Solutions 2.

WxJOOO Mole fraction of solute =

m =----------
MWxWt. of solvent in grams (3) moles of solute
moles of solute + moles of solvent
Temperature has no effect on molality and mole
(4) All are correct
fraction since the quantities of solute and solvent
are expressed by weights. 13. Which of the following is correct?
Molarity and normality change with tempera- (I) No. of moles in a solution=
ture since the volume of solvent changes with
temperature.
.
mo Iantyx v·LO ,.tires= -w-
MW
(2) No. of millimoles =
Objective Questions
molarityx V in mL =~xJOOO
8. Which of the following statement is correct? MW
(1) A molal solution is that contains one mole of (3) Moles and millimoles of reactants react ac-
solute in 1000 g of solvent cording to stoichiometric ratio of balanced
(2) Molality does not change with temperature chemical equation
(3) Unit of molality is mole kg- 1 (4) All are correct
(4) All are correct statements 14. A solution of known normality is diluted to two
9. A , E, M and n are atomic weight, equivalent times. Which of the following changes occur dur-
weight. molecular weight and valence of an ele- ing dilution?
ment, respectively. The correct relation is (I) Equivalent of solute
(I) A=Exn (2) A=MIE (2) Moles of solute
(3) A=Mlm (4) M=Axn (3) Milli equivalent or milli moles of solute
(4) Normality of solute
10. Which of the following statement is correct?
(I) Molecular weight changes with valency IS. The term 'standard solution' is used for the solu-
(2) Molar concentration of a solution in water is tion whose
always equal to normality of a solution (l) Normality is known (2) Molarity is known
(3) Sum of the mole fractions of all components (3) Strength is known (4) All
in a solution is always exactly one 16. Increase in temperature of an aqueous solution
(4) Equivalent weight of an element is not vari-
causes
able
(I) decrease in molarity
11. Regarding equivalent weight of a substance, which (2) decrease in molality
of the following statement is not correct? (3) decrease in mole fraction
(I) Equivalent weight of an acid depends on the (4) decrease in % w/w
reaction involved with the base 17. One mole of chlorine combines with certain weight
(2) The equivalent weight of an acid is obtained
of a metal giving 111 g of its chloride. The same
by dividing its molecular weight by its acidity
amount of metal can displace 2 g of hydrogen
(3) Equivalent weight of an oxidant is molecular
from an acid. The atomic weight of the metal is
weight divided by number of electrons gained
( I) 40 (2) 20
by one molecule of oxidant
(4) Equivalent weight of a salt is the formula
(3) 80 (4) 60
weight divided by total charge on the cation or 18. 5 mL of N HCI, 20 mL of N/2 H 2SO, and 30 mL
the anion of the salt of N/3 HN03 are mixed together and volume is
made to 1 L. The normality of the resulting solu-
12. Which of the folJowing is correct?
tion is
(1) For a binary solution, sum of the mole frac-
(1) N/5 (2) N/10 (3) N/20 (4) N/40
tions of all components is equal to one
19. I g of pure calcium carbonate was found to require
Mole fraction of I moles of I (ti b'
(2) ora mary 50 mL of dilute HCI for complete reaction. The
Mole fraction of 11 moles of II solution) strength of HCI solution is given by
2.6 Objective Chemistry - Vol. II

(I) 4 N (2) 2 N 28. If 250 mL of a solution contains 24.5 g H 2SO 4• the

(3) 0.4 N (4) 0.2 N molarity and normality. respectively. are
20. What will be the normality of a solution obtained ( l} IM.2N (2) IM.0.5N
by mixing 0.45 N and 0.60 N NaOH in the (3) 0.5 M. l N {d) 2 M. I N
ratio 2: I by volume? 29. An aqueous solution of urea containing 18 g of
{l) 0.4 N (2) 0.5 N urea in 1500 cm 3 of solution bas a density of
(3) 1.05 N (4)0.15N l.052 g/cm3• If the molecular weight of urea is 60,
then the molality of solution is
21. 100 mL of each 0.5N NaOH, N/5 HCI and N/IO
H 2SO 4 are mixed together. The resulting solution (I) 0.2 (2) 0.192
will be (3) 0.226 (4) 0.113
( I) acidic (2) neutral 30. The mole fraction of NaCl in a solution contain-
(3) alkaline (4) None of these ing I mole of NaCl in 1000 g of water is
22. What volume of 0.8M solution is contained in (1) 0.0177 (2) 0.001
0.1 mole of solute? (3) 0.5 (4) 0.244
(l) 100 mL (2) 125mL 31. 84 g of a metal carbonate reacts with 40 mL
(3) 500 mL (4) 0.125 mL of N/2H 2SO4 • The equivalent weight of metal
23. To what extent must a given solution containing carbonate is
40 mg AgNO 3 per mL be diluted to yield a solu- (I) 84 g (2) 64 g (3) 42 g (4) 38 g
tion containing 16 mg of AgNO3 per ml? 32. The normality of 1% (w/v) H 2SO4 is nearly
(I) Each mL should be diluted to 2.5 mL (I) 0.02 (2) 0.2
(2) To each mL of solution 2.5 mL of water (3) 0.1 (4) l
should be added
(3) To 1.5 mL of solution 2 mL of water should be 33. Equal volumes of O.IM AgNO3 and 0.2 M NaCl
added are mixed. The concentration of NO3 ions in the
(4) To 1.5 mL of solution 1.5 mL of water should mixture will be
be added (I) 0.1 M (2) 0.05 M
(3) 0.2 M (4) 0.15 M
24. 171 g of sugar (MW = 342) are dissolved in I 000 g
of water at 30°C. Its 34. 1.5 L of solution of normality N and 25 l of 2 M
{l) Molarity< Molality HCI are mixed together. The resultant solution has
(2) Molarity = Molality a normality of 5. The value N is
(3) Molarity > Molality (.I) 6 (2) IO
(4) None (3) 8 (4) 4
25. Concentration of HCI is ION• 100 mL of IN HCI 35. The molarity of 15% (w/v) solution of H 2SO4 of
can be obtained by diluting density 1.1 g/ cm 3 is approximately
(I) IO ml of cone. HCI to 100 ml (I) 1.2 (2) 1.4
(2) 20 ml of cone. HCI to 100 ml (3) 1.8 (4) 1.68
(3) 100 ml of cone. HCI to 200 ml 36. The density of NH 4 OH solution is 0.6 g/mL. It
(4) 100 mL of cone. HCI to 100 ml contains 34% by weight of NH 4 OH. Calculate the
26. 45 g of acid of MW 90 neutralized by 200 mL of normality of the solution.
5 N caustic potash. The basicity of the acid is (1) 4.8 N (2) ION
(1) I (2) 2 (3) 0.5 N (4) 5.8 N
(3) 3 (4) 4
37. If 0.5 mole of BaCl2 is mixed with 0.2 mole
27. Mixing up equal volumes of 0.1 M NaOH and of Na 3 P04 , the maximum number of mole of
0.1 M CH 3COOH yields a solution which is Ba3(PO,)2 that can be formed is
(I) basic (2) acidic (I) 0.7 (2) 0.5
(3) neutral (4) none (3) 0.3 (4) 0.1
 Solutions 2.7

38. 500 mL of NaOH solution contains 4 g. To neu- (1) 0.1 M (2) 10-2 M
tralize 25 mL of this solution, the volume of deci- (3) 10-3 M (4) 10~ M
normaJ HCI required is
46. Which of the following solution has the highest
( I ) 25 mL (2) 40 mL
normality?
(3) 50 mL (4) 60 mL
(I) 8 g of KOH per 100 mL
39. 50 mL of 0.2 N K 2 Cr2O 7 is required to oxidize (2) N phosphoric acid
40 mL FeSO4 solution. The weight of iron pre- (3) 6 g of NaOH per I 00 mL
sent in I L, if atomic weight of iron is 56 (4) 0.5 M H 1SO4
(1) 14g (2) 1.4g
47. Equal volumes of l M K 2 SO4 and 1 M AJi(SO4 ) 3
(3) 140 g (4) 28 g
solutions are mixed. Then which of the following
40. An aqueous solution is 0.01 M CH1OH. The con- is correct?
centration of this solution is nearly equal to (I) The concentration of K + is I M
(I) 0.01 % CH1OH (2) The concentration of AI3+ is I M
(2) 0.0lm CH1OH (3) The concentration of so;- is 2 M
(3) mole fraction of CH 1OH = 0.01 (4) The concentration of aJI the three ions is I M
(4) 0.99 m H2 O
48. Equal volumes of 1 M Na 2SO 4 and I M K2SO 4
41. Which of the following should be done in order to are mixed. Then which of the following is correct?
prepare 0.4N NaCl starting with 100 mL of 0.3M ( I) The concentration of Na• ion becomes 0.5 M
NaCl? (2) The concentration of So!- ion becomes 2 M
(1) add 5.85 g of NaCl (3) The concentration of K + ion become 0.5 M
(2) and 20 mL water (4) The concentration of all the three ions becomes
(3) add 0.01 mol NaCl IM.
(4) evaporate 10 mL of water
49. If an alloy consists of a mixture of 25 g of metal A
42. If equal volumes of 0. 1 M aluminium sulphate (at. wt= 50) and 30 g of metal B (at. wt= 60). then
and 0.1 M potassium sulphate are mixed together. the mole fraction of A is equal to
then the concentration of so; - ion is (I) 0.23 (2) 0.48 (3) 0.50 (4) 0.70
(1) 0.1 M
50. To convert 10 N HCI to 1/10 N HCI of 1000 cm3.
(2) 0.05 M
(3) 0.2 M
( 1) I cc cone. HCl should be converted to 1000 cc
(4) 0.4 M solution
(2) 10 cc cone. HCl should be converted to 1000 cc
43. The volume of 0.025 M H 1 P04 required to neu- solution
tralize 25 mL of 0.03 M Ca(OH)z is (3) 200 cc cone. HCI should be converted to
(I) 20 mL (2) 25 mL 1000 cc solution
(3) 40 mL (4) 50 mL (4) 100 cc cone. HCI should be converted to
1000 cc solution
44. I 00 mL of 0.2 M Na OH is exactly neutralized by a
mixture of which of the following?
Answers
(1) IOOmLofMHCl+ IOOmLofO.l M H 1 S04
(2) 100 mL of 0.lM HCI + 50 mL of 0.1 M (8) 4 (9) 1 ( 10) 3 (11) 2 (12) 4
H 2SO4 ( 13) 4 (14) 4 ( 15) 4 ( 16)I ( 17) J
(3) 50mLof0.IM HCI+ 50mLof0.I M H 2S04 ( 18) 4 (19) 3 (20) 2 (21) 3 (22) 2
(4) 50 mL of 0.IM HCI + 100 mL of 0.1 M (23) 1 (24) 1 (25) I (26) 2 (27) I
H2SO 4 (28) 1 (29) 2 (30) I (31) 3 (32) 2
(33) 2 (34) 2 (35) 4 (36) 4 (37) 4
45. 10.6 g of a substance of molecular weight 106 was (38) 3 (39) I (40) 2 (41) 3 (42) 3
dissolved in 100 mL. Ten millilitre of this solution (43) I (44) 2 (45) 2 (46) 3 (47) 4
is diluted to I L. The molarity of the resulting (48) 4 (49) 3 (50) 2
solution is