 120–160 L of water during a summer day in Freiburg, Germany.
Technical simplicity, long maintenance-free operation, and high-quality 2.2. Description of solar heating system
potable water output are important aims that will enable the successful
application of such systems. The pressurized water is heated by solar energy in the solar collector
The main objective of this work is to develop, analyze and optimize system. Then, it flows through six FPCs with total area 12 m2 (6 × 2 m2)
solar energy driven AGMD systems, thereby helping ensure the avail­ in the series arrangement, or through three ETCs with an area of 8 m2.
ability of distillate water using solar desalination. In this work, a com­ The main specifications of FPCs and ETCs are given in Tables 3 and 4,
plete test rig was installed in Port Said city, Egypt to evaluate the respectively. The water then passes through the heat exchangers to ex­
performance of MD module driven by solar energy using the FPC and change the heat between the solar system and the AGMD unit. A pump is
ETC heating source. Data using the TRNSYS program has been used to circulate the water in the system, as shown in Fig. 3.

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Fig. 1. The experimental pilot plant.

Table 1
Air gap membrane distillation module properties and specifications.
Material Polyethylene (PE)

Total net Membrane surface area 14.4 m2


Diameter 0.4 m
Height (width of envelope) 0.4 m
Length of envelope 3m
Thickness of flow channel 2 mm
Air gap thickness 1 mm
Porosity of membrane sheet 85%
Tortuosity of membrane sheet 1.56
Thermal conductivity of membrane sheet 1.35 W/m K
Thickness of membrane sheet 76 µm
Mean pore size diameter 0.3 µm
Packing density 115 m2/m3
No. of evaporator (hot feed) channels 6
No. of condenser (coolant) channels 6
No. of distillate channels 12

Fig. 2. Cross section of AGMD module.


Table 2
The spacer characteristics.
2.3. Weather data
Parameter Value
Fig. 4 shows the changing year-round climate conditions. In Port Channel thickness 2.01 mm
Said city, the weather is generally pleasant, warm, and moderate. It is Spacer filament thickness 1.005 mm
Spacer angle Φ (0–90) 60 deg
noted that there is a change in a temperature during the year, which
length filament 4.17 m
reaches 35.55 ◦ C in August. The wind speed is mild and does not exceed
9.13 m/s. The irradiation varies throughout the year and reaches
221.75 kWh/m2 in August, as shown in Fig. 4, when the temperature is 3. Simulation
high. The experiment is performed under Port Said City weather in June.
The simulation covers a whole year, and the results are for various days A solar combined membrane distillation (SCMD) system was exper­
in summer and winter (sunny and cloudy). imentally tested. Modeling of of air gap membrane distillation and solar
membrane distillation system were carried out.

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Table 3 Eq. (2) [19].


FPC specifications.
Q̇u = m0 Cpf (T0 − Ti ) (2)
Parameter Value
− 1
Area of absorber [m2] 2.10 m0 is the mass flow rate of the solar fluid (kg∙h ); Cpf is the specific
Area of aperture [m2] 2.16 heat capacity of the solar fluid (kJ∙h− 1); and T0 andTi are the inlet and
Dimensions (Length × width × thickness) [mm] 1892 × 1204 × 99 outlet temperatures, respectively, of the solar fluid (K).
Area of gross [m2] 2.28 The heat exchanger counter flow effectiveness is given by Eq. (3)
Max working pressure [bar] 10
Stagnation temperature [⁰C] 189
[17].
Thermal capacity [KJ/(m2K2)] 10,330 ( ( ))
Incidence angle [⁰] 50 1 − exp − CUA 1 − Cmin
Cmax
Instantaneous efficiency based on aperture area 0.713
min
ε= ( ) ( ( )) (3)
Peak power [Watt] 1540
1 − Cmax exp − Cmin 1 − CCmax
Cmin UA min

UA is the overall loss coefficient between the heater and its sur­
Table 4 roundings during operation (kg∙h− 1), Cmax is the maximum capacity rate
ETC specifications.
(kJ∙h− 1∙K), and Cmin is the minimum capacity rate (kJ∙h− 1∙K). The
Parameter value required heating rate including efficiency effects in the auxiliary heaters
Number of tubes 30 is given by Eq. (4) [17].
Collector dimensions (length, height) [mm] 2110 × 1960
Tube dimension (length, diameter) [mm] 1800 × 58 Qaux = Qloss + Qfluid
area of aperture [m2] 2.84
Area of solar absorption [m2] 2.44 where
Capacity of fluid in copper pipe [liter] 1.82 ( )
Max working pressure [bar] 6 Qloss = UA T − Tenv + (1 − ηhtr )Qmax and

3.1. Modeling of air gap membrane distillation module Qfluid = ṁ0 Cpf (Tset − Ti )

Qaux is the required heating rate (kg∙h− 1), including efficiency ef­
An AGMD model is run using the software Minitab and experimental fects; Qfluid is the rate of heat addition to the fluid stream (kg∙h− 1), and
data. The results from Minitab are subsequently used to create a Qloss is the rate of thermal losses from the heater to the environment
component in TRNSYS that behaves as an AGMD in a simplified and (kg∙h− 1). Qmax is the maximum heating rate of the heater (kg∙h− 1), ηhtr is
approximate manner. The experiment was installed at Port Said Uni­ the efficiency of the auxiliary heater, m0 is the outlet fluid mass flow rate
versity, Egypt. The experimental data shown in Table 5 are tested and (kg∙h− 1), and Cpf is the fluid specific heat (kJ∙h− 1).Ti is the fluid inlet
analyzed with Minitab, and a multiple regression model is obtained. The ( )
independent variables are the hot inlet temperature Thi, cold inlet temperature (K), T is the brackish water average temperature,Tset is the
temperature Tci, hot feed flow rate Vh (L/h), and cold feed flow rate Vc ⋅ set temperature of the heater internal thermostat (K), and Tenv is the
(L/h). The dependent variables are the permeate flow J (kg/h), hot temperature of the heater surroundings for loss calculation (K).
outlet temperature Tho, and cold outlet temperature Tco. Another part of the MD configuration is considered in evaluating the
The minimum and maximum values of the model are listed in thermal performance of an MD module, namely, the GOR, which relates
Table 6. the heat consumed to obtain a permeate flow to the thermal energy
The relationship between J and Thi is usually exponential [17], but it supplied to the outside. The GOR is given by Eq. (5) [19].
is mainly linear in the Thi range of 40 ◦ C–80 ◦ C of Thi, as seen in the GOR = mp × Hv/Qe, (5)where Hv is the heat of vaporization (J/kg)
literature [12]. The model created in Minitab fitted the data into a and mp is the permeate flow (kg/s).
quadratic equation with a general form. The regression quadratic model Hv is calculated as given in formula (6) [20].
with coded parameters can be expressed by Eq. (1) [18]. Hv = 2501.897149–2.407064037 × T + 0.001192217 × T2 −
0.000015863 × T3 (6)where T is the average temperature at the inlet of
J = α0 + α1 Thi + α2 Tci + α3 Vc + α4 Vh + α12 Thi Tci + α13 Thi Vc + α14 Thi Vh + α23 Tci Vc the evaporator and at the outlet of the condenser (◦ C).
(1) The thermal energy supplied is evaluated as given in Eq. (7) [1]
Qe = mf × Cp × (Tfeed,in – Tcooling,out), (7)where mf is the feed water
2 2 2 2
+ α24 Tci Vh + α34 Tci Vh + α34 Vh Vc + α11 Thi + α22 Tci + α33 VC + α44 Vh . flow rate (kg/h), Cp is the thermal capacity of the feed water (kWh/kg
α0 is the starting point for the orthogonal-type central composite

C), Tfeed,in is the evaporator inlet temperature (◦ C), and Tcooling,out is the
design with four variables. temperature at the condenser outlet (◦ C).
Minitab optimizes the equation to the best fit, removing terms that The main objective of MD operation is to provide a large amount of
do not help explain additional variations in the permeate flow J. The permeate stream with the bottom potential energy. The needed energy is
final regression equations for J,Tcout , and THout are determined in terms evaluated via the STEC (kWhm− 3), outlined because the external heat
of the actual operating parameters as follows. required to get the amount of permeate flow, expressed by the subse­
These relationships hold for the data range shown in Table 8. The R2 quent relationship between the energy efficiency magnitude relation Qe
is high and close to 1 in each case, and the p-value of each variable in the and the permeate flow (VP) as given in Eq. (8) [20].
model is statistically significant (lower than 0.05). In total, 99.74%, STEC = Qe/Vp (8)
97.16%, and 99.97% of the variations in J, THout, and Tcout, respectively, The efficiency of the MD system is estimated by Eq. (9) [16]. The
can be explained by the regression model. Therefore, the model can be overall temperature of the feed is used to calculate the heat of
explained more than 97.16% of the data, and the p-value is lower than 1. evaporation.
The results are listed in Table 8. η = mp × Hv/Qin, (9)Where the thermal energy supplied can be
The basic method for measuring collector efficiency is to expose the expressed by Eq. (10) [16].
active receiver to solar radiation and measure the inlet and outlet tem­ Qin = mf × Cp × (Tfeed,in – Tfeed,out) (10)where mf is the flow rate of
perature of the liquid and the liquid flow rate. The useful gain is given in the feed water (kg/h), Cp is the heat capacity of the feed water (kWh/kg

C), Tfeed,in is the inlet temperature of the evaporator (◦ C), and Tfeed,out is

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Fig. 3. Schematic of the solar system and the flow diagram.

the evaporator outlet temperature (◦ C). reading and processing meteorological data), type 91 heat exchangers,
With these equations, a TRNSYS program [19] is used to predict the type 1 FPCs, type 71 ETCs, type 2 differential temperature controller,
long-term performance of different solar water collector systems for the type 3 single speed pump, type 57 unit converter, and type 65 online
AGMD process. A complete test bench is constructed to evaluate the plotter, as shown in Figs. 5 and 6. The tables show the values of the
performance of the solar-powered MD module during the heating pro­ parameters employed in the TRNSYS models.
cess of the ETCs and FPCs. The test bench is in Port Said City, Egypt
(31◦ 20ˊN 32◦ 22ˊE); the city is near the northern coast of Egypt, 4. Results and discussion
bordering the Mediterranean.
Data validation of the solar-powered AGMD module was conducted
at the same operating conditions. The influence of ETCs and FPCs on
3.2. Modeling of solar membrane distillation system
thermal capacity and permeate flux in winter and summer were dis­
cussed in detail. The effect of water flow rate from 2 L/min to 10 L/min
The model of the solar thermal MD system is developed using
on gain output ratio and specific thermal energy consumption were
TRNSYS, which can be a quasi-stationary simulation program. The
investigated. The daily accumulated of solar intensity, freshwater pro­
components are represented as selectable preformats and inter­
ductivity and reduction of CO2 against the solar collector configurations
connected in any desired way to build the system model. An information
were presented and discussed. Comparison study was undertaken to
flow sheet is developed to facilitate the choice of system parts. The data
evaluate the current system and previous related works.
flow diagram for the models is shown in Table 7. The most component of
the model is the AGMD unit, which is represented by a new equation in
TRNSYS. Additional model components include TYPE109-TM2 (for

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A. Marni Sandid et al. Energy Conversion and Management 243 (2021) 114431

Fig. 4. (a) Ambient air temperature, wind speed and (b) Monthly irradiation.

Table 5
Permeate fluxes at different water feed flow rates and temperatures.
No. of exp. Tci (◦ C) Thi (◦ C) Vh L/h Vc L/h Tco (◦ C) Model Deviation% Tho (◦ C) Model Deviation % J (L/h) Model Deviation %
1 34.76 45.10 600 600 43.68 0.4 36.91 1.4 3.04 3.3

2 34.79 50.77 600 600 48.57 0.6 37.78 0.2 7.23 3.2
3 35.11 54.44 600 600 51.74 0.1 38.74 0.2 9.91 2.9
4 34.94 59.73 600 600 56.28 0.0 39.29 0.2 13.83 1.2
5 34.66 64.81 600 600 60.70 0.2 39.67 0.4 18.01 1.9
6 34.76 46.38 360 360 45.11 0.4 36.92 0.5 2.38 2.6
7 34.50 51.64 360 360 49.75 0.7 37.09 0.1 4.75 1.9
8 34.55 54.93 360 360 52.68 0.2 37.48 0.6 6.17 4.6
9 34.60 59.55 360 360 56.80 0.2 38.00 1.3 8.17 1.9
10 34.73 64.23 360 360 60.94 0.6 38.62 0.3 10.17 2.6
11 34.60 45.77 180 180 45.44 0.1 36.53 0.2 0.33 4.3
12 34.26 50.26 180 180 49.48 0.2 36.37 0.0 1.41 1.4
13 34.36 55.17 180 180 53.98 0.0 36.80 0.5 2.39 0.7
14 34.42 60.12 180 180 58.50 0.2 37.18 0.6 3.40 3.8
15 34.57 64.96 180 180 62.88 0.4 37.67 0.1 4.35 4.1
16 34.68 50.11 120 120 49.85 0.1 36.81 0.5 0.13 4.7
17 34.54 55.31 120 120 54.60 0.2 36.88 0.7 0.87 2.8
18 35.20 60.17 120 120 58.98 0.1 37.98 0.7 1.41 3.9
19 35.14 64.71 120 120 63.08 0.3 38.12 0.2 2.01 4.0
20 29.28 80.00 210 180 79.40 0.1 31.70 2.5 15.33 1.4
21 30.02 72.00 210 180 70.95 0.1 31.70 2.2 10.86 0.8
22 30.23 55.00 210 180 53.85 0.1 31.41 0.7 6.02 3.9

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A. Marni Sandid et al. Energy Conversion and Management 243 (2021) 114431

Table 6 and 600 L/h for both hot and cold flow. The variation in the distillate
Range of data. water flow with the feed flow rate at the selected hot feed inlet tem­
Data Thi (◦ C) Tci (◦ C) J (L/h) perature in the AGMD module are investigated in the range of
50 ◦ C–65 ◦ C. The trend shows that the increase in feed flow considerably
Min 40 30 0.13
Max 80 35 18.01 increases the permeate flow. Therefore, the feed flow is a highly effec­
tive variable for increasing the permeate flow at different feed temper­
atures. The exponential nature of the increase in flow is found at 600 L/
h. Over the entire hot feed inlet temperature range (50 ◦ C–65 ◦ C), a
Table 7
Operational conditions of tested air gap membrane distillation module.
45.5% increase in flux is obtained at the feed flow rate of 120 L/h, 52.6%
at 360 L/h, and 61.3% at 600 L/h.
Operational parameter Specification

Feed flow rate, L/min 2, 6 and 10 4.2. Thermal capacity and permeate flux
Hot water operation temperature, ◦ C 40–80
Coldwater operation temperature, ◦ C 30–35
Salinity of hot flow, g/kg 40–60
Fig. 9 shows the outlet temperatures for the FPCs and ETCs, which
Salinity of cold flow, g/kg 35 have areas of 12 and 8 m2, respectively. The outlet temperature in­
creases and reaches 70 ◦ C and 91 ◦ C in winter (December) and summer
(June), respectively. Moreover, the ETCs seem to be more effective than
Table 8 the FPCs in each season. Overall, the plots show a remarkable influence
Minitab results summary. of the hot feed temperature during the day in winter and summer, with
the percentage reaching 16.5%–23.4%.
Equations R2 p- Independent variable that
value contributes the most
Fig. 10 shows the feed inlet temperatures of AGMD, coming from the
heat exchangers and using the FPCs and ETCs. The system runs under the
J ¼ 377.35–0.1874*Vh + 99.74% 0.008 Tci, Thi, Vh and Vc
following operating conditions: hydrophobic PE membrane with a pore
0.1452*Vc-21.56*Tci-
0.0178*Thi 0.00001*Vc*Vc + size of 0.3 µm, feed flow rate of 10 L/min, and feed salinity of 35 g/L.
0.3068*Tci*Tci The feed inlet temperatures reach 56 ◦ C in winter and 65.6 ◦ C in sum­
+0.001262*Vh*Thi mer. Therefore, the percentage increase (8%–10.7%) in the high tem­
Tho ¼ -9.69–0.0087*Vc + 0.003 Tci, Thi and Vc
peratures with the use of the ETCs is higher than that with the FPCs.
1.3005*Tci + 0.0243*Thi
+0.000204*Vc*Thi 97.16%
Fig. 11 shows the change in the permeate flux at constant inlet flow
Tco ¼ -37.5 + 0.0069*Vh- 0.004 Tci, Thi, Vh and Vc rate of hot and cold flow. The trend shows that the permeate flux in­
0.0122*Vc + 1.215*Tci + 99.97% creases with time. Therefore, the ETCs are more effective for increasing
1.6879*Thi+ the permeate flux throughput than the FPCs at the different times.
0.000009*Vc*Vc-
Moreover, the exponential increase in throughput can be observed
0.000101*Vh*Thi
− 0.02201*Tci*Thi better in summer than in winter. Over the entire range of the permeate
flux (8.2–18.11 kg/h) and between the ETCs and FPCs, the flux increases
by 18.81% in winter and by 30.44% in summer.
4.1. Model validation
4.3. Gain output ratio and specific thermal energy consumption of air gap
According to the experimental characteristics of the AGMD module, membrane distillation system
the simulation results are valid with experimental data obtained from
the pilot solar thermal MD system mounted in Port Said City, Egypt. This Fig. 12 depicts the influence of the average feed water temperature
section aims to test the validity of the input data and output results and flow rate on the GOR and STEC of the AGMD module. In this figure,
under the same operating conditions for the AGMD module in order to the coolant flow rate Vc is kept equal to the feed flow rate Vh. The water
obtain correct and accurate findings. Fig. 7 compares the experimental flow rate varies from 2 L/min to 10 L/min at each average feed water
results and the simulation results obtained from the adopted model. temperature (43 ◦ C, 46 ◦ C, 49 ◦ C, and 52 ◦ C). Likewise, the feed water
Then, it explains the impact of the feed inlet temperature on the temperature varies from 50 ◦ C, 55 ◦ C, and 60 ◦ C to 65 ◦ C. As shown in
permeate flux at the hot and cold feed flow rates of 210 and 180 L/h. The Fig. 12, the GOR increases from 0.5 to 4.4 as hot feed water temperature
hot feed inlet temperature in the AGMD module is varied from 55 ◦ C to increases, while the STEC decreases from 346.55 kWh/m3 to 158.83
80 ◦ C. The system runs under the following operating conditions: hy­ kWh/m3. Therefore, these variables effectively increase the GOR of the
drophobic PE membrane with a pore size of 0.3 µm, thickness of 76 µm, AGMD system. This effect is more evident at the high feed water tem­
and total membrane area of 14.4 m2. As shown in Table 5 and Fig. 8, the peratures and flow rates. An increase in the average feed temperature
hot and cold feed outlet temperatures and the permeate flux of the from 43 ◦ C to 52 ◦ C and a decrease in the flow rate from 10 L/min to 2 L/
AGMD module are calculated by the present model. It is found that the min resulted in a GOR increase from 12.9% to 59% but an STEC decrease
variation between the experimental and simulation results are less than from 10.5% to 25%.
5%. The results show that increasing the feed inlet temperature leads to
significant increase in the permeate flux. Increasing the feed inlet tem­ 4.4. Thermal energy efficiency of air gap membrane distillation system
perature increases the vapor production and the driving force to
permeation (the transmembrane temperature difference, and conse­ Fig. 13 shows the effect of the average feed temperature on thermal
quently the difference in partial pressures across membrane surfaces) efficiency at different flow rates of the AGMD module. The flow rate is
which enhance vapor transfer across the membrane. varied from 2 L/min to 10 L/min, while all the other parameters are kept
Fig. 8 compares the experimental and computational values of constant, as mentioned in Fig. 12. As shown in Fig. 13, the thermal ef­
permeate flux at different hot feed flow rate and inlet feed temperature. ficiency increases by 72% at the average feed temperature of 52 ◦ C and
An experiment is conducted to determine the impact of the feed flow flow rate of 10 L/min. The thermal efficiency at the high feed temper­
rate on the AGMD flux; the feed flow rates are variable, whereas all the atures is 17.2%–86.9% higher than obtained efficiency at low feed
other parameters are constant. It can be noticed that the distillate water temperatures. Over the entire range of the average feed temperature
flow of the AGMD module calculated by the present model has a good (43 ◦ C–52 ◦ C), and 86.9% increase in thermal efficiency is obtained at
agreement with the experiment. The feed flow rate is set as 120, 360, the feed flow rate of 2 L/min, 35.8% at 3 L/min, 17.2% at 6 L/min, and

8
A. Marni Sandid et al. Energy Conversion and Management 243 (2021) 114431

Fig. 5. Diagram of the AGMD system using FPC in the TRNSYS simulation.

22.3% at 10 L/min. Therefore, increasing the feed temperature and flow ETCs. Apparently, the cumulative daily freshwater yield is greatly
rate increases the difference in partial pressure, which assists in the increased using the ETC system. The peak freshwater yield achieved for
permeation process across the membrane. this experimental set by the ETC system is 78.87 kg/day. Furthermore,
the daily reduction in CO2 emissions due to the use of the FPC system is
12.73 kg. These numbers demonstrate the ratio of the CO2 reductions to
4.5. Mitigation potential of carbon dioxide emissions
the solar collector configuration, known as the increase in freshwater
yield with ETCs. In the case of the ETC system, the daily accumulated
Fossil fuel power plants make a serious contribution to world carbon
decrease in CO2 as a result of using the planned AGMD system reaches
dioxide (CO2) emissions. This severe environmental downside needs
19.93 kg.
urgent attention. It can be comparatively resolved by increasing the
Results of the comparison study between the performance of the
utilization of renewable energy sources, including solar energy, as a
current proposed system and the results of several surveyed studies are
clean source of energy to reduce CO2 emissions [21]. Another benefit of
listed in Table 9. In comparison to the other published data, the current
implementing water desalination technology, besides sustainability, is
study achieved a remarkable improvement as STEC has been reduced to
its cleanliness. Furthermore, AGMD systems, which use FPCs and ETCs
158 kWh per 1 m3. This can be attributed to the modified system
to desalinate water through heat, introduce a new property trend that
configuration to reduce the amount of heat source required to raise the
will reduce dependence on grid electricity; therefore, they are heavily
temperature. As above mentioned, the coolant flow from the first AGMD
involved in decreasing carbon oxide emissions. The CO2 emission
module was used to heat the feed stream that entered the second AGMD
reduction using the planned AGMD system is expressed by Eq. (11) [22].
module within the second H.EX. (Fig. 1). Superior enhancement in the
mt=me× dE×tlife (11) GOR has been obtained in the present membrane desalination system
using solar collectors compared to other surveyed systems. This can be
where mt is reduction in CO2 (g) emission levels throughout the life ascribed to the low thermal energy needed to raise the feed temperature.
cycle, me is the average CO2 (904 g/kWh) emission from a coal-fired
power plant [23], and dE (kWh/day) is the total daily energy savings 5. Economic study
of the planned AGMD system; the economic life (tlife) of AGMD system is
set as 20 years [24]. The total cost of producing drinking water from the solar combined
Fig. 14 shows the cumulative solar intensity, reduction in CO2 membrane distillation (SCMD) system is enlarged by the running cost
emissions, and freshwater yield of various solar harvesting configura­ and therefore the capital cost. In this study, economic evaluation was
tions on a daily basis. This figure illustrates that the cumulative daily performed exploitation levelized cost of water (LCOW) and average cost
radiation values during the test days, namely, June 28 and 29 are 11.951 of water to assess the cost-effectiveness of the water generated by the
and 12,000 W/day, respectively, in the experiments with the FPCs and SCMD system. LCOW determines the cost per cubic meter of water

9
A. Marni Sandid et al. Energy Conversion and Management 243 (2021) 114431

Fig. 6. Diagram of the AGMD system using ETC in the TRNSYS simulation.

Fig. 8. The simulation and the experimental data of the permeate flux with (J1
Fig. 7. The simulation and the experimental data of the permeate flux, hot and “ Vh = Vc = 600 L/h “, J2 “ Vh = Vc = 360 L/h “ and J3 “ Vh = Vc = 120 L/h “).
cold feed outlet temperatures of the AGMD module with (Vh = 210 L/h, Vc =
180 L/h).
and operation costs of LCO and M($), and operating costs of the powered
system components. The cost analysis of a solar system that uses FPCs
produced over a lifelong period [30]. The detailed LCOW formulas and ETCs with the SCMD system is shown in Tables 10–12. The distillate
utilized in the present work are given in Eqs. (12)–(16). The calculations cost of 1 m3 of LCOW water can be expressed as given in Eq. (12) [31].
take into account the capital costs awarded by LCinv ($), maintenance

10
A. Marni Sandid et al. Energy Conversion and Management 243 (2021) 114431

Fig. 9. Distribution of collector outlet temperature along the day during


summer and winter season.
Fig. 12. Average temperatures on STEC and GOR of the AGMD system (Vh =
Vc = 10, 6, 3 and 2 L/min).

Fig. 10. Distribution feed inlet temperature of AGMD using FPCs and ETCs.

Fig. 13. Average temperatures on the thermal efficiency of the AGMD system
(Vh = Vc = 2, 3, 6, and 10 L/min) η = mp × Hv/Qin,

LCinv × CRF + LCO&M + rc − ASV


LCOW = (12)
VP
The factor of capital recovery crf is represented in Eq. (13) [31]

I × (1 + I)N
crf = (13)
(1 + I)N − 1

where I is the rate of annual interest.


The results of the salvage price (0.5 of the reusable components) and
fund factor (FF) provide the annual salvage price are expressed by Eqs.
(14) and (15) [32]
ASP = FF × LCinv (14)
The FF can be calculated as given in Eq. (15)
Fig. 11. Distribution Permeate flux of AGMD along the day.
I
FF = (15)
(1 + I)N − 1
The water production by the proposed SCMD system during the year

11
A. Marni Sandid et al. Energy Conversion and Management 243 (2021) 114431

Fig. 14. The daily accumulated of solar intensity, freshwater productivity and reduction of CO2 against the solar collector configurations.

Table 9
Comparison between the present study and previous studies.
Present study Literature

[25] [26] [27] [28] [14] [29]

Feed water flow rate (L/h) 600 200 250–400 – 500 600 180
Inlet feed temperature to the evaporator 52 85 – 60–80 85 80 70
STEC (kWh/m3) 158.83 200 200–300 200–300 600 269.8 1080
GOR 4.4 4 0.3–0.9 0.4–0.7 – 2.21 0.41

is estimated to be 18,390 and 28,789 kg with the use of the FPC and ETC
Table 10 solar systems, respectively. The capital cost of the MD system is USD
Cost breakdown of FPC case.
1,729.2, and those of the solar FPC and ETC systems are USD 1,942.5
Investment costs Unitary cost (US$) Quantity Costs (US and USD 1,505.5, respectively. The annual interest rate is set as 10%, the
$)
lifetime (N) of the SCMD system is considered to be 20 years [36], and
FPC cost (Ccol) 100 /m2 12 m2 1,200 membrane replacement is planned every five years. A crf of about
Solar Pump 50 50 11.73% is determined by Eq. (13), and the maintenance and operating
Heat storage tank 800 /m3 0.3 m3 240
[33]
costs are taken as 8% of the capital cost [37].
Hydraulics/piping 30%⋅Ccol [34] 360 The running costs of the pumps of the proposed SCMD system during
Installation costs 5% of total component cost 92.5 the year can be evaluated on the basis of the operating costs using the
[35] formula (16) [32].
Total 1,942.5
rc = 365 × Wp × Time of day × Cost of kWh (16)

where Wp is the power consumption of the pumps, and the cost of


Table 11
Cost breakdown of evacuated tube collectors case. electricity is USD 0.016/kWh [38]. The operating cost estimation with
the LCOW of the SCMD system is shown in Table 13.
Investment costs Unitary cost (US$) Quantity Costs (US
The LCOW values for the SCMD system are approximately USD
$)
26.08/m3 and USD 14.73 m3 for the FPCs and ETCs, respectively.
ETC cost (Ccol) 110 /m2 8 m2 880
Table 14 shows a comparison between the current and previous studies,
Solar Pump 50 50
Heat storage tank 800 /m3 0.3 m3 240 with 20 years as the economy-associated work–life expectancy [39]. The
[33] table also shows the combination of the SCMD system with a heat source
Hydraulics/piping 30% Ccol [34] 264 from the ETC module, which leads to a significant reduction in the water
Installation costs 5% of total component cost 71.7
[35]
Total 1,505.7
Table 13
Cost estimation with levelized cost of water of solar membrane distillation
system.
Table 12 Parameters FPC case (US$) ETC case (US$)
Cost breakdown of membrane distillation system.
ASV 32.05 28.23
Components (MD) (US$) LCinv 3,671.7 3,234.7
AGMD moduleMembrane 36 $/m2 [33] 1000529.2 LCO&M 73.43 64.69
Galvanized steel, stand and constructions 50 rc 7.00 7.88
Water pump 50 CostofkWh 0.016 0.016
Piping, valves and tanks 100
LCOW/ m3 26.08 14.73

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A. Marni Sandid et al. Energy Conversion and Management 243 (2021) 114431

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