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Q 1.

Which chloro derivative of benzene among the following would under go


hydrolysis most readily with aqueous NaOH to furnish the corresponding
hydroxy derivative?

Q 2. In SN2 reaction of the type


DMF
R – Br + Cl– ሱۛۛሮ R – Cl + Br –
Which one of the following has the highest relative rate?
(a) CH3CH2CH2Br
(b) CH3CH(CH3)CH2Br
(c) C(CH3)3CH2Br
(d) CH3CH2Br
Q 3. CH3CH2CH(Cl)CH3 obtained by chlorination of n – butane, will be
(a) d – form
(b) l – form
(c) meso form
(d) racemic mixture
Q 4. Which of the following is gem dihalide?
(a) CH3CHBr 2
(b) BrCH2CH2Br
(c) CH3CHBrCH2Br
(d) CH3CHBrCH2CH2CH2Br
Q 5. Which of the following can reactive towards SN1 reaction?
(i) C6H5CH(C6H5)Br
(ii) C6H5CH(CH3)Br
(iii) C6H5C(CH3)(C6H5)Br
(iv) C6H5CH2Br
(a) (iii) only
(b) (i) and (iii)
(c) (i), (ii) and (iii)
(d) All of these

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