1.

In haloalkane _____ bond is formed between carbon and halogen.

(a) Ionic
(b) Van der Waals
(c) Covalent
(d) Hydrogen

2.
In haloarene compounds, halogen combines with carbon having which hybridisation?
(a) sp2
(b) sp3
(c) sp
(d) dsp2
3.
In haloalkane, carbon in C-X bond possesses which partial electric charge ?
(a) Chargeless
(b) Positive
(c) Negative
(d) Anionic

4.
What is B in R-OH + PX5 → R-X + B + HX ?
(a) HPOX3
(b) H3PO3
(c) POX3
(d) H3PO2
5.
Which catalyst is used in preparation of bromobenzene by bromination of benzene ?
(a) FeBr3
(b) HBr
(c) AlBr3
(d) Br2
6.
By which name the reaction CH3-Br + Ag-F → CH3F + AgBr is known ?

(a) Grignard
(b) Wurtz
(c) Fitting
(d) Swartz

7.
What are nucleophilic reagents according to Lewis theory ?
(a) Acid
(b) Base
(c) Neutral molecules
(d) Positive ions
8.
On which of the following factors the stability of carbocation depends ?
(a) Resonance
(b) Temperature
(c) Trasition state
(d) Reaction rate
9.
What is called an optically active substbnce ?
(a) Which reflects polarised light
(b) Which rotates the plane of polarised light
(c) Which increases rate of polarised light
(d) Which absorbs polarised light

10.
Arrange giving the sequence order to Br, CI, F and H combined with asymmetric carbon.
(a) H, CI, Br, F
(b) H, CI, F, Br
(c) Br, CI, F, H
(d) H, F, Br, CI

11.
Which substance is inflamable ?
(a) DDT
(b) Freon
(c) CHI3
(d) CHCI3

12.
Which bond is form between carbon and halogen in alkyl halide and aryl halide ?
(a) Ionic
(b) Metallic
(c) Hydrogen
(d) Covalent
13.
Which one is not the use of haloalkanes and haloarenes ?
(a) Drugs
(b) As anesthetic
(c) As solvent
(d) In cement

14.
For which diseases, haloalkanes and haloarenes are used ?
(a) Typhoid
(b) Malaria
(c) Both (A) and (B)
(d) None
15.
In dihalide if both halogen are combined with adjacent carbon atom then such halide are known
as ____
(a) geminal halide
(b) vicinal halide
(c) aryl halide
(d) All of these
16.
GIn IUPAC nomenclature method geminal dihalide and vicinal dihalide are known as _____
(a) alkylidine halide
(b) alkylene dihalide
(c) dihaloalkane
(d) dihaloalkyne

17.
Give the reactivity order of alcohol with haloacid.
(a) 1° > 2° > 3°
(b) 1° > 3° > 2°
(c) 3° > 2° > 1°
(d) Not given
18.
High purity and more quantity of haloalkanes are obtained by _____
(a) Reaction of alcohol with sodium halide and con.H2SO4.
(b) Reaction of alcohol with phosphorus halide.
(c) Reaction of alcohol with H2S in presence of ZnCl2.
(d) Reaction of alcohol with SOCl2.
19.
Iodo alkane is obtained by the reaction of bromoalkane or chloroalkane with solution of NaI
prepared in dry acetone. This reaction is known as _____
(a) Finkelstein reaction
(b) Swartz reaction
(c) Wurtz fitting reaction
(d) Grignard reaction

20.
The boiling point of haloalkanes are higher than their corresponding alkanes. Why ?
(a) C - X bond is polar, so intermolecular forces increases.
(b) C - X bond is non polar, so intermolecular forces increases.
(c) No of carbons are more in haloalkane
(d) M.wt of halides are more than alkanes.
21.
The boiling points of haloalkane compounds are higher than haloarene compounds. Why ?
(a) Presence of strong bond because of short C - X bond length.
(b) Presence of strong bond because of long C - X bond length.
(c) Haloarenes are arometic.
(d) Haloarenes possess more carbon than haloalkane.
22.
Which one is not a type of stereo chemistry ?
(a) Functional group isomerism
(b) Conformational isomers
(c) Optical isomers
(d) Geometrical isomers
23.
The optically active substances which rotate the plane of polarised light towards right hand side
are called _____
(a) levo rotatory (l)
(b) dextro rotatory(d)
(c) racemic mixture
(d) asymmetric carbon

24.
Which one is Lewis base ?
(a) RCOO:-
(b) : SHΘ
(c) : NH2Θ
(d) All of the given
25.
What is the C - Cl bond length in chlorobenzene ?
(a) 169 pm
(b) 177 pm
(c) 196 pm
(d) 167 pm
26.
What is hybridization of carbon containing halogen in haloarenes ?
(a) sp
(b) sp3
(c) sp2
(d) dsp2

27.
_____ is proved harmful to ozone layer.
(a) CFC
(b) CHCl3
(c) CHI3
(d) DDT
28.
Which device is used to measure the magnitude of rotation of the plane of polarised light ?
(a) pH meter
(b) Potentiometer
(c) Spectrometer
(d) Polarimeter
29.
The compounds which possess equal mixture of (+) and (-) isomers are called _____
(a) equimolar mixture
(b) racemic mixture
(c) hybrid mixture
(d) homologous mixture

30.
The easy method to represent three dimensional structure in two dimension is _____
(a) racemic mixture
(b) van't floff rule
(c) fischer structure
(d) resolution
31.
Isopropyl chloride undergoes hydrolysis by _____
(a) SN1 mechanism
(b) SN2 mechanism
(c) SN1 and SN2 mechanisms
(d) Neither SN1 nor SN2 mechanism
32.
A set of compounds in which reactivity of halogen atom in their ascending order is _____
(a) Chlorobenzene, Vinyl chloride, Chloroethane
(b) Chloroethane, Chlorobenzene, Vinyl chloride
(c) Vinyl chloride, Chlorobenzene, Chloroethane
(d) Vinyl chloride, Chloroethane, Chlorobenzene
33.
Alkyl chloride on dehydrochlorination gives _____
(a) Propadine
(b) Propylene
(c) Alkyl alcohol
(d) Acetone

34.
Which of the following compounds is not chiral ?
(a) 1- chloropentane
(b) 2- chloropentane
(c) 1-chloro 2-methylpentane
(d) 3-chloro 2-methylpentane
35.
Which of the following is most reactive towards nucleophilic substitution reaction ?
(a) CH2 = CH - Cl
(b) C6H5Cl
(c) CH3CH = CHCl
(d) ClCH2 - CH = CH2
36.
Chlorination of toluene in presence of light and heat follwed by treatment with aqueous NaOH
gives.
(a) o-cresol
(b) p-cresol
(c) Mixture of o-cresol and p-cresol
(d) Benzoic acid

37.
For the following : (a) I- (b) Cl- (c) Br- the increasing order of nucleophilicity would be _____
(a) Br- < Cl- < I-
(b) I- < Br- < Cl-
(c) Cl- < Br- < I-
(d) I- < Cl- < Br-
38.
Which of the following is correct order of decreasing SN2 reactivity ?
(a) R2CHX > R3CX > RCH2X
(b) RCH2X > R3CX > R3CX
(c) RCH2X > R2CHX > R3CHX
(d) R3CX > R2CHX > RCH2X (X = halogen)
39.
When you heat chloroform with silver powder _____ is formed.
(a) ethene
(b) ethyne
(c) methane
(d) ethane

40.
_____ is obtained when 1-chloro butane reacts with alcoholic potash ?
(a) 1- butanol
(b) 2-butene
(c) 1-butene
(d) 2-butanol
41.
Chlorobenzene reacts with sodium metal in presence of dry ether to prepare diphenyl the name
of the reaction is _____
(a) Fittig reaction
(b) Wurtz-fitting reaction
(c) Sandmeyer reaction
(d) Gattermann reaction
42.
Which of the following is a nucleophilic substitution reaction ?
(a) HNO3
(b) HI
(c) SO2
(d) H2O
43.
Which of the following compounds contain maximum number of π-bonds ?
(a) Bromobenzene
(b) 1, 3-Dibromobenzene
(c) 1, 3, 5-Tribromobenzene
(d) All compounds given have same number of π-bonds.

44.
What is 'P' and 'Q' in the following reaction ? R - OH + NaX + 'P' → R - X + 'Q' + H2O
(a) P = NaHSO4, Q = H2SO4
(b) P = SOCl2, Q = SO2
(c) P = H2SO4 , Q = NaHSO4
(d) P = SO2, Q = SOCl2
45.
What is the change in type of hybridisation of carbon atom participating in SN2 reaction at
transition state ?
(a) sp2 to sp3
(b) sp3 to sp
(c) sp to sp2
(d) sp3 to sp2
46.
What is called CCl2F2 ?
(a) Freon 22
(b) Freon 12
(c) Freon 21
(d) Freon 122

47.
Give the correct decreasing order of density of (i) n - C3H7Cl (ii) n - C3H7Br (iii) n - C3H7I
(a) (i) > (ii) > (iii)
(b) (iii) > (ii) > (i)
(c) (iii) < (ii) < (i)
(d) (i) < (ii) < (iii)
48.
The degree of halide in isobutyl chloride is _____ .
(a) 4º
(b) 2º
(c) 3º
(d) 1º
49.
The hybridization of carbon attached to chlorine in benzyl chloride is _____ .
(a) dsp2
(b) sp3
(c) sp
(d) sp2

50.
Which of the following is an example of a germinal Halide ?
(a) 1, 2 dichloropropane
(b) 1, 4 dichlorobutane
(c) 2 - chlorobutane
(d) 1, 1 dichloropropane

51.
The best method to prepare vicinal dibromoethane is to react _____
(a) Ethene with Br2
(b) Ethene with HBr
(c) Ethyne with Br2
(d) Ethyne with 2 moles of HBr
52.
Which of the following compound is obtained by Sandmeyer reaction ?
(a) Benzyl chloride
(b) Aniline
(c) Chlorobenzene
(d) Phenol
53.
What is the correct order of bond enthalpy of methy halides ?
(a) CH3-F < CH3-Cl < CH3-Br < CH3-I
(b) CH3-F > CH3-Cl > CH3-Br > CH3-I
(c) CH3-F > CH3-Cl < CH3-Br = CH3-I
(d) CH3-F > CH3-Cl = CH3-Br > CH3-I

54.
Which carbon-halogen bond has the lowest bond enthalpy ?
(a) C-I
(b) C - Cl
(c) C-F
(d) C - Br
55.
Which of the following has less bond enthalpy ?
(a) CH3 - I
(b) CH3 - F
(c) CH3 - Cl
(d) CH3 - Br
56.
Which compound rotates the plane of polarized light to the left ?
(a) Laevo
(b) Dextro
(c) Racemic
(d) Diasteromer

57.
How many isomers are possible for Tartaric acid ?
(a) d and l
(b) (±)
(c) Meso
(d) All of the above
58.
if a molecule contain 'n' even number of chiral carbon atoms and it has a plane of symmetry,
then how many optical isomers does it possess?
(a) 2n
(b)

(c) 2(n-1)
(d) 22n-1
59.
If a molecule has n number of different chiral centres, then, how many possible stereoisomers
will it have ?
(a) 2n
(b) n2
(c) 2n+1
(d) 2n-1

60.
Which is the decreasing order of priority for R-S nomenclature ?
(a) -I, -NO2, -CHO, -CH2CH3
(b) -CHO, -COOH, -OH, -CH3
(c) -CHO, -COOH, -OCH3, -I
(d) -NH2, -OH, -NO2, -CH3

61.
How many stereomers will be obtained from 2, 3-dihydroxy butanoic acid ?
(a) 2
(b) 4
(c) 8
(d) 3
62.
A molecule having 3 different chiral carbon atoms, how many stereo-isomers it will have ?
(a) 3
(b) 6
(c) 8
(d) 9
63.
Which of the following will have a mesomer isomer also ?
(a) 2-chlorobutane
(b) 2, 3-dichlorobutane
(c) 2, 3-dichloropentane
(d) 2-hydroxy propanoic acid
64.
The number of stereoisomers possible for a compound of the molecular formula CH3-CH=CH-
CH(OH) . Me is _____ .
(a) 6
(b) 3
(c) 2
(d) 4
65.
Which amino acid does not contains chiral carbon ?
(a) Histidine
(b) Glycine
(c) Alanine
(d) Threonine
66.
Mention the compound not containing any chiral carbon atom ?
(a) 2 - methyl butanal
(b) 2, 2 dimethyl propanoic acid
(c) 2 - hydroxy propanoic acid
(d) 1, 2 dichloro propane

67.
Which of the following is nucleophilic addition reaction ?
(a) Hydrolysis of Ethyl chloride by NaOH
(b) Purification of Acetaldehyde by NaHSO3
(c) Alkylation of Anisol
(d) Decarboxylation of Acetic acid
68.
A organic compound shows complete inversion during SN2 reaction is _____ .
(a) (CH3)3CCl
(b) (CH3)2CHCl
(c) CH3Cl
(d) (C2H5)2CHCl
69.
Which of the following is obtained by hydrolysis of ehtylmagnesium bromide ?
(a) CH3.CH2-CH = CH2
(b) CH3 - CH3
(c) C4H10
(d) CH2 = CH2

70.
Which compound from the following reacts most readily by SN1 mechanism ?
(a) Methyl chloride
(b) Ethyl chloride
(c) 2-chloro propane
(d) 3º-butyl chloride
71.
The rate of the second order reaction depends on _____ .
(a) concentration of neucleophile
(b) only concentration of substrate
(c) concentration of product
(d) concentration of two reactants

72.
Williamson synthesis is _____ .
(a) SN reaction
(b) SN1 reaction
(c) SN2 reaction
(d) None of the above
73.
Addition reaction of alkene with hydrogen halide is known as _____ .
(a) Hydration
(b) Halogenation
(c) Sandmeyer reaction
(d) Hydrohalogenation

74.
Which of the following is a free radical Halogenation reaction ?
(a) Benzene converted to bromobenzene
(b) Phenol converted to chlorobenzene
(c) Benzene diazonium chloride converted to chlorobenzene
(d) Propane converted to 1-chloropropane and 2-chloropropane
75.
By which name the reaction CH3Br + AgF → CH3F + AgBr, is known ?
(a) Grignard
(b) Fittig
(c) Wurtz
(d) Swartz
76.
Which of the following has higher SN2 reactivity ?
(a) 2-bromo propane
(b) 2-bromo-2-methyl butane
(c) 1-bromo propane
(d) 2-bromo-2-methyl propane

77.
The electron attracting group (-NO2) is in both ortho and para positions in chlorobenzene and
substitution of Cl- by : OH- group takes place at high temperature like 368 K. How much
product is obtained ?
(a) 45%
(b) 76%
(c) 93%
(d) 55%
78.
Chlorobenzene can be prepared by reacting aniline with : _____ .
(a) Hydrochloric acid
(b) Chlorine in presence of anhydrous AlCl3
(c) Cuprous chloride
(d) Nitrous acid following by heating with cuprous chloride
79.
By which reaction hexane can be prepared from 1-chloropropane ?
(a) Wurtz reaction
(b) Wurtz - fitting reaction
(c) Finkelstein reaction
(d) Swartz reaction

80.
What is 'A' in the following reaction ?
A + NaOH → CHCl3 + HCOONa + H2O

(a) Chloroform
(b) Chloral hydrate
(c) Chloral
(d) Carbon tetrachloride

81.
Where Freon-12 is used ?
(a) In refrigerator and airconditioner
(b) As antiseptic in medicine
(c) For extinguishing fire
(d) As cooking gas

82.
Which two reagents are required to produce D.D.T. ?
(a) Chloral and chloroform
(b) Chloral and chlorobenzene
(c) Chloroform and chlorobenzene
(d) Chloroform and CCl4
83.
Which of the following compounds causes red rashes, if it comes in direct contact with skin ?
(a) CCl4
(b) CHCl3
(c) CH3Cl
(d) CH2Cl2

84.
The boiling point of the following haloalkanes follow the order _____ .
(a) C2H5Cl > C2H5Br > C2H5I
(b) C2H5I > C2H5Cl > C2H5Br
(c) C2H5I > C2H5Br > C2H5Cl
(d) C2H5Br > C2H5I > C2H5Cl
85.
Which of the following statements is correct ?
(a) Most of the molecules obtained from plants or animals are unsymmetrical.
(b) In Fisher projection the groups in normal position are to be seen on the front side of the
plane of paper.
(c) Geometrical isomerism is seen only in compounds having double bonds.
(d) All the tetrahedral carbons are chiral carbons.
86.
Which of the following compounds does not show optical activity ?
(a) p.Br-C6H4-CH2-CH2-CH3

(b) C6H5-CHCH3-CH2Br

(c) C6H5C.(CH3)2Br

(d) C6H5-CH2-CHBr-CH3

(a) (a) and (d)

(b) (a) and (c)
(c) (b) and (d)
(d) (c) and (d)

87.
The order of ease of SN1 reactions in alkyl halides is _____ .
(a) 3º-halide >2º-halide > 1º-halide > CH3X
(b) CH3X > 1º-halide > 2º-halide > 3º-halide
(c) 3º-halide < 2º-halide < CH3X < 1º-halide
(d) 3º-halide >2º-halide = 1º-halide > CH3X
88.
For which of the following only two isomeric monochloro derivatives are possible ?
(a) n-butane
(b) 2, 4-dimethyl pentane
(c) Benzene
(d) 2-methyl propane
89.
Choose the correct option about the following sentences. (T = True and F = False)
(i) In SN1 reaction, always racemic mixture is formed and for SN2 reaction, in 50% cases,
racemic mixture is formed.

(ii) SN1 reaction occurs through carbonium io mechanism, while SN2 reaction occurs through
free radical mechanism.

(a) T, F
(b) F, F
(c) F, T
(d) T, T

90.
How many chiral carbon atoms are there in 1-chloro-2, 5-dimethyl cyclohexane ?
(a) 3
(b) 1
(c) 2
(d) 0

91.
Select the correct order of some important group for absolute configuration of Chiral
compound.
(a) -SO3H > -CH2OH > -COOR > -OCOR
(b) -SO3H > -OCOR > -COOR > -CH2OH
(c) -CH2OH > -COOR > -OCOR > -SO3H
(d) -SO3H > -COOR > -OCOR > -CH2OH

92.
What are 'X' and 'Y' in the following reaction ?
3CCl4 + 2X

3CCl2F2 + 2SbCl3

(a) X = SbF3, Y = SbF5

(b) X = SbCl3, Y = SbCl5
(c) X = SbF3, Y = SbCl5
(d) X = SbCl5, Y = SbF3
93.
The correct priority order for the R and S nomenclature of 3-bromo-2-methyl pentane molecule
is _____ .
(a) -Br, -C2H5, -CH(CH3)2, H
(b) -Br, -(CH3)2CH, -C2H5, H
(c) -(CH3)2CH, -C2H5, -Br, H
(d) -H, -C2H5, -CH(CH3)2, -Br

94.
What is the correct relation for SN2 reaction ?
(a) rate = K [S] [Nu]
(b) rate = K [S]2
(c) rate = K [Nu]2
(d) rate = K [S]2 [Nu]2
95.
Toluene reacts with halogen in the presence of iron (III) chloride giving ortho and para halo
compounds. What is this reaction called ?
(a) Electrophilic elimination reaction
(b) Electrophilic substitution reaction
(c) Free radical addition reaction
(d) Nucleophilic substitution reaction
96.
Give the name of the following reaction.
CH3CH2Cl + NaI

CH3CH2I +NaCl

(a) Swartz reaction

(b) Finklstein reaction
(c) Grignard reaction
(d) Wurtz reaction

97.
Which is the correct priority order ?
(a) -COOH, -CONH2, -CHO, -COCH3
(b) -COOH, -CONH2, -COCH3, -CHO
(c) -COOH, -COCH3, -CONH2, -CHO
(d) -COCH3, -CONH2, -COOH, -CHO
98.
What amongst the following is followed in a reaction of C6H5CH2Cl with NaOH(aq) ?
(a) SN1 mechanism
(b) SN2 mechanism
(c) Saytzeff rule
(d) Either (A) or (B) depending on the temperature of reaction

100.
Which of the following reaction is an example of nulceophilic substitution reaction ?
(a) 2RX + Na → R - R + 2NaX
(b) RX + H2 → RH + HX
(c) RX + Mg → RMg X
(d) RX + KOH → ROH + KX\
102.
Which is the correct priority order ?
(a) -COOH, CONH2, -CHO , -COCH3
(b) -COOH, CONH2, -COCH3 , -CHO
(c) -COOH, COCH3, -CONH2 , -CHO
(d) -COCH3, -CONH2 , -COOH, -CHO
103.
Arrange the following halides in increasing order SN2 reactivity : CH3Br, CH3CH2Cl, CH3Cl,
(CH3)2CHCl
(a) (CH3)2CHCl > CH3CH2Cl > CH3Cl > CH3Br
(b) (CH3)2CHCl < CH3CH2Cl < CH3Cl < CH3Br
(c) CH3CH2Cl > CH3Cl > CH3Br > (CH3)2CHCl
(d) CH3CH2Cl < CH3Cl < CH3Br < (CH3)2CHCl

104.
Arrange the following halides in increasing order of SN2 reactivity : (i) iso-buryl halide (ii) neo-
pentyl halide (iii) n-propyl halide
(a) (iii) < (i) < (ii)
(b) (i) < (iii) < (ii)
(c) (i) < (ii) < (iii)
(d) (ii) < (i) < (iii)
105.
Which branched chain isomer of the hydrocarbon with molecular mass 72 u gives only one
isomer of mono substituted alkyl halide ?
(a) Neopentane
(b) Isohexane
(c) Neohexane
(d) Tetiary butyl chloride
106.
What is DDT among the following ?
(a) A fertilizer
(b) Biodegradable pollutant
(c) Non-biodegradable pollutant
(d) Greenhouse gas

107.
An acyl halide is formed when PCl5 reacts with
(a) amide
(b) alcohol
(c) acid
(d) ester
108.
The major product obtained on treatment of CH3CH2CH(F)CH3 with CH3O-/CH3OH is
(a) CH3CH2CH(OCH3)CH3
(b) CH3CH = CHCH3
(c) CH3CH2CH = CH2
(d) CH3CH2CH2CH2CH2OCH3
109.
A : Benzyl bromide when kept in acetone water it produces benzyl alochol. R : The reaction
follows SN2 mechanism.
(a) a
(b) b
(c) c
(d) d

110.
A : Rate of reaction of alkyl halide in Williamson's synthesis reaction is 1°R X > 2°R X > 3°R
X
R : It is a type of bimolecular substitution reaction [SN2]

(a) a
(b) b
(c) c
(d) d