3-7. O|APA| AAT EYE ty Al ox Et Al (equation of state) AO] ASS, ASS B YAS AAJ EBSA tio * ore IMligeal gas) St StM7+A(perfect gas) - EAL ZS] BS FALSE 71a) - EXO] A71B PALS > Qe - BEI RS 71M - OS IMLATEH ASA Chet 74 SHE 71a] lal) * O|At7| Ai] 4FEH SB Al (Ideal gas equation of state) J => 7M 2] SAMA APS ZH SAL (1) #21(Boyle)2| 44] (= Mariotte law) LEA ARS BUM 7/AMS| MAS Sf ef oy Bhs] 2H SECh. “. QS x4 =29 (PV=constant ) (2) Charles and Gay-Lussac2| 44] SEMA) AAS SEAL 7/A/9] AAS BCLS & oO} bl ei] SECt. Vv , AA =2% ( —=constant ) ager T« Bud ip a on E21 4e BO ca} ; HES OI BOHRIC BoyleQ| 44] Charles2| 44] (3) Boyle-Charles°] 44 : 2&9} Se{o] SAloy Asp PY constant => 5. SABLE AS (4) OS 71M EHEPSAL PV=mRT .. Pv=RT -. P=pRT AqSa(kPa), T : SLE(K), R : WAVSE(kd/kgK) =v: HIMIS(m3kg) v=V/m, m: B8(kg), p : B&E(kg/m) p=1/v * 7|*|At44(Gas constant) R => 7/412] SO Old} CHE SAZto| et sIch R R = —*[k/(kg -K) wy es “WI Ry (= 8.34kd/kmol-K) : 21##7|4141¢(universal gas constant) M: 7|AIS| ARSE* = X}2#(Molar mass) : M E19]: SE 1mol2| Bet or BS tkmol2| BA J z@ jo wm ot $:m=MN,N: 2 (mole number) * OSA SASSIAS| SEY PV = mRT (237/12) [mR = (MN)R = NRy] * PV=NR,T (S71) [v= Vim] “ Pv=RT (BS71%) [vbar = VIN] Pvbar = RT * Al Z71Al7t OS7lAlS] SEUSS S CARO WHE BZ (1) FEO] LOOK SICH. (P << Per) (2) 2=7t OrOf BCH. (T >> T.,) (3) BAHZEO| ZtofoF gic (4) HAA O| BES SCH. (= BAO] AD Ae Ltopor sh) [OLA] 3-10] cH7/et o5kPa, ASA SB A s0H) EO] 04 9) 7417] 2240] 210kPa, 220kPa0| OH, Eto] O2| MAS WIScCh. SAMS SASH} 26°CA Y SA HO Efo/ojo| S7IZES Poe, [718] S71 ols 1Mlolch.[etd] Has © 8 AL# ol ELnlatol Riruorat *P, = Paoger + Pain = (210 + 95)kKPa = 305kPa "P= Pyage2 + Pam = (220 + 95)KPa = 315kPa (2) MAO] ASS Gh pv=mRT AS EVs — gy = Peg, = 3 MPa 5:0 4. 273)K = 307.8K T; 7? * 305kPa + of 24254 Ol Xt(Compressibility factor) Z : BeIAI7E FHA SES SOHAL OAM SHE HOYLE BES Ley Z = \ anal V ideal Viable : Table A-62| tS S 7] £04] 4 2] 4] 4] Videal ? 187/412! 4|4|24(RTIP) Pv =ZRT 32. Z= 2% RT Z=1 :ideal gas Z>1,Z<1 : real gas => Z7H ESE PHATE AA AES OUS7/AO| ASLS HE HOC (2 <1: SAE AS, Z>1: BA}Zt AH) = PBA