Translated from French to English - www.onlinedoctranslator.

com

Revision date: 29/10/2019 Revision: 1.0

SAFETY DATA SHEET BELZONA® 4301

(MAGMA CR1 HI-BUILD) BASE

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product Name BELZONA® 4301 (MAGMA CR1 HI-BUILD) BASE

Product number SN2942

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses For reconstruction and profiling of surfaces subject to chemical attack. For industrial use
only.

Uses advised against The product should not be used for purposes other than those recommended in the relative
instructions for use.

1.3. Details of the supplier of the safety data sheet

Supplier Belzona Polymerics Limited

Claro Road, Harrogate
HG1 4DS
United Kingdom
+ 44 1423 567641
sds@belzona.com

Maker Belzona Polymerics Limited

Claro Road, Harrogate
HG1 4DS
United Kingdom
+ 44 1423 567641
sds@belzona.com

1.4. Emergency number

Emergency number + 33 1 45 42 59 59 (24 hours a day, 7 days a week)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC N° 1272/2008)
Physical hazards Unclassified

Human Health Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317
Hazards

Environmental hazardsAquatic Chronic 2 - H411

Reference The full text for all hazard statements is displayed in section 16.

2.2. Label elements

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Hazard pictograms

Signal word Attention

Hazard statements H315 Causes skin irritation. H319 Causes

serious eye irritation. H317 May cause an
allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements P273 Avoid release to the environment.

P280 Wear protective gloves, protective clothing, eye protection.

P501 Dispose of contents/container according to national regulations.

Contains EPOXY RESINS (AVERAGE MOLECULAR WEIGHT <= 700), EPOXY PHENOL NOVOLAC RESIN,
EPOXY-BISPHENOL F RESIN

2.3. Other hazards

Not applicableAccording to the information sent by our suppliers, no persistent, bio-accumulating and toxic substances
(PBT) nor very persistent and very bio-accumulating substances (vPvB).

SECTION 3: Composition/information on ingredients

3.2. Blends

EPOXY RESINS (AVERAGE MOLECULAR WEIGHT <= 700) 10-30%

CAS number: 25068-38-6 EC number: 500-033-5 REACH registration number: 01-

2119456619-26-xxxx

Classification
Skin Irrit. 2 - H315 Eye Irrit.
2 - H319 Skin Sens. 1 -
H317 Aquatic Chronic 2 -
H411

EPOXIDE PHENOL NOVOLAC RESIN 10-30%

CAS number: 28064-14-4 EC number: 500-108-2 REACH registration number: 01-

2119454392-40-XXXX

Classification
Skin Irrit. 2 - H315 Eye Irrit.
2 - H319 Skin Sens. 1 -
H317 Aquatic Chronic 2 -
H411

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EPOXY-BISPHENOL F RESIN 5-10%

CAS number: 9003-36-5 REACH registration number: 01-

2119454392-40-xxxx

Classification
Skin Irrit. 2 - H315 Eye Irrit.
2 - H319 Skin Sens. 1 -
H317 Aquatic Chronic 2 -
H411

GLYCIDOXYPROPYLTRIMETHOXYSILANE 1-5%
CAS number: 2530-83-8 EC number: 219-784-2

Classification
Eye Dam. 1 - H318

The full text for all hazard statements is displayed in section 16.

SECTION 4: First aid

4.1. Description of first aid

General Information If in doubt, or if symptoms persist, please consult a doctor. Never give anything by mouth
to an unconscious person.

Inhalation Get out into the fresh air. Make sure the patient is warm and in a quiet place. Don't give him
anything to swallow.

Ingestion If the product is accidentally swallowed, consult a doctor immediately. Rest the patient.
Rinse his mouth thoroughly with water. Do NOT force him to vomit.

Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water or use a
specialized skin cleanser. NEVER use solvents or thinners. If irritation or inflammation
persists, please seek medical attention.

Eye contact Remove contact lenses. Flush eyes with plenty of cool, clean water for at least 15 minutes,
keeping eyelids wide open, and seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact Prolonged or repeated contact with the skin or mucous membrane may give rise to
irritating symptoms such as redness, blisters or dermatitis. The onset of symptoms may be
delayed. May cause allergic skin reaction.

Eye contact Irritating to eyes.

4.3. Indication of any immediate medical attention and special treatment needed

Indications for the doctor None.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Extinguishing media Use: sand, alcohol-resistant foam, carbon dioxide, dry chemical, water mist for larger
appropriate fires.
NEVER use a water jet.

5.2. Special hazards arising from the substance or mixture

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Combustion products In the event of a fire, hazardous decomposition products may be formed, such as smoke,
dangerous carbon monoxide and carbon dioxide.

5.3. Tips for firefighters

Protective measures to Fire will produce thick black smoke containing hazardous combustion products. Exposure to
take when fighting a fire decomposition products may present a medical hazard. You may need to use an appropriate
self-contained breathing mask. Cool sealed containers exposed to fire with water spray.
Prevent runoff from fire hoses from entering drains or waterways.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Individual precautions Remove non-essential personnel. Avoid contact with skin and eyes.

6.2. Environmental Precautions

Environmental Precautions Prevent accidental spills from entering drains and sewers. If large quantities of the product
flow into drains or sewers, contact the local Water Company immediately; or, in the event of
contamination of a stream, river or lake, the appropriate national control authorities.

6.3. Methods and material for containment and cleaning up

Cleaning methods Scrape up most of the product and put it in an appropriately labeled container. Cover spill
area with sand or other inert material then sweep up and pour into container. Clean the
surfaces with a mixture of water and detergent. Ensure that product spills or associated wash
water do not enter drains or waterways.

6.4. Reference to other topics

Reference to other sections For personal protective equipment, see Section 8. For disposal information, see
section 13. .

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions
Vapors may accumulate in container headspace during transit or prolonged storage. Avoid
inhalation of vapors when opening container. Whenever possible, open containers and mix
components in a well-ventilated room away from the area of application. Avoid contact with
skin and eyes or clothing. Prohibit the consumption of food and drink, as well as cigarettes in
storage and use areas. For personal protection, see Section 8. Always keep containers of the
same material as the supply container in stock. Good housekeeping practices should be
followed as well as regular and safe disposal of waste. FIRE/EXPLOSION This product is
combustible. Eliminate all sources of heat, sparks or open flame.

General advice on
occupational hygiene
Wash at the end of each work period and before eating, smoking and using the toilet. Make
sure that the means necessary for an eye wash (fountain, bottle, flask, etc.) are easily
accessible. Never put contaminated items or materials, e.g. spatulas, applicators, brushes,
rags, etc., in his pockets. When necessary, contaminated work clothes and shoes should be
removed to avoid cross-contamination of surfaces, the risk of unintentional skin contact and
ingestion.

7.2. Conditions for safe storage, including any incompatibilities

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Storage precautions
Follow label precautions. Store between 5°C and 30°C unless otherwise specified, in a dry,
well-ventilated place, away from heat sources, flammable sources and direct sunlight. No
Smoking. Prevent unauthorized access. Keep away from oxidizers and strongly alkaline and
strongly acidic materials. STORAGE PRECAUTIONS TO PROTECT THE ENVIRONMENT
Accidental spills, improper storage of chemicals, waste or improper waste disposal activities
can cause pollutants to seep into the ground and seriously harm the ground water table
which is a vital source for drinking water. All waste, especially liquid waste, must be stored on
site,

7.3. Specific end use(s)

Specific end use(s) Application using the plastic applicator provided. Mix with the Hardener component before
use. For more information please refer to the appropriate Belzona® User Guide.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limit values
No exposure limit value known for component(s).

EPOXY RESINS (AVERAGE MOLECULAR WEIGHT <= 700) (CAS: 25068-38-6)

DNELs Workers - Dermal; Short term systemic effects: 8.3 mg/kg Workers - Inhalation;
Short term systemic effects: 12.3 mg/m³ Workers - Dermal; Long term systemic
effects: 8.3 mg/kg Workers - Inhalation; Long term systemic effects: 12.3 mg/m³
General population - Dermal; Short term systemic effects: 3.6 mg/kg General
population - Inhalation; Short term systemic effects: 0.75 mg/m³ General
population - Oral; Short term systemic effects: 0.75 mg/kg General population -
Dermal; Long term systemic effects: 3.6 mg/kg General population - Inhalation;
Long term systemic effects: 0.75 mg/m³ General population - Oral; Long term
systemic effects: 0.75 mg/kg

PNECs pure water; 0.003 mg/l sediment

(freshwater); 0.5 mg/kg sea water;
0.0003mg/l
Sediments (sea water); 0.5 mg/kg
intermittent release; 0.013mg/l
Wastewater treatment plant; 10 mg/l
sediment; 0.05mg/kg

EPOXY-BISPHENOL F RESIN (CAS: 9003-36-5)

DNELs Workers - Dermal; Short term local effects: 0.0083 mg/cm² Workers - Dermal;
Long term systemic effects: 104.15 mg/kg bw/day Workers - Inhalation; Long
Term Systemic Effects: 29.39 mg/m³ Consumer - Dermal; Long term systemic
effects: 62.5 mg/kg bw/day Consumer - Inhalation; Long term systemic effects:
8.7 mg/m³ Consumer - Oral; Long term systemic effects: 6.25 mg/kg bw/day

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PNECs pure water; 0.003 mg/l sediment

(freshwater); 0.294 mg/kg sea water;
0.0003mg/l
Sediments (sea water); 0.0294 mg/kg
intermittent release; 0.0254mg/l
Wastewater treatment plant; 10 mg/l Soil;
0.237mg/kg

ZIRCONIUM OXIDE (CAS: 1314-23-4)

DNELs Workers - Dermal; Long term systemic effects: 15.75 mg/kg bw/day Workers -
Inhalation; Long term systemic effects: 5 mg/m³
General population - Oral; Long term systemic effects: 7.9 mg/kg bw/day General
population - Inhalation; Long term systemic effects: 2.5 mg/m³ General population
- Dermal; Long term systemic effects: 7.9 mg/kg bw/day

8.2. Exposure controls

Technical checks Open containers in a well-ventilated area.

appropriate

Eye/face protection Wearing eye protection such as safety glasses or goggles is recommended while handling
and using this material. Eye protection should be selected in accordance with EN 166
Personal eye protection. During subsequent machining, grinding, abrading or removal of
this product appropriate eye protection should be selected based on the type of tools or
equipment being used.

Hand protection Hand protection should be selected in accordance with EN 374 Protective gloves against
chemical hazards. The puncture-free life of the selected gloves should be longer than the
expected time of use. In any case, if this is not possible, the gloves must be changed in time
and in any case before the breakthrough-free life is exceeded. If in doubt, seek advice from
the glove supplier, for the different types of gloves to consider. You can use barrier creams to
reinforce the protection of certain skin areas exposed to the product, but they cannot
completely replace physical protection. Do not apply these creams after skin exposure.
SPECIFIC RECOMMENDATIONS Wear protective gloves made of the following material:
Neoprene. Nitrile rubber. STANDARD APPLICATIONS Medium-heavyweight gauntlet gloves
offering adequate wrist protection. EMERGENCY REPAIRS OR SINGLE UNIT APPLICATION
Lightweight, disposable gloves are usually adequate.

Other skin and body STANDARD APPLICATIONS Synthetic polyethylene coverall such as Tyvek PRO-TECH® or
protection equivalent coverall manufactured to EN 13034 Type 6, Protective clothing against liquid
chemicals Type 6. In case of extreme contamination of clothing, remove clothing and wash
the skin with soap and water, or a specialized skin cleanser. EMERGENCY REPAIRS OR SINGLE
UNIT APPLICATION Cotton coveralls are normally adequate.

Respiratory protection Respiratory protection is not normally required, but the potential hazards of the Hardener
component should be considered for mixing and application purposes.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Aspect Dough.

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Color Red.

Smell Epoxy resin.

Odor threshold Not applicable.

pH Not applicable.

Fusion point Not available.

Initial boiling point and >200°C/>392°F @ 760mmHg

boiling range

Flash point > 200°C/>392°F Closed cup.

Evaporation rate Not available.

Flammability (solid, gas) Not applicable.

Boundaries Not applicable.

upper/lower
flammability or
explosive limits

Vapor pressure <0.0001kPa @ 20°C/68°F

Vapor density >1

Relative density 1.45 - 1.55 @ 20°C/68°F

Solubility(ies) Immiscible with water.

Partition coefficient Not available.

Self-temperature Not available.

flammability

Temperature of 200°C/392°F
decomposition

Viscosity Technical impossibility.

Explosive properties Not applicable.

Oxidizing properties Not applicable.

9.2. Other information

Other information This section contains only typical values relating to health, safety and environmental
guidance and is not intended to represent technical documentation for the product.

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity No known reactivity hazards associated with this product.

10.2. Chemical stability

Chemical stability Stable if the storage and handling conditions are respected (see Section 7).

10.3. Possibility of hazardous reactions

Possibility of No hazardous reactions expected when stored and handled as recommended.

hazardous reactions

10.4. Conditions to Avoid

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Conditions to Avoid There are no known conditions which are likely to result in a hazardous situation.

10.5. Incompatible materials

Incompatible materials Keep away from oxidants and strongly alkaline and strongly acidic materials to avoid the
possibility of an exothermic reaction.

10.6. Hazardous decomposition products

Decomposition products Does not break down used or stored as recommended.

dangerous

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
Indications (Oral LD₅₀) Based on available data, the classification criteria are not met.

Acute Toxicity - Dermal

Indications (dermal LD₅₀) Based on available data, the classification criteria are not met.

Acute toxicity - inhalation

Indications (LC₅₀ inhalation) Based on available data, the classification criteria are not met.

Skin corrosion/irritation Animal

data Irritating to skin.

Serious eye damage/eye irritation

Eye damage Irritating to eyes.
serious/eye irritation

Respiratory sensitization
Respiratory sensitization Based on available data, the classification criteria are not met.

Skin sensitization
Skin sensitization Based on the characteristics of the epoxy component(s) and the toxicological data of identical
preparations, it is possible that this preparation is a skin sensitiser. Repeated skin contact may
cause sensitization and cross-sensitization to other epoxy resins.

Germ cell mutagenicity

Genotoxicity testing - in Based on available data, the classification criteria are not met. vitro

Genotoxicity testing - in Based on available data, the classification criteria are not met.
vivo

Carcinogenicity
Carcinogenicity Based on available data, the classification criteria are not met.

Carcinogenicity IARC Unlisted.

Carcinogenicity NTP Unlisted.

Reproductive toxicity
Reproductive toxicity - Based on available data, the classification criteria are not met.
fertility

Reproductive toxicity -Based on available data, the classification criteria are not met. development

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Specific target organ toxicity — single exposure

Single exposure STOT one Based on available data, the classification criteria are not met.

Specific target organ toxicity — repeated exposure Repeated

exposure STOT resp. Based on available data, the classification criteria are not met.

Aspiration hazard
Aspiration hazard Based on available data, the classification criteria are not met.

Route of exposure Skin and/or eye contact.

Medical Considerations Skin contact is a significant risk. People who have had skin sensitization problems in the past
should only work with processes for which the product is used under appropriate medical
supervision.

Toxicological information on components

EPOXY RESINS (AVERAGE MOLECULAR WEIGHT <= 700)

Toxicological effects Repeated skin contact may lead to sensitization with possibly cross-sensitization to other
epoxies. In rare cases, low molecular weight liquid epoxy resins can cause an allergic
respiratory reaction like asthma, based on limited human information. The evidence

available is not however, considered to fall within the classification criteria as laid out
within the OSHA Hazard Communication Standard nor the Controlled Products
Regulations.

EPOXIDE PHENOL NOVOLAC RESIN

Toxicological effects Repeated skin contact may lead to sensitization with possibly cross-sensitization to
other epoxies.

SECTION 12: Ecological information

Ecotoxicity There is no data on the product itself. The following information is provided based on
available data on the individual components.

12.1. Toxicity

Toxicity Based on the content of epoxy resin (average molecular weight <=700) and epoxy phenol
novolak resin, this product is expected to have experimental LC50/EC50/IC50 values
between 1 and 10 mg/l for most sensitive species.

12.2. Persistence and degradability

Persistence and degradability Based on the content of epoxy resin (average molecular weight <=700) and epoxy phenol
novolak resin, this product is not expected to be readily biodegradable according to
OECD/EC guidelines.

12.3. Bioaccumulative potential

Bioaccumulative potential Based on epoxy resin (average molecular weight <=700) and epoxy phenol novolak
resin content, this product is expected to bioaccumulate.

Partition coefficient Not available.

12.4. Mobility in soil

Mobility No data available on the product itself.

12.5. Results of PBT and vPvB assessment

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Results of PBT and vPvB Not applicableAccording to the information sent by our suppliers, no persistent, bio-
assessment accumulating and toxic substances (PBT) nor very persistent and very bio-accumulating
substances (vPvB).

12.6. Other Adverse Effects

Other Adverse Effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods Do not allow to enter drains or water courses and do not dispose of in places where surface water and ground water could be

contaminated. Controlled waste includes non-hazardous industrial waste and hazardous chemical waste. Disposal of all controlled

waste should be in accordance with appropriate local and national regulations. In addition, hazardous chemical waste must be

disposed of in accordance with national regulations established under Council Directives 75/442/EEC on waste and 91/689/EEC on

hazardous waste. If in doubt about the information in this safety data sheet, advice should be sought from the appropriate national

control authorities for methods of correct elimination. TRANSIT PACKAGING COMPONENT DISPOSAL: Protective shrink wraps or

stretch wraps, crates and accessories that have not been contaminated with the product should be reused or recycled. UNREACTED

PRODUCT and uncleaned empty containers and contaminated packaging should be disposed of as hazardous chemical waste.

REACTED PRODUCT, contaminated mixing boards, spatulas, applicators, brushes, theoretically empty containers and mixing bowls -

when completely dried - should be disposed of in the same manner as non-hazardous products. have not been contaminated by the

product must be reused or recycled. UNREACTED PRODUCT and uncleaned empty containers and contaminated packaging should

be disposed of as hazardous chemical waste. REACTED PRODUCT, contaminated mixing boards, spatulas, applicators, brushes,

theoretically empty containers and mixing bowls - when completely dried - should be disposed of in the same manner as non-

hazardous products. have not been contaminated by the product must be reused or recycled. UNREACTED PRODUCT and uncleaned

empty containers and contaminated packaging should be disposed of as hazardous chemical waste. REACTED PRODUCT,

contaminated mixing boards, spatulas, applicators, brushes, theoretically empty containers and mixing bowls - when completely

dried - should be disposed of in the same manner as non-hazardous products.

Waste class Waste code list: 08 04 09* * Hazardous waste according to Directive 91/689/EEC. The code
shown in this section is general input. Codes should be assigned based on the end use of the
product. If there is a more specific code, this should be used in preference to the above code.
If in doubt, check the hazardous waste list, your local approved waste recycling center or the
national control agency.

SECTION 14: Transport information

General Labeling and packaging requirements may vary depending on the type of load and
packaging. Please see current shipping guidelines. Transport within user's premises: always
transport in airtight, upright containers. Make sure those transporting the product know the
procedures to follow in the event of an accident or accidental spillage.

14.1. UN number

UN number (ADR/RID) 3082

UN number (IMDG) 3082

UN number (ICAO) 3082

14.2. UN Proper Shipping Name

Shipping Name (ADR/RID) Environmentally hazardous substance, liquid, nos contains Epoxy resins

Shipping Name (IMDG) Environmentally hazardous substance, liquid, nos contains Epoxy resins

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Shipping Name (ICAO) Environmentally hazardous substance, liquid, nos contains Epoxy resins

14.3. Transport hazard class(es)

ADR/RID class 9

IMDG-class 9

ICAO class/division 9

14.4. Packing group

Packing group III

(ADR/RID)

Packing group (IMDG) III

Packing group (ICAO) III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

Yes. Labeling requirements vary depending on the net hazardous quantity. Please see current shipping guidelines.

14.6. Special precautions for user

Not applicable.

14.7. Bulk transport in accordance with Annex II of the Marpol Convention and the IBC Code

Bulk transport Goods not transported in bulk.

in accordance with appendix II of
the Marpol 73/78 convention and
the IBC code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations OCCUPATIONAL ILLNESSES See Table of

Occupational Illnesses 51.

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labeling and packaging of substances and mixtures, as
amended.
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December
2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemical
Substances (REACH), establishing a European Agency chemicals, amending Directive 1999/45/
EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No
1488/94 and Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC,
93/105/EC and 2000/21/EC, as amended. In accordance with Regulation (EC) No 453/2010.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

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General Information
The information included in this safety data sheet does not constitute the user's personal
assessment of the risks incurred in the workplace, and required by other health and safety
legislation. As the specific conditions of use are beyond the supplier's control, the user is
responsible for enforcing the appropriate measures required by national legislation. The
information included in this safety data sheet is based on current knowledge and current
national legislation. The advice provided by it deals with health, safety and the environment
in relation to the product, and does not in any way constitute a guarantee of the technical
performance or the capacity of the product for particular uses. .

Key Literary References .......

and Data Sources

Classification procedures Where there is no test data available for the mixture, the classification has been determined
according to Regulation (EC) based on the hazard data of the individual components in accordance with EC 1272/2008.
No 1272/2008

Training tips For further information, contact your supplier, your Belzona sales representative or Belzona
directly.

Review Comments New wording. Please note the REVISION DATE. If the Safety Data Sheet you are reading is
more than 24 months old or if you have any doubts about its validity, please contact your
local Belzona consultant or Belzona directly (sds@belzona.com ) . Updated information will
be sent to you.

Revision date 29/10/2019

Revision 1.0

SDS number 41253

SDS Status French. Approved.

Hazard statements in full
H315 Causes skin irritation. H317 May cause
an allergic skin reaction. H318 Causes serious
eye damage. H319 Causes serious eye
irritation.
H411 Toxic to aquatic life with long lasting effects.

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