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Jmat

Journal of Advanced and High-Performance Materials


for the building and infrastructure community
An official publication of the National Institute of Building Sciences
Advanced Materials Council

Winter 2011

The Next Wave of Innovation


ADVANCED MATERIALS COUNCIL
Advanced materials are building-and infrastructure-related materials that exhibit high-performance attributes
but have not reached widespread application in the commercial marketplace.
High-performance attributes include enhanced security, safety, resiliency, energy conservation, environmental
sustainability, durability, cost effectiveness, functionality, productivity and maintainability.
MEMBERS:
Younane Abousleiman Gary Fischman Long Phan
University of Oklahoma National Research Council National Institute of Standards and
Technology, Building and Fire Research
Akmal Ali John Fortune Laboratory, Materials and Construction
U.S. Department of Homeland Security U.S. Department of Homeland Security Research

Steven McKnight Lee Glascoe Martin Savoie


National Science Foundation Lawrence Livermore National Laboratory U.S. Army Corps of Engineers, Engineering
Research and Development Center,
Blaine Brownell William Grosshandler
Construction Engineering Research
University of Minnesota National Institute of Standards and Technology,
Building and Fire Research Laboratory Laboratory
Kathryn Butler Bogdan Srdanovic
National Institute of Standards and Clint Hall
Sandia National Laboratory APS Consulting
Technology, Building and Fire
Research Laboratory, Fire Research
Division Don Hicks Mary Toney
U.S. Army Corps of Engineers, Engineering National Science Foundation
Terry Butler Research and Development Center,
U.S. Department of Homeland Security Construction Engineering Research Jeffrey Urban
Laboratory Lawrence Berkeley National Laboratory
Alexander Cheng
University of Mississippi Mary Ellen Hynes M Vallett
U.S. Department of Homeland Security Port Authority of New York & New Jersey
Thomas Coleman
U.S. Department of Homeland Security
Mila Kennett Catlin Van Roon
U.S. Department of Homeland Security U.S. Department of Homeland Security
Tod Companion
U.S. Department of Homeland Security
William Koch John Voeller
Defense Threat Reduction Agency
Black & Veatch
Fernando Cortez-Lira Ashok Kumar
Analytical Research, LLC U.S. Army Corps of Engineers, Engineering John Jy-An Wang
Research and Development Center, Oak Ridge National Laboratory
Bruce Davidson Construction Engineering Research Laboratory
U.S. Department of Homeland Security Andrea Watson
Sean Lang National Renewable Energy Laboratory
Shane Davis U.S. Department of Homeland Security
U.S. Department of Homeland Security Michael Werner
Victor Li MBDC
Beverly DiPaolo University of Michigan
U.S. Army Corps of Engineers, Engineering Jack Wise
Research and Development Center, William Luecke Sandia National Laboratory
Construction Engineering Research National Institute of Standards and
Laboratory Technology, Metallurgy Division George Zipperer
Defense Threat Reduction Agency
Chris Doyle Philip Mattson
U.S. Department of Homeland Security U.S. Department of Homeland Security Abdul Zureick
Robert Dye Georgia Institute of Technology
Delia Milliron
Los Alamos National Laboratory Lawrence Berkeley National Laboratory
STAFF:
Mitchell Erickson Yellapu Murty Earle Kennett
U.S. Department of Homeland Security Cellular Materials International, Inc. National Institute of Building Sciences

Mohammed Ettouney Laura Parker Drew Rouland


Weidlinger Associates, Inc. U.S. Department of Homeland Security National Institute of Building Sciences

Christopher Featherston Roland Pellenq Bob Payn


U.S. Department of Homeland Security Massachusetts Institute of Technology db Interactive

2 Journal of Advanced and High-Performance Materials


Contents

Jmat
Features:
8 Advanced and High-
Performance Materials
Program
Published for:
The National Institute of Building Sciences
11 An

22
Advanced Materials Council Advanced Materials
1090 Vermont Avenue, NW, Suite 700
Washington, DC 20005-4950 Database: A Gateway
Phone: (202) 289-7800 for Future and Secure
Fax: (202) 289-1092
nibs@nibs.org Infrastructures
www.nibs.org

PRESIDENT 16 High-Ductility Concrete for CFRP Strengthening


Henry L. Green, Hon. AIA Resilient Infrastructure Systems
SENIOR VICE PRESIDENT
Earle Kennett
22 Carbon Fiber-Reinforced
Published By:
Matrix Group Publishing Inc.
Polymer Strengthening for
Alternate Load Paths to
27 Evolution of Elastomeric
Retrofits for Concrete
Return undeliverable copies to:
5190 Neil Road, Suite 430 Mitigate Progressive Collapse Masonry Unit Walls for
Reno, NV 89502 Vulnerabilities Enhanced Blast Resistance
Tel: (204) 953-3120
Toll free: (866) 999-1299 at the Engineer Research and
Fax: (866) 244-2544 Development Center

31
Email: sales@matrixgroupinc.net

31 Emergent
Web: www.matrixgroupinc.net
Materials for
President & CEO
Jack Andress
Security, Energy and the
Environment
Senior Publisher
Maurice LaBorde Emergent
mlaborde@matrixgroupinc.net
Materials
Publishers
Peter Schulz
Jessica Potter
Trish Bird

Editor-in-Chief
Shannon Savory
ssavory@matrixgroupinc.net

Editor
Karen Kornelsen Messages:
Finance/Accounting & Administration
Shoshana Weinberg, Nathan Redekop,
Pat Andress
05 Message from the Institute President
Henry L. Green
accounting@matrixgroupinc.net

Director of Marketing & Circulation


Shoshana Weinberg 07 Message from the U.S. Department
of Homeland Security, Science and
Sales Manager Technology Directorate, Homeland
Neil Gottfred
Security Advanced Research Projects
Matrix Group Inc. Account Executives Agency (HSARPA) Acting Director
Rick Kuzie, Miles Meagher, Ken Percival, Lesley
Dion, Graeme Muirhead, Brian Davey, Jim Christopher Doyle
Hamilton, Chris Frenza, Andrew Ducharme,
Declan O’Donovan, Jeff Cash, Dawn Russell, On the cover:
Colleen Bell, Susann Coston
The challenge facing researchers
Layout & Design will be to develop advanced ma-

16
Travis Bevan terials that will protect buildings
from natural and manmade di-
Advertising Design sasters while allowing designers
James Robinson to meet aesthetic, energy perfor-
mance and sustainability goals.
©2011 Matrix Group Publishing Inc. All rights
reserved. Contents may not be reproduced by
any means, in whole or in part, without the High-Ductility
prior written permission of the publisher. The
opinions expressed in this publication are not
necessarily those of Matrix Group Publishing Inc.
Concrete
Winter 2011 3
Message from the National Institute of Building Sciences

Over the years, the nation has seen an increased need to


address security issues facing our buildings and structures.
We need to accomplish this while keeping in mind the
ramifications security can impose on the emergency egress
from buildings and how other attributes must not be lost in
the whole realm of achieving high-performing buildings.

Henry L. Green, Hon. AIA

It is truly an honor to introduce JMAT joins our family of journals, constructors and building owners in
the inaugural issue of the Journal of Ad- alongside the Journal of Building Enclo- the design, construction and occupan-
vanced and High-Performance Materi- sure Design and the Journal of Building cy of buildings and structures. The Na-
als for the building and infrastructure Information Modeling, to provide a full tional Institute of Building Sciences is
community (JMAT). We at the National range of discussions on how to improve dedicated to the research and advance-
Institute of Building Sciences are excit- the building process and achieve high- ment of technology to improve the built
ed to work with the U.S. Department of er performing buildings. environment. The Institute was creat-
Homeland Security (DHS) in the devel- The Department’s interest in advanced ed for this very purpose—to support
opment of this publication. DHS is a vi- materials that assist in the develop- building research and the technologi-
tal leader in securing our nation’s built ment of more resilient buildings is evi- cal development of advances in build-
environment. dent by their support for the Advanced ing science and the promotion of such
At the beginning of 2010, the Insti- Materials Council. The DHS Science advances through the dissemination of
tute established an Advanced Materi- and Technology Directorate  (S&T) In- information and the promulgation of
als Council consisting of members from frastructure Protection and Disaster standards to improve the built environ-
national laboratories, university re- Management Division’s (IDD) mission ment.
search centers, DHS and other feder- to improve and increase the nation’s Matching the nation’s security needs
al agency programs, the private sector, preparedness for and response to nat- with achieving sustainability, durabili-
and international research programs. ural and man-made threats through ty and having a sense of the impact on
The purpose of the Council is to create superior situational awareness, emer- environmental concerns must be ad-
and maintain an interactive Advanced gency response capabilities and crit- dressed in a comprehensive manner
and High-Performance Materials Da- ical infrastructure protection is one rather than a singular focus. The ma-
tabase, which will allow for the overall that is closely aligned with the Insti- terials outlined in the coming issues of
coordination and development of ad- tute’s mission to serve the nation by this publication will provide a basis for
vanced and high-performance materi- supporting advances in building sci- this overarching view of matching the
als research. ence and technology to improve the needs for security with all of the attri-
Over the years, the nation has seen built environment. Together our col- butes needed in achieving total high
an increased need to address security lective efforts will work to achieve our performance.
issues facing our buildings and struc- mutual goals. We at the Institute hope you find
tures. We need to accomplish this while The scope of this publication is the new Journal of Advanced and High-
keeping in mind the ramifications se- ideally suited to support developing Performance Materials for the building
curity can impose on the emergency solutions, modeling and simulation and infrastructure community (JMAT)
egress from buildings and how other at- tools, and reach back capabilities to a helpful and educational resource. We
tributes must not be lost in the whole improve federal, state, local, tribal and would love to get your feedback and
realm of achieving high-performing private sector preparedness for and re- find out what you think. Please send us
buildings. sponse to all-hazards events impacting an email at nibs@nibs.org.
JMAT will serve as a resource on ma- the U.S. population and critical infra-
terials used in the built environment to structure. Happy reading!
achieve resilience, integration and du- This important new informa-
rability, while providing security as a tion source will provide an addition- Henry L. Green, Hon. AIA
hallmark of high-performing buildings. al resource for architects, engineers, President

Winter 2011 5
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Message from the U.S. Department of Homeland Security

The need to protect critical infrastructure from natural and


manmade disasters and the commitment to making the
federal building stock more secure, energy efficient, and
environmentally sustainable are not separate or mutually
exclusive tasks. They are interconnected by the integrated
design process, which describes the linkages among
project design objectives.
Christopher Doyle

There are amazing things natural and manmade disasters and We anticipate that some of the materi-
happening in the world of advanced the commitment to making the federal als that will populate the Advanced and
materials for buildings and infrastruc- building stock more secure, energy effi- High-Performance Materials Database
ture. One enormous boon for our com- cient, and environmentally sustainable will protect key infrastructures and fa-
munity is the comprehensive Advanced are not separate or mutually exclusive cilities in ways that will provide conti-
and High-Performance Materials Data- tasks. They are interconnected by the nuity of operations during a disruptive
base, developed by the U.S. Department integrated design process, which de- event and provide long-term durability.
of Homeland Security (DHS) Science scribes the linkages among project de- In November, DHS hosted the “De-
and Technology Directorate (S&T) and sign objectives. To achieve the goal of signing for a Resilient America: A Stake-
managed by the National Institute of zero-net-energy federal buildings by holder Summit on High Performance
Building Sciences (NIBS). This data- 2030—as prescribed in Executive Or- Resilient Buildings and Related Infra-
base enables builders and designers der 13514—we will need new materi- structure.” This Summit, held in the na-
to search for materials based on their als and products not yet on the market. tion’s capital, brought representatives
physical performance attributes and Likewise, to make our buildings more from Federal, State and local agencies;
appearance, compliance with applica- secure, we will need new materials that associations; and private industry to ad-
ble testing standards, and SAFETY Act are stronger, lighter, and more cost- dress this important topic. To contin-
certification. The SAFETY Act provides effective than we now have. It makes ue the conversation, the Institute’s next
important legal liability protections for sense to develop new materials that edition of JMAT will focus specifically
providers of Qualified Anti-Terrorism meet both goals—for the new buildings on resiliency.
Technologies. we construct over the next 20 years, and The DHS Science & Technology Di-
Many significant activities have oc- for the renovation of our existing build- rectorate is interested in developing
curred since DHS began working with ings that will remain in use for many an Infrastructure Resilience Program.
NIBS. Together, we held the first ever Se- years to come. For it to be valuable to all of us, the SEE
curity, Energy, and Environmental (SEE) DHS and NIBS are also focused on Summits, Council meetings and sym-
Summit in 2009. In 2010, we convened the need for resilience in our critical in- posiums must be successful and the
two meetings of the Advanced Materi- frastructure and key resources (CIKR). database must be useful and compre-
als Council, kicked off the development The National Infrastructure Adviso- hensive. Your participation will go a long
of the Advanced and High-Performance ry Council (NIAC) defines infrastruc- way in helping us achieve our goals.
Materials Database, hosted a Resilien- ture resilience as: “the ability to reduce
cy Summit and held our first Advanced the magnitude and/or duration of dis- Christopher Doyle
Materials Symposium. ruptive events. The effectiveness of a Acting Director, Homeland Security
There are compelling reasons for resilient infrastructure or enterprise Advanced Research Projects Agency
DHS’s interest in the DHS/NIBS Ad- depends upon its ability to anticipate, (HSARPA)
vanced Materials Program. The need absorb, adapt to, and/or rapidly recov- U.S. Department of Homeland Security
to protect critical infrastructure from er from a potentially disruptive event.” Science and Technology Directorate

Winter 2011 7
Feature

Advanced and High-Performance


Materials Program
By Mila Kennett, Program Manager, U.S. Department of Homeland Security,
Science and Technology Directorate, Infrastructure Protection and Disaster Management Divison

When pioneer Joseph Goodrich 1999). The Kendall building, which was Advanced and High-Preformance Ma-
decided in 1844 to build his house in constructed immediately following the terials Program. Its main objective is to
Milton, Wisconsin, his quest for du- conflagration, is considered the ear- mobilize the research and development
rability and sturdiness seems to have liest fireproofed building in the Unit- community and to bring together the de-
been motivated, among other things, ed States because for the first time, the sign and engineering experts, building
by a concern about the potential re- builders protected the structural ele- and infrastructure owners and operators,
peat of the local native warriors’ incen- ments with terracotta tile, a material advanced materials researchers, technol-
diary raids that had troubled the area still used today for this purpose. ogy providers and first responders within
during the Black Hawk War of the pre- Today, the natural hazards and securi- a forum located at NIBS. Other partici-
vious decade. He used “poured grout” ty threats to our nation’s building invento- pants include federal agencies, universi-
(concrete) to erect the walls by adding ry have multiplied, but so have the efforts ty research centers, national laboratories,
Portland cement, newly imported from of researchers and practitioners who are foreign governments, private research
England, to a mixture of stone, grav- developing new high-performance con- centers and commercial research and de-
el and water. The construction of Mil- struction materials that can aid in reduc- velopment organizations. The Program
ton House not only marked the first use ing the variety of risks to buildings and will be organized and managed around
of Portland cement in the United States infrastructure. While advanced construc- two activities overlapping but neverthe-
but also made history as the first con- tion materials are being introduced at a less complementing each other. Each
crete structure in the nation. rapid rate, no effective national system activity has a specific role in the organi-
The development of new construc- of identification, testing, monitoring or zational structure of the Program.
tion materials and technologies has al- coordination of these developments ex-
ways been driven by the need to protect ists. The Department of Homeland Secu- Buildings And High-
people from either the adverse effects rity (DHS), whose overriding and urgent performance Solutions
of natural forces or violent attacks by mission is to lead the unified national ef- DHS is currently making an enor-
their enemies. This was accomplished fort to secure the country and prepare for mous effort to attend to the physicality
by creating structures that were able and respond to all hazards and disasters, of the built environment. Until recent-
to provide safety from the extremes of has a special interest in promoting the ly, the Department’s coordinated efforts
weather, floods, winds, fires or earth- development of advanced and high-per- were oriented to protecting people and
quakes, and be a secure haven from ag- formance materials. Through the efforts infrastructure against the effects of ex-
gression. Instances of this dynamic can of its Science and Technology Directorate plosives and chemical, biological and
be found throughout history. (S&T), specifically the Infrastructure Pro- radiological (CBR) agents. These efforts
For example, following the Great tection and Disaster Management Divi- were centered on seeking innovative
Chicago Fire of 1871, which practical- sion (IDD), the Department is taking the approaches in detection and promot-
ly destroyed one of the country’s main lead in this important undertaking that ing the development of field equip-
economic and population centers, the will provide the means to preserve and ment, technologies and procedures to
city initiated a massive reconstruction improve the existing infrastructure and interdict person-borne bombs, car and
program. In an effort to reduce the risk build new, more resilient facilities. truck bombs, and shoulder-fired mis-
of future similar disasters, local archi- siles before they can reach their targets.
tects and builders introduced a pano- S&T/IDD Program with Within this framework, the reduction
ply of new materials and technologies, National Institute of of risks from explosives and CBR haz-
as well as innovative uses of tradition- Building Sciences (NIBS) ards relied heavily on electronic securi-
al materials. The designers and builders DHS has entered into partnership ty, security personnel, cameras and the
of the Home Insurance Company build- with the National Institute of Build- screening of personnel.
ing introduced the principles of skele- ing Sciences (NIBS) to pursue a series of The Buildings and High-Performance
ton construction and were also the first goals oriented toward the development Solutions Component is designed to
ever to use Bessemer steel rolled beams and dissemination of the state-of-the-art provide an overall programmatic frame-
instead of the wrought iron beams technology for improving homeland se- work for identification, exploration,
commonly used at the time (Randall, curity. The partnership is known as the documentation and dissemination of

8 Journal of Advanced and High-Performance Materials


advancements and improvements to Advanced Materials design and adoption of new innovative
the materials, systems and technologies Project and advanced systems that meet a range
that provide the physical configuration Research institutions, universities, of high-performance requirements, in-
of the nation’s building inventory and National Laboratories, and industry cluding dramatically reduced energy
critical infrastructure in order to opti- have developed a large variety of ad- use and enhanced blast protection. A
mize all major attributes including blast vanced materials and intelligent sys- secondary objective of this project is to
protection, energy efficiency, sustain- tems in the last decade. However, these prepare a Basic Research Program that
ability, safety, security, durability, pro- efforts are not systematically followed- would allow S&T/IDD to undertake the
ductivity, functionality and operational up on, nor are they effectively shared most novel and state-of-the-art basic re-
maximization (FIGURE 1). among the producers and end users of search in the area of security and associ-
This effort is an integral part of the S&T these materials. Testing protocols vary, ated fields (FIGURE 2).
mission objective to establish and imple- leaving the construction industry with- The Advanced Materials effort seeks
ment the concept of integrated or multi- out appropriate guidelines. The Ad- to set the research goals, priorities and
attribute design and research. It will drive vanced Materials project is therefore agenda for advanced materials devel-
and coordinate the research and develop- intended to foster and promote the opment. It can be considered as the
ment of advanced and high-performance
materials and systems and promote the
cross-fertilization of public, private and
international advanced materials re-
search. A high level National Technical
Committee has been identified to over-
see this project. The result of this multia-
gency project will provide DHS/S&T/IDD
the capability to review, understand and
promote the adoption of mitigation mea-
sures to improve the building stock and
critical infrastructure in the areas of blast
resistance, energy efficiency and environ-
mental sustainability.
The deteriorated state of the nation’s
built environment has led the research
community to look at the use of alter-
native materials of lower cost and light-
er weight, that contribute to enhanced
performance, reduced maintenance
and increased durability. The industry Figure 1.
and research institutions have devel-
oped a large variety of these new ad-
vanced materials. DHS and NIBS are
working together to develop a high-
performance building envelope mod-
el and other building components and
subcomponents. The project would be
charged with the integration, compila-
tion, harmonization and promotion of
uniform and consistent high-perfor-
mance building standards in the build-
ing industry to ensure acceptable and
appropriate levels of performance. An
institutional effort would monitor the
work of five expert committees (archi-
tectural, structural, mechanical, fenes-
tration, and risk and uncertainties) to
assure harmonization and to avoid the
creation of metrics that would cause
conflicts or duplications in the evalua-
tion and delivery processes. Figure 2.

Winter 2011 9
principal engine of the Program and Berkeley National Laboratory; Universi- and produce the expected results. Ade-
will serve to document, process and ty Research Centers; industry; and for- quate information and communication
organize the results of research activ- eign governments. The AMC will set the flows are critical for achieving technolo-
ities and prepare them for dissemina- overall Program agenda and provide gy transfer goals.
tion through various outreach activities, guidance for advance materials tech- Widespread utilization of new tech-
such as the Database Website Interface. nology transfer. It will appoint and or- nologies and high-performance mate-
The application of advanced materials ganize working committees to guide the rials will lead to renewal and rebuilding
and technologies will permit us to man- design of the database taxonomy, its ap- of physical infrastructure across the
age our infrastructure assets more ef- plication and usage, and develop other nation. Demonstration projects will
fectively and dramatically reduce the aspects of Program outreach. show the benefits of advanced materi-
risks from adverse environmental con- als and make the case for their applica-
sequences or terrorist attacks. For this Looking Ahead tion throughout the United States, thus
program, two interrelated databas- The need to improve the state of the incorporating high-performance con-
es have been developed: the Advanced nation’s critical infrastructure and to struction materials and systems into
Materials Database (AMD) and the In- provide adequate and effective protec- the mainstream practice. Design and
novative Technologies and Systems tion against hazards and threats is great construction standards will be perfor-
(ITS) database. The AMD has the pur- indeed. New high-performance materi- mance-based rather than prescriptive
pose to catalogue, document and ex- als and systems can play a very signif- and will reflect a new era of technolog-
change materials information among icant role in accomplishing this task. ical innovation and asset management,
industry and the research communi- Today, advanced and high-performance thereby advancing the state of critical
ty in an effort to promote the use of ad- materials can be employed to provide infrastructure.  n
vanced materials for efficient and cost infrastructure protection against mul-
effective retrofit. The ITS plays a crucial tiple threats and simultaneously satisfy Mila Kennett received a degree in ar-
role in helping to introduce and broad- other needs such as energy conserva- chitecture and urban design from the
ly publicize a wide range of technolog- tion, low environmental impact, or cost- Universidad Autonóma de Santo Do-
ical advances that will fundamentally effectiveness. For example, reinforcing mingo and a Master of Arts degree in in-
change the way we manage buildings an existing or newly built masonry ternational development with a major
and physical infrastructure. structure with sensor-embedded tex- in urban economics from American Uni-
The access to the databases’ infor- tiles and nano-particle-based mortars versity in Washington, D.C. She has more
mation by the general public will be provides increased strength and ductil- than 15 years of experience on projects
controlled by a tiered security system, ity against earthquakes, improved frag- in Latin America, Asia, the Middle East,
in order to protect classified as well mentation properties against blast and Europe, and the United States. Kennett’s
as proprietary information. By bring- in-service data capability for conducting main focus has been on natural disaster
ing together organizations with a stake structural health monitoring, lifecycle mitigation; building security; risk assess-
in infrastructure protection and inno- management performance prediction ments; planning and implementation of
vative technologies, this Program will and incident emergency assessment for development programs; and manage-
help facilitate development, wider use first responders (Messervey et al., 2009). ment of pilot programs with national
and integration of advanced and high- Although new materials and technol- and local governments and non-govern-
performance materials and innovative ogies such as these are being developed mental organizations.
technologies in the design, construction at an ever-increasing rate, the pace of
and protection of critical infrastructure. their adoption and utilization is lagging. References
The overall leadership for this com- One of the greatest challenges today 1. Frank Alfred Randall, John D. Ran-
ponent will be provided by the Ad- is how to communicate and promote dall, 1999. History of the Develop-
vanced Materials Council (AMC), the adoption of new advanced materi- ment of Building Construction in
composed of representatives from fed- als and technologies. The private sector Chicago. Second Edition.
eral agencies such as the Department and public agencies must have the right 2. T. B. Messervey, D. Zangani &
of Homeland Security, Department of tools, guidelines and information to fa- S. Casciati, 2009. Smart High-
Energy, the Environmental Protection cilitate adoption and utilization. There- Performance Materials for the
Agency, the Department of Defense, the fore, it is necessary to stress that effective Multi-Hazard Protection of Civil
National Science Foundation, and the innovative technology transfer is as im- Infrastructure. Safety and Security
National Institute of Science and Tech- portant as innovative research and Engineering III.
nology, to name but a few. Other mem- development of advanced materials. In- 3. National Science and Technology
bers will include representatives from novations in high-performance materi- Council, Committee on Technolo-
National Laboratories, such as the U.S. als and construction technologies must gy, 2008. Federal Research and De-
Army’s Engineer Research and Devel- be tested, demonstrated, document- velopment Agenda for Net-Zero
opment Center, Lawrence Livermore ed, discussed and applied repeatedly, if Energy, High-Performance Green
Buildings.
National Laboratory, and Lawrence they are to penetrate industry practice

10 Journal of Advanced and High-Performance Materials


Feature

An Advanced Materials Database:


A Gateway for Future and Secure
Infrastructures
The development of a new database to track advanced materials, their
applications and their attributes will go a long way toward encouraging their use.
By Mohammed Ettouney, PhD, P.E., MBA, F.AEI, Weidlinger Associates, New York City, NY; Mila Kennett, U.S.
Department of Homeland Security, Washington, D.C.; Earle Kennett, National Institute of Building Sciences,
Washington, D.C.; and Bob Payn, db Interactive, Austin, TX

The development of new materials attributes to improve, in a cost effective While striving to achieve all of these
has stagnated in past decades. The in- manner, the rehabilitation and con- unique features, the design of the data-
dustry has been primarily driven by struction of buildings and infrastruc- base aims to be simple to use and com-
codes and standards, which establish ture nationwide. prehensive in scope.
minimum requirements based large- This article describes the structure Generally speaking, the web-based
ly on industry performance and the ac- of the Advanced Material Database and database has three main components
ceptable public health levels that can be its usefulness to infrastructures stake- that are closely related. These compo-
met by products and materials current- holders. nents are:
ly manufactured by our industry. How- 1. Front-end (input fields);
ever, the events of September 11, 2001, A general description 2. The database structure; and
Hurricane Katrina and the financial cri- There are numerous web-based ma- 3. User queries and search capabilities.
sis that has affected the United States terial databases that are available on A detailed description of these com-
from 2007 to present, has unveiled the the internet. These databases vary in ponents follows.
need to achieve new high-performance complexity, applications and objec-
materials that enable designers, devel- tives. The Advanced Materials Database The front-end
opers and owners to produce buildings is also web-based. Its main objective is One of the main difficulties in build-
and infrastructure that resist natural to enhance the utilization of advanced ing a database is the technique of en-
and manmade hazards. There is also materials to increase the security and tering the information into the system.
the need to create solutions that ad- safety of infrastructure at reasonable This is particularly true for a materials
dress safety, durability, energy and en- costs. database, since it is such a complex is-
vironmental concerns such as strength, In order to achieve such an objec- sue. The information in a materials da-
stiffness and ductility. tive, several unique features were de- tabase varies greatly from quantitative
A range of new materials has recent- veloped for the database. The database to qualitative. It also can be determin-
ly been developed that includes im- will: istic or probabilistic. Sometimes the
portant high-performance attributes. 1. Enhance the utilization of advanced database user wants to explain some
These attributes incorporate securi- materials in improving the security material properties in short notes and
ty, blast protection, resiliency, durabil- and safety of infrastructures; in other instances, the user needs to
ity and cost effectiveness. As the rate 2. Provide organized descriptions of provide much longer text or articles.
of development of advanced materi- advanced materials; In order to accommodate these
als increases, the need for a system- 3. Provide descriptions of the testing varied needs, the input fields to the
atic organization of the properties of protocols of the materials; Advanced Materials Database were de-
these materials becomes necessary. 4. Help in establishing interactions signed to include many input modes. A
The U.S. Department of Homeland Se- between security designs, energy binary field (yes/no) is provided to de-
curity (DHS) acknowledges the fact savings and environmental sustain- scribe the utilization of the material
that new requirements call for the de- ability; in certain situations. For example, you
velopment of metrics and benchmarks 5. Help in utilizing advanced materials may ask, “Has this material been used
that will provide a range of verification in emerging engineering paradigms for blast hardening?” Or, “Is this mate-
and validation methods for each high- such as performance-based engi- rial applicable to use in the transporta-
performance attribute in order to op- neering; and tion sector?”
timize the use of new materials. This 6. Help manufacturers of newly devel- Binary fields are usually coupled
new approach is seen as a step toward oped materials apply for U.S. Safety with other fields that allow the users
a new strategy that integrates all major Act approval. to explain their answers in more detail.

Winter 2011 11
A limited-length alpha-numeric notes simple numeric fashion. Because of the qualitative choice and it is strong-
field will be available to users to pro- this, a qualitative mode of input is also ly recommended that the database us-
vide short descriptions or explanations provided. Such a mode is available ers explain the basis of their qualitative
whenever needed. For example, the when the material’s properties need to choice in this field. Examples of a qual-
notes can be used to explain a particu- be described qualitatively. In such a sit- itative use include descriptions of the
lar binary choice, or to clarify a partic- uation, a qualitative scale is allowed. corrosion behavior of a particular ma-
ular value of a material property. When The qualitative scale contains six class- terial or environmental issues that
longer descriptions or essays are need- es: might relate to a material.
ed, the user can upload files to specif- 1. Very High (VH); Most material properties are de-
ic locations in the database. Files can 2. High (H); scribed in the database using numer-
contain previously published papers, 3. Medium (M); ic (qualitative) fields. Examples of such
a description of materials, graphics or 4. Low (L); properties include mechanical proper-
pictures, tests or a list of citations. 5. Very Low (VL); and ties such as ductility or tensile strength,
The database recognizes that there 6. Not Applicable (NA). energy-related properties such as R-
are fields that can’t be described in a A notes field always accompanies value, physical properties such as tem-
perature coefficient, or environmental
properties such as toxicity.
Each material property can be de-
scribed numerically in one of several
modes. The simplest mode is the single-
number entry which would describe the
average value of that property. Anoth-
er mode is a two-numbers range that
would provide a range for that property.
In such a situation, the internal statis-
tical queries of the database would as-
sume that the probability distribution
function of that particular property is
uniform (Figure 1).
A truncated normal probability dis-
tribution can be described for a particu-
late material property by entering three
Figure 1. Uniform Probability Distribution of the Material Property. This is used in the numbers: upper bound, lower bound
database when only the maximum and minimum values of the property are known. and coefficient of variation (Figure 2).

Figure 2. Truncated Normal Probability Distribution of the Material Property. This is used in the database when the maximum,
minimum and standard deviation values of the property are known.

12 Journal of Advanced and High-Performance Materials


There are many material properties, as earthquakes, wind and floods (thus as delineated by U.S. DHS), material
such as viscosity, that are temperature the integration principle). As new ma- categorization (polymers, metals, ce-
dependent. To accommodate temper- terials are developed, additional ma- ramics, etc.) and general issues (materi-
ature dependency, the users have the terial characteristics, or infrastructure al names, history, researchers, owners,
option of specifying a temperature-de- performance demands, might need to etc.). A description of the interrelation-
pendency table with up to five tempera- be added to the database (thus the scal- ship of the material with the U.S. Safety
ture instances. ability principle). Finally, it is desirable Act is a sub-component of the general
to have the database aid the users in issue component (Figure 5).
The structure of the an active way by employing some deci- Material characteristic components
database sion-making algorithms within it. include physical properties (strength,
The structure of the Advanced Mate- Figure 4 shows the basic compo- stiffness, ductility, fatigue, etc.), and
rials Database was designed with three nents of the database. The first com- also include embedded algorithms
principles in mind: integration, scal- ponent is the attributes component, that would evaluate how the materi-
ability and decision-making (Figure which contains several performance al’s properties would meet certain per-
3). The integration principle acknowl- qualities that are needed from modern formance demands, such as blast event
edges that infrastructures are subjected infrastructures (including being able to demands from infrastructures. The ma-
to many demands. One of the most im- withstand bomb blasts, earthquakes, terial characteristics component also
portant demands is to ensure the secu- winds and floods). Other performance includes energy (for example, potential
rity of the stakeholders. Because of this, attributes can be added in the future, as energy savings) and environmental (for
the material properties and behavior needed. example, potential environmental ben-
in regards to bomb blasts is one of the Other database components are efits) material properties and materi-
governing factors in designing the data- material descriptions, material char- al composition. The testing component
base structure. acteristics and material testing. Mate- contains descriptions of the materi-
The economic and efficient utiliza- rial description components include al testing protocol (destructive, non-
tion of materials necessitates the con- the potential utilization of the materi- destructive, testing standards, etc.),
siderations of other demands too, such al in infrastructure sectors (18 sectors testing results and the manufacturing

ADVANCED MATERIALS DATABASE:


Basic Principles

Figure 3. The basic principles of the database.

Winter 2011 13
methods/processes (pultrusion, found- the database that have a 90 percent designs). What are the environmen-
ry, QA/QC, etc.) of the material. chance that its flexural ductility is tal properties of those materials?
greater than 12? • In addition to the powerful que-
Database queries 2. List all database materials that have ry capability of the database, it is
In order to take advantage of the rich an average tensile strength of 60 ksi possible to show some query re-
contents of the database, a varied set (or more), an average R-value of 3.0, sults graphically. For example, for
of user queries can be used, and they and minimal toxicity levels. a desired ductility level, how would
can be either alpha-numeric or graph- 3. Show all database materials that can four specified materials compare?
ic. Alpha-numeric queries are based on be used for blast design with mini- Figure 6 shows possible graphical
searching the database using filters or mal environmental effects. results of such a query. A 2D cross-
search words. Examples of some po- 4. Show all blast-related materials that correlation between material prop-
tential queries are: have desired optical properties (can erties can also be shown graphically.
1. What are the available materials in be used for energy-efficient glass For example, for a required ductili-
ty and tensile strength, the corre-
lations and ranges of ductility and
strength of six materials that are
ADVANCED MATERIALS DATABASE specified by the user can be shown
in a graphical form, as in Figure 7.

Benefits of the database


The design of the Advanced Mate-
rials Database can result in many ad-
vantages:
• Enhanced security: by understand-
ing the different capabilities of the
materials, an enhanced design that
takes advantage of such capabilities
is possible.
• Cost savings by using the most suit-
able material for a given demand.
• Increased multidisciplinary inter-
action between stakeholders (re-
searchers, manufacturers, owners,
engineers and architects) at differ-
ent stages of the development of
Figure 4. An overview of the Advanced Materials Database. materials. Such an increased inter-
action has the promise of increased
performance and security while re-
ducing overall costs.
• By having different demands (per-
formance attributes, such as blast,
earthquakes, wind and floods) re-
lated together within the organized
structure of the database (Fig-
ure 4), a multihazard design of in-
frastructures can be performed
efficiently. Multihazard designs can
improve security, while reducing
costs.
• The database includes a compre-
hensive mix of material properties
and performance attributes. This
mix can result in the utilization of
environmentally friendly and en-
ergy-efficient blast mitigation solu-
tions for infrastructures.
Figure 5. Safety Act considerations in the database. • The probabilistic capability of the

14 Journal of Advanced and High-Performance Materials


database would help the de- Mila Kennett is a senior program Earle Kennett is senior vice pres-
velopment and utilization of manager in the Infrastructure Protec- ident and chief operating officer for
emerging probabilistic-based en- tion and Disaster Management Division the National Institute of Building
gineering design paradigms, such (IDD) of the DHS Science & Technology Sciences.
as performance-based engineer- Directorate. She manages several projects Bob Payn specializes in web devel-
ing, risk-based designs and lifecycle of the DHS S&T Counter-IED Research opment for the building and construc-
analysis of infrastructures. Program and is responsible for all IDD tion industry. He is a principal at db
• The database has a component international programs and activities. interactive Inc.
that specifically addresses the U.S.
Safety Act. This will help newly de-
veloped materials gain Safety Act
approval.
• The included testing and manufac-
turing component in the database
would improve testing accura-
cy, thus improving the reliability of
new materials. This will, in turn, in-
crease confidence and speed the
incorporation of such materials in
construction of infrastructure.
To summarize, the development of
the Advanced Materials Database can
result in increased security and effi-
ciency of infrastructures, while reduc-
ing overall costs. n

Mohammed M. Ettouney, Sc.D., P.E.,


M.B.A., F.AEI, is a principal at Weidlinger
Associates. He has over 40 years of build-
ing-related experience with earth-
quakes, vibrations, structural health,
blast and progressive collapse. Figure 6. A Decision-Making Graph: Single Component.

Figure 7. A Decision-Making Graph: The Cross-Correlation of Two Components.

Winter 2011 15
Feature

High-Ductility Concrete for


Resilient Infrastructures
Earthquakes, fires and blasts are known for their enormous capability to
destroy everything in their path. Could a new type of concrete hold the
answer to lessening the damage?
By Victor C. Li, University of Michigan

Civil infrastructure, including approach behind ECC, highlights of its the U.S. Army Engineer Research and
buildings, bridges, roadways, tunnels, tensile properties and some recent field Development Center (ERDC) (Neeley
dams and airfield pavements, may be applications of this emerging materi- and Walley, 1995). These later develop-
subjected to multi-hazards such as al are reviewed. The article concludes ments have been further aided by the
earthquakes, fires, storm surges, winds, with brief comments on the future de- availability of particle-packing models,
projectiles and blast loading. Protection velopment of smart functional ECCs. ultra-fine particles and strong chemical
from catastrophic failures of infrastruc- dispersants, and a specialized curing re-
ture due to such extreme loadings can- Design approach and gime, whereby compressive strengths in
not be assured despite many decades of properties of ECC excess of 200 MPa and tensile strength
research in structural design and ma- The design approach behind ultra- in excess of 10 MPa have been reported.
terials development. This is illustrated ductile ECC is significantly different Even with fiber reinforcement, howev-
by events such as the 1995 Alfred Mur- from that behind ultra high-strength er, this class of material shows tension-
rah Federal Building bombing, the 1994 concrete. The most fundamental prin- softening responses when tested under
Northridge Earthquake in California, ciple of designing ultra high-strength uniaxial tensile loading, with a strain
and the 2005 Hurricane Katrina in the concrete is the tight packing of parti- capacity no more than 0.2 percent.
Gulf of Mexico. cles, leaving as little void as possible in As pointed out earlier, high-strength
Within the concrete technology com- the hardened composite. This approach concrete performs well under pure com-
munity, the development of increasing- results in a delay of cracks growing out pression loading. However, many struc-
ly high-strength (compressive) concrete from material defects and extends the tures experience flexural and shear
over the last several decades has given strength and stiffness of the concrete. loading that invariably introduces ten-
hope for stronger structures. Howev- This delay in crack initiation is a result sile stresses into the material. In dynamic
er, there is also increasing recognition of both smaller defect sizes and high- loading, compressive stress waves travel-
that when a certain level of compres- er intrinsic matrix toughness, in accor- ing through the thickness of a concrete
sive strength is reached, the failure of a dance with fracture mechanics. element and approaching a free surface
structure or structural element will be However, once a crack grows, its would reflect back as a tensile wave that
dominated by brittle fracture in tension. propagation is unstable and results in results in high-velocity debris ejected
This recognition has led to an expan- a high composite brittleness. The ad- on the back side of the structure (Forqu-
sion of materials property development dition of fibers reduces this brittleness, in and Erzar, 2009). No amount of steel
towards tensile ductility in recent years making the material usable in a struc- reinforcement can prevent this type of
(see, e.g. Fischer and Li, 2006). This new tural member. failure mode involving concrete spalling
focus of research and development may One of the pioneers of this ultra and fragmentation, since the reinforce-
provide a rational basis to support the high-strength design approach is Dr. ment always requires a concrete cover.
construction of new infrastructure and Hans Henrik Bache at Aalborg Port- Even on the direct impact side, the
the rehabilitation of existing infrastruc- land Group, in Denmark in the 1980s. materials adjacent to the crater un-
ture for enhanced, robust resiliency The result was a fiber-reinforced, high- der a penetrating object often devel-
against multi-hazards. strength concrete known as Densit, op tensile radial cracks (Cargile et al,
This article introduces Engineered with compressive strength reaching 2002). Again, this suggests the pres-
Cementitious Composite (ECC), which 120 mega pascals (MPa) (Bache, 1981). ence of high local tensile stress. Con-
has its microstructure designed from Since then, a number of derivatives crete structural elements subjected to
the ground up for tensile ductility. As of this class of concrete material have fire often spall due to a combination of
a result, the material shows high dam- been developed and commercialized. differential thermal stress and internal
age tolerance under a variety of load- These include Ductal, developed by La- pressure generation by vaporization of
ing conditions. After a brief summary Farge in France (Richard and Cheyr- capillary pore water. The resulting ten-
of the micromechanics-based design ezy, 1995), and Cor-tuf, developed by sile stresses eventually lead to brittle

16 Journal of Advanced and High-Performance Materials


fractures of the surface concrete, en- combinations of fiber, matrix and inter- coupon test. Figure 2 shows the com-
abling direct contact between next face characteristics. In this manner, the pressive strength development curve
line reinforcing steel and flames, and design goal of ECC is targeted at tensile of an ECC. In this example, the tensile
reducing the time it takes for steel to strain-hardening with ductility of sever- ductility and the compressive strength
soften and structurally collapse. al percent (several hundred times that of are 3 to 4 percent and 70 MPa at 28
In order to withstand tensile stress- normal concrete). Compressive strength days (Wang and Li, 2007). A very high
es and prevent brittle fractures, a high is retained but ensured not to violate the strength version of ECC (with the com-
composite material toughness is pre- tensile strain-hardening criteria. pressive strength reaching over 160
ferred. If the fracture failure mode is ful- Figure 1 shows the tensile stress- MPa) has recently been developed at
ly suppressed by the material’s tensile strain relationship of a typical ECC ma- the University of Michigan in collabora-
ductility (for example, if the material terial obtained from a uniaxial tension tion with the ERDC.
can be made to undergo plastic yielding
deformation without localized fracture),
the phenomena highlighted earlier can
be avoided. As a result, the structure ex-
periences high damage tolerance. This
forms the design philosophy behind
ECC that results in the development of a
fundamentally ductile concrete.
ECC is designed based on the mi-
cromechanics of crack initiation, fiber
bridging and steady-state crack propa-
gation (Maalej and Li, 1994; Lin and Li,
1997; Li et al, 2002) in a brittle matrix
reinforced with randomly distribut-
ed short fibers. By deliberately allow-
ing cracks to form at a tensile stress
just below the fiber-bridging capacity
(for example, before fiber bridging ca-
pacity is exhausted via fiber pull-out or
rupture), and by controlling the crack Figure 1. The typical tensile stress-strain curve of ECC . Image courtesy of Wang and Li,
width through the crack-propagation 2007.
mode (flat crack versus Griffith-type
crack), ECC has the ability to under-
go non-catastrophic damage in the
form of multiple crack formation while
maintaining tensile load-bearing ca-
pacity.
Analogous to ductile metal where
strain hardening is accompanied by dis-
location damage to the material, ECC
undergoes tensile strain-hardening ac-
companied by the formation of multi-
ple microcracks. Macroscopically, the
brittle fracture mode of normal con-
crete is turned into a “plastic yielding”-
like mode in ECC. To control when
microcracks should be allowed to initi-
ate and whether the flat crack propaga-
tion mode dominates over the Griffith
crack mode, micromechanical param-
eters of the fiber, matrix and the fiber/
matrix interface in the composite must
be properly tuned. Guided by the mi-
cro-fracture and fiber-bridging models,
the optimized micromechanical param- Figure 2. The typical compressive strength development curve of ECC. Image courtesy of
eters are then translated into specific Wang and Li, 2007.

Winter 2011 17
FIGURE 3 shows the bending behav- (Kong et al, 2003) and sprayable ECC composite materials designed on a mi-
ior of ECC under a flexural load. When (Kim et al, 2003) have been developed. cromechanical basis.
loaded to beyond the elastic range, the In addition, lightweight ECC (Wang and
material flexes rather than fractures, Li, 2003) with density below 1 g/cc, and Applications of ECC
hence the nickname “bendable con- high-early-strength ECC (Wang and Li, ECC is used in water and energy in-
crete.” 2006) with compressive strength reach- frastructure as well as in the building
The availability of a micromechan- ing 21MPa at 4 hours have also been and transportation industrial sectors.
ics-based model allows highly versatile developed. These various versions of Apart from cost-saving considerations,
tailoring of ECC for a variety of desirable ECC have been designed to meet spe- the driving force behind the applica-
fresh and hardened concrete character- cific performance requirements in dif- tions of ECC includes enhanced safe-
istics, in addition to strength and ductil- ferent applications. ECC is a family of ty (Li, 1993), durability (Lepech and Li,
ity. For example, self-compacting ECC fiber-reinforced ductile cement-based 2006; Sahmaran and Li, 2010) and envi-
ronmental sustainability (Lepech et al,
2008).
Sprayable ECC was applied to the
rehabilitation of irrigation channels in
the western United States (Figure 4).
In this application, the damage toler-
ance of ECC was used to combat the
perennial freeze-thaw failure of normal
concrete channels. ECC has been dem-
onstrated to be resistant to freeze-thaw
cycles with or without the presence of
de-icing salts (Lepech and Li, 2006; Sah-
maran and Li, 2007). Other applications
of ECC in water infrastructure include
the surface repair of an eroded dam in
Hiroshima, Japan (Kojima et al, 2004).
In this application, the water-tightness
of ECC was exploited.
ECC was used as a surface protec-
tion coating (Figure 5) for pipelines
Figure 3. This image shows the extreme flexing capabilities of ECC under a large used in the oil/gas industry. Damage re-
bending load. Image courtesy of UM News Services. sistance, improved durability and flexi-
bility were cited as the rationale behind
its use in this application (Lepech et
al, 2010). Other potential applications
of ECC being considered in energy in-
frastructure include its adoption in the
foundation and the towers of offshore
wind turbines.
ECC was used in the form of cou-
pling beams (Figure 6) in the core
of tall buildings (Maruta et al, 2005).
These coupling beams provide high
energy-absorption capabilities under
reverse-cyclic-shear loading during
seismic events. These coupling beams
were precast offsite and installed on-
site by casting the core wall around the
beams from floor to floor. Other poten-
tial building/housing infrastructure in-
cludes prefabricated modular floor and
roof panels comprised of a thin-walled
ECC slab and a steel truss substructure
Figure 4. Sprayable ECC applied to irrigation channel repair. Image courtesy of LFL & (Fischer et al, 2009). The advantageous
Associates, 2008. characteristics of these composite

18 Journal of Advanced and High-Performance Materials


panels include a lightweight, high load- By virtue of enhanced durabili- reduction of 38 to 48 percent, total
ing capacity and modular manufactur- ty and reduced maintenance needs, primary energy and global warming
ing process. a lifecycle cost reduction of 12 per- potential of 40 percent and 33 per-
ECC was applied to transporta- cent, accompanied by a resource use cent respectively, as well as a 34 to 76
tion infrastructure as a link-slab (Fig-
ure 7) in a bridge deck (Lepech and Li,
2009) on Grove Street Bridge in South-
east Michigan in 2005. The tensile de-
formability of ECC was exploited to
accommodate bridge deck movements
induced by thermal expansions and
contractions. The objective was to elim-
inate the maintenance requirements
associated with typical bridge-deck-ex-
pansion joints. The Michigan Depart-
ment of Transportation’s ECC Special
Provision states a minimum of tensile
strain capacity of two percent to ac-
commodate the deformation demand
due to combined temperature, shrink- Figure 5. ECC surface coating for oil/gas pipe protection. Image courtesy of Lepech et al,
age and life loading. 2010.

Figure 6. (a) The 41-story Nabeaure Yokohama Tower under construction and (b) Schematics showing coupling beams (in yellow) on
each floor. Image courtesy of T. Kanda, 2005.

Winter 2011 19
percent reduction of water pollutants While an increasingly large da- is being studied (Hou, 2008). It is en-
were estimated (Keoleian et al, 2005). tabase of mechanical and physical visioned that future generations of re-
This ECC link-slab design was adopt- properties has been accumulated by silient civil infrastructure will also be
ed in 2006 in the A22 highway segment researchers around the world that intelligent with the ability to self-re-
that extends from Bolzano to the Aus- supports the damage-tolerant be- port health conditions in terms of
trian border bridge in north Italy. In havior of ECC under a variety of me- damage and recovery extents. Such in-
addition, the 972m long cable-stayed chanical and environmental loading telligence supports the recovery of in-
Mihara Bridge in Hokkaido, Japan em- types, its potential application for in- frastructure functions subsequent to
ployed a 38mm thick continuous ECC frastructure resiliency against multi- extreme loading events, as well as as-
overlay on a steel plate (Mitamura et al, hazards should be further studied sists in maintenance scheduling op-
2005). This bridge opened to traffic in systematically. The impact resistance timized for safety and sustainability
2005. In this application, the high ten- of ECC was recently investigated by under normal service loading. n
sile ductility of ECC was converted into Yang and Li (2006, 2010) using drop
higher flexural resistance with a thin- weight tests. These studies reveal that Parts of the research described in this
ner cross section of the bridge deck. special care must be exercised in for- article have been sponsored by the Na-
mulating ECC for high-rate loading, tional Science Foundation, the Nation-
Conclusions which induces rate sensitivity. When al Institute of Science and Technology,
ECC has been established as one of the fiber, matrix and fiber/matrix in- and the U.S. Army Engineer Research
the most ductile concretes in full-scale terface are properly tailored, however, and Development Center. The author
applications today. Its tensile ductili- the extreme ductility shown in Fig- gratefully acknowledges these sup-
ty has been translated into enhanced ure 1 can be retained under impact ports.
safety and durability, and the environ- loading. These investigations should
mental sustainability of a broad array of be expanded to include high-velocity Victor C. Li is an E. Benjamin Wylie
civil infrastructures in the water, ener- projectile and blast loading effects. Collegiate Professor of Civil and En-
gy, building and transportation sectors. The fact that ECC exhibits dam- vironmental Engineering as well as a
These initial applications demonstrate age tolerance also makes it attractive Professor of Materials Science and En-
several important considerations in as a future multifunctional materi- gineering at the University of Michigan.
any newly developed material, includ- al. For example, the self-healing abil- His research interests include the de-
ing economic feasibility, field scale ity of ECC was recently reported. Both sign, processing and characterization
processing of the material, and ma- recovery of transport (permeability) of advanced fiber-reinforced cementi-
terial ingredient localization. Equally and mechanical properties (stiffness) tious composites, and the elevating of
important, they add to the knowledge were observed (Yang et al, 2009) af- the ultra-ductility of such materials to
base of how and where such a material ter the deliberately damaged sample the mechanical and durability perfor-
should be applied in future infrastruc- was exposed to water and air. In addi- mance of structural elements and sys-
ture systems. tion, self-sensing functionality of ECC tems.

Figure 7. (a) ECC link-slab on (b) Grove Street Bridge in Ypsilanti, MI. Image courtesy of Lepech and Li, 2009.

20 Journal of Advanced and High-Performance Materials


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ber Reinforced Cementitious Mate- of Cementitious Composites for Civ- Composites. ACI Materials Journal.
rials. PhD Thesis, Department of il Engineering Applications. JSCE 103 (2) 97-105, 2006.
Civil and Environmental Engineer- Journal of Structural Mechanics and 28. Wang, S., and V.C. Li. Engineered Ce-
ing, University of Michigan, Ann Ar- Earthquake Engineering. 10 (2) 37- mentitious Composites with High
bor, MI (Advisor: Prof. J. P. Lynch). 48, 1993. Volume Fly Ash. ACI Materials Jour-
7. Keoleian, G.A., A. Kendall, J.E. Det- 17. Lin, Z. and V.C. Li. Crack Bridging in nal. 104 (3) 233-241, May-June,
tling, V.M. Smith, R. Chandler, M.D. Fiber Reinforced Cementitious Com- 2007.
Lepech, and V.C. Li. Life Cycle Model- posites with Slip-hardening Interfac- 29. Yang, E.H. and V.C. Li. Rate Depen-
ing of Concrete Bridge Design: Com- es. Journal of Mechanics and Physics dence in Engineered Cementitious
parison of Engineered Cementitious of Solids. 45 (5) 763-787, 1997. Composites, in Proc., Int’l RILEM
Composite Link Slabs and Conven- 18. Maalej, M., and V.C. Li. Flexural Workshop HPFRCC in Structural
tional Steel Expansion Joints. ASCE Strength of Fiber Cementitious Com- Applications. Published by RILEM
J. Infrastructure Systems, 11 (1) 51- posites. ASCE Journal of Civil Engi- SARL, 83-92, 2006.
60, 2005. neering Materials. 6 (3) 390-406, 30. Yang, E.H. and V.C. Li. Damage
8. Kim, Y.Y., H.J. Kong and V.C. Li. De- 1994. Characteristics and Micromechanics
sign of Engineered Cementitious 19. Maruta, M., Kanda T., Nagai S. of Impact Resistant Engineered Ce-
Composite (ECC) Suitable for Wet- and Yamamoto, Y. New High-rise mentitious Composites, to appear in
mix Shotcreting. ACI Materials Jour- RC Structure Using Pre-cast ECC Proc., 18th European Conference on
nal., 100 (6) 511-518, 2003. Coupling Beam. Concrete Journal Fracture (ECF-18), Dresden, Ger-
9. Kojima, S., Sakat, N., Kanda, T. and 43(11):18-26, 2005. many, 2010.
Hiraishi, T. Application Of Direct 20. Mitamura, H., Sakata, N., Shakushi- 31. Yang, Y., M.D. Lepech, E.H. Yang,
Sprayed ECC For Retrofitting Dam ro, K., Suda, K. and Hiraishi, T. Ap- and V.C. Li. Autogenous Healing of
Structure Surface – Application For plication of Overlay Reinforcement Engineering Cementitious Compos-
Mitaka-Dam. Concrete Journal Method on Steel Deck Utilizing En- ites under Wet-Dry Cycles. Journal of
42(5):35-39. (In Japanese), 2004. gineering Cementitious Compos- Cement and Concrete Research. 39,
10. Kong, H.J., S. Bike, and V.C. Li. ites – Mihara Bridge. Bridge and 382-390, 2009.

Winter 2011 21
Feature

Carbon Fiber-Reinforced Polymer Strengthening


for Alternate Load Paths to
Mitigate Progressive Collapse Vulnerabilities
New tests being conducted are showing that innovative FRP composites have
the potential to strengthen structures. What will this mean for the buildings of
the future?
By Zachery I. Smith and Edward R. Fyfe, Fyfe Company

In the past fifteen years, fiber- pressures, it was not focused on global innovative FRP composite anchors to
reinforced polymers (FRP) have been structural enhancement. establish continuity at beam-column
used successfully to add considerable Progressive collapse retrofit stud- connections, improving catenary ac-
blast-resisting capacity to a number of ies take a wider view of the structure. tion in the event a vertical component
structural elements (for example, col- As defined by the U.S. General Servic- is lost. This retrofit scheme reduces the
umns, walls and slabs). Until recently, es Administration (GSA), progressive potential for progressive collapse and
the testing of single degree of freedom collapse is “a situation where local fail- could be the best design solution for ret-
validation and use of FRPs for force ure of a primary structural component rofitting existing structures vulnerable
protection has been focused on local leads to the collapse of adjoining mem- to failure because of the as-built rein-
component enhancement. Whether bers which, in turn, leads to additional forcement discontinuities. More impor-
this included adding flexural capaci- collapse. Hence, the total damage is dis- tantly, this work broadens the scope of
ty to slabs for uplift pressures, increas- proportionate to the original cause.” influence of FRP composites from local
ing shear capacity in bearing columns This article looks at new testing and component strengthening in years past
or adding flexural capacity to CMU recently completed projects that use to more global structural strengthen-
walls for out-of-plane induced blast FRP composites in combination with ing through alternate load paths and/or
structural redundancy.

Progressive collapse –
the challenge
Progressive collapse presents sev-
eral challenges for the engineering
community. Statistically, there is a low
probability of it occurring, while, at the
same time, the disproportional poten-
tial damage cannot be marginalized.
Unlike seismic excitation and other
natural phenomena, there is not a sta-
tistical return period and magnitude of
the event. This limits assessing the risk
with progressive collapse to the single
parameter of the greatest estimated po-
tential damage.
As stated by the Unified Facilities
Criteria (UFC 4-023-03), “the risk as-
sessment reduces to a consideration
of consequences.” The risk is primarily
measured in the potential human casu-
alties. ASCE 7 outlines two approaches
to mitigate the potential for progressive
collapse: direct design and indirect de-
sign. Analyzing future or existing build-
ings by either method is a rigorous but
simple engineering exercise. The test-
Figure 1. A building elevation with column removed. ing and applications discussed in this

22 Journal of Advanced and High-Performance Materials


article will focus on the alternate load discontinuous reinforcement at pseu- line, and at mid-span in the negative
path procedure. do beam-column connections to sim- moment regions. Test specimens were
With new construction, there are ulate a double-span scenario in which 30 feet long with a cross section of 6
several conventional steps that an engi- a column is lost in a blast event (Fig- inches wide and 12 inches deep (Fig-
neer can take to add structural integri- ure 1). The objective was to find the ure 2). It should be noted that these
ty to a new building. The real challenge most effective scheme to retrofit an structural tests neglected any sup-
comes from engineering structural ret- existing beam to support loads from port a typical building would provide
rofits for existing reinforced concrete a double-span case. The test sam- via the surrounding slab, column line
and masonry structures. Trying to add ple included six beams with a variety above, or phenomena such as the Vi-
redundancy with conventional mate- of carbon-fiber reinforced polymer erendeel truss action. Various con-
rials via alternate load paths to cross (CFRP) retrofit schemes and a con- figurations of CFRP were applied to
over failed vertical components in ex- trol specimen. To resist progressive retrofit the beams for continuity, so
isting buildings, without adding signifi- collapse by way of the alternate load they could develop catenary forc-
cant structural members and impeding path method, GSA guidelines require es. Generally, combinations included
usable space or aesthetics, is challeng- that a structure must survive a load of CFRP strengthening to the underside
ing to say the least. Reinforced concrete 2x (dead load + 0.25 live load) applied of the beams, with fiber anchors go-
buildings and masonry structures have in the tributary area surrounding the ing through the stub column section
similar vulnerabilities, in that their dis- lost load-bearing member. The factor for positive moment reinforcement or
continuities make them susceptible to of two on the structural loads tries to CFRP strengthening on the top side
progressive collapse. The lack of con- capture the inherent dynamic load- for negative moment strengthening.
tinuity of the bottom reinforcement at ing in the event a vertical component The CFRP system used was a uni-
the beam-column connection (rein- is lost. These guidelines for dynamic directional primary carbon fiber rein-
forcement cutoff ) makes them espe- loads were built into the testing pro- forced polymer with a published tensile
cially vulnerable. cedure. modulus of 11,900 ksi and measured per
Each beam specimen was mod- ASTM D3039 to have a tensile modu-
The test program eled after 1970s building construction lus of 12,500 ksi. The specified concrete
The test program evaluated sev- standards, with discontinuity in pos- and steel were fairly standard strengths,
en reinforced concrete beams with itive moment regions at the column at 4,000 psi and 60,000 psi respectively.

Figure 2. A test specimen.

Winter 2011 23
With new construction, there are several The retrofitted specimens can be
divided into two categories, those
conventional steps that an engineer strengthened in the positive moment
region and those strengthened in the
can take to add structural integrity to a negative moment region. Both retrofit
schemes have the same objective—to

new building. The real challenge comes develop catenary forces.

Positive moment
from engineering structural retrofits retrofits
Positive moment retrofits used
for existing reinforced concrete and CFRP laminates in combination with
fiber anchors to establish continuity
masonry structures. through the column section. A hole
was drilled through the column sec-
Restraints for the test specimens developed at the ends and on either side tion to pass through a large carbon fi-
were provided to simulate vertical, ro- of the column. As the applied load was ber anchor that would splay out onto
tational and axial factors. The end re- continually increased, high deflections the CFRP laminates applied to the
straints provided compression and put the beam in catenary action, when bottom of the beams (Figure 4). This
tension supports. The loading was ac- the maximum vertical load reached 52 retrofit was designed with ductility by
complished with three loading points percent of the prescribed progressive ensuring the steel would yield prior to
at mid-span and six feet on either side collapse resistance. The load carried by the CFRP laminate fracturing. In addi-
of mid-span. Axial resistance was also catenary action of the existing steel re- tion to the large carbon fiber anchor
provided by a braced frame on both inforcement was nearly twice the load passing through the column section,
ends of the specimen. Note that for lo- carried before the plastic hinges devel- smaller carbon fiber anchors were
gistical ease the beams were inverted oped, but still half the required resis- used to enhance the bond interface of
for testing. All specimens had instru- tance to prevent progressive collapse. the laminates to prevent a premature
mentation for three load cells, five dis- It should be noted that the test spec- failure from debonding.
placement inducers and numerous imens were designed to prevent a brit- The positive moment retrofitted
strain gauges on the CFRP and steel re- tle shear failure, which could cause a specimens reached 55 and 60 percent
inforcing bars. premature failure in an actual struc- of the prescribed resistance to prevent
ture (figure 3). However, FRP could progressive collapse. One explanation
Catenary action with also provide a substantial amount of for these specimens not meeting a 100
CFRP composites for shear capacity to an existing beam sec- percent of the prescribed resistance
alternative load paths tion to prevent such a brittle shear fail- stems from their limited rotational
When the control specimen, NR-2, ure. This was not the intent of the test capacity. The concrete sections with
without CFRP laminates, was exposed program, since FRP’s ability to add limited rotational capacity can frac-
to 23 percent of the load required for beam shear capacity has been demon- ture the steel reinforcing bars before
progressive collapse resistance, hinges strated numerous times in the past. catenary action can be realized. Thus,

Figure 3. The development of a CFRP system to provide continuity in existing reinforced concrete buildings vulnerable to progressive
collapse. Image courtesy of Orton, S.L.

24 Journal of Advanced and High-Performance Materials


the enhanced progressive collapse composites to be designed to the limited to strengthening walls locally
with CFRP in the positive moment re- sides of the masonry beams rather for out-of-plane pressures and pos-
gions may only be accomplished if the than the bottom of the beams. The sibly spall control. Here the scope of
designer ensures that the rotational positive moment demand was fair- the CFRP composites was broadened
ductility in the concrete section is suf- ly minor in comparison to the neg- to strengthen the entire structure to
ficient to reach catenary action. ative bending demand. This design withstand a threat through added
used a flexural strengthening retro- structural redundancy versus trying
Negative moment fit as opposed to relying on the CFRP to strengthen one component against
retrofits composite to develop catenary ac- local failure.
The negative moment retrofits are tion. The project is a great example
simpler logistically because they do of global strengthening as opposed Conclusions
not require developing the carbon fi- to simply local component strength- The research that has been complet-
ber anchor through the column sec- ening. Traditionally, an FRP compos- ed thus far has shown that CFRP com-
tion as with the positive moment ite on this project would have been posites can successfully change load
retrofits (Figure 5). The testing also
showed that since the CFRP lami-
nates are developing the negative
steel reinforcement, they allowed
hinges to form away from the sec-
tions with limited rotational ductility
and avoided fracturing the steel rebar
before catenary action was realized.
Hence, this proved to be the most
successful retrofit strategy for reach-
ing the prescribed progressive col-
lapse resistance with one specimen
reaching 108 percent of the progres-
sive collapse resistance target. We’d
like to clarify that for this test pro-
gram, the summary percentages refer
to the strength provided relative to to-
tal resistance needed to prevent pro-
gressive collapse per GSA guidelines.

Case study
In the winter of 2009, a U.S. Army Figure 4. CFRP composites in the positive moment region to develop catenary forces.
barracks required a complete reno-
vation, which included structural is-
sues related to anti-terrorism/force
protection (AT/FP) requirements. To
satisfy the progressive collapse re-
sistance requirements, in case the
building lost a masonry pier, the en-
gineer-of-record selected the alter-
nate load path design method, which
would strengthen the exterior mason-
ry beams to take up the added loads.
Thus, the existing masonry beams
had to be designed and strengthened
to span a length that is twice the span
length of the original design (Figure
6).
This was accomplished by add-
ing CFRP composites in the nega-
tive and positive bending regions of
the masonry beams (Figure 7). Lo-
gistical constraints forced the CFRP Figure 5. Carbon anchor through stub column. Image courtesy of Orton, S.L.

Winter 2011 25
paths in existing structures and reduce Further, load paths can be altered This paper presents summary results
their vulnerability to progressive col- without realizing catenary forces, from Dr. Sarah Orton’s PhD dissertation.
lapse. This can be accomplished in two which can offer higher performance Fyfe Co. greatly appreciates the continued
ways: by adding continuity to induce levels with lower deflections, but re- research and support offered by Dr. Orton.
catenary action or by enhancing flex- quire substantially more CFRP com- Fyfe Co. donated the materials for this test
ural capacity of the beam sections. To posites. This method is recommended program, while funding came from the
realize catenary action in an existing where post-event serviceability may National Science Foundation. For a com-
structure, the designer can either ret- be required (for example, hospitals) plete study of the results summarized, see
rofit the positive or negative moment or with more brittle structural com- PhD dissertation by Orton (2007).
regions with CFRP composites to al- ponents, such as masonry beams that
low plastic hinges to form when a ver- have limited rotational ductility. Zachery I. Smith, P.E., serves as the
tical component is lost. However, the Whether a designer uses CFRPs for en- vice president of government services for
designer is cautioned that the applica- hanced flexural capacity or to induce the Fyfe Company, developing blast mit-
tion of this methodology in the positive catenary action, load paths can be suc- igation and force protection solutions
moment region is constrained by rota- cessfully changed in existing struc- for a wide variety of projects.
tional ductility of the concrete section, tures—adding a needed alternative to Edward R. Fyfe is the president and
which must be sufficient to support cat- the retrofit options for resisting pro- founder of Fyfe Co. and a leading pio-
enary forces. gressive collapse.  n neer in the FRP strengthening industry.

References
1. General Services Administration
(GSA). Progressive Collapse Anal-
ysis and Design Guidelines. Gen-
eral Services Administration, June
2003.
2. Unified Facilities Criteria (UFC).
Design of Buildings to Resist Pro-
gressive Collapse, UFC 4-023-03.
3. National Institute of Standard and
Technology (NIST). Best Practices
for Reducing the Potential for Pro-
gressive Collapse in Buildings. NI-
STIR 7396, Feb. 2007, 194 pp.
4. ACI Committee 318. Building
Code Requirements for Structural
Figure 6. Axial load versus displacement. Image courtesy of Orton, S.L.
Concrete (ACI 318-99).

5. Orton, S.L. Development of CFRP


System to Provide Continuity
in Existing Reinforced Concrete
Buildings Vulnerable to Progres-
sive Collapse dissertation. Uni-
versity of Texas at Austin, Austin
TX, 2007, 363 pp.
6. Orton, S.L.; Jirsa, J.O.; and Bay-
rak, O. Use of CFRP to Provide
Continuity in Reinforced Concrete
Buildings Vulnerable to Progres-
sive Collapse. 8th International
Symposium on Fiber Reinforced
Polymer (FRP). Reinforcement
for Concrete Structures, Patras,
Greece, July 2007.
Figure 7. CFRP composite on a masonry structure for alternate load paths.

26 Journal of Advanced and High-Performance Materials


Feature

Evolution of Elastomeric Retrofits for Concrete


Masonry Unit Walls for Enhanced Blast Resistance
at the Engineer Research and Development Center
New elastomeric materials have been developed by ERDC which are expected to
improve technical performance and provide major economic advantages.
By C.F. Johnson; B.P. DiPaolo, PhD; and S.C. Woodson, PhD, P.E., Research Structural Engineers,
U.S. Army Engineer Research and Development Center (ERDC)

Blast effects from improvised propagation velocity decreases with time the dynamic loads applied to a structure
explosive devices, such as car bombs, (and distance), but it is typically greater are peak reflected pressure and impulse,
can produce extremely severe loading than the speed of sound in the medium. taking clearing effects into account.
conditions on buildings. The nonbear- As the shock front propagates away from The objective at ERDC is to develop
ing infill unreinforced concrete mason- the explosion center, the peak incident elastomeric material retrofits for unre-
ry unit (CMU) wall system is particularly pressure at the location of the shock inforced CMU walls that will resist the
vulnerable to the out-of-plane pressure front will decrease. pressure and impulse blast effects and
loading from a high-explosive detona- When the wave reaches a surface mitigate the secondary debris hazard to
tion. This system is one of the most com- (such as a wall or a structure) that is the building occupants to the greatest
monly used wall systems in buildings not parallel to the direction of propa- extent possible, without performing ma-
around the world due to its low cost, ma- gation, a reflected pressure will be gen- jor retrofits on the main building frame.
terial availability and ease of construc- erated. The reflected pressure will have
tion. the same general shape as the incident General retrofit
However, when exposed to external pressure, but the peak (Pr) will typical- research methodology
blast loads, unreinforced CMU walls can ly be significantly higher than that of the The engineering approach, as shown
disintegrate into a large number of frag- incident wave. The magnitude of the re- in Figure 1 for the development of ef-
ments that will propagate into a structure flected pressure depends on the magni- fective and practical protective designs,
at high velocities and cause occupant in- tude of the incident wave and the angle involves the use of material testing,
jury or death. Therefore, there is a critical of the inclined (often vertical) surface. analytical models and multi-scale
need for advanced building materials to The impulse delivered to the structure experiments, exposing prototype struc-
retrofit and improve the blast resistance is defined as the area under the pres- tural systems to high explosive (HE)
of CMU walls. To address this need, new sure-time curve, modified to account for blast effects. First, multiple materials are
elastomeric materials with and without “clearing” around the structure. selected and statically tested in the labo-
fiber reinforcement have been devel- Clearing around the structure af- ratory to determine the physical charac-
oped, tested and evaluated by the U.S. fects the duration of the reflected pres- teristics. Then the resistance functions,
Army Engineer Research and Develop- sure and depends on the distance to or applied load versus deflection curves
ment Center (ERDC). An overview of the the nearest free surface, which will de- (Figure 2a) for the individual materials
evolution of these elastomeric materials termine the rate of flow around the ob- or composite systems, are developed in
is presented here, with respect to their ject (for example, the flow will try to go the static water chamber (SWC).
technical performance, and economic around the wall in order to continue be- The water pressure producing the
and logistic advantages. hind the obstacle). This secondary flow static load on the specimen slowly in-
from the high to the lower pressure re- creases until the specimen fails or a
Blast effects and blast gions reduces the reflected pressure to predetermined load or deflection is
resistance the stagnation pressure, a value which achieved. The unique design of the
Explosions produce a shock wave or is in equilibrium with the incident wave SWC allows researchers to evaluate larg-
high pressure front, which propagates pressure. If the reflected pressure cannot er samples of the elastomeric materials
outward from the “point” of detona- be relieved by the secondary flow (such (second picture from the top right cor-
tion. The shock front depicts an almost as in the case of an infinite plane wave ner in Figure 1) or sub-scale retrofitted
instantaneous rise in pressure (see up- impinging on an infinitely long wall), the CMU walls in the vertical/upright po-
per left of Figure 1), with an associat- incident wave will be reflected at every sition. The resistance functions for the
ed time-to-peak termed “rise time”. The point on the surface, and the duration of materials are then used in engineering
peak incident pressure (Ps) is at the end the reflected pressure will be the same as level (single-degree-of-freedom) models
of this initial phase. The incident pres- for the incident wave. to predict the dynamic response of the
sure is the pressure on a surface paral- In summary, the two primary param- retrofitted walls.
lel to the direction of propagation. The eters to be considered in determining The materials or systems that perform

Winter 2011 27
the best in the scaled static experiments concrete or steel. Given enough resourc- the experimental program. The first sys-
are then evaluated in sub-scale dynamic es, time and funds, it is possible to great- tem involved unreinforced and fiber-re-
experiments, either conducted at the lo- ly enhance the survivability of most inforced spray-on polyureas as a retrofit
cal high explosive test site or at the Blast existing structures. However, depend- material for infill CMU walls (Figure
Load Simulator Facility. From the para- ing upon the level of protection desired, 2b). The polyurea is a two-component
metric studies conducted in the sub- it is typically expedient and economical system shipped in fifty-gallon drums.
scale static and dynamic experiments, to use catcher retrofit systems for non- The components are mixed in a com-
refined retrofit systems are developed structural components. pressed air driven spray-rig that requires
and evaluated in a series of full-scale HE In 1996, ERDC began evaluating applicators to attend training classes for
experiments. Using the engineering level catcher retrofit systems. These systems operational and maintenance guidance.
models, Pressure-Impulse (P-I) diagrams were not intended to provide addition- The individual operating the spray-
that mathematically relate a specific al strength to the wall but rather, focused rig must wear extensive safety gear
damage level to a range of blast pressures on containing the fragments by a net or (jump suit, clean air pump, face shield
and corresponding impulses are devel- barrier to reduce the secondary debris and gloves) during application. The ret-
oped for the retrofit material/systems. hazard to occupants in the building. rofit material is sprayed onto the inte-
The iso-response curves on the P-I In the late 1990s, geotextiles anchored rior surface of the CMU wall and onto
diagram allow the user to rapidly assess at the floor and roof slabs were used as a one-foot strip along the top and bot-
the response of an element and poten- catcher systems. However, research over tom supports for anchorage. The retrofit
tial damage levels for a defined structure the last decade has emphasized new and thickness is controlled by the skill of the
and specified load. Once the dynamic innovative materials, systems and appli- individual operating the device. Multi-
response is validated, then failure crite- cation procedures that focus on more ple layers of the material can be applied
ria, application instructions and guide- efficient, economic, transportable, con- to the wall with or without woven fiber
lines are developed, so the technology sistent and reliable retrofit systems. The reinforcement. The spray-on polyurea
can be transitioned for use. retrofit techniques must also attempt to cures within a few minutes upon appli-
accommodate a variety of existing con- cation to the CMU wall and has extreme-
Retrofit techniques and ditions, while incorporating aesthetic ly good adhesion to the CMU blocks.
materials considerations and operational require- The spray-on polyurea retrofits require
Two common types of retrofit systems ments. expensive equipment, specialized train-
are strengthening and catching. Conven- In 2000, ERDC initiated research on ing and strict maintenance procedures
tional retrofit procedures often focus on elastomeric materials for retrofitting for implementation.
adding additional blast resistance to the CMU walls. Overall, five distinct sys- The second system consists of trow-
wall through the addition of mass, using tems were developed and validated in el-on polymeric materials. This system

Figure 1. Engineering methodology for wall retrofit development.

28 Journal of Advanced and High-Performance Materials


requires a mixer, paddle, grooved trow- Each layer of material overlaps at least larger than the width of the elastomer-
el, flat trowel, buckets and paint brush- a foot onto the top and bottom sup- ic film. The grooved trowel recommend-
es for application. Before application of port, and mechanical anchorage is pro- ed for this application is approximately a
the polymeric material begins, the top vided at each support. Safety glasses, quarter of the depth used in the previous
and bottom supports are primed with a gloves and sleeves are recommended system. The grooves created by the trow-
two-component chemical using a paint during application of the trowel-on ma- el serve two purposes. First, they control
brush. A respirator must be worn dur- terial. The quality of the retrofit depends the thickness of the material and second,
ing application of the primer. The three- on the ability of the workers to produce they are used to monitor the amount of
component polymeric material must be consistent material mixtures and layer pressure the installers should exert when
mixed in proper proportions and applied thickness. applying the films. The trowel-on mate-
to the wall in a timely manner. Applica- The next retrofit system uses the trow- rial must be applied to the wall quick-
tion works best with at least two people. el-on polymeric materials from the pre- ly, so that the film can be applied before
The material thickness is controlled by vious system as an adhesive to mount the material cures. Each sheet of film is
the individuals handling the trowels. unreinforced or fiber-reinforced elasto- applied from floor to ceiling with a one-
The first person uses a flat trowel to meric films (Figure 2d). By using the foot overlap on the supports. To apply
apply the material to the wall (Figure elastomeric film, the amount of trowel- the film, a simple rubber roller is need-
2c). Then the second person redistrib- on material is reduced to the minimal ed to ensure that all of the air is removed
utes the material using the grooved thickness required to provide sufficient between the CMU wall and the film.
trowel to spread the material to the de- adhesion. The installers should only apply enough
sired thickness, which is controlled by The application procedure for the pressure to smooth the grooves in the
the depth of the notch in the trowel. The trowel-on material is essentially the same trowel-on material. If the installers push
first layer must be allowed to cure before as described in the previous example. too hard, the block will appear. If the in-
application of the second layer begins, However, the steps are slightly altered, as stallers do not exert enough pressure, the
using a flat trowel to fill in the grooves follows. The trowel-on material is applied grooves will be apparent and air will be
left by the notched trowel in layer one. from floor to ceiling in sections slightly trapped under the film.

Figure 2A. Resistance functions – full scale films. Figure 2B. Spray-on.

Figure 2C. Trowel-on. Figure 2D. Trowel-on w/film.

Winter 2011 29
Quality control is greater from the pre- film into the desired lengths. It is recom- adhesion, the entire CMU block or the
vious system in that the films are manu- mended that the quality of the supports face shells may remain intact with the
factured to specific thickness, strength be evaluated to determine if mechanical retrofit materials after the blast event. As
and elongation properties. However, anchorage, chemical adhesive, or both the retrofit systems evolved, equipment
equipment requirements have not been should be used to secure the film at the and training requirements were simpli-
reduced from the previous system, and top and bottom supports. fied and quality assurance and control
timing is critical when applying the ma- All of the retrofit systems discussed in increased, while reducing the logistical
terials in this system. this article have successfully been evalu- constraints. In achieving the objectives
The final retrofit system is illustrated ated at a minimum threat level which is of reduced training and logistics, struc-
in Figures 2e and 2f, and uses pres- higher than all three “Locations” and all tural retrofits for mitigating the second-
sure sensitive adhesives (PSA) applied the “Building Categories” for “Conven- ary debris hazard become more suitable
to unreinforced or fiber-reinforced elas- tional Construction Standoff Distanc- for expedient use in occupied facilities
tomeric films, respectively. As shown on es” for both of the “Applicable Explosive with inadequate blast resistance.
the resistance functions in Figure 2a, Weights” (I & II) as described in Table In addition, the result of the research
the unreinforced films are more ductile, B-1 of the Unified Facilities Criteria, described here demonstrates the effec-
while the fiber-reinforced films are less DoD Minimum Antiterrorism Standards tiveness of using the methodology to
ductile, but much stronger. The fiber- for Buildings (UFC 4-010-01, October 8, develop, test and evaluate an advanced
reinforced film shown in red was a more 2003, including Change 1, January 22, material system for extreme loading
balanced design, which demonstrated 2007). The minimum threat level was caused by blast effects. However, blast
the ability to increase strength and add also higher than the “Minimum Standoff resistance is only one of a number of cri-
additional ductility in a single film. The Distance” for all of the “Building Catego- teria for fully effective advanced build-
reliability and consistency of the retrofit ries” except for “Inhabited Buildings” in ing materials. These materials must also
system are improved from the previous a “Controlled Perimeter, or Parking and be durable and resist environmental
systems, since these entire systems (film Roadways without a Controlled Perime- threats such as floods, hurricane force
and adhesive) can be produced in the ter,” (as identified on Table B-1). winds and seismic loads, with econom-
controlled environment of a manufac- ic and construction efficiency. Current-
turing facility. The elastomeric film can Conclusion ly, efforts are directed to expand the
be produced in rolls of specified width The five retrofit systems illustrated in methodology to include multi-perfor-
that can be easily cut to fit the height of Figure 2 offer solutions that decrease mance-based criteria in the research
the CMU wall. the vulnerability of occupants to sec- and development of advanced building
The film is applied by removing a ondary debris hazards associated with materials to sustain and protect critical
protective liner from the PSA and plac- CMU infill walls exposed to airblasts infrastructure. n
ing the film on the wall from floor to ceil- generated from HE events. These inno-
ing. Application of each successive sheet vative retrofit systems take advantage of The research and development work
of film should overlap the previous sheet the toughness and resiliency of modern overviewed in this paper was sponsored
by at least four inches and should ex- polymer materials to deform and effec- by the Department of the Army and was
tend at least one foot onto the bottom tively absorb the blast energy while con- the result of the efforts of a U.S. Army En-
and top supports. It is recommended taining the wall fragments. The research gineering Research and Development
that a primer be used with the system to at ERDC has evolved from spray-on elas- Center (ERDC) team of engineers and
improve the adhesion to the CMU block. tomers requiring expensive and high- technicians, and commercial vendors.
A water-based primer that does not re- maintenance equipment, to trowel-on Permission to publish was granted by
quire a respirator is applied to the wall elastomeric materials requiring mini- the Director, Geotechnical and Structures
using a simple paint roller. The only mal tools, to fiber-reinforced elastomer- Laboratory, ERDC. It is approved for pub-
equipment required to apply the film is ic films using PSAs that require a simple lic release; distribution is unlimited.
a roller to remove trapped air between roller and knife.
the block and film and a knife to cut the Depending upon the strength of the Carol F. Johnson performs research
in the area of protective materials and
structures and directs the research activ-
ities of the Blast Load Simulator Facility
at the ERDC.
Dr. B.P. DiPaolo performs basic re-
search on materials and structural forms
for protective structures applications.
Dr. S.C. Woodson has over 30 years of
research experience regarding experi-
mental and analytical studies of struc-
Figure 2E. Film w/PSA. Figure 2F. Reinforced film w/PSA. tural response to dynamic loads.

30 Journal of Advanced and High-Performance Materials


Feature

Emergent Materials for Security,


Energy and the Environment
Advanced materials can be used for more than structural applications. Security,
energy and the environment will all benefit from further research in this area.
By Blaine Brownell, University of Minnesota, School of Architecture

The term “advanced materials” boundaries, making previous standards and improved sustainability over tra-
may be applied to a variety of high-per- obsolete. The ongoing pursuit of thin- ditional precast concrete. In addition,
formance materials designed to meet a ner and more porous products allows the reduction of concrete enables the
wide array of functional objectives. The for resource conservation—with impli- integration of insulation, which can in-
designation is typically associated with cations for both energy and the envi- crease R-values of wall panels. Carbon-
materials designed for robust structur- ronment. Although these materials are Cast cladding panels can weigh up to
al or security applications, including generally expensive and difficult to ob- 66 percent less than conventional pre-
products created for military or aero- tain, many of these products are being cast panels. This weight reduction per-
space uses. While this remains a prima- developed for a broad market. mits engineers to reduce substructure
ry focus, there has also been a growing High-performance textiles like Zetix, or specify smaller cranes for lifting the
trend to address energy conservation for example, offer superior protection panels into place.
and environmental remediation objec- against explosive events such as car Traditional concrete has many prob-
tives in the development of advanced bombs, IEDs, industrial accidents, hur- lems including the lack of durability
materials. ricanes and tornadoes (Figure 1). Man- and sustainability, failure under severe
These additional aims represent the ufactured from monofilament polyester loading and the resulting expenses of
responsible acknowledgment of re- elastomers wrapped with ultra-high repair. University of Michigan has de-
source depletion and biodiversity loss, molecular-weight polyethylene (UHM- veloped a new type of fiber-reinforced
and the recognition of these goals al- WPE) and woven together with ballistic- concrete that looks like regular con-
lows for a broader and more holistic Nylon, Zetix textiles may be used for crete, but is 500 times more resistant
view of advanced materials—highlight- window protection, blast screens and to cracking and 40 percent lighter in
ing promising intersections and syn- fragmentation liners, as well as body weight. As a result, the so-called Engi-
ergies between the different objectives armor enhancements. Zetix addresses neered Cement Composite (ECC) has
of security, energy and the environ- a limitation of most blast-defense sys- been nicknamed “bendable concrete,”
ment. The following themes of perfor- tems, which are only capable of coping and it defies common expectations re-
mance, response, energy, optimization with a single explosive event. The un- lated to conventional mechanical be-
and remediation may be used to cate- usual construction of the Zetix fabrics havior in concrete.
gorize advanced materials that address means that they effectively “vent” much This performance is made possible
these objectives and their relationships. of the blast energies through lessening by tiny fibers accounting for two per-
The first three themes address materi- the load on the support structure. As a cent of volume, in addition to the use
al technologies that may be used to re- result, they offer a multiple-blast event of smaller aggregate. Because of its long
duce security threats to buildings and solution for natural or human-initiated life, ECC is expected to cost less over a
infrastructure. The last two themes disasters. structure’s lifecycle. According to lead
highlight ways to improve existing se- Reinforced concrete also has wit- researcher Victor Li, “the broad field of
curity-focused materials’ environmen- nessed gains in mechanical perfor- micromechanics has tried to under-
tal performance. mance and material productivity. These stand how composite materials behave.
are important accomplishments in We went one step further and used the
Performance light of concrete’s high embodied-en- understanding as a material design ap-
Throughout human history, materi- ergy and carbon footprint. CarbonCast, proach in the development of ECC.”
al innovation has been defined by the for example, is a precast-concrete tech- (Victor Li’s article on ECC is found on
persistent testing of limits. Advanced nology that uses a carbon-fiber grid for page 16 of this magazine.)
materials focused on performance are secondary reinforcing or shear transfer.
stronger, lighter, more durable and Because carbon fiber reinforcing resists Response
more flexible than their convention- corrosion, CarbonCast precast prod- Responsive material systems are
al counterparts. These materials are ucts require less concrete cover, result- endowed with the ability to undergo
notable because they surpass known ing in added durability, lighter weight a physical metamorphosis based on

Winter 2011 31
environmental stimuli—such as archi- amounts of energy as they carry most integrity of the structure is significant-
tectural surfaces that flex and “breathe” of the world’s cargo. Many of the poly- ly compromised. Inspired by biologi-
in the presence of polluted air. These mer composites typically used for such cal systems in which damage triggers
surfaces may also possess the ability to modes of transporation are over-en- a healing response, Scott White, from
self-heal, especially in situations that gineered to avoid structural failure, a the Beckman Institute at the University
anticipate high physical stresses or re- fact that reduces the advantage of such of Illinois, developed a structural poly-
quire ultra lightweight components. light-weight constructions. Natural meric material with the ability to auto-
The collective promise of such technol- Process Design’s Self-Repairing Poly- nomically heal cracks (Figure 2). The
ogies is that our constructed environ- mer Composites are made from graph- incorporation of a microencapsulated
ment will become smarter, at least in ite oil, resulting in lighter material. In a healing agent and a catalytic chemical
the sense that it will actively alert us to a recent project for the United States Air trigger within an epoxy matrix accom-
variety of measurements that we do not Force, the composite portion of the air- plishes this healing process. An ap-
currently monitor well. Building surfac- plane fuselage was made to be 30 per- proaching crack ruptures embedded
es will also become more interactive, cent lighter than conventional materials microcapsules, releasing healing agent
expanding interface design beyond the based on the use of Self-Repairing Poly- into the crack plane through capillary
product scale to architectural and ur- mers. If this material can be success- action. Polymerization is triggered by
ban scales. fully implemented in traveling craft, contact with the embedded catalyst,
The self-repairing capability of new a significant reduction in CO2 contri- bonding the crack faces. Although this
advanced materials not only suggests butions will be possible. A subsequent material is still under development in
reduced maintenance and replace- phase of research could address build- laboratory conditions, its eventual ap-
ment, but also increased durability and ing panels made of self-repairing com- plication in the form of self-repairing
longevity. Moreover, self-repairing ma- posites, which would similarly reduce polymeric panels for architectural clad-
terials can be lighter than their con- the building’s CO2 footprint while en- ding is a compelling vision.
ventional counterparts, thus reducing suring a more durable building shell. Shape-memory materials allow for
embodied energy and greenhouse gas Self-healing plastics offer benefits the development of objects and surfac-
production. for a broad range of polymer-based es that can actively respond to shifting
One target application for such ma- applications. Structural polymers are environmental conditions. Developed
terials is aircraft and marine vessels that susceptible to damage such as cracks by Soo-in Yang and David Benjamin,
are significant contributors to global that form deep within the structure Kinetic Glass is a responsive surface
warming. Airplane vapor trails release where detection is difficult and repair that reacts to environmental conditions
carbon dioxide (CO2) as well as oth- is almost impossible. Once cracks have and changes shape via curling or open-
er pollutants, and ships expend large formed within polymeric materials, the ing and closing gills. The surface is thin,
lightweight and transparent with no
motors or mechanical parts. The system
may be used with a variety of switch-
es or sensors and controlled via micro-
processors and complex algorithms,
allowing one to perform a variety of ap-
plications. In one case, the system can
detect unhealthy levels of CO2 in in-
terior spaces. Kinetic Glass “breathes”
when high levels are encountered, en-
hancing air movement and signaling
the problem to building occupants.

Energy
With so much attention being paid
to greenhouse gas-related emissions
and imminent fuel supply limits, en-
ergy has become a pressing topic of
concern. Predictions of global peak oil
inspire both the search for alternative
fuel sources as well as the conserva-
tion of energy in all of its uses. Energy
itself is now a major security issue and
Figure 1. Zetix, which is made by Auxetix Ltd., is an example of a high-performance bio-based fuel sources such as etha-
textile. nol, biodiesel and biomass have begun

32 Journal of Advanced and High-Performance Materials


to replace a small percentage of petro- powerful tool for energy savings and materials self-assemble according to
leum-derived sources. security. Architectural core daylighting predetermined chemical processes. Re-
Meanwhile, renewable energy indus- has been identified as a beneficial form purposing waste materials via low en-
tries such as solar and wind power are of conservation, maximizing the deliv- ergy preparations is another means
propelled by increased market support ery of sunlight to interior spaces during for reducing energy while limiting the
and government subsidies. Predictions daytime hours. Parans Daylight AB has waste stream burden.
of future energy delivery models indi- developed a sunlight transmission sys- Strong Enviroboard (SEB) is a mul-
cate a profound transformation from tem for buildings that consists of light- tifunctional wallboard and floorboard
central, long distance-based service collecting panels, light-transporting composed of magnesium oxide, aer-
models to highly dispersed, commu- cables and light-emitting luminaires. ated rock and recycled cellulose from
nity-based frameworks. Such models SkyPort collecting panels contain two furniture manufacturing. When layers
will require buildings to be more ac- layers of optics and are easily mounted of ingredients are poured into a mold,
tive participants in energy production, to any roof structure. Captured sunlight the composition bonds exothermically
and new technologies promise to add is transported via bundled fiberoptic at room temperature, thus requiring no
energy-harnessing functionality to ar- cables. The luminaires emit this sun- added energy. SEB is made completely
chitectural surfaces—thus diversifying, light as a mixture of parallel light beams of nontoxic materials and cannot grow
stabilizing and increasing the security and ambient light. The Parans system mold because it is not affected by wa-
of a building’s “energy portfolio.” allows building occupants to monitor ter. SEB has virtually no thermal ex-
Building-integrated renewable ener- the weather even in the absence of win- pansion and is immune to freeze-thaw
gy technologies supply much-needed dows or skylights, thus reestablishing a cycles. The combination of SEB with
energy without requiring an investment connection with the outside environ- liquid mineral-system coatings offers a
in additional building surfaces. Made ment. 100 percent breathable, fire proof, mold
from single crystalline silicon, Sphelar proof and waterproof interior or exteri-
has the durability and reliability of Optimization or wall without primer.
conventional silicon-based photo- Energy considerations are obvious- The reincorporation of waste mate-
voltaics (PV), yet the micro-spheri- ly not limited to fuel and building op- rials into new products is seen as both
cal shape of cells makes it lightweight eration concerns; the power required a diversion of material from the waste
and extremely pliable. Manufactured during material manufacture and pro- stream as well as a savings in the em-
by Kyosemi, Sphelar has a high photo- cessing is also under scrutiny. Low- bodied energy that would be invested
electric conversion efficiency, omni- embodied energy and zero-energy in new materials. Fly ash, for exam-
directionality, module transparency, processes are slowly beginning to re- ple, is the waste product of burning
and configurability in series or parallel place conventional methods requiring coal that is largely comprised of car-
circuits. Sphelar modules can be easily large amounts of energy. The most in- bon and contains many heavy metals.
integrated with curtain walls, windows, teresting of these involve biochemical Fly ash is often combined with cement
roofing materials and canopies. The and exothermic procedures whereby as an additive, but only up to a certain
technology is also ideal for ubiquitous
computing and electronics, because
the micro spherical particles are small-
er and more effective than convention-
al photovoltaics.
Wind energy-harnessing capabilities
may also be integrated within build-
ing surfaces. Grow is a hybrid energy-
delivery device inspired by ivy. Grow’s
“leaves” are flexible organic photovolta-
ic panels that capture solar energy and
convert it into electricity. Each leaf is at-
tached by way of a robust piezoelectric
generator at the leaf’s stem. When the
leaves flutter in the wind, the stems flex
to produce electricity while also creat-
ing a provocative kinetic experience.
Grow’s modular system is designed to
be attached to any building surface that
receives sunlight and wind.
In addition to harnessing new Figure 2. An example of a self-healing polymer, created at the Beckman Institute,
forms of power, conservation is also a University of Illinois.

Winter 2011 33
replacement of existing highway bar-
riers, which are wall systems designed
The ongoing pursuit of thinner and more porous to reduce noise and light pollution for
adjacent neighborhoods. The new Su-
products allows for resource conservation—with perabsorber system not only mitigates
implications for both energy and the environment. these forms of pollution but also the
more significant air pollution generat-
Although these materials are generally expensive ed by vehicle emissions. The inclusion
and difficult to obtain, many of these products are of this surface application on future
concrete-barrier systems will produce
being developed for a broad market. a significant increase in photocatalyza-
tion of air pollution in urban areas.
The study of biological behavior can
reveal simple methods for performance
percentage of concrete may be fly ash. Remediation enhancement in advanced materials.
Dr. Carolyn Dry has developed a meth- An important sustainable design A team of scientists under Dr. Wilhelm
od of fabricating building panels and concern is indoor environmental qual- Barthlott at the University of Bonn dis-
insulation out of nearly 100 percent fly ity, considering the high percentage of covered the so-called “lotus effect” by
ash in order to sequester these heavy time people spend indoors. Off-gassing learning from the lotus plant. The leaves
metals so that they do not leach out and materials such as carpet and adhesives of the lotus plant are immaculately clean
pollute the environment. Essentially have been identified as contributors of after every rainfall because dirt and mi-
cooking the ash into a solid, Dry utiliz- harmful volatile organic compounds croorganisms are unable to obtain a
es a flux that allows processing at lower (VOC) to indoor air, and the reduction hold on the microstructured, non-wet-
temperatures—thus using less energy of VOCs has been a primary goal in en- table surfaces of the leaves. As a result,
and chemicals. Components such as vironmental building programs. Fur- rain simply washes dirt and other parti-
building panels, bricks and insulation ther thinking about natural processes cles away. The Lotusan facade paint de-
may be produced without the need for has resulted in products designed to veloped by the researchers is the first
binders such as cement. undo the damage caused by polluting successful practical application of the lo-
The integration of high-performing industrial practices. These so-called re- tus effect, and about four million square
chemical additives can enhance the mediating materials photocatalyze air- meters of facade surfacing have since
multifunctional capabilities of building borne pollution and employ passive been coated with Lotusan paint, which
materials. Hycrete’s Element is an en- self-cleaning technologies to do more has reduced the typical energy, time and
vironmentally friendly admixture that good than harm, rather than simply material expenditures associated with
integrally waterproofs concrete used minimizing harm. maintaining building exteriors.
in commercial construction. Element TX Active is a photocatalytic cement
eliminates the need for external mem- that decreases the harmful substanc- Conclusion
branes typically used to waterproof es present in the air and preserves the As we monitor the frontiers of tech-
concrete, thereby making the concrete finished surface of buildings. Incor- nological development, emergent ma-
more-easily recyclable following de- porating titanium dioxide as its active terials offer promising capabilities
molition. This approach can eliminate ingredient, the cement reduces con- for advanced and high-performance
thousands of pounds of volatile organ- centrations of airborne pollutants, such building applications. Given the press-
ic compounds (VOCs), CO2 and non- as nitrogen oxides and volatile organic ing challenges we face on a number of
renewable content. Additionally, the compounds. The cement is specifical- fronts, it makes sense that we give pri-
admixture enhances structural dura- ly designed for high-profile architec- ority to those materials that address
bility by protecting against corrosion tural work and complies with European multiple areas—especially opportu-
of steel rebar. In eliminating the need Standard EN 197/1 requirements. Con- nities for enhancing the most critical
for a manually applied membrane, Hy- crete made with the cement has the matters of security, energy and the en-
crete Element can also save time in same physical and mechanical proper- vironment. n
construction schedules. With typical ties as traditional concrete, with added
membrane applications, contractors self-cleaning properties. Blaine Brownell is an architect and
must often wait for the concrete to dry Clemson-based Fieldoffice has de- former Fulbright scholar with a re-
before a waterproofing sub-contractor veloped a new wall system utilizing search focus on emergent materials. He
can apply the membrane—even after this cement, which the manufactur- authored the Transmaterial series with
rainfall and re-wetting. In contrast, Hy- er predicts will reduce air pollution in Princeton Architectural Press, and is
crete Element is dosed during concrete urban areas by 50 percent when cov- currently an assistant professor at the
mixing and is not subject to weather ering just 15 percent of urban surfaces. University of Minnesota - School of Ar-
delays. One recommended application is the chitecture.

34 Journal of Advanced and High-Performance Materials


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