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Journal of Atmospheric and Solar–Terrestrial Physics 199 (2020) 105217

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Journal of Atmospheric and Solar-Terrestrial Physics


journal homepage: www.elsevier.com/locate/jastp

Assessment of particulate matter concentration and gaseous pollutants in


urban and rural regions over the Emirate of Abu Dhabi, UAE
D.V. Phanikumar a, Ghouse Basha b, *, M. Venkat Ratnam b, Niranjan Kumar Kondapalli c, f, T.B.M.
J. Ouarda d, Kishore Pangaluru e
a
Department of Science and Technology, Technology Bhavan, New Mehrauli Road, New Delhi, India
b
National Atmospheric Research Laboratory, Department of Space, Gadanki, India
c
Space and Atmospheric Sciences Division, Physical Research Laboratory, 380009, India
d
INRS-ETE, National Institute of Scientific Research, Quebec City (QC), G1K9A9, Canada
e
Department of Earth System Science, University of California, Irvine, CA, 92697, USA
f
National Center for Medium Range Weather Forecasting, Ministry of Earth Sciences, Nodia, UP, India

A R T I C L E I N F O A B S T R A C T

Keywords: In order to understand the air quality and plausible sources of atmospheric pollutants over the Emirate of Abu
Pollutants Dhabi (EAD), a detailed analysis is performed by utilizing three years of simultaneous measurements of various
Particulate matter gaseous pollutants such as SO2, NO2, CO, and O3 along with PM2.5 and PM10 concentrations during the period
Emirate of Abu Dhabi
2011–2013. The diurnal variation of O3 and SO2 shows noontime maximum in urban and rural regions during all
Sources
seasons, while NO2 and CO show higher levels in the morning and evening. During winter, maximum (minimum)
O3 (NO2) is observed in the rural region and in contrast, the urban region depicts maximum in spring and
summer both during day and night. Large variability is observed during the day and night for all pollutants. The
PM2.5 concentration shows similar diurnal variation as in the case of CO and NO2, peaking during daytime in
winter and spring in the urban region, while the nighttime peak values are prominent irrespective of the season.
It is also to be noted that the minimum (maximum) PM10 values are observed in the urban (rural) regions during
daytime in all seasons except in winter. The frequency distribution of the hourly mean concentrations of the
primary pollutants in the urban and rural regions elucidates that the observed discrepancies in the background
concentration levels of different pollutants may be due to different atmospheric conditions. The observations also
reveal that the linear relationship between maximum ozone concentration and maximum temperature might not
be valid above 313 K. The present observations are discussed in the light of current understanding of the dis­
tribution of trace species and plausible sources over EAD region.

1. Introduction to ozone (O3) production (Katheeri et al., 2012; Ran et al., 2014).
Most previous efforts in understanding the chemical composition of
The major sources of air pollution over the Emirate of Abu Dhabi the pollutants have been made in Asia and the Western world (Ada­
(EAD) are dust, sand storms, and greenhouse gas emissions as well as mopoules et al 1996a, b, c; Guo et al., 2009; Lin et al., 2011; Ran et al.,
industrial pollution. Moreover, urbanization transportation and indus­ 2014). These studies have shown an increase in O3 concentration and its
trialization has degraded the quality of air pollution over EAD in the precursors emissions in Asia. Nevertheless, its levels seem to be either
recent years. Atmospheric pollutants that significantly influence EAD constant or decreasing over the United States and Europe (Akimoto,
are particulate matter (PM10 and PM2.5) whose major contribution 2003; Beig and Brasseur, 2006; Naja et al., 2003). Apart from these, very
comes from dust storms (Kchih et al., 2015; Basha et al., 2015a, 2019). few reports are available in the literature focusing on air pollutants over
The other pollutants such as sulfur dioxide (SO2), nitrogen dioxide the Middle East and the Persian Gulf region (Li et al., 2001; Lelieveld
(NO2), and carbon monoxide (CO) mainly originate from emissions of et al., 2009; Katheeri et al., 2012). Li et al. (2001) concluded that
power generation, household usage, vehicle exhaust, fuel combustion as stratospheric O3 does not contribute much to the summertime O3
well as small and large-scale industries; These gaseous pollutants do lead maximum over the Middle East. In continuation to this, Lelieveld et al.

* Corresponding author.

https://doi.org/10.1016/j.jastp.2020.105217
Received 10 April 2019; Received in revised form 4 February 2020; Accepted 5 February 2020
Available online 8 February 2020
1364-6826/© 2020 Elsevier Ltd. All rights reserved.
D.V. Phanikumar et al. Journal of Atmospheric and Solar-Terrestrial Physics 199 (2020) 105217

(2009) extended their study to understand the surface O3 concentration measurements of O3 (Model -O342M), SO2 (Model-AF22M), NO2
especially over the Persian Gulf and suggested that this region is highly (Model-AC32M), CO (Model-CO12M) and PM2.5 and PM10 (Model-
favorable for O3 air pollution and also argued that the O3 precursor MP101M). These instruments measure O3 based on UV attenuation, SO2
emissions levels are high over this region. Katheeri et al. (2012) studied on fluorescence, NO2 on chemiluminisence and CO on NDIR technique.
the air pollutants over Al Mirfa (24.12� N; 53.44� E), UAE during The minimum detection limit (MDL) of O3, SO2, and NO2 is 1 ppbv,
2007–2009 and this study reveals that the average hourly values for while CO has an MDL of 50 ppbv; PM2.5 and PM10 have MDLs of 0.5 μg/
NO2, SO2, and 8 h average of CO were within the acceptable levels of m3. Hourly-averaged values have been recorded throughout the obser­
400, 300 and 30,000 μg/m3, respectively, whereas the levels of O3 as 8 h vational period of January 2011–December 2013.
average. On the other hand, the priorities of the Environmental Agency In order to understand the air pollution over any region, information
Abu Dhabi (Environment Vision, Abu Dhabi, 2012) are to ensure a about the basic surface meteorological parameters are required.
sustainable way of reducing ambient air pollution, thereby increasing Dispersion and dissipation of pollutants involve atmospheric mixing,
air quality (Environmental Agency of Abu Dhabi report, 2012). Also, it is settling, and deposition, which are greatly affected by the degree of
well know that most of the pollutants are trapped in the boundary layer atmospheric turbulence which, in turn, depends on local weather con­
(Basha and Ratnam, 2009; Ratnam and Basha, 2010; Basha et al., 2018). ditions (e.g. temperature and wind speed). Hence, measurements of
In this context, continuous and simultaneous measurements of pollut­ parameters like temperature, relative humidity, wind speed, and direc­
ants (SO2, NO2, O3, CO, PM2.5, and PM10) over EAD during three years tion from the Automatic Weather Station (AWS), National Climate Data
(2011–2013) are utilized here to better understand their variability and Center, USA have been utilized during the observational period. The
plausible sources for the observed discrepancies. Observations and data wind rose diagrams are plotted using Origin software.
analysis are described in detail in Section 2. The variations in gases and
particulate matter along with plausible sources are discussed in Section 3. Study area
3. Finally, summary and concluding remarks are presented in Section 4.
In order to give a comprehensive picture of EAD, we have grouped
2. Materials and method similar observational locations by their characteristics and two main
regions are studied for their air pollution: Urban (Hamdan street, Kha­
The Environmental Agency of Abu Dhabi monitors gaseous pollut­ dejah school and Khalifa school) and Rural (Bida Zayed, Gayathi school
ants, particulate matter and meteorology over EAD. A set of commercial and Liwa Oasis) sites as shown in Fig. 1 based on population density. The
instruments from Environment SA Company are used to obtain the northwesterly part of EAD is mostly “urban,” while the western part is

Fig. 1. Map of Emirate of Abu Dhabi (http://www.ngdc.noaa.gov/mgg/topo/globe.html). Urban sites are shown by red circles and rural ones by blue dots. The
colored scale refers to the terrain’s altitude.

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D.V. Phanikumar et al. Journal of Atmospheric and Solar-Terrestrial Physics 199 (2020) 105217

considered “rural” region covered mostly by desert. The location of as emphasized in a recent report. Another plausible reason could be the
these sites is shown in Fig. 1 and their coordinates are given in Table 1. extreme precipitation events that are high over the urban sites and low
The stations are divided into urban (red dots), and rural (blue dots) in the rural regions, therefore O3 concentration reduces in the urban
regions. The main reason behind this distinction is to see the percentage sites due to high precipitation in urban sites.
contribution of different source regions over EAD. However, all stations The diurnal variation of SO2 shows a daytime maximum in all sea­
considered in this study have low elevation. sons over the urban at different timings. However, the rural region
shows different pattern in all seasons with peaks in the evening hours
4. Results and discussion indicating that the source region could be different. The SO2 maximum
during winter is higher followed by that in spring, summer, and fall. The
4.1. Meteorological variables higher values of SO2 in the urban region throughout the day and in all
seasons may be due to the increase in local (vehicular and industrial)
In order to understand the meteorological conditions prevailing over emissions in that region. The diurnal variation of NO2 and CO shows
EAD in different seasons, we have plotted surface temperature, relative morning and evening peaks with daytime minimum in all seasons (CO
humidity and wind speed obtained from the National Climate Data observations are not available over the rural region). As expected, NO2
Center (https://www.ncdc.noaa.gov/cdo-eb/datasets) over Abu Dhabi levels are greater over the urban region. The NO2 morning peak is higher
International Airport (24.4419� N, 54.6501� E) as shown in Fig. 2 for in winter than its evening counterpart, while in the case of CO, the
different seasons winter (December–February), spring (March–May), evening peak is greater. The NO2 variations are stronger in winter fol­
summer (June–August) and fall (September–November). The tempera­ lowed by spring, fall, and summer. Large variability is observed from
ture, relative humidity, and wind speed shows clear diurnal variation in season-to-season especially in spring and summer; this variability de­
all the seasons. The magnitude of temperature variability is large during pends upon different source and transport mechanisms dominant in
spring and fall whereas it is low during winter. The maximum (mini­ different seasons. The large variability observed during the day and
mum) temperatures during winter are 26 � C (17 � C), spring 40 � C (28 nighttime levels in all pollutants may be attributed to larger emissions

C), and fall 40 � C (29 � C). Although variability is low in summer the from heating in combination with temperature inversions which are
minimum temperature is 32 � C whereas maximum it reaches to 42 � C dominant during nighttime (Lin et al., 2011).
around 13 LT (local time). During winter humidity reaches maximum of Monthly mean variations of O3, SO2, NO2, and CO in urban and rural
about 73% followed by fall (60%), spring (55%), and summer (54%) at regions during period 2011–2013 are displayed in Fig. 5a–d. The solid
night and minimum values of relative humidity are observed at 10 a.m. black lines represent the monthly variations at individual sites. It is
The wind speed show clear diurnal observations in different seasons evident that maximum values of O3 are prominent in June in all regions
with maximum wind speed of ~6.5–7 m/s at 13 LT in all the seasons. with varying magnitudes though. In general, minimum or very low
Fig. 3 shows the monthly variation of wind direction in terms of per­ concentration of pollutants during the summer monsoon (June–August)
centage occurrence over EAD during 2011–2013. The wind direction is is observed. However, EAD experiences higher temperatures and
divided into four quadrants namely 0o-90� , 90o-180� , 180o-270� , and negligible precipitation implying non-wash out of pollutants and hence
270o-360� . The most prevailing wind direction throughout the year is buildup of concentration of the primary pollutants during summer. The
from the northwestern (270o–360� ) sector that is also known as “Shamal variability of SO2 is comparable in both urban and rural regions. The
wind” in the Arabian Gulf region. This is implying that the Persian Gulf meteorological pattern in winter over EAD region could have contrib­
region may be responsible for bringing moist air over EAD. Moreover, uted for the accumulation of pollutants for the observed variation.
during winter, spring, and fall, winds from the 90o-180� sector also Higher values in summer can be attributed to non-washout of pollutants
contribute to some extent (~25%) in bringing desert dust to this region. because of negligible precipitation over this region (Basha et al., 2015b;
Minor frequency of wind occurrence from other directions throughout Chandran et al., 2015). A CO-tracer model study over the Indian region
the year depicts contribution of local emission sources apart from major showed that the wintertime higher CO levels are mainly due to
contribution from long-range transport of dust from distant locations. anthropogenic emission and inflow of CO from other regions (Kumar
et al., 2013).

4.2. Diurnal and seasonal variation of surface pollutants 4.3. Particulate matter

Fig. 4a-p show the diurnal variation of air pollutants (SO2, NO2, O3, In order to understand the distribution of particulate matter over
CO) during the period 2011–2013 over EAD for winter, spring, summer EAD, we studied diurnal and monthly variations of PM2.5 and PM10
and fall for urban and rural regions. As expected, O3 starts increasing concentrations during the observational period as shown in Figs. 6 and
during daytime and decreases during nighttime in both urban and rural 7. Fig. 6 shows the diurnal variation of PM2.5 and PM10 during four
regions confirming that the precursors in this region are leading to seasons over the urban and rural regions. It is observed that PM2.5 is
daytime ozone production via photochemistry. Except during winter, showing diurnal variations somewhat similar to those of NO2 and CO,
the daytime O3 peak is higher over the urban sites when compared with while PM10 shows a little different diurnal variation. Moreover, PM2.5 p.
the rural ones. The higher O3 peak observed during winter at the rural m.10 shows similar values in the urban region as compared to the rural
sites may be associated regional mixing/downward transport of O3 regions in all seasons during daytime except in summer. The nighttime
which plays a vital role in transporting O3 from higher altitudes to lower values are also high in all regions, probably due to heavy daytime traffic
troposphere thus demonstrating the complexity in the estimation of O3 in the urban region. Temporal and spatial discrepancies from urban to
rural sites can be interpreted by the local sources and favorable mete­
Table-1 orological conditions over the study region. On the other hand, the
Urban and rural sites over EAD used in this study. diurnal variation of the PM10 concentrations in the rural regions shows
Region Station Name Area Type Lat (N) Lon (E) higher values during daytime in all seasons except in winter. The pri­
mary source for the higher values of the PM10 concentration over this
1 Abu Dhabi city Hamdan Street Urban 24.48893 54.36372
2 Abu Dhabi City Khadejah School Urban 24.48156 54.36933 region is due to the site ground morphology itself being a desert;
3 Abu Dhabi city Khalifa School Urban 24.43009 54.40843 therefore, transport of dust from the adjacent desert as well as from
4 Western Region Bida Zayed Rural 23.65226 53.70389 distant locations soon lead to higher values (Katheeri et al., 2012). Also,
5 Western Region Gayathi School Rural 23.83551 52.81033 the observed discrepancies can be explained by the favorable wind
6 Western Region Liwa Oasis Rural 23.09579 53.60641
conditions and probable transport of desert dust from other locations.

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Fig. 2. a-l: Mean seasonal diurnal variation of EAD air temperature, (a–d), relative humidity (e–h) and wind speed (i–l), observed over EAD for winter (first row),
spring (second row), summer (third row) and fall (fourth row) during the period January 2011–December 2013.

Fig. 3. Frequency of occurrence of wind direction (o) observed over EAD during January 2011–December 2013.

The urban region shows low values in all seasons indicating either less variation of PM2.5 and PM10 (Fig. 7) shows a maximum during the
contribution from desert dust to the urban air pollution or transport month of June followed by July and August and starts decreasing. The
mechanism dominates due to highly variable sea breeze. The monthly PM10 concentrations show significant difference between the rural and

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D.V. Phanikumar et al. Journal of Atmospheric and Solar-Terrestrial Physics 199 (2020) 105217

Fig. 4. a-p: Diurnal variation of O3 (a–d), SO2 (e–h), NO2 (i–l) and CO (m–p) observed in the four seasons averaged during January 2011–December 2013. Urban and
rural regions are shown in red and blue colors, respectively. The first row of the plots refers to winter, the second to spring, the third to summer and the fourth to fall.

urban regions during the months of March to end of August (Fig. 7b). In
addition, higher concentration of PM10 is observed over the rural than
the urban region (Fig. 7b).

4.4. Frequency distribution

Fig. 8 shows the frequency distribution of daily averaged O3, SO2,


NO2, CO, PM2.5, and PM10 over the urban (red circles) and rural (blue
triangles) during the observational period. The highest probability in the
frequency distribution curve provides an idea about the background
levels of that particular pollutant in a specific region (Giavis et al., 2009;
Lin et al., 2011). This kind of distribution is very important for under­
standing the overall morphology of any region. It is interesting to note
that the frequency distribution of each pollutant has a distinctive pattern
and a broad peak at higher concentrations depicting the variability of
these pollutants in urban and rural regions, respectively. The O3 distri­
bution curve shows the highest probability at lower concentrations
(30–40 ppbv) in both urban and rural regions and depicts relatively
broad and identical frequency distribution in both regions. The SO2
distribution shows similar frequency peak at a concentration <1.52
ppbv in both regions, but with higher probability in the rural one. On the
other hand, the frequency distribution of NO2 shows a lower peak at the
concentration of ~7.95 ppbv with highest probability in the rural region
than in urban region.. The frequency distribution of CO over the urban
region shows a dominant and broad peak at ~550 ppbv. PM2.5 and PM10
show similar distribution for both urban and rural regions. On the other
hand, the PM2.5 (PM10) distribution curve shows a broad (narrow) peak
at a concentration of ~40 μg/m3 (~200 μg/m3).

4.5. Variation of O3 concentration with temperature

In order to understand the atmospheric chemistry, which has an ef­


fect on the O3 production, we have plotted daily values of the maximum
Fig. 5. Monthly mean variation of O3, SO2, NO2 and CO averaged during O3 concentration with maximum temperature and maximum RH for all
January 2011–December 2013. Urban and rural regions are shown in red and four seasons in Fig. 9. Jacob et al. (1993) showed that O3 and temper­
blue colors, respectively. ature do not have a direct relationship; however, indirect effects are
observed with the increase in solar radiation leading to an increase in
temperature that could favor chemical reactions rates and thereby

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Fig. 6. Diurnal variation of PM2.5 (a–d) and PM10 (e–h) concentrations observed during different seasons averaged during January 2011–December 2013. Urban
and Rural regions are shown in red and blue colors, respectively.

Fig. 7. Monthly mean variation of PM2.5 and PM10 concentrations averaged during January 2011–December 2013. Urban and rural regions are shown in red and
blue colors, respectively.

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D.V. Phanikumar et al. Journal of Atmospheric and Solar-Terrestrial Physics 199 (2020) 105217

Fig. 8. Number of concentration values of O3, SO2, NO2, CO, PM2.5 and PM10 for urban (red) and rural (blue) regions over the period 2011–2013.

Fig. 9. Dependency map of daily maximum ozone mixing ratio (ppbv) with daily maximum temperature (K) and relative humidity (%) during January
2011–December 2013 over EAD. The different colors of the symbols correspond to include of relative humidity depicted by the color scale.

increase O3 measurements. Apart from these, increase in the mixing studies have observed an increase in O3 concentration with increase in
layer height also contributes to O3 enhancement (Ojha et al., 2012). temperature following a linear relationship with a slope of 2–8 ppb K 1
Initially, lower temperatures (293–303 K) are associated with a (Steiner et al., 2010). Our observations from EAD show an increasing
decreasing trend in the O3 concentration. In addition to that, previous trend of O3 concentration with increasing in temperature with a slope of

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D.V. Phanikumar et al. Journal of Atmospheric and Solar-Terrestrial Physics 199 (2020) 105217

~ 3–5 ppb K 1 in between 303 and 313 in K as evidenced from previous originates from northwesterly in all the seasons and mostly concentrated
reports (NRC, 1991; Steiner et al., 2010). It is also interesting to note due to local emissions. Similarly, NO2 also shows as that of SO2 expect
that the increase in O3 concentration with increase in temperature may during summer which is transporting from west side. The CO originates
not be valid after 313 K. A decrease is noticed in O3 concentration with slightly different from other pollutants. During winter and spring CO
increase in temperature during summer instead. This region provides a originates from northwesterly and south easterly part. Both PM2.5 and
very good opportunity to study the variation of O3 concentration in very PM10 represents different picture in their incoming source. During
high temperatures (318–323 K) in summer because a non-wash out of winter, PM2.5 and PM10 originates mostly from southeasterly whereas
pollutants due to lack of rainfall occurs (Ouarda et al., 2014). It should during spring it is from northwesterly part. The PM10 and PM2.5 depicts
also be noted that we did not observe any specific relationship between same source of origin during fall. It is also interesting to note that higher
RH and O3 concentration. Thus, it is clear that the relationship between (lower) concentrations of the pollutants and particulate matter seem to
O3 concentration and temperature is not straight forward; on the con­ be originating from northwesterly (southwesterly) directions, also pro­
trary it involves complex dynamical because it includes solar radiation, nounced in winter, and spring, though, with varying contribution per­
chemical reactions, and meteorological conditions for understanding the centages. On the other hand, summer and fall depict slightly contrasting
mixing/transport processer. picture showing dominant northwesterly (generally called as “Shamal
wind”) wind direction with less contribution from local emission sour­
4.6. Regional transport and source regions of pollutants ces. It is also worth mentioning that higher concentrations of the pol­
lutants and particulate matter are emanating from the same source
In order to get a clear picture about the plausible sources of the direction irrespective of the season.
pollutants observed over EAD, we have plotted concentration rose dia­
grams of the pollutants O3, SO2, NO2, CO (Fig. 10a–d) and PM2.5 and 5. Summary and concluding remarks
PM10 (Fig. 11a–d) for the four seasons. The pollutants are originating
from different sources during different seasons. In general, O3, SO2, NO2 1. In this study, the characteristics of O3 and its precursors with
shows dominances in northwesterly with different spatial distribution. special emphasis on particulate matter during the period 2011–2013
During winter, O3 originates completely from northwestern part were studied over the EAD region. The observations were grouped into
whereas in other seasons it originates western part (Fig. 10a-d). The SO2 two regions namely urban and rural, based on regional characteristics.

Fig. 10. Average concentration rose diagrams of O3 (a–d), SO2 (e–h), NO2 (i–l), and CO (m–p) four seasons over EAD in the period 2011–2013. The color bar
represents concentration. Each row of plots corresponds to a specific season and each column to a specific pollutant.

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D.V. Phanikumar et al. Journal of Atmospheric and Solar-Terrestrial Physics 199 (2020) 105217

Fig. 11. Average concentration rose diagrams of PM2.5 (a–d) and PM10 (e–h), four seasons over EAD in the period 2011–2013. The color bar represents concen­
tration. Each row of plots corresponds to a specific season and each column to a specific pollutant.

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This study has provided an insight into the existing levels of air pollution Akimoto, H., 2003. Global air quality and pollution. Science 302, 1716–1719. https:
//doi:10.1126/science.1092666.
and their sources over EAD. Diurnal variation of O3 shows maximum in
Basha, G., Ratnam, M.V., 2009. Identification of atmospheric boundary layer height over
the afternoon and minimum between 6LT and 9LT whereas NO2 shows a tropical station using high resolution radiosonde refractivity profiles: comparison
morning and evening peaks with a minimum at noon hours. Monthly with GPS radio occultation measurements. J. Geophys. Res. 114, D16101. htt
variations variation of O3 (NO2) show maximum (minimum) in June ps://doi:10.1029/2008JD011692.
Basha, G., Phanikumar, D.V., Kumar, K.N., Ouarda, T.B.M.J., Marpu, P.R., 2015a.
(August). The diurnal variation of SO2 shows a daytime maximum in all Investigation of aerosol optical, physical, and radiative characteristics of a severe
seasons in the urban region; however, the rural region shows different dust storm observed over UAE. Rem. Sens. Environ. https://doi.org/10.1016/j.
peaking time depending on the seasons. SO2 is maximum in winter rse.2015.08.033.
Basha, G., Ouarda, T.B.M.J., Marpu, P.R., 2015b. Long-term projections of temperature,
followed by spring, summer, and fall. The diurnal pattern of CO over the precipitation and soil moisture using non-stationary oscillation processes over the
urban region shows an interesting picture of higher levels during day­ UAE region. Int. J. Climatol. 35, 4606–4618.
time (9 LT) then decreases sharply reaching minimum around 16 LT and Basha, G., Kishore, P., Ratnam, M.V., Ravindra Babu, S., Velicogna, I., Jonathan, H.,
Jiang, Chi, Ao, O., 2018. Global climatology of planetary boundary layer top
starts increasing again reaching a maximum at 21 LT. The monthly obtained from multi-satellite GPS RO observations. Clim. Dynam. https://doi.org/
variation of SO2 and CO shows a steady behavior throughout the year 10.1007/s00382-018-4269-1, 1432-0894.
with a marginal maximum in March–June. The O3 increases with in­ Basha, G., Venkat Ratnam, M., Niranjan Kumar, K., Ouarda, T.B.M.J., Kishore, P.,
Velicogna, Isabella, 2019. Long-term variation of Dust episodes over the United Arab
crease in temperature up to 313 K then O3 decreases with further in­ Emirates. J. Atmos. Sol. Terr. Phys. 187 (2019), 33–39. https://doi.org/10.1016/j.
crease in temperature. The plausible reason for the observed jastp.2019.03.006.
discrepancies could be a combination of dominant photochemical re­ Beig, G., Brasseur, G.P., 2006. Influence of anthropogenic emissions on tropospheric
ozone and its precursors over the Indian tropical region during a monsoon. Geophys.
actions and strong wind persisting during the summer season (Lelieveld
Res. Lett. 33, L07808. https://doi: 10.1029/2005GL024949.
et al., 2009). PM2.5 is mainly influenced by local emissions (traffic and Chandran, A., Basha, G., Ouarda, T.B.M.J., 2015. Influence of climate oscillations on
other industrial activities) and shows a peak during daytime in winter temperature and precipitation over the United Arab Emirates. Int. J. Climatol.
and spring in the urban region as compared to the rural one. The sources https://doi: 10.1002/joc.4339.
Environmental Agency of Abu Dhabi, 2012. EAD’s Efforts in Improving Abu Dhabi
for PM10 are believed to be from desert dust and sea spray; they there­ Emirate’s Air Quality. A Magazine for the Environmental Center for Arab Towns.
fore present a minimum (maximum) in the urban (rural) region during Issue 3 (September).
daytime in fall and winter due to the prevailing meteorological condi­ Giavis, G.M., Kambezidis, H.D., Ly Koudis, S.P., 2009. Frequency distribution of
particular matter (PM10) in urban environments. Int. J. Environ. Pull. 36 (1,2,3),
tions. Monthly observations clearly show dominance of PM10 over the 99–109.
rural region peaking in May–June possibly indicating that the desert Guo, H., Jiang, F., Cheng, H.R., Simpson, I.J., Wang, X.M., Ding, A.J., Wang, T.J.,
dust is the predominant source for the high particulate matter concen­ Saunders, S.M., Wang, T., Lam, S.H.M., Blake, D.R., Zhang, Y.L., Xie, M., 2009.
Concurrent observations of air pollutants at two sites in the Pearl River Delta and the
tration over this region. The frequency distribution curves unveil facts implication of regional transport. Atmos. Chem. Phys. 9, 7343–7360.
based on the dominant peak (highest probability) and nature of peak Jacob, D.J., Logan, J.A., Gadner, G.M., Yevich, R.M., Spivakovsky, C.M., Wofsy, S.C.,
concentration in primary pollutants in the urban and rural regions. The 1993. Factors regulating ozone over the United States and its export to the global
atmosphere. Geophys. Res. 98, 14817–14826.
sources of these trace species are very complex and may be caused by Katheeri, E.A., Jallad, F.A., Omar, M.A., 2012. Assessment of gaseous and particulate
differing atmospheric conditions (see Fig- 8). pollutants in the ambient air in Al Mirfa city United Arab Emirates. J. Environ.
It is also interesting to observe that the values of Al Mirfa urban site Protect. 3, 640–647. https://doi.org/10.4236/jep.2012.37077, 2012.
Kchih, et al., 2015. Aerosol and air quality research, 15, 454–464. https://doi.org/
(Katheeri et al., 2012) are closely matching these of the rural region of
10.4209/aaqr.2014.10.0255.
our study. Apart from the above reasons, the other contributing factors Kumar, R., Naja, M., Pfister, G.G., Barth, M.C., Brasseur, G.P., 2013. Source attribution of
that could be responsible for the observed pollutant levels include carbon monoxide in India and surrounding regions during wintertime. J. Geophys.
locally generated (anthropogenic emission sources), long-range trans­ Res. Atmos. 118, 1981–1995. https://doi:10.1002/jgrd.50134.
Lelieveld, J., Hoor, P., Jockel, P., Pozzer, A., Hadjinicolaou, P., Cammas, J.P., Beirle, S.,
port (meteorological conditions), Stratosphere-Troposphere exchange 2009. Severe ozone air pollution in the Persian Gulf region. Atmos. Chem. Phys. 9,
processes, lack of convective mixing and precipitation and finally con­ 1393–1406.
ditions favorable for photochemical reactions affecting concentration of Li, Q., Jacob, D.J., Logan, J.A., Bey, I., Yantosca, R.M., Liu, H., Martin, R.V., Fiore, A.M.,
Field, B.D., Duncan, B.N., 2001. A tropospheric ozone maximum over the Middle
primary pollutants and thereby modifying the O3 concentration over this East. Geophys. Res. Lett. 28, 3235–3238.
region. In future, more coordinated and simultaneous efforts should be Lin, W., Xu, X., Ge, B., Liu, X., 2011. Gaseous pollutants in Beijing urban area during the
made to further reduce the levels of primary gas pollutants thereby heating period 2007–2008: variability, sources, meteorological, and chemical
impacts. Atmos. Chem. Phys. 11, 8157–8170. https://doi: 10.5194/acp-11-8157-
limiting the O3 concentration and understanding the source regions of 2011.
the primary pollutants, mixing and advection processes with prevailing Naja, M., Akimoto, H., Staehelin, J., 2003. Ozone in background and photochemically
meteorological conditions over the EAD region. aged air over central Europe: analysis of long-term ozonesonde data from
Hohenpeissenberg and Payerne. J. Geophys. Res. 108 (D2), 4063. https://doi: 10.10
29/2002JD002477.
Acknowledgements NRC (National Research Council), 1991. Rethinking the Ozone Problem in Urban and
Regional Air Pollution. National Academy Press, Washington, DC.
Ojha, N., Naja, M., Singh, K.P., Sarangi, T., Kumar, R., Lal, S., Lawrence, M.G., Butler, T.
The authors would like to thank the Environmental Agency of Abu
M., Chandola, H.C., 2012. Variabilities in ozone at a semi-urban site in the Indo-
Dhabi for providing the concentration of pollutants, and meteorological Gangetic Plain region: association with the meteorology and regional processes.
data during 2011–2013 reported in this study. The authors are indebted J. Geophys. Res. 117, D20301. https://doi.org/10.1029/2012JD017716.
to the Editor Professor Pancheva and two anonymous reviewers whose Ouarda, T.B.M.J., Charron, C., Niranjan Kumar, K., Marpu, P.R., Ghedira, H., Molini, A.,
Khayal, I., 2014. Evolution of the rainfall regime in the United Arab Emirates.
comments helped considerably improve the quality of the paper. J. Hydrol 514, 258–270.
Ran, L., Lin, W.L., Deji, Y.Z., La, B., Tsering, P.M., Xu, X.B., Wang, W., 2014. Surface gas
References pollutants in Lhasa, a highland city of Tibet – current levels and pollution
implications. Atmos. Chem. Phys. 14, 10721–10730. https://doi: 10.5194/acp-14-1
0721-2014.
Adamopoules, A.D., Kambezidis, H.D., Sipsas, A.B., 1996a. Meteorological factors that Ratnam, M.V., Basha, G., 2010. A robust method to determine global distribution of
influence O3 concentration in the Athens basin. Fresenius Environ. Bull. 5 (1–2), atmospheric boundary layer top from COSMIC GPS RO measurements. Atmos. Sci.
37–42. Lett. 11, 216–222. https://doi.org/10.1002/asl.277.
Adamopoules, A.D., Kambezidis, H.D., Sipsas, A.B., 1996b. Meteorological factors that Steiner, A.L., Davis, A.J., Sillman, S., Owen, R.C., Michalak, A.M., Fiore, A.M., 2010.
influence SO2 concentration in the Athens basin, Fres. Environ. Bull. 5 (5–6), Observed suppression of ozone formation at extremely high temperatures due to
270–275. chemical and bio-physical feedbacks. Proc. Natl. Acad. Sci. 107 (46), 19685–19690.
Adamopoules, A.D., Kambezidis, H.D., Sipsas, A.B., 1996c. Meteorological factors that https://doi:10.1073/pnas.1008336107.
influence CO concentration in the Athens basin. Fresenius Environ. Bull. 5 (5–6),
351–356.

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