Unit 8 Acids and Bases

1 1
d Titration Curves
Htt CHzCHzCÉ fÉ
agency
H

j a
concentration 841
strongacid Ht andstrongBase
14
Fettesson If dÉÉ
calculatednot
weak acids partially ionize in
water to produce Hzotions
P t tnotdan
cotDwater
47mi
water is amphoteric can behave as an acid or base
ReactionQuotient
Quantitiesof products or
rxnoIctD
caIII.IE it
calcwith
water Ka of weak acid
Acid dissociation
ii constant A
og meon equivalence p measure of acid strength

a
tf a
coz thecost of m.mn
solids is and purecounsel weakacidhaltstrong Base excesson is En't to
ka I for a weakacid
A solution ofweakacidinvolves
pts a cantthocietacaaltoticaa
qq.gesscon.fm
are not included in Q because
ptrateavivalencepointisbasic
equilibriumbetween an un ionized
thot cos Hot Qc I Qp IcaIIeauivaenap
of ran baseand
water betweenconjugate

Egg.jo
coz not base
that is astrong because

Base acid K Equilibriumconstant usedinstead of one we

v point and
e'avivalenceptivieantaience
it's conjugate
resistschange in
co
upon
pka 10g ka
Q when a system is at equilibrium addition of on ya

941
Kc o weakbase Y strongacid when Ctia Cat pHpka
ptl logCtizot potts logCott HendersonHasselbach when Cha Ca J propria
pts pratlog Eas
gyppxygggiiiiiiiiiiiiiiii phat equivalence
of ran
not
pointsac
acidwith
betweenconjugate
because'trant d
water
astros
when CHA CaT pHpka

d
migf.ggigiinEIm
o and
contributionis
or pressures of reactantsand excesstitltyte

products Iftemperature changes

BufferzoneweakBasealandit's
basecat
conjugate Largerkalkbs strongeracidbase
Autoionization of water K will change smamp.am onsuaad
tho it thou head min Buffer zones
weak acid strongBase Acid
weakbase strong
BASE ACID CA CB DYE.ci pfo8ffI G'fauokured n
weak basespartiallyionize in

iffy
water to produce oh ions
Kw CHzOtJCotiJ 250C.k 1 10
1 c
gigginied roars
mm Kb of weak base
verysmall F strongest E
ie if reactants arefavoured F as acid strengtht
o asstrengthofbased involvesequilibrium between
µ K is smaller a
startingpts buffer
zone staring put an un ionized baseandit's
Bissersumpt Biggerdropa buffer
zone
K I products reactants conjugate acid
ma on
Inf's'afetrensatestrength't
In eats'trenstat

K Cl products c reactants strongBases

Kb CHB'TCOAT pkb logKb
strongacids
pure water Fully associate in water
to producerotations
ftp.dissogateionnswaterto
ciote.naoti.rote.rboti.com
CB
Chzot
pKw 14.0 ptl
COM pH putt 7 14
log l 0 10 25 C
K reactiongoesto completion
1000
no reverse reaction
na ter tee cos
no andMason 88111sm'etaffydroxides f fÉÉÉÉÉÉÉ
IIas
cazot decreases
ionizationincreases

00
m K co 0001 the forward reactiondoes
me Torgina

As temperature increasesTpkwdecreasest Example Buffers pHrange pka II

As temperature increases i kwincreases
endothermic
At Equilibrium Q K
if Q K the numeratormustdecrease
to make Q K Products decrease
original
Addjoominen
100.0miofo.iomticizoo.omofo.us
mad
In
concentrationhalves
ge n p
1.30 1.00 0.30
a solutionthatresistschangeinpH
when asmallamountofstrongacid
or it'sbaseisaddedtosolution
Temp
and reverse reactionis favoured 200.0mi of0.50MNaOH 0.507102004410.300
no ing or weakbaseand it's c a salt
0.33M x sourced for e
aa G3 10
15 If Qe K the numeratormustincrease e g teno and no g
to make Q k the productsmust 300.0miof o33mn aot13.52 13.70 0.17 fromsodiumsaltof cA likenano
25 in o i ox 300.0midistilledwater 400.0midistilledwater pH7.00
increase and forward Reaction Chzot ka ptl pkawhen
30 13 8 1 oxio The largerthe change in concentration nochange concentrationsofweak
acidand
3 2 10
1 ng am conjugatebase are equal