Paragraph for Question Nos. 22 to 24 ‘S(+) Mono Sodium Glutamate (MSG) is a flavour enhancer used in many foods. Fast foods often contain substantial amount of MSG and is widely used in Chinese food. If one mole of above MSG was placed in 845 ml solution and passed through 200 mm tube, the observed rotation was found to be + 9.6°. Find out the specific rotation of (-) MSG: (A) +24" (8) +56.8° (c)-48" (D) None of these Find out the approximate percentage composition of (-) MSG in a mixture containing (+) MSG and (MSG whose specific optical rotation is -20°. (A)83.3.% (8) 16.7% (C)91.6% (0) 74% 133.8 g of (+) MSG was put in 338 ml solution and was mixed with 16.9 g of (-) MSG putin 169 ml solution and the final solution was passed through 400 mm tube. Find out observed rotation of the final solution (A) + 1.6° (8)+4.8° (c)+3.2" (D) None of theseeee sporn Chose specraaton ot +10" Inwater ‘The antibiotic cephalosporin og he vey Tey Cophalosporin C 2 ween as (84 (C5 (Os a Wonuesmemntaclt ible tactic a (Bs (c)16 (0)32 2k Kemnanserinl eh hme nahrt at STE — (A)90% (8) 80% (C)10% (0) 20% Comprehension (Q.35 to Q.36) It plane-potarized lights passed through one enantiomer of achiral substance (either the pure enantiomer ‘solution of), the plane of polarization ofthe emergent ightis rotated. A substance that rotates the pl Cf polarized light is sad to be optically active. Individual enantiomers of chiral substances are optica active. “OL ‘Total stereoisomer of given compound willbe as (B)4 5 oe ‘Which of te folowing compound show optical isomerism (Assuming cyclobutane rng is planar) 38, ~ L “ ‘a (8) (c) (0)Match the column. ) ®) H COOH Nn Column Plane of symmetry Centre of symmetry ‘Show geometrical isomerism ‘Show optical isomerism @ ) @Q) ® ) H coon Me Nu Column It ' 1 a Nv2 Match tne column ‘column © RA cl Br ‘Total numberof etereo lsomers are odd ‘Totalnumber of stereccanter are even or have centre of symmetry. Compounds hang plane of spray ‘or axis of symmetry ‘Compounds have ze dipole in glen form. Column It ) EnantomersWw hemes we 4 28, Identify correct acidic strength order in the following compounds H(i) i) O23 ZA CH S iii) (a) i>ii> iti (b) ii>iii>i (d) iti>i>ii 29. Identify correct acidic strength order in the following compounds @ ‘HO. O Gi) rf Gi) HO OH (0) i>iii> it (d) iti>i>ii —Y rill () ii>iti>i 30. The acidity of the protons H in each of the following is eet © lirtiat —_@eti>i iit @ aisisa© ° A riirii — & ii>itiai (9 toto (@) Miva 2 Oe Oa oO 6 as (9 isis (@) >in e. 3. Bae ala cement oO wfy* wa He Arist — oiewri © burs @urba Se tycoon ni A dm ety AP tae Wi isistigs gepiists (a.tpmas ae akin te Eo. SE ne (@ i>ii>ai >it © iis fa) >it 36. Se eg eek @ OQ a) OC (ii) 0 | , (2 | h ii>ti>i—(&) >> i (©) i>iti>ii @) iti> toad(69, Select the correct statement (0) CV Rita is ore basi ta & 9° Q @ (venom Os Aste 70. Which ofthe following is most basic? ° ° ° 5 ‘71. Which of the following is most basic? 2 wy /, @d