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Re-suspension of road dust: contribution, assessment and control through


dust suppressants—a review

Article  in  International journal of Environmental Science and Technology · September 2018


DOI: 10.1007/s13762-018-2001-7

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International Journal of Environmental Science and Technology
https://doi.org/10.1007/s13762-018-2001-7

REVIEW

Re‑suspension of road dust: contribution, assessment and control


through dust suppressants—a review
S. Gulia1   · P. Goyal1 · S. K. Goyal1 · R. Kumar2

Received: 6 December 2017 / Revised: 13 August 2018 / Accepted: 15 September 2018


© Islamic Azad University (IAU) 2018

Abstract
High level of particulate matter pollution in the urban areas of major cities is significantly affecting the human health due to
its toxic chemical constituents. Re-suspension of road dust along with tyre and brake wear are the dominant sources of PM
pollution in the urban area in both developed and developing countries. This paper mainly reviews the contribution of road
dust in ambient PM level, factors affecting re-suspension of road dust and chemical reagents available for dust suppression.
The emission of road dust re-suspension significantly varies based on amount of silt deposited on the road, type of road
(paved and unpaved road, concrete material of the paved road), number and types of vehicles movement. The chemical reagent
such as calcium magnesium acetate, magnesium chloride and calcium chloride are reported to significantly reduce the PM
emissions from road dust in developed countries. Therefore, the efficacy of these chemicals in reducing the road dust from
the urban road in developing countries needs to be evaluated along with the cost–benefit analysis and comparison with the
conventional approach of dust control (road cleaning and washing). However, the associated factors in different countries
may vary significantly as compared to Western countries.

Keywords  Road transport · Road dust · Particulate matter · Chemical dust suppressant · Water sprinkling

Introduction pollution episode during the months of October and Novem-


ber from last few years in Delhi and surrounding cities is one
The elevated level of air pollution in major cities of the of the examples of the impact of seasonal effects and high
world, especially fast-growing developing countries, is one activities of various sources. During this period, pollution
of the major concerns due to its associated adverse effects levels exceed almost 9–10 times of the National Ambient
on human health and the surrounding environment. High Air Quality Standard (NAAQS) values (CPCB 2009; Gulia
exposure to elevated particulate matter (PM) concentrations et al. 2017). The primary sources of air pollution including
results in both chronic and acute health diseases based on the PM and gaseous pollutants in the urban area are vehicular
toxicity of chemical constituents in PM (Wargo et al. 2006; exhaust emissions, re-suspension of road dust, dust emission
Heal et al. 2012; HEI 2017). The high levels of airborne PM from construction activities, industries, waste burning, diesel
also create low visibility and cause material damage. Man- generator (DG) sets emission and many more unidentified
agement of urban air pollution is a very complex issue with and unaccounted sources (Sharma and Dikshi 2016). This
high spatiotemporal variability and dependence on mete- heterogeneity in sources is less in developed countries as
orological factors which sometimes results in severe smog compared to developing ones.
episodes (Gokhale and Khare 2007). The occurrence of air The major significant sources of PM in urban areas are re-
suspension of the road dust, emission from vehicle exhaust
and open biomass burning. Numerous studies reported that
Editorial responsibility: M. Abbaspour.
the road transport-related air pollution is one of the domi-
* S. Gulia nant sources of urban air pollution and continuously contrib-
s_gulia@neeri.res.in uting emission throughout the year (Sahu et al. 2011). The
1 movement of vehicles on the road generates both gaseous
CSIR-NEERI Delhi Zonal Centre, A‑93/94, Naraina
Industrial Area Phase‑1, New Delhi 110028, India and PM pollution, and the later one generates from vehicles
2
CSIR-NEERI, Nehru Marg, Nagpur 440020, India

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International Journal of Environmental Science and Technology

exhaust (due to combustion of fossil fuel) and re-suspension of ­PM10 (Vega et al. 2001). In another study, Grigoratos and
of road dust due to the movement of tyres. Martini (2015) found that at an urban location, brake wear
Re-suspension of road dust is the major contributor dur- contributed up to 55% by mass to total non-exhaust traffic-
ing the months of summer season, while vehicular emissions related ­PM10 emissions and up to 21% by mass to total traf-
and biomass burning are the major contributors during the fic-related ­PM10 emissions. Recently, Bogacki et al. (2018)
winter season in Delhi city (Sharma and Dikshi 2016). It is conducted a study at four selected streets of Krakow (South-
a serious problem in urban cities worldwide (Etyemezian ern Poland) to determine P ­ M10 emissions from re-entrained
et al. 2003a, b). Review of non-exhaust vehicular emissions road dust. It was observed that road dust contributes up to
of ­PM10 and P­ M2.5 and evaluation of its control options are 25% of total P­ M10 concentrations in winter season and 50%
the main focus of the present analysis. The paper reviewed in summer season. The contribution of road dust in Asian
and discussed the contribution of re-suspension of road dust tropical countries is found more compared to cold European
in PM level at different environmental conditions, factors countries due to high silt loading rate on roads. In one of the
affecting the re-suspension of road dust, its measurement studies, Gupta et al. (2007) found that road dust contributes
and estimation methodologies and different control options 21% of ambient P ­ M10 at a residential location in Kolkata.
with more focus on dust suppressants. Further, in the end, However, Gummeneni et al. (2011) found that the road dust
possible applications of dust suppressant on major roads in contributes 40% of P ­ M10 emissions and 26% of P ­ M2.5 emis-
Delhi city have been estimated for road dust control. The sions at an urban location in Hyderabad. In another study,
literature review has been carried out during the year 2017. Gupta et al. (2012) reported highest P­ M10 levels at an indus-
trial area (27%) followed by urban residential area (18%) and
Re‑suspension of road dust least at a slum residential area (15%) in Mumbai.
Further, Pipalatkar et al. (2014) reported highest P ­ M2.5
The most important sources of PM from non-exhaust emis- levels at commercial location (10%) followed by industrial
sions are tyre and brake wear and road surface wear that location (7%) and least at a residential location (6%) in Nag-
emit fine and coarser particles, respectively (Keuken et al. pur city. Recently, Nagpure et al. (2016) estimated the trend
2010). Besides, re-suspension of deposited road dust is one of non-exhaust vehicle emission load of PM in India from
of the direct sources of PM. In Madrid, road dust re-suspen- the year 1991–2020 and found that about 5000 tons of ­PM10
sion contributed ~ 29% of the total P­ M10 concentrations (in emissions from all total non-exhaust sources (including road
range of 23.2–44.1 µg m−3) in the urban area which can be dust suspension, tyre wear and break wear) was in 1991,
reduced up to 15% by efficient street washing (Karanasiou followed by 8000 tons in 2001 and 20,000 tons in 2011,
et al. 2011). The dust re-suspension influencing parameters and as per business as usual scenario, this would become
such as ambient temperature, relative humidity and wind 60,000 tons in 2020. Among all three sources, road dust
speed are observed to be 31 °C, 30% and 1.5 m s−1. Later, contributed 91–92%, while brake and tyre wear contributed
they have analysed that early morning street washing just only 7% and 2%, respectively. It was estimated that share of
before peak traffic hours is the most effective way of dust heavy-duty commercial vehicles (HDCVs) and buses was
control (Karanasiou et al. 2014). highest (34–35%) among the vehicles types moving on road
Further, Amato et al. (2011) estimated that out of total during the entire study period (1991–2020) which might be
non-exhaust vehicle’s PM emission, the road wear con- due to their high dust spreading capacity. For tyre wear, the
tributed 30–60% in Barcelona and Girona cities in Spain share of cars was highest (47–62%) throughout the study
compared to Zurich city where contribution was 15–30%. period. In the case of ­PM10 emissions from brake wear, the
This difference might be due to low silt loading rate on the contribution of cars, HDCVs and buses was estimated to be
road in Zurich (0.2–1.3 mg m−2) compared to Barcelona the highest compared to other vehicles. CPCB (2010a) in
(3.7–23.1 mg m−2) and Girona (1.3–7.1 mg m−2). Later, source apportionment study found that road dust contributes
Amato et al. (2016a, b) reported that in Barcelona, road dust up to 56% of ­PM10 concentration during summer period in
contributed 9–15% of ambient P ­ M10 at the residential urban Delhi city. Later, Sharma and Dikshi (2016) found that road
location and 23–44% at road kerbside site. However, Ho dust contributes up to 27% in P ­ M10 concentrations in Delhi
et al. (2003) reported that crustal matter contributed 11% of city during summer season. This change might be due to
­PM10 and 6% of P ­ M2.5 at urban location in Hong Kong. On improvement in road infrastructure and road cleaning prac-
the other hand, in Mexico City, this estimate was about 54% tices adopted by local authorities in Delhi city and also due

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International Journal of Environmental Science and Technology

Table 1  Contribution of road dust in ambient PM level


Authors Study location Study period Contribution from non-exhaust PM emission

Gupta et al. (2007) Kolkata, India November 2003–November 2004 PM10 (paved road in residential area): 21%
Amato et al. (2009) Barcelona, Spain 15–22 June 2007 PM10 (urban environment)
City centre (8.9%), ring road (34.5%)
Harbour (1.65%)
Amato et al. (2011) Zurich, Girona, Barcelona Zurich: Barcelona and Girona: 30–60% (road wear)
February 2008 Zurich: 15%–30% (road wear)
Girona: July 2008
Barcelona: June 2007
Karanasiou et al. (2011) Madrid, Spain 22–24 September 2010 Road dust contribute 29% of ambient P ­ M10 in urban
area
Gummeneni et al. (2011) Hyderabad, India January 2004–May 2005 Contribution of road dust at urban location in ­PM10
(40%) and P­ M2.5 (26%)
Gupta et al. (2012) Mumbai, India April 2007–March 2008 Contribution of road dust in ­PM10 level
Industrial: 27%;
Urban residential area: 18%;
Slum residential area: 15%
Pipalatkar et al. (2014) Nagpur, India Residential: Contribution of road dust in ­PM2.5 level
September–November 2009 Residential: 6%;
Commercial:
Commercial: 10%;
December 2009–January 2010
Industrial: Industrial: 7%
January–February 2010
Amato et al. (2016a, b) Barcelona, Spain February–March 2009 Contribution of road dust in ambient ­PM10 level
Background site: 9–15%;
Kerbside: 23–44%

to different monitoring locations used in both the studies. Factors affecting re‑suspension of road dust
Table 1 describes the national and international studies on
the contribution of road dust re-suspension in total ambient The literature discussed above concludes that significant
­PM10 and ­PM2.5 level in urban areas. fraction of urban P­ M10 and P
­ M2.5 concentrations is due
The results of various published studies indicate that to non-exhaust traffic emissions such as road dust re-
contribution of road dust re-suspension was found sig- suspension, brake wear and tyre wear. Nicholson (1988)
nificant in urban areas of both developed and develop- described the process of particle re-suspension and its
ing countries. However, the contribution of road dust in influencing parameters. The major influencing factors of
ambient PM level in tropical countries is considered more road dust emission are silt loading on the road, vehicle
due to dry meteorological conditions when compared to types, tyre type (studded and non-studded), pavement
cold countries. The scarce scientific knowledge on non- type, vehicle speed and surrounding land use type.
exhaust fugitive emissions from road traffic especially
in developing countries leads to unreliable description Road conditions
of these particles in air quality models which results in
under-prediction/forecasting of air pollution level. Such The movement of vehicles on paved road generates less
dispersion models are key tools for decision-making in ­PM10 when compared to unpaved road type. Further, the
urban air quality management. size of deposited dust particles and the topography of the
road surface are also important influencing parameters. The

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International Journal of Environmental Science and Technology

re-suspension of particles is more on a smooth surface than as 0.2–1.3 mg m−2, 1.3–7.1 mg m−2 and 3.7–23.1 mg m−2,
irregular surface of an asphalt road. Further, wetness of road respectively. In Utrecht, Netherland and Madrid, Spain,
(wet road) prevents re-suspension of particles when com- these values were measured to be 2.3  mg  m −2 and
pared to dry road. 1.35–4.40 mg m−2, respectively (Amato et al. 2012; Kara-
nasiou et al. 2014). The silt loading rate is always observed
Surrounding environment to be higher side on the industrial paved road than an urban
road which might be due to poor maintenance and deposition
The surrounding area also influences the road dust re-sus- of dust during transport of materials in uncovered trucks.
pension and its chemical composition. Amato et al. (2009) Turoczi et al. (2013) found that silt loading rate on urban
estimated that contribution of re-suspension of road dust in road in three cities (Egyetem, Cholnoky and Jutasi) of Hun-
the total urban ­PM10 level was 8.9% at the city centre and gary was observed to be in the range of 3.4 - 4.9 mg m−2.
34.5% at heavy trafficked ring road in Barcelona, Spain. In In the recent study, Amato et al. (2016a, b) measured silt
one of the studies in China, Jia et al. (2011) reported that loading of 3–6 mg m−2 and 20–40 mg m−2 for urban and
road dust originates mainly from soil (50%), smoke (25%), industrial paved roads, respectively. However, in Indian cit-
and coal and cement dust (15%) in Changzhi city; however, ies, the silt loading rates have been measured in the range
these values are 47%, 26% and 20% in Taiyuan city and of 36–90 mg m−2 which seems to be very high compared
48%, 21% and 22% in Jincheng city. It is also reported that to Western countries. The high silt loading rate is basically
vehicle-induced turbulence is more influencing factor than due to poor cleaning of roads and tropical meteorological
wind speed in road dust re-suspension in urban area. conditions. The comparative analysis of silt loading rate in
different cities of the world is presented in Table 2.

Silt loading rate Traffic characteristics

The silt loading rate is an important parameter to evalu- The intensity of turbulence generated at the back of the vehi-
ate the deposited dust on the road which directly emits and cle influences the re-suspension of road dust which varies
contributes to ambient PM level. Amato et al. (2011) meas- as per vehicles speed and shape as well as vehicle body dis-
ured the silt loading rate in Zurich, Giorana and Barcelona tance (ground clearance) from the road surface (Amato et al.

Table 2  Comparative analysis of silt loading rate in different cities


References Study Area Study Period PM10 Silt Loading Rate
Concentration

CPCB (2010b) Pune (India) 2007–08 123–254 µg m−3 (daily Average on urban road
Bangalore (India) 2007 average) 90 mg m−2
41–266 µg m−3 (daily aver- 36 mg m−2
age)
Amato et al. (2011) Zurich February 2008 30–40 µg m−3 (monthly Zurich: 0.2–1.3 mg m−2
AIRUSE (2016a, b) Girona July 2008 average) Girona: 1.3–7.1 mg m−2
Barcelona June 2007 Barcelona: 3.7–23.1 mg m−2
Sahu et al. (2011), Delhi, India 2010 238 µg m−3 (daily average Average on urban paved (10%
Marrapu et al. (2014) of city) unpaved) road 53.1 mg m−2
Amato et al. (2012), Barcelona (Spain) 17 June–20 July 2009 30 - 40 µg m−3 (monthly Barcelona: 3.6 mg m−2
AIRUSE (2016a) Utrecht (Netherland) average) Utrecht: 2.3 mg m−2
Han and Jung (2012), Seoul (Korea) Icheon 2010 Annual average Average on urban paved road
Sharma et al. (2014) (Korea) ~50 µg m−3 50 mg m−2
~ 60 µg m−3 25 mg m−2
Karanasiou et al. (2014) Madrid, and Barcelona June–July 2009 23–46 µg m−3 in Madrid, On urban paved road
(Spain) daily average) 1.35–4.40 mg m−2
Utrecht (Netherland)

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International Journal of Environmental Science and Technology

2011). Further, particles re-suspend at a threshold value of speeds. In one of the studies, Hussein et al. (2008) reported
the airflow speed which depends on speed and size of the that the particle mass concentrations behind the studded tyre
vehicles (Nicholson 1988). Abu-Allaban et al. (2003) com- at vehicle speed 100 km h−1 were about ten times higher
pared the dust re-suspension from different types of vehi- than at 20 km h−1. Similarly, Pirjola et al. (2010) reported
cles and reported that heavy-duty vehicles (HDVs) emit that by increasing vehicles speed from 50 to 80 km h−1, the
6–8 times more dust when compared to light-duty vehi- emission level increased by approx. 60% for studded tyres.
cles (LDDVs) because of their high vehicles weight and
more friction with the road surface. They have observed
that ­PM10 was generated in the range of 40–780 mg km−1 Road dust emission assessment
­vehicle−1 for LDV and 230–7800 mg km−1 vehicle−1 for
HDV from re-suspension of road dust in different cit- Estimation of road dust emissions
ies of USA. However, re-suspension of road dust emit-
ted ­PM2.5 in the range of 2–25  mg  km −1  vehicle −1 for The assessment of PM emission load from road dust re-
LDV and 15–300 mg km−1 vehicle−1 for HDV. Further, suspension is necessary to further design the control strate-
Bukowiecki et  al. (2010) reported that in Switzerland, gies of overall ambient PM level in an area. Presently, an
­PM10 emissions from road dust re-suspension due to the empirical equation developed under USEPA AP-42 emission
movement of LDVs were 24 ± 8 mg km−1 vehicle−1, and factors is in practice worldwide (where indigenous emission
HDVs were 498 ± 86 mg km−1 vehicle−1 in street canyon factor is not developed) to estimate the road dust emission
urban road. However, these values along freeway were load (USEPA 2011). Separate equations are used for paved
measured to be 50 ± 13 mg km−1 vehicle−1 for LDV and and unpaved road. The input variables required for these
288 ± 72 mg km−1 vehicle−1 for HDV. In another study, formulations are constant values (specific to particle size),
Denby et al. 2013 found that HDVs contribute more to road silt loading rate deposited on the road surface and average
wear as compared to LDVs which is mainly due to high- vehicles weight on the road (Han and Jung 2012).
friction generation by large weighted vehicles. In one of the studies, Denby et al. 2013 developed NOR-
TRIP (NOn-exhaust Road TRaffic Induced Particle) model
Type of vehicle’s tyre and tested in seven European countries to assess the non-
exhaust road dust particle load. NORTRIP is a coupled
Further, studded tyres cause more pavement wear as com- road dust and surface moisture model, with sub-models
pared to non-studded tyres as they provide enhanced vehicle for calculating road dust emissions and the road surface
grip to the road (Zubeck et al. 2005). The high wearing effect moisture. Road dust sub-models predict road dust through a
of the studded tyre is due to stud impact and abrasion due mass balance approach and determine emissions through re-
to scratching when stud leaves the surface (Lampinen 1993; suspension of dust along with tyre and brake wear sources.
Kupiainen 2007). Gertler et al. (2006) reported that the Road surface moisture sub-models determine road surface
wintertime abrasives for traction control result in increased moisture which is essential for the prediction of suspension
PM emissions. In one of the studies, Pirjola et al. (2010) and retention of dust from road surface. Later, Kauhaniemi
indicated that the studded tyre gives 2–28 times higher con- et al. 2014 evaluated performance of NORTRIP model with
centration as compared to a non-studded tyre in summer. In monitored road dust in Central Helsinki and found satisfac-
another study, Kupiainen and Pirjola (2011) reported that tory results. In another study, Norman et al. (2016) used
studded tyres result in higher emission levels than studless NORTRIP model to simulate real-time road dust emissions
tyres. in Oslo and Stockholm and found model performance satis-
factory at kerbside. Amato et al. (2016a, b) applied a model
Speed of vehicle called URBan Information System (URBIS) for road dust
emissions that allows for a more robust estimation of popu-
Nicholsan et al. (1989) reported that increase in vehicle’s lation exposure and health outcomes. On simulation, it was
speed increases dust re-suspension because of the greater observed that road dust contributes 9–15% to P ­ M10 levels at
amounts of turbulence that induces re-suspension at higher background sites and 23–44% at traffic sites.

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International Journal of Environmental Science and Technology

Measurement of road dust emission Numerous chemical dust suppressants of different varie-
ties are available to suppress the fugitive dust emissions, but
Other than above estimation, researchers used different they are more expensive than that of water, though they are
measurement techniques to assess the re-suspension of road more effective in suppressing dust and are applied in much
dust. For example, TRAKER (Testing Re-entrained Aerosols less quantity. While the applications of water and chemical
Kinetic Emissions from Roads) is a technique for measure- dust suppressants are proven as effective options for miti-
ment of concentrations of suspendable ­PM10 above road gating dust, they have to be used judiciously. Their usage,
surfaces which represent an estimate of a road’s potential while reducing dust, can trigger hazardous environmental
to emit particular size PM. It uses real-time aerosol sensors consequences which should be considered before deciding
fixed on a moving vehicle to monitor concentration of dust on the extent to which water and chemical dust suppressants
suspended from the road (Kuhns et al. 2003). It estimates are to be utilized.
­PM10 concentrations by subtracting background concentra- Calcium magnesium acetate (CMA) and magnesium
tions measured in the form of the monitoring system from chloride ­(MgCl2) have been proposed as dust binder and
the concentrations measured immediately behind the front thus used for application on paved roads in Sweden, Austria,
tyres of the system (Han and Jung 2012). Germany and UK in order to mitigate road dust emissions
Another dust emission monitoring system, SNIFFER, (Norman and Johansson 2006; Barrett et al. 2012). CMA and
measures non-exhaust particles under real-world driving ­MgCl2 were used in combination in a South European city,
conditions. In this technique, dust samples are monitored characterized by a relatively dry climate. In this scenario,
approx. 5 cm behind the left rear tyre using TEOM (Tapered emissions of road dust were estimated to reduce ­PM10 and
Element Oscillating Microbalance) and ELPI (Electrical ­PM2.5 background levels by 16–17% and 6–8%, respectively
Low Pressure Impactor) principle-based sampler. Another (as annual average between 2003 and 2009). Application of
ELPI sampler is located at the front of vehicle to measure CMA on daily basis in Hornland and Manor road in London
background concentrations (Pirjola et al. 2010, 2012). reduced the road dust emission by 31–59% and 41%, respec-
tively (Barrett et al. 2012). The frequency of 4- to 5-day
interval of ­CaCl2 and mixture of CMA/CaCl2/MgCl2 could
Dust suppressant for road dust control reduce dust emissions by 30–40% in Helsinki and Sweden,
respectively (Gustafsson et al. 2010; Kupiainen et al. 2011).
Based on the discussions above, it is concluded that re-sus- Road dust control activities (using M ­ gCl2) have been
pension of road dust is one of the major sources of PM con- recently tested in one of the commercial districts of Barce-
centration in urban environment. Therefore, control of PM lona. This has resulted in a daily reduction in ­PM10 meas-
emissions from re-suspension of road dust can significantly ured at traffic site by 7–10%, wherein larger decrease was
reduce the ambient PM level. observed for specific tracers of mineral and brake dust. The
In developing countries including India, sprinkling of application of C­ aCl2 reduced road dust by 12% at one of the
water on road (road washing) is one of the measures for roadways in Netherland in four months duration (McCrae
road dust control at selected road. The manual and mechani- 2009). Similarly, the frequency of 10-day interval of M ­ gCl2
cal cleaning of deposited road dust is also being practiced suppression on road can reduce 56% of dust emissions in
in many cities. Presently, water is one of the most primitive Norwegian tunnel (Norway), whereas active asphalt (as
agents which is used as dust control measure in these coun- dust suppressants) if applied on daily basis can reduce up
tries. But it is less efficient as compared to other chemical to 10% (Aldrin et al. 2008). The application of ­MgCl2 or
agents (Amato et al. 2010). Amato et al. (2010) reviewed the mixture of ­CaCl2/MgCl2 on daily basis could reduce up
effectiveness of street sweeping, washing and dust suppres- to 17% and 50–70% of road dust emissions in Trondheim
sants for control of road dust emissions and suggested that (Norway) and Colorado (USA), respectively (Sanders et al.
more observations are needed to address exhaustively the 1997; Berthelsen 2003). The recurrence of CMA after
performance of these road dust control mechanisms. Foam- every 21 days or after several days in a row can reduce road
based systems are also used to reduce dust in many places dust emissions by 35% in Stockholm (Sweden) (Norman
in developed countries. and Johansson 2006). In recent past, Gatosa et al. (2015)

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International Journal of Environmental Science and Technology

assessed the effects of water and stillage molasses on Gravel Factors affecting efficiency of dust
road at a sugarcane estate in Zimbabwe and observed that suppressant
dust deposition rates decreased by 77–83% when treated
with molasses as compared to water which reduced only The chemical and physical properties of the dust suppres-
(18–39%). Recently, Amato et al. (2016a, b) compared the sants are one of the important influencing parameters in
street washing (with water) and calcium magnesium ace- deciding their efficacy in controlling the road dust. It is
tate (CMA) efficiencies at two industrial roads (paved and found that most of them are whitish and transparent in col-
unpaved) in the ceramic industrial site of L’Alcora (Eastern our and having pH in the range of 6–10. All these chemicals
Spain). The results indicated that street washing (18%) was are water soluble and sprinkled on the road in water mix-
more effective than CMA in first few hours observations. ture. The chemical mix in water is suggested as 4% (CMA),
However, effectivity of both control measures should be 30–35% ­(MgCl2) and 32–38% ­(CaCl2). This percentage
evaluated for longer period along with the economic aspect range varies based on the moisture absorbing efficiency
as dust suppressant adheres for longer duration as compared of the chemical. The principle of dust control of all these
to water. In another study, Plessis et al. (2016) compared chemicals is more or less same. They are spread on the road
the road washing (water) and lingosulphonate efficacies at in solution form and a film is formed over the dust particles
two mine haulage road sections, and it was observed that in which reduces the evaporation rate of water and absorbs
case of dust palliative, application frequency decreased by moisture from the air, thus resulting in dust attachment with
50% and dust fallout by 53.8%. Also, the economic aspect the road, even at higher movement of traffic on the road. The
in terms of savings on maintenance, running and fuel cost of duration of effectiveness of dust suppressant always depends
the vehicles was 30% less for dust suppressant as compared on chemical dose and its moisture absorbing capacity; the
to water only scenario. However, no particular study was higher the dose, the more will be the time interval for next
found during literature review which shows the application spray. It is also reported that quantity of chemical that needs
of chemical dust suppressant in India for reduction in dust to be applied second time is always less than the first one or
emissions. approx. 40–50% of the initial dose. These chemicals are non-
Table 3 describes the reduction in road dust re-suspension toxic and biodegradable but generate heat due to exothermic
due to the use of dust suppression chemicals on the road in reactions which need to be handled with precautions. Table 4
different cities of the world. The quantity of chemical used describes physiochemical properties of selected well-known
on road varies according to the type of road, i.e. paved and dust suppressants discussed in the previous section.
unpaved road, concrete or black top road.

Table 3  Review of the chemical agent used for dust suppression on paved roads
Study Name of chemical City/country Quantity of Frequency of PM10 emission reduc-
chemical applied chemical applied tion from road dust (%)
(g m−2) on road

Sanders et al. (1997) CaCl2/MgCl2 Colorado (USA) – Daily 50–70%


Berthelsen (2003) MgCl2 Trondheim (Norway) – Daily 17%
Norman and Johansson CMA Stockholm (Sweden) 40 21 days 35%
(2006)
Aldrin et al. (2008) MgCl2 Norwegian tunnel (Nor- 20–40 Daily 56%
way)
McCrae (2009) CaCl2 Roadway (Netherland) – 4 months 12%
Gustafsson et al. (2010) CMA/CaCl2/MgCl2 Sweden 20 4–5 days 30–40%
Kupiainen et al. (2011) CaCl2 Helsinki (Finland) 20–30 Daily 60%
Barrett et al. (2012) CMA Manor Road (UK) 10 Daily 41%
Barrett et al. (2012) CMA Horn Lane (UK) 10 Daily 31–59%

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International Journal of Environmental Science and Technology

Table 4  Comparative analysis of physiochemical properties of selected dust suppressants


Sr. no. Parameters Calcium magnesium acetate (CMA) Magnesium chloride Calcium chloride

1 Colour White to grey White to grey white Colourless, white, off-white


2 pH 8–10 7 9
3 Chemical formula C8H12CaMgO8 MgCl2·6H2O CaCl2
4 Form of use
 Water 96% 65–70% 62–68%
 Chemical 4% 30–35% 32–38%
5 Principle of dust When CMA spreads, dust particles On application of ­MgCl2, com- Used as dust palliative for unpaved
suppressants on the surface are imprisoned in pound attracts moisture from air surfaces to control dust. Being
agent the substrate and cling firmly to it. and resists evaporation, thereby hygroscopic and deliquescent, it
It is the Calcium and magnesium binding with fine dust particles to keeps the surface moist and inhib-
ion that remain on the dust surface keep road dust stabilized its dust creation over a wide range
and absorb moisture thereafter of temperatures and humidity
6 Toxicity Low toxicity and biodegradable Non-toxic and safe for handling Non-toxic, but generates heat when
mixed with water. Need precau-
tion for handling
7 Cost ($ per ton) 1150–2100 150–160 105
Reference AIRUSE (2017) Eddie and Roger (2009) Leo Caouette (2017), OCE (2017)

The cost of these chemicals (per ton) is about altitude of ~ 215 m above mean sea level. The vehicles popu-
$1150–2100, $400–700, $150–160 and $105 for CMA, lation has increased up to 8.83 million in 2015. The current
sodium alginate, M ­ gCl2 and C­ aCl2, respectively. These total road length in Delhi city is 33,198 km with 864 signal-
chemicals have low corrosive nature, safe for concrete road, ized and 418 blinker traffic intersections. Out of the total
excellent inhibitor which reduces chloride corrosion and road length, arterial/ring road/NHs is about 470 km, main
safe for human health. However, at high dosage, CMA solu- road length is about 350 km, and main feeder road length is
tion may reduce friction between road pavement and tyres about 2000 km, where high traffic movement takes place and
(AIRUSE 2016b). For traffic safety, a number of measures road dust control will be more desirable (CPCB 2010a). As
need to be taken such as low-speed limit, i.e. it needs to be per Indian Meteorological Department (IMD 2017), Delhi
50–30 km h−1 and needs to put warned road signals for driv- city experiences four major seasons across the year: summer
ers of possible slippery conditions. (March–May), monsoon (June–September), post–monsoon
(October–November) and winter (December–February).
However, monsoon in Delhi city starts rarely in the month
of June. It generally reaches Delhi during second/third week
Application of dust suppressants for Delhi of July month. The summer is dry with ambient temperature
city: a scenario analysis going up to 48 °C. During winter, frequent ground-based
inversion conditions occur with temperatures going down
The particulate matter pollution in Delhi city is at alarming to 4 °C.
stage and has already exceeded the daily as well as annual As discussed earlier, street washing and cleaning are not
average NAAQS. Road dust emissions are reported as one so effective to manage the dust emissions; therefore, a theo-
of the significant sources of PM in Delhi city (CPCB 2010b; retical estimation has been done to see the application of dust
Pant et al. 2015; Sharma and Dikshi 2016). Therefore, it is suppressants in reducing the dust emissions from roads in
necessary to control the PM emissions from re-suspension Delhi city. However, no such study is found during literature
of the dust due to the movement of vehicles to further bring survey which shows effectivity of these dust suppressants in
down the ambient PM levels. tropical atmospheric city. So, some assumptions have been
Delhi city has a population of 16.8 million, which has considered in estimation of dust suppressant’s efficiency in
grown at a decadal growth rate of 47% (Census of India reduction in road dust emissions in Delhi city. Some of these
2011) and spread over an area of 1483  km 2 at average are :(1) The dust suppressant performs with same efficacies

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International Journal of Environmental Science and Technology

Table 5  Theoretical estimation of cost required for reduction of road dust in Delhi by applying dust suppressant
Sr. no. Description of items Dust suppressant used in
developed countries
CMA MgCl2 CaCl2

1 Initial dose required (in g m−2) which may be effective up to 1 week (Table 3) 10 30 25
2 Efficiency of dust emission control-based doses as mentioned in Sr. no. 1 (in %) (from Table 3) 40 56 60
3 Quantity of dust suppressants (kg) required for 1-km road stretch of width 3.5 m (single-lane road) 35 105 87.5
4 Cost of materials (in USD per ton) (from Table 4) 1625 155 105
5 Total cost of material for 1-km road stretch (in USD) 57 16 9
6 Total cost required for arterial/ring road/NHs—470 km (assuming average four lane road, two lane 160 46 26
on both sides into and fro way), main road—350 km (assuming average four lane road, two lane
on both sides into and fro way) and main feeder road—2000 km (assuming average two-lane road,
single lane on both sides into and fro way (in thousand USD)
7 Total cost required for Delhi (in million INR) 27 8 4
8 Reduction in ambient P ­ M10 concentration in Delhi city (assuming daily average concentration level of ~14% ~20% ~21%
250 µg m−3 and road dust contribution is 35%, Sharma and Dikshi 2016)

as performed in cold climatic countries (Table 3), (2) silt Conclusion


loading on road does not significantly impact its efficiency,
and (3) it performs with same dose and frequency of applica- The present paper has critically reviewed the literature to
tion on roads having different silt loading rates. find out the contribution of road dust in ambient PM level,
Table  5 describes the theoretical estimation of cost factors affecting re-suspension of road dust and chemical
required for reduction in road dust in Delhi by applying dust reagents for control of dust emission. The analysis of review
suppressant. These dust suppressants, i.e. CMA, M ­ gCl2 and can be summarized as:
­CaCl2, have been compared for the same.
It is found that C
­ aCl2 is more effective and economical 1. Re-suspension of road dust along with tyre and brake
in reduction in dust emission from re-suspension of road wear are the dominant sources of PM pollution in the
dust compared to other two selected dust suppressants. The urban area in both developed and developing countries.
­CaCl2 can reduce the ambient ­PM10 concentration by 21% 2. The type of vehicles (HDV or LDV), the speed of vehi-
with cost of ~ INR 4 million (only material cost) for selected cles, silt loading rate on the road, climatic conditions,
road for a week. Other related costs such as manpower and type of road and surrounding land use are important
water tanker cost are not included in this. The given cost is influencing parameters of PM emission from re-suspen-
for dust suppressant applying first time on the road, which sion of road dust.
will be reduced almost half for the second time on the same 3. The chemical reagents such as calcium magnesium ace-
road and this will be reduced further in subsequent appli- tate, magnesium chloride and calcium chloride are found
cations of dust suppressant. Therefore, annual cost of dust to be used as dust suppressants in individual form and/
suppressants can be worked out based on the frequency and or in combinations. These chemical reagents are found
quantity of materials required in subsequent applications. to significantly reduce the PM emission from road dust
The calculation provides just an idea on the application of in developed countries.
dust suppressants on Delhi road and its efficacy in reduc- 4. Based on theoretical estimations and assumptions, C­ aCl2
tion in dust emission which is based on some assumptions. is found to be more effective and economical dust sup-
However, comprehensive study including experimental setup pressant to reduce road dust emission on Delhi roads
can give more insight into the application of these dust sup- when compared to CMA and ­MgCl2.
pressants for Delhi city which has different climatic condi- 5. The efficacy of these chemicals in reducing the road dust
tions, road infrastructures, road materials, traffic volumes, from the road in developing and tropical countries needs
etc., than the cities of developed Western countries where to be evaluated along with cost–benefit analysis. It is
these dust suppressants work satisfactorily. also suggested to compare the chemical reagents with

13
International Journal of Environmental Science and Technology

the conventional approach of road dust control (road Berthelsen BO (2003) The use of magnesium chloride as dust
cleaning and washing) used in developing countries as reducer at E6 through Trondheim (in Norwegian). Report no.
TM2003/2, Trondheim Municipality, Environment Division,
the road and meteorological conditions in these coun- Trondheim, Norway, ISBN: 82-7727-087-9
tries are different than developed Western cold climatic Bogacki M, Mazur M, Oleniacz R, Rzeszutek M, Szulecka A (2018)
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Krakow and its impact on air quality. In: Proceedings of Xth
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ducting this work. F, Prevot ASH, Baltensperger U, Buchmann B, Gehrig R (2010)
­PM10 emission factors for non-exhaust particles generated by
road traffic in an urban street canyon and along a freeway in
Switzerland. Atmos Environ 44:2330–2340
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