J, H, Wood, C. W. Keenan, W. B. Bull
1. 8! Bowman, University of Tenneseee,
Knoxville. Harper and Row, Pub-
lishers, New York, 1963. vill +531
pp. Figs. and tables. 17. 25 em,
BOOK REVIEWS 2.
“This text isto a large extent an adapts-
tion and condensation of a mare compre~
hensive text plished in 1061 by two of
the above autho (Kenan and Wood).
Reviewed in This Issve- The present text ie designed for students
preparing for careers other than pro-
fessional’ chemists, One recsives "the
J. H. Wood, C. W. Keenan, W. E. Bull, and X. 8. Bowman, Fundamentals of impression that the authors made the
College Chenistey mttake of confusing abbreviation of
Tigorous text with simplification of
Kathrine Blood Hegiman, Chenistey fr the Applied Sciences Inateral, "This weakness more apparent
inthe portions of the text dealing with the
oar Neca, Probe aor Comitey inthe tons ofthe et dealing nt the
ear Bring a rd 3 ring, Motor Choa! Kiain thn inte cpa devs o desert
\ ino sty
zal T Ovrman, Basi Conc of Nuclear Chersatey cre cen for te
Sicy W. Penson, Chesil Casati agro ta ne fice
Witian H, Neral and Freee C. Shi, Genoa Chess ee ree
J.T tals, Programe srt for Sand Tad fave med toed by cern
ft . icf topics which « deeade ago oecupied prom-
“ome P. Lyemght and Clarence M. Wiliam, A Guide to Prognmed | flat pains moet oral ebony
Tanti tanta "On the her “han, mee
Chars. Detonator, Ching 1+ Atami Sewtare and Bond Prorat ove than i sal",
" Organi erry and Waco
Ven H. Bah, Phys See: A Stay of Matt and ergy To cfc nde tina of
‘acu Natanot, Irae Specie of Tnogeic nnd Cortaation Compounds | Tvant materia on ales and nulay
gon W. Bey, Pye and Chori Metis of Separation aan oe han thy ee of
Eeaching Both general and organic chem=
istry, the viedom of induding iil
material from the fields of organic and
Atfred Prock and Gladys MeCoutey, Topics in Chernical Physica: Based on the
Harvant Lectures of Peter Debye
Welter J. Moore, Physical Chemistsy Biochemistry, for example, the Haworth
Ta Gu prema in Ph hexagonal evelie (pyranose) formula for
Jiri Hare, eb aly Colletion of Problems in Physieal Chomistry gisae a s exp are omg
ef Sameivn, Ton Exchange Separations in Analytical Chemistry hensive treatment of some of the other
: a Y e fundamentals of general chemistry
HH, Jafé sod Mion Orchin, Theory and Applications of Ultraviolet Spectro- "To he spectic. Although atomic struc
scopy ture is discussed in Chapter 2 in keeping
vith modern trends, material concerning
tathode raya the disoovery and characters
ind Karl Myrtack, editors, The Enzymes. Volume Ces of fundamental subatomic particles,
heses Coupled to A'TP Cleavage fand the like haa not been Included here
priaetr fs wat done in the larger text. The
f fudent ie simply told that "Modern
researches indicate the existence of about
Fred W. Billmeyer, Jr, Textbook of Polymer Science
Paul D. Boyer, Hoary La
%, Group Transfer; 8)
Willian 1, Nastul, Physical Techniques in Biological Recoarch.
Special Methods
Maret Parkin and Elmer H.St,eitors, Comprehensive Biochemistry. Yolk | twenty partis of mater. Only three of
ses 34 these age impestant in ou presen study:
Alee A. Kramer, Russian-English Chemical Reader: Russko-Angliskays Kniga etre eontcariaial
alga hteniys yo Ebel, ‘suffice for students having had a solid
Aezonder ‘King and. Hons Prombers, German-English Chemival Terminology: | course in highschool chemistry, one
‘Enaliche und deutacho chemise Fachausdrcke {qustiont whether students having cal
SXverage preparation and ality? wil
Aniheny Standen, editor, Enoyelopedis of Chemeat Teehaclogy. Volume 1, | pe’ aale fo formulate any worthadile
AeA concept of the structure of atoms on the
Fz Soba, Ton Flotation Sha ech an abbreviated ase,
aoe ‘The sections dealing with valence bonds:
Chaves D. Holand, Malticomponent Distilation leo ules from brevity of presentation
‘The aon-polar and polar characteristics of
substances receives only alight and in
‘Gdental treatment. No reference is mado
1M. Kolthaf, Philip J. Eleing and Ernest B. Sandel, editors, Treatise on Ana-
Ita! Chemistry.” Part TT, Analytical Chemistry of the Elements. Volumes
aan jin the index to either the Bronsted or
Moret Plrkin an Hiner H, Stat, eiort, Compshesive Banistry: Vi Tenis coeeptof sede and bast although
ine 8 {he Rept detnton re wed witout
Moree Frkin and Finer H. Stole, editors, Comprehensive. Biochemistry. eT i te et ola kaon
Vatu 10
Er Tis omer ns rel tn in
Mareel Florkin and Elmer H. Stotz, editors, Comprehensive Biochemists Vol ‘regular chemistry major. It should
ume IT bias ay pointed out that some of these concepts:
| met) ee ee oe
Volume 40, Number 9, September 1963 / 497(Chemiatry” whieh was sed aa a text at
four eallege fora year. We ate inclined to
holley im the main that this condensation
of a larger and. worthwhile text wil not
adequately mect the needs of the type of
susdent tacks to serve,
‘The format of the book is i good
taste and the publishers have done thei
ob well, An Instructor's manual listing
‘sxmple examinations, solutions to. probe
rm, Iectire demonstrations, andthe ike
‘accompanies the text.
Joux Da: Vins
‘Calin Callge
Grand Rapids, Michigan
Chemistry for the Applied Scioncor
Katherine Blood Hofman, Plorida State
University, Tallahassee, Prentir-Hal,
Inc Englewood Clifa, New Jersey,
Jo. sit +429 pp. Figs. and tables.
1X 2em. $65,
"This tentbook is described in ite Preface
as “designed primarily for one’ year
college-level couree.” The title implies
that Tt might be a suitable text for engi=
neering students, among others. Acti
tally itis of more limited soope, ARhogh
the author makes no statement shout the
type of student or the particular course
Aowaed which the book it aimed, i¢ seems
tently to have been written to Farsi
background in chemistry to home econom=
ies students of student nurses. Viewed
in this light, the book has much to recom=
mente
‘The development of the principles of
chemistry, (atoms, moleeula, ehemienl
bonding. formulas, equations, typea of
compounds, statexo matter, te), aceapies
the hist 13 chapters (155 pages). Eleven
chapters, (and 146 pages), develop onganie
thomistey from structural thoory through
hnydrocarbong, aleahols, aldelydes, and
Ketones, ete to amino acids and proteins,
‘The author interposse a. yory brit
Chapter 22, Unit of Lifes "The Coll be-
tween eyelie compounds and earbon
hydrates Wo no particular effect. The
Inet five chapters have primarily ta dy
vith bioehomstry and physiology
‘Obviously, a texthook whieh attempts
to over sha wide area of cheistey
ranot be eamplete atl detailed Ta all
‘area. ‘The decision about what to in-
chde, what to abbreviate, and what to
‘omit ‘must be considered ‘carefully with
fone’ aim clearly in mind ‘The wuthor
fostumee that the atdent ising the text
hook will have had no previous experience
in. chemistry." Tndeed, the mnemonic
devices used for the solving af ste sli
tion oncentration problems in Patter
for Writing Pantions and in torneo
with the names of the classes of organic
fimpounds. suguest that this book is
‘weiten particularly for students’ who,
fightly cr wrongly, feel that they: ha
litle “talent for the physieal sciences,
Por such a student the discussion of the
tlecteon configuration of the elaen
Chapter 8 and the use of the
‘hart wil be upsetting; tho uso of valence
498 / Journal of Chemical Education
orbitals in Chapters 14,15 willbe frighten
Ing; and the discussion of stereoisomers
in Chapter 19 wll be completely confusing.
Allin all, however, the thor hie
chosen wisely, if this) reviewer's inter
pretation of the aim of this book be cor
ect, and this texthook should prove to
be tsefal and wsluable to eudents who
ticed. some understanding of chemistry
fsa backgroind for courses in nrition,
pharmacology, and physiology. Beyond
2 few oversights in filing to correct in
proof tome of the ‘mames of “organic
fompouinds, B-methyl pentane and 2,25
trimethyl pentane appear as feo words,
for example), there are few misleading 1
inaccurato statements, This reviewer
was somewhat strpried to read under
Methods of Science in Chapter I that the
final step inthe scientific mthod consists
of “Accepting a thoory established beyond
fll reasonable doubt ss a seieatifie low,”
hhowavor. A. theory ie not capable of
Ioeing proved. true in the sense th
the laws it accounte for aro;. indeed a
theory may’ or may not be true but what
iscaid about it should be.
Auuns 8, Hussey
Narthiestorn Univertty
Eeanaton, Minos
Problems in Inorganic Chemistry
Howori Nechamkin, Trenton. State
College, ‘Trenton, New Jersey. D. Van
Nostrand Co.) Ine, Prinecion, New
Jemey. ix E169 pp. Figs. and
tables 1421 em, $8.75
‘The title of this little paper volume is
mast misleading. Bach! of the first
ihteen chapters opens with a several
page review ofthe topic. The “problems”
fin the topic follow. "The ast chapter only
includes problems and no text. ‘Further
more the toplet covered. inchide. The
Nucleus, Crystals, Thermodynamics, and
Chemica! Kinetice a well ue the more
‘usual topie ineuded under the heading of
Inorgante Chemistry. Tn the ast chapter
1 comiderable portion of the problem
would be better classed ae qualitative
analysis Tt is obvious that the real
attempted coverage is miuch broader than
the title professes,
‘Ansvtert ure included to most of the
questions; however spot check of the
Answers reveals s numberof editorial errors
and. on unfortuate number of factual
frroms. Unfortunately the same mist be
Said of the text material. Avery. few
‘examples will suifice to describe what the
reviewer Gnds disturbing.
NH is described as being eapable of
behaving as either a Lewis or a Bronsted
thus, while CH, is deseribed as eapable of
hohaving asa Bronsted bace onl.
Aqueous solutions of eopper(t) ebloride
are written @ CusCl, lutions
‘oO resets with NaNH ip one plane to
produce NaN; and 110, but in another
plice to preduve the proper presuets,
NaN, NaOH, and NH
‘norine, and
bromine to form stable. tetrahaldes
which release halogen snd foe galore
PbXeealteon heating.
‘The reviewer has formed the
opinion that it would be most tn
tse thie material with students at any
level
SY Tr
University of Novth Carotina
Chapel Hil
Modern Chemical Kinetics
Henry Eyring sod Bavard M. Eyring
both of the: University of Utah,” Salt
Lake City. Reinhold Publishing Corp.
New York, 1968. ix + 114 pp. Flax
and tables” 125 X 19m, Paperbound,
S195.
In the paperback series, Selected Topies
in Modern Chetnstry, severalaneas of
chemistry normally dealt with only briefly
ina first-year course have boen expanded
into little books that ean be neh pe
plomonts tan standard text. This
hook is unlike the volumes which have
Previously” appeared in the serie: "be:
feause of the complesity of the subject
Imattor treated, it be directed “chiely
towaed upperciass chemistry students
rather than thote inthe earlier college
years”. This fact ie clears indicated by
VanderWerl inthe Series
brave undertaken to
sketch some of the important develop
ments of the last three decades in the fl
‘ofchemistey that deals with reaction rate,
Tn ordee to tint this eres the book had
to be so short that the writing of it mist
have involved ite authors in considerable
frustration. ‘The mmber of undergrad
uate students who have “attained the
activated state required to appreciate thie
hook is definitely hinted.” This situation
‘would be impeesible to avoid in a book
‘orauch brevity dealing with atopic of sch
depth, bresdth and volume. Tn the pre-
ce the withors reveal that thelr purpose
isto infect at least a few readers ‘ith
“che typical reaction Kinetiest's ents
sm for hi eet.”
“Tho fist chopter deals with the origin
of the activated state coneept and prewnts
brietythe historical development required
for proper appreciation of the subeeqsent
chapters. Wilhelmy’s study of the rate
bf inversion of suerose in 1880 inagtrated
the modera era of chemical kinetin
Willelmy wa the frst to formulate cor
rectly the Kinetic law of a frstorder reac
tion.” The next important step was the
proposal by Goldberg and Wang i
everal_ papers appearing between. i85
nil 1879, of « Principle of Mae Action in
reaction ‘rates and ‘chemical equilibria,
In IS77 van't Hof independently stated
the Principle of Mass Action, and. in
1889 Archeniue propesed the hypothesis
that. molecules must get into an activated
state before they ean reset, "This wok
ia concerned primarily with the siteo-
‘quent development of the aotivated state
oncept as motivated by the hope for aa
fa prin ealeslation of the rate of rea
tion,
“in the second chapter the authors dis.
‘ess potential energy surfaces in eonfigurae