VNaOH (mL) pH dpH/dV

0.00 2.06 14.00

pH
0.50 2.08 0.04
1.00 2.10 0.04 12.00
1.50 2.13 0.06
2.00 2.17 0.08 10.00
2.50 2.20 0.06
3.00 2.23 0.06 8.00
3.50 2.26 0.06
4.00 2.30 0.08 6.00
4.50 2.34 0.08
5.00 2.38 0.08 4.00
5.50 2.43 0.10
2.00
6.00 2.49 0.12
6.50 2.54 0.10
0.00
7.00 2.60 0.12 0.00 5.00 10.00
7.50 2.67 0.14
8.00 2.74 0.14
8.50 2.85 0.22
9.00 2.96 0.22
9.50 3.09 0.26
10.00 3.22 0.26
10.50 3.37 0.30
11.00 3.51 0.28
11.50 3.64 0.26
12.00 3.77 0.26
12.60 3.88 0.18
13.00 3.96 0.20
13.50 4.06 0.20
14.00 4.15 0.18
14.50 4.22 0.14
15.00 4.29 0.14
15.50 4.37 0.16
16.00 4.45 0.16
16.50 4.54 0.18
17.00 4.63 0.18
17.50 4.73 0.20
18.00 4.86 0.26
18.50 4.99 0.26
19.00 5.17 0.36
19.50 5.41 0.48
20.00 5.86 0.90
20.05 5.93 1.40
20.10 6.03 2.00
20.15 6.11 1.60
20.20 6.32 4.20
20.25 6.46 2.80
20.30 6.65 3.80
20.35 7.13 9.60
20.40 8.76 32.60
20.45 9.64 17.60
20.55 10.10 4.60
20.60 10.28 3.60
20.65 10.42 2.80
20.70 10.53 2.20
20.75 10.62 1.80
20.80 10.71 1.80
21.00 10.95 1.20
21.50 11.25 0.60
22.00 11.42 0.34
22.50 11.53 0.22
23.50 11.71 0.18
24.55 11.84 0.12
 35.00

ΔpH/ΔV
30.00

25.00

20.00

15.00

10.00

5.00

0.00
00 10.00 15.00 20.00 25.00

VNaOH (mL)
VNaOH (mL) pH dpH/dV Cacid Cmuối CH+ X
0.00 2.06 Vtđ1
0.50 2.08 0.04 9.24E-02 4.76E-03 8.32E-03 8.08E-01 Vtđ2
1.00 2.10 0.04 8.36E-02 9.09E-03 7.94E-03 6.48E-01
1.50 2.13 0.06 7.57E-02 1.30E-02 7.41E-03 5.23E-01
2.00 2.17 0.08 6.83E-02 1.67E-02 6.76E-03 4.20E-01
2.50 2.20 0.06 6.16E-02 2.00E-02 6.31E-03 3.23E-01 f
3.00 2.23 0.06 5.54E-02 2.31E-02 5.89E-03 2.33E-01 R
3.50 2.26 0.06 4.96E-02 2.59E-02 5.50E-03 1.48E-01
4.00 2.30 0.08 4.43E-02 2.86E-02 5.01E-03 6.80E-02
4.50 2.34 0.08 3.93E-02 3.10E-02 4.57E-03 -1.07E-02
5.00 2.38 0.08 3.47E-02 3.33E-02 4.17E-03 -8.98E-02
5.50 2.43 0.1 3.03E-02 3.55E-02 3.72E-03 -1.68E-01
6.00 2.49 0.12 2.63E-02 3.75E-02 3.24E-03 -2.48E-01
6.50 2.54 0.1 2.24E-02 3.94E-02 2.88E-03 -3.35E-01
7.00 2.60 0.12 1.88E-02 4.12E-02 2.51E-03 -4.28E-01
7.50 2.67 0.14 1.54E-02 4.29E-02 2.14E-03 -5.30E-01
8.00 2.74 0.14 1.22E-02 4.44E-02 1.82E-03 -6.48E-01
8.50 2.85 0.22 9.19E-03 4.59E-02 1.41E-03 -7.85E-01
9.00 2.96 0.22 6.32E-03 4.74E-02 1.10E-03 -9.68E-01 -1.50E+00 -
9.50 3.09 0.26 3.59E-03 4.87E-02 8.13E-04 -1.25E+00
10.00 3.22 0.26 1.00E-03 5.00E-02 6.03E-04 -2.10E+00
10.50 3.37 0.3 4.83E-02 1.46E-03 4.27E-04 1.40E+00
11.00 3.51 0.28 4.48E-02 3.81E-03 3.09E-04 1.03E+00
11.50 3.64 0.26 4.14E-02 6.05E-03 2.29E-04 8.17E-01
12.00 3.77 0.26 3.82E-02 8.18E-03 1.70E-04 6.58E-01
12.60 3.88 0.1833333 3.45E-02 1.06E-02 1.32E-04 5.05E-01
13.00 3.96 0.2 3.22E-02 1.22E-02 1.10E-04 4.17E-01
13.50 4.06 0.2 2.94E-02 1.40E-02 8.71E-05 3.16E-01
14.00 4.15 0.18 2.67E-02 1.58E-02 7.08E-05 2.23E-01
14.50 4.22 0.14 2.41E-02 1.76E-02 6.03E-05 1.35E-01
15.00 4.29 0.14 2.16E-02 1.92E-02 5.13E-05 4.90E-02
15.50 4.37 0.16 1.92E-02 2.08E-02 4.27E-05 -3.59E-02
16.00 4.45 0.16 1.69E-02 2.23E-02 3.55E-05 -1.22E-01
16.50 4.54 0.18 1.47E-02 2.38E-02 2.88E-05 -2.10E-01
17.00 4.63 0.18 1.26E-02 2.52E-02 2.34E-05 -3.02E-01
17.50 4.73 0.2 1.05E-02 2.65E-02 1.86E-05 -4.02E-01
18.00 4.86 0.26 8.57E-03 2.79E-02 1.38E-05 -5.13E-01
18.50 4.99 0.26 6.67E-03 2.91E-02 1.02E-05 -6.41E-01
19.00 5.17 0.36 4.83E-03 3.03E-02 6.76E-06 -7.99E-01
19.50 5.41 0.48 3.05E-03 3.15E-02 3.89E-06 -1.01E+00
20.00 5.86 0.9 1.33E-03 3.27E-02 1.38E-06 -1.39E+00
20.05 5.93 1.4 1.16E-03 3.28E-02 1.17E-06 -1.45E+00
20.10 6.03 2 9.97E-04 3.29E-02 9.33E-07 -1.52E+00
20.15 6.11 1.6 8.29E-04 3.30E-02 7.76E-07 -1.60E+00
20.20 6.32 4.2 6.62E-04 3.31E-02 4.79E-07 -1.70E+00
20.25 6.46 2.8 4.96E-04 3.32E-02 3.47E-07 -1.83E+00
20.30 6.65 3.8 3.30E-04 3.33E-02 2.24E-07 -2.00E+00
20.35 7.13 9.6 1.65E-04 3.34E-02 7.41E-08 -2.31E+00 -3.00E+
20.40 8.76 32.6 0.000E+00 3.355E-02 1.738E-09 Err:502
20.45 9.64 17.6 -1.642E-04 3.366E-02 2.291E-10 Err:502
20.55 10.10 4.6 -4.910E-04 3.388E-02 7.943E-11 Err:502
20.60 10.28 3.6 -6.536E-04 3.399E-02 5.248E-11 Err:502
20.65 10.42 2.8 -8.157E-04 3.409E-02 3.802E-11 Err:502
20.70 10.53 2.2 -9.772E-04 3.420E-02 2.951E-11 Err:502
20.75 10.62 1.8 -1.138E-03 3.431E-02 2.399E-11 Err:502
20.80 10.71 1.8 -1.299E-03 3.442E-02 1.950E-11 Err:502
21.00 10.95 1.2 -1.935E-03 3.484E-02 1.122E-11 Err:502
21.50 11.25 0.6 -3.492E-03 3.587E-02 5.623E-12 Err:502
22.00 11.42 0.34 -5.000E-03 3.688E-02 3.802E-12 Err:502
22.50 11.53 0.22 -6.462E-03 3.785E-02 2.951E-12 Err:502
23.50 11.71 0.18 -9.254E-03 3.970E-02 1.950E-12 Err:502
24.55 11.84 0.1238095 -1.201E-02 4.153E-02 1.445E-12 Err:502
 10.20
20.40
3.30
pH

3.00
f(x) = − 0.529140383889973 x + 2.38669860877909
R² = 0.974296170736402
2.70

2.40

2.10

1.80

1.50
-1.50E+00 -1.00E+00 -5.00E-01 0.00E+00 5.00E-01 1.00E+00

7.50
pH

f(x) = − 1.05035054924469
6.60 x + 4.4293538927255
R² = 0.985043962172299

5.70

4.80
 5.70

4.80

3.90

3.00
-3.00E+00 -2.00E+00 -1.00E+00 0.00E+00 1.00E+00 2.00E+00

X
VKMnO4 (mL) ΔE (mV) ΔE/ΔV logX
0.00 436
0.50 447 2.20E+01 -1.31
1.00 454 1.40E+01 -0.99
1.50 460 1.20E+01 -0.79
2.05 466 1.09E+01 -0.63
2.50 471 1.11E+01 -0.52
3.00 476 1.00E+01 -0.41 VKMnO4 (mL) ΔE (mV)
3.50 481 1.00E+01 -0.31 3.50 481
4.00 485 8.00E+00 -0.22 4.00 485
4.50 489 8.00E+00 -0.14 4.50 489
5.00 494 1.00E+01 -0.06 5.00 494
5.50 498 8.00E+00 0.02 5.50 498
6.00 503 1.00E+01 0.11 6.00 503
6.50 507 8.00E+00 0.19 6.50 507
7.00 513 1.20E+01 0.28 7.00 513
7.50 518 1.00E+01 0.37 7.50 518
8.00 524 1.20E+01 0.47
8.50 531 1.40E+01 0.59
9.00 539 1.60E+01 0.72
9.50 549 2.00E+01 0.90 0.720
E (Fe3+/Fe2+) (mV)
10.00 569 4.00E+01 1.15
10.10 572 3.00E+01 1.23 f(x) = 0.0547909630666239
0.710
10.20 577 5.00E+01 1.31 R² = 0.997997026252143
10.30 586 9.00E+01 1.41
0.700
10.40 597 1.10E+02 1.54
10.50 619 2.20E+02 1.72
10.60 645 2.60E+02 2.03 0.690
10.65 827 3.64E+03 2.33
10.70 1077 4.32E+03 #DIV/0! 0.680
10.75 1097 2.70E+03 Err:502
10.80 1120 4.30E+02 Err:502 0.670
-0.40 -0.30 -0.20 -0.10 0.00 0.
10.95 1130 6.67E+01 Err:502
11.00 1136 1.20E+02 Err:502
11.10 1143 7.00E+01 Err:502
11.50 1153 2.50E+01 Err:502
12.00 1159 1.20E+01 Err:502
12.50 1163 8.00E+00 Err:502
13.00 1167 8.00E+00 Err:502
13.50 1170 6.00E+00 Err:502
14.50 1174 4.00E+00 Err:502
15.50 1177 3.00E+00 Err:502
 1400

Eđo (mV)
1200

1000

E (Fe3+/Fe2+) (mV) logX 800

0.677 -0.31
0.681 -0.22
600
0.685 -0.14
0.690 -0.06
0.694 0.02 400
0.699 0.11
0.703 0.19 200
0.709 0.28
0.714 0.37 0
0.00 2.00 4.0

0.720 E đo ΔE/ΔV

f(x) = 0.0547909630666239
0.710 x + 0.693345017023286
R² = 0.997997026252143
0.700

0.690

0.680

0.670
.40 -0.30 -0.20 -0.10 0.00 0.10 0.20 0.30 0.40 0.50

logX
1400 4.50E+03

ΔE/ΔV
4.00E+03
1200
3.50E+03
1000
3.00E+03
800 2.50E+03

600 2.00E+03

1.50E+03
400
1.00E+03
200
5.00E+02

0 0.00E+00
0.00 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00

VKMnO4 (mL)
E đo ΔE/ΔV