Professional Documents
Culture Documents
1. Scope Sections
Steel Products 12
1.1 This practice covers the sampling of all grades of steel, General 12.1
both cast and wrought, and all types (grades) of cast irons and Selection of a Laboratory Sample or a Sample for 12.2
blast furnace iron for chemical and spectrochemical determi- Analysis from a Cast Product
Selection of a Laboratory Sample or a Sample for 12.3
nation of composition. This practice is similar to ISO 14284. Analysis from a Wrought Product
1.2 This practice is divided into the following sections. Preparation of a Sample for Analysis 12.4
Sections Sampling of Leaded Steel 12.5
Requirements for Sampling and Sample Preparation 6 Sampling and Sample Preparation for the Determination 12.6
General 6.1 of Oxygen
Sample 6.2
Selection of a Sample 6.3 Sampling and Sample Preparation for the Determination 12.7
Preparation of a Sample 6.4 of Hydrogen
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Spoon Sampling 8.2 standard. No other units of measurement are included in this
Probe Sampling 8.3 standard.
Preparation of a Sample for Analysis 8.4
Sampling and Sample Preparation for the Determination of 8.5
1.4 This standard does not purport to address all of the
Oxygen and Hydrogen safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
Liquid Steel for Steel Production 9
General 9.1
priate safety and health practices and determine the applica-
Probe Sampling 9.2 bility of regulatory limitations prior to use. For specific
Spoon Sampling 9.3 statements, see 6.4.3.5, 9.4.4.3, and 12.5.1 as well as Section 5.
Preparation of a Sample for Analysis 9.4
Sampling and Sample Preparation for the Determination 9.5
of Oxygen
2. Referenced Documents
Sampling and Sample Preparation for the Determination 9.6 2.1 ASTM Standards:2
of Hydrogen
A 48/A 48M Specification for Gray Iron Castings
Pig Irons 10 A 751 Test Methods, Practices, and Terminology for
General 10.1 Chemical Analysis of Steel Products
Increment Sampling 10.2
Preparation of a Sample for Analysis 10.3
E 135 Terminology Relating to Analytical Chemistry for
Metals, Ores, and Related Materials
Cast Iron Products 11 E 415 Test Method for Atomic Emission Vacuum Spectro-
General 11.1
Sampling and Sample Preparation 11.2
metric Analysis of Carbon and Low-Alloy Steel
E 1010 Practice for Preparation of Disk Specimens of Steel
and Iron for Spectrochemical Analysis by Remelting
1
This practice is under the jurisdiction of ASTM Committee E01 on Analytical
2
Chemistry for Metals, Ores, and Related Materials and is the direct responsibility of For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Subcommittee E01.01 on Iron, Steel, and Ferroalloys. contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Current edition approved April 15, 2009. Published May 2009. Originally Standards volume information, refer to the standard’s Document Summary page on
approved in 1996. Last previous edition approved in 2006 as E 1806 – 96 (2006). the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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FIG. 1 Sequence of Sampling and Sample Preparation of (a) Liquid Iron and Steel and (b) Cast Iron and Steel Products
samples for analysis, may be unavoidable. This variability will 6.2.2 Size:
form an inherent part of the repeatability and reproducibility of 6.2.2.1 Ensure that the dimensions of a laboratory sample in
the analysis. the form of a solid mass are sufficient to permit additional
6.2.1.3 Ensure that the sample is free from surface coatings samples for analysis to be taken for reanalysis when necessary
and from moisture, dirt, or other forms of contamination. using an alternative method of analysis.
6.2.1.4 The sample should be free from voids, cracks, and 6.2.2.2 A sample shall be prepared consisting of a sufficient
porosity and from fins, laps, or other surface defects. mass to provide for any reanalysis necessary. Generally, a mass
6.2.1.5 Take particular care when selecting and preparing of 100 g will be sufficient for a sample in the form of chips or
the sample where a sample taken from a melt is expected to be powder.
heterogeneous or contaminated in any way. 6.2.2.3 The dimensional requirements for a sample in the
6.2.1.6 A sample taken from a melt shall be cooled in such form of a solid mass will depend upon the method selected for
a manner that the chemical composition and metallurgical analysis. In the case of atomic emission and X-ray fluorescence
structure of the sample is consistent from sample to sample. spectrometric methods, the shape and size of the sample will be
6.2.1.7 It is important to recognize that analysis by some determined by the dimensions of the sample chamber. The
spectrochemical methods may be influenced by the metallur- dimensions for samples given in this practice are for guidance
gical structure of the sample, particularly in the case of irons only. Refer to Test Method E 415 for sample size requirements
with white and grey iron structures, and steels in the as-cast for atomic emission spectrometry.
and wrought conditions. 6.2.3 Identification:
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8.1.1 The following methods are applicable to the sampling into a split mold made from graphite, hematite iron, or copper
of liquid iron from cupola furnaces and electric furnaces, to obtain a sample in the form of a small, flat plate, 4 mm to
holding furnaces in duplex processes, and ladles and treatment 8 mm in thickness. Remove the sample from the mold, as soon
vessels. as it is solid, to avoid overheating the mold and the risk of
8.1.2 Liquid iron intended for the production of iron cast- breakage of the sample. Break off any riser.
ings may be subject to inhomogeneity and particular care is 8.2.3.2 The sample, commonly described as a coin sample,
required in the design of strategies and methods of sampling to may be circular, rectangular, or square in shape with typical
meet the requirements of the particular production process. For sizes, respectively, 35-mm to 40-mm diameter, (50 by 27) mm
example, liquid iron in holding furnaces tends to stratify, and and (50 by 50) mm. Generally, disk samples are cast vertically
sampling should ensure that analysis is representative of the and rectangular and square samples are cast horizontally.
melt as a whole. 8.2.3.3 The mold is constructed in two pieces that are
8.1.3 In batch processes, two or more samples should be clamped together in use: one piece is a flat chill plate, and the
taken from melting furnaces preferably when approximately other is a block with the mold cavity. The edge of the mold
one third and two thirds of the melt has been discharged and an cavity may be tapered to facilitate removal of the sample from
average analysis determined. In continuous processes, samples the mold.
should be taken at regular intervals of time. 8.2.3.4 A coin sample with one or more attached pins can be
8.1.4 Methods of sampling normally are designed to chill obtained using a combination-type mold. The pins are broken
the liquid metal of a sample cast from a spoon, as rapidly as off from the disk and used, if required, as test portions for
possible, to produce a metallurgical structure of white iron free analysis by a thermal method. A vertical mold of this type,
a separate parting tool to cut the pin transversely to obtain a test probe sample to cool somewhat in air, to a dull red color, and
portion of a suitable mass for analysis. Avoid overheating the then quench in water in a manner that does not cause cracking.
pin during the preparation of test portions for the determination In some cases, probe samples are transported to the laboratory
of hydrogen, and cool at frequent intervals using crushed, solid while still hot.
carbon dioxide. 9.3 Spoon Sampling:
8.5.3.2 There should be no delay between preparation of the 9.3.1 Procedures:
test portion and analysis.
9.3.1.1 For sampling from the melt, lower the spoon
through the slag into the melt and fill with liquid steel. The
9. Liquid Steel for Steel Production spoon should first be immersed into the slag layer to coat it
9.1 General: with slag so as to reduce chilling and prevent adhesion of the
9.1.1 The following methods are applicable to the sampling sample to the spoon. Withdraw the spoon, and remove any slag
of liquid steel from furnaces, ladles, and other vessels, and by skimming the surface of the liquid steel in the spoon.
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probes are distinguished in Annex A2. Methods of use should 9.6.3.1 Cut a test portion of a suitable mass for analysis
minimize and control the rapid diffusion of hydrogen from the from the central sections of the probe sample. Cutting should
probe sample that occurs during storage of the sample, and be carried out in such a manner to minimize heating the probe
preparation of the test portion. Losses by diffusion may be sample. Use a copious flow of cooling fluid during cutting or
large at ambient temperatures especially from small-diameter cool the sample at frequent intervals, or use a combination of
samples. both methods of cooling.
9.6.1.2 The probe sample should be free from cracks and
NOTE 5—Cutting without heating the sample can be accomplished by
surface porosity, and from moisture, particularly entrapped rapidly breaking pieces from the probe sample with manual or hydraulic
water. The condition of the test portion can influence strongly bolt cutters.
the analytical measurement. Methods of analysis may differ in
their sensitivity to the presence of water in the sample. If a 9.6.3.2 Prepare the surface of the test portion by filing, grit
suction sampling probe is used, the method of operation should blasting, acid etching, or light grinding. If filing is used, abrade
avoid risk of introduction of moisture into the sample. the surface by hand with a fine-cut file. If grit blasting is used,
9.6.1.3 The choice of a method of sampling is dependent on a grit-blasting machine should be reserved exclusively for this
the temperature of the melt, the method of analysis, and the purpose to avoid contamination from the grit. If grinding is
analytical precision required. These relationships should be used, cool the test portion at frequent intervals. It is difficult to
investigated to establish a suitable method for a particular prevent the sample from being heated with any of these surface
steel-making practice that will give samples of the quality preparation methods. If the test portion is of good quality, no
required. Procedural detail should be rigidly adhered to in surface preparation using any of these methods should be
order to obtain consistency in the quality of analysis. necessary.
9.6.1.4 It is essential to maintain the probe sample and the 9.6.3.3 Degrease the test portion by immersion in acetone,
test portion at a temperature that is as low as possible at all dry by exposure to a rough vacuum, and analyze immediately.
stages following sampling, and during storage and sample Alternatively, prepare the test portion by immersion in
preparation. The sample should be stored in a refrigerant, either propanol-2 (isopropyl alcohol), and then dry it with diethyl
liquefied nitrogen or a mixture of acetone and solid carbon ether.
dioxide in the form of a slurry is suitable.
9.6.1.5 The probe sample and the test portion should be kept 10. Pig Irons
cold when cutting the sample and during preparation of the test 10.1 General:
portion. Cooling may be carried out by immersion in water that 10.1.1 The following methods are applicable to the sam-
is ice-cold or preferably in a refrigerant. Remove any moisture pling of iron from the blast furnace that has been cast into
present on the surface of the test portion after cooling; immerse pieces of a simple shape, known as a pig, usually in the form
the test portion in acetone; then dry by exposure to a rough of a double lozenge or some other similar shape. The various
vacuum for a few seconds. types of pig irons are classified in ISO 9147. Other types of
9.6.1.6 Discard samples that have been cooled or stored iron may be used in the manufacture of cast iron, for example,
inadequately. iron produced in a cupola furnace or an electric melting
9.6.1.7 Preparation of the surface of the test portion by furnace.
abrading should be kept to a minimum consistent with the need 10.1.2 Use special care to ensure the collection of a repre-
to remove all oxidation products and surface defects. sentative sample from pig irons.
9.6.1.8 Analyze the test portion immediately after prepara- 10.2 Increment Sampling:
tion. 10.2.1 Number of Increments—Ensure that the number of
9.6.2 Methods of Sampling: pigs taken as incremental samples are representative of the
9.6.2.1 A range of commercially available sampling probes batch or consignment. In the case of a consignment supplied in
designed to provide pin-shaped or pencil-shaped samples of bulk, if there is no other agreement between the supplier and
of pigs is obtained. grinding at a position midway along the length and width to
10.2.2.4 Where it is not possible to gain access to the whole expose an area of metallic surface of at least 50 mm in
of the surface of the stockpile, or where access to the stockpile diameter. Drill a hole through the cross section of the pig, and
is unsafe, the points of sampling shall be prescribed in a cease drilling at a point approximately 5 mm from the opposite
definite order on the surface of the stockpile. face. If necessary drill a further hole parallel to the first hole.
10.2.2.5 Alternatively, use a mechanical shovel to obtain a (See Fig. 3(a), Fig. 3(b), Fig. 3(c), and Fig. 3(d).)
number of subsamples from positions in the stockpile selected 10.3.2.2 For non-machinable iron, break the pig at a posi-
at random. Select one pig at random from each subsample. tion midway along its length. Break off pieces from the
10.2.3 Consignment of Mixed Pig Irons: fractured face; crush these pieces to a particle size of approxi-
10.2.3.1 A consignment of pig iron may contain a number of mately 5 mm; then grind using a vibratory grinding mill to a
different batches of pig iron that may be from different sources. particle size of less than 150 µm.
If pigs of different shapes and sizes can be distinguished in the 10.3.2.3 Mix equal quantities of the material obtained from
consignment, a visual assessment should be made of the each pig. From this mixture obtain a sample of sufficient mass
proportions of each type of pig iron present. for analysis by coning and quartering.
10.2.3.2 Incremental samples then should be taken of each
10.3.2.4 Alternatively, analyze the material obtained from
type of pig iron in the consignment to constitute separate
each pig separately to obtain an average value for the consign-
subsamples of pigs in order to obtain a weighted average
ment.
analysis for the consignment.
10.3.3 Sample for Analysis by a Thermal Method:
10.3 Preparation of a Sample for Analysis:
10.3.1 General: 10.3.3.1 To prepare samples in the form of chips or frag-
10.3.1.1 If the pigs taken as incremental samples contain ments from machinable iron, at the center of each pig, and on
remnant magnetism as a result of handling with magnetic opposite faces, drill a hole 12 mm to 14 mm in diameter.
grabs, demagnetize them by means of a demagnetizing coil to Remove scale and any other impurities around the holes on
prevent separation of coarse and fine particles during drilling. both sides of the pig. Then drill another hole coaxial with the
10.3.1.2 To obtain chips by machining, drill at a low speed first hole, 20 mm to 24 mm in diameter, so that large chips,
(100 r/min to 150 r/min) using a freshly sharpened tool and approximately 1 mm to 2 mm in size, are obtained.
adjust the speed and feed to produce chips of uniform size with 10.3.3.2 To prepare samples in the form of chips or frag-
a minimum of fine material. A drill with a diameter of 12 mm ments from non-machinable iron, obtain small pieces from the
to 14 mm is suitable for obtaining chips. Resharpen the drill at pig as described in 7.4.2.1, and then crush these pieces using a
frequent intervals and avoid overheating both the sample and percussion mortar to a particle size between approximately
the tool. 1 mm and 2 mm.
10.3.3.3 Mix equal quantities of the material obtained from
each pig. From this mixture obtain a sample for analysis by
TABLE 1 Minimum Number of Pigs to Be Taken as Incremental coning and quartering.
Samples from a Consignment of Pig Iron 10.3.3.4 Alternatively, analyze the material obtained from
Consignment, Tons Number of Pigs each pig separately to obtain an average value for the consign-
< 10 9 ment.
10–20 11 10.3.3.5 To prepare samples in the form of a solid mass, cut
20–40 12
40–80 14 a slice, approximately 3 mm thick, from the complete cross
80–160 16 section of the pig at a position midway along its length and
160–300 18 clean the edges by grinding. From this slice, cut pieces at
300–600 21
> 600 24 positions corresponding to those shown in Fig. 3(e) or Fig. 3(f)
to constitute test portions of a mass suitable for analysis.
Alternatively, saw or break the pig at a position midway along 11.2.1.1 Sample and prepare samples in accordance with the
its length. Using a trepanning tool, drill either three or five grade of iron, type of casting, and the method selected for
holes at positions corresponding to those shown in Fig. 3(e) analysis.
and Fig. 3(f) to obtain pins of approximately 3 mm in diameter. 11.2.1.2 Clean the sample product or laboratory sample by
Break the pins into pieces to constitute test portions of a mass scratch-brushing, grinding, or shot-blasting to remove adhering
suitable for analysis. particles of sand and to expose areas of metallic surface.
10.3.3.6 Analyze a representative number of the test por- Ensure that both the inner and outer surfaces of hollow castings
tions to obtain an average value for each pig. are clean.
11.2.2 Sample for Analysis by a Chemical Method:
11. Cast Iron Products 11.2.2.1 Machine the sample to obtain chips by drilling or
11.1 General: turning at a low speed (100 r/min to 150 r/min) using a
11.1.1 The location and method of taking a laboratory tungsten-carbide-tipped tool, adjusting the speed and feed to
sample from a cast iron product shall be agreed upon between produce chips of uniform size with a minimum amount of fine
the supplier and the purchaser in relation to one of the methods particles. Take care to avoid overheating both the sample and
described in the following paragraphs. the tool. There is a risk of fracture of the tool when using a
11.1.2 The sample can be selected from a test bar or block carbide-tipped drill in which case the chips should be dis-
cast onto the casting for the purpose of mechanical testing. carded. Milling shall not be employed owing to the high
11.1.3 Take special care to ensure the collection of a proportion of fines produced.
representative sample from cast iron products. There may be 11.2.2.2 Chips should be as solid and compact as possible
differences in chemical composition, particularly in the con- with a mass of approximately 10 mg in order to prevent
tents of carbon, sulphur, phosphorus, manganese, and magne- crumbling of graphite. Do not wash chips with a solvent or
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sium between the selected sample and that of the casting or treat them magnetically because of the risk of altering the
castings as a whole. Segregated elements may concentrate distribution of metal and graphite. A 10-mm diameter tool is
towards the upper surfaces of a casting and under cores. These suitable for obtaining chips by drilling. The size range of chips
regions should be avoided when selecting a laboratory sample. intended for the determination of carbon or nitrogen should be
Sectional dimensions and areas of differential heating or approximately from 1 mm to 2 mm.
cooling require special attention. Careful consideration is 11.2.2.3 When machining is not practical, the sample can be
necessary in the design of sampling strategies for high phos- broken into pieces and pieces crushed using a percussion
phorus engineering iron, and malleable and ductile irons. Pay mortar or a vibratory grinding mill to obtain a sufficient mass
particular attention when sampling grey irons to ensure that the of sample for analysis of particle size less than 150 µm. Use
sample is representative of the chemical composition of the this method only when it can be shown that pulverization does
product especially where segregation is suspected. not lead to contamination of the sample.
11.1.4 Samples obtained from cast iron products that con- 11.2.2.4 For grey irons, obtain chips from the central section
tain free graphite may not be suitable for accurate analysis by of a casting, that is, from a region that represents approxi-
using atomic emission or X-ray fluorescence spectrometric mately one third of a complete section of the casting. Do not
methods. In such cases, it is preferable to use other methods of use chips obtained from the as-cast surface. Where possible
analysis, obtaining suitable samples as described in 11.2.2 and and depending upon the shape of the casting, obtain the chips
11.2.3. by drilling the casting at several positions. Mix chips obtained
11.2 Sampling and Sample Preparation: in this way to constitute the sample for analysis. For a casting
11.2.1 General: of large section, it may be impracticable to drill through the
Analyze a representative number of pieces and obtain an a piece from the laboratory sample of a suitable size for the
average value. The mass of a piece selected as a test portion analysis method.
should not be less than 0.3 g. 12.3.2.3 To obtain a sample in the form of chips, mill the
11.2.4 Sample for Analysis by a Spectrochemical Method: whole of the cross-sectional area of the laboratory sample.
11.2.4.1 Use a saw or abrasive cutting disk to cut a sample Where milling is impractical, drilling may be employed but is
of suitable size from the sample product or laboratory sample. not recommended for rimming steels. The most suitable
11.2.4.2 Prepare a cut surface by grinding using a fixed- drilling position depends on the shape of the section as follows:
head machine or by linishing, or by a combination of both
12.3.2.4 For a section of symmetrical shape, (for example, a
methods. Air cool the sample to avoid overheating. Do not use
billet, a round, a slab) obtain chips by drilling a cross-sectional
liquid coolants.
cut face in a direction parallel to the longitudinal axis at points
NOTE 7—A fixed-head grinder is preferred to a swing grinder for midway between the center and edges (see Fig. 4(a) and Fig.
surface preparation, the latter type of equipment may not produce a flat 4(b)).
surface on the sample for analysis.
12.3.2.5 For a section of complex shape, for example, an
11.2.4.3 The method selected for remelting should produce angle, a tee, a channel, or a beam, obtain chips by drilling at
a chill cast sample with a white iron structure. Particular points indicated in Fig. 4(c), Fig. 4(d), Fig. 4(e), Fig. 4(f), and
attention should be given to avoid partial losses of elements. Fig. 4(g) leaving a clearance of at least 1 mm around the drill.
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FIG. 4 Sampling Positions for Steel Sections
12.3.2.6 For a rail, obtain chips by drilling a hole, 20-mm to 12.3.4.2 Where the sample product is of insufficient cross
25-mm diameter in the head of the rail at a position halfway section for machining, for example, a thin gage sheet, a strip,
between the centerline and edge of the rail (see Fig. 4(h) and a wire, mill over the combined transverse sections obtained
Fig. 4(j)). either by bundling the material after cutting into suitable
12.3.2.7 Where drilling into the end or cut face of the lengths, or by folding.
section is impractical, obtain chips by drilling inwards from the 12.3.4.3 For a sheet or a strip where the rolling direction is
surface perpendicular to the main axis. unknown, take lengths of strip in two directions at right angles,
12.3.3 Plates or Slabs—Cut a laboratory sample of a and combine the resulting samples.
suitable size for analysis in the form of a solid mass or chips 12.3.5 Tubes and Pipes—Sampling may be in accordance
from a point midway between the centerline and the outer edge with one of the following methods:
of the plate. In the example shown in Fig. 4(k), the laboratory 12.3.5.1 Cut a laboratory sample at a position 90° from the
sample is 50 mm wide. Where this is not practical, take the weld on a welded product.
sample from a position agreed upon between the supplier and 12.3.5.2 Cut across the tube and turn or mill across the cut
the purchaser as being representative of the plate composition. face to obtain a sample in the form of chips. Thin section tubes
12.3.4 Light Sections, Bars, Rods, Sheets, Strips, and Wires: may be flattened before milling.
12.3.4.1 Where the sample product is of sufficient cross- 12.3.5.3 Drill through the wall of the tube or pipe at several
sectional area, cut a slice transversely to constitute the labora- positions around its circumference to obtain a sample in the
tory sample and obtain a sample for analysis as described in form of chips.
12.3.2. 12.4 Preparation of a Sample:
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ANNEXES
(Mandatory Information)
A1. SAMPLING PROBES FOR USE WITH LIQUID IRON AND STEEL
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A1.2.6.3 The dual-thickness probe samples are illustrated in
Fig. A1.2(b), in which part of the disk is reduced in thickness
and is suitable for the punching out of slugs. The slugs are
4 mm to 6 mm in diameter and are used as test portions in
thermal methods of analysis. The thicker section of the disk of
a dual-thickness probe sample is used for analysis by spectro-
chemical methods. A probe sample with a hardness of greater
than approximately Rockwell 25 HRC may require heat
treatment before punching.
A1.2.7 Probes of the type shown in Fig. A1.3 in which the
FIG. A1.1 Examples of Immersion Probes Filled by Ferrostatic sample chamber is filled by gravity consist of a two-piece or
Pressure (a) With the Deoxidant in the Sample Chamber and (b)
with the Deoxidant in a Separate Mixing Chamber
four-piece steel cylindrical mold that is contained in a refrac-
tory assembly and attached to a cardboard tube.
A1.2.7.1 The mold has a side entrance port that is protected
in some way to prevent ingress of slag. The assembly may be
A1.2 Immersion Sampling Probes
sleeved with refractory to minimize splashing during immer-
A1.2.1 Immersion probes can be inserted into the melt sion; overall length of the assembly and cardboard tube is
either by hand or by mechanical means using a lance of steel 400 mm to 800 mm. Immersion times are usually 2 s or 3 s.
piping fitted into the cardboard tube or attached directly to the A1.2.7.2 This type of probe is used in situations where the
probe assembly. Immersion times vary depending on the disk-and-pin type of sample is not satisfactory for analysis. It
design of the probe and the conditions of sampling, in is used to obtain samples from liquid iron and steel in ladles
particular the temperature of the melt, but are normally and from liquid steel in ingot molds and continuous casting
between 3 s and 8 s. tundishes. The sample is typically 30 mm in diameter by
A1.2.2 The lance is constructed so that air from the mold 70 mm long.
cavity and gases produced during the combustion of cardboard A1.2.8 Probes of special design are used to obtain samples
can escape easily. A handle bar is incorporated for controlling from liquid iron in the blast-furnace runner and from the
the lance during immersion and withdrawal. torpedo car and transfer ladle. These probes incorporate chill
A1.2.3 When sampling from ladles and secondary treatment plates of varying thickness to ensure that the liquid iron of the
vessels, a mechanical system can be used to lower and raise the sample is chilled very rapidly. Two types are illustrated as
lance. follows:
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A1.3 Stream Sampling Probes metallurgical structure of the sample that may vary through the
A1.3.1 Probes of the type shown in Fig. A1.6(a) consist of thickness of the disk. The type of sampling probe used and the
a steel split mold with an exposed entry tube of silica held by method of preparing the disk sample should be selected to
a plug in a cardboard tube of length 100 mm to 225 mm. provide a surface structure of either white or grey iron in
Samples are of the disk-and-pin type. accordance with the requirements of the analysis method.
FIG. A1.6 Examples of (a) Stream Sampling and (b) Suction Sampling Probes
A1.6.2.1 In the case of a disk sample obtained from liquid A1.6.3 In routine practice, probe samples should be exam-
iron, it is usually necessary to remove a layer of thickness ined regularly to ensure the suitability of the prepared sample
approximately 0.5 mm to 1 mm from the surface of the disk for the analysis method.
sample.
A2. SAMPLING PROBES FOR USE WITH LIQUID STEEL FOR THE DETERMINATION OF HYDROGEN
A2.1 General held in a cardboard tube. The top end of the tube is open or may
A2.1.1 Disposable probes for taking samples from liquid be covered with aluminum foil. The tube has a side entrance
steel for the determination of hydrogen usually consist of a port covered with aluminum foil. The tube may contain
mold made from pressed steel or silica tubing mounted in a aluminum wire as a deoxidant, typically a mass of approxi-
thick-walled protective cardboard tube. Probes are designed to mately 0.1 g. This type of probe is used in a wide range of
obtain a pin-shaped or pencil-shaped sample, 7 mm to 12 mm applications for taking samples from liquid steel.
in diameter by 75 mm to 150 mm long, from liquid steel in
A2.3 Suction Sampling Probes
ladles, ingot molds, and continuous casting tundishes and
molds. A2.3.1 Types of Probes for Suction Sampling:
A2.1.2 Several types of sampling probes are available A2.3.1.1 An evacuated probe of the type shown in Fig.
commercially; the main features of which are described in the A2.1(c) consists of a steel sleeve and a sample chamber made
following sections with illustrative examples shown in Fig. from high-purity iron with an internal diameter of 4 mm. The
A2.1. probe is mounted in a cardboard tube and sheathed with a
A2.1.3 The dimensions given in this annex are for informa- heat-resistant material. The probe may have a protective slag
tion only. cap. On immersion in the melt, the fusible cap melts and liquid
steel is aspirated into the evacuated sample chamber, which
A2.2 Immersion-Sampling Probes then closes as the metal solidifies, thus sealing the probe.
A2.2.1 Two Types of Probes for Immersion Sampling: Hydrogen, which diffuses from the sample, is captured in the
A2.2.1.1 Probes of the type shown in Fig. A2.1(a) consist of outer evacuated chamber and is measured when the probe is
a silica tube, 7 mm to 9 mm in internal diameter contained in inserted into specially designed analytical equipment and the
a protective cardboard tube. The top end of the tube is open and probe pierced. Any residual hydrogen remaining in the sample
the bottom end is capped with aluminum foil to prevent ingress can be measured separately after removal of the sample
of contaminants. The cardboard tube is 250 mm or 400 mm in together with the sample chamber.
length depending upon the application and has a refractory A2.3.1.2 Probes of the type shown in Fig. A2.1(d) consist of
anti-splash coating. This type of probe is used for taking a pressed steel split mold, 7 mm to 9 mm in internal diameter
samples from liquid steel at temperatures near to the liquidus by 75 mm long, with a silica entry tube. The mold is held in a
point of the steel. cardboard tube by a collar. Air is removed from the mold to
A2.2.1.2 Probes of the type shown in Fig. A2.1(b) consist of create a partial vacuum by using a compressed air venturi
an exposed silica tube, 10 mm to 12 mm in internal diameter, pump.
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FIG. A2.1 Examples of Probes Used for Sampling Liquid Steel for the Determination of Hydrogen: (a) and (b) Immersion Sampling
Probes, (c) an Evacuated Sampling Probe, and (d) a Suction Sampling Probe
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