3®° SEM./ CHEMICAL / 2022(W) Th4 INDUSTRIAL STOICHIOMETRY Full Marks: 80 Answer any five Questions including Q No.1& 2 Figures in the right hand margin indicates marks. 1) Answer All questions oP What is normality? What is its unit? What is mole fraction? po» What is vapour pressure? Explain Henry’s law. Define partial pressure. What is stoichiometric ratio? Pe ome ‘What is excess reactant in a chemical operation? i. What is yield in a Chemical Process? j. Define selectivity in a Chemical Process. 2, Answer Any Six Questions a. Find the mass of nitrogen in 100 kg of urea sample containing 96.42% pure urea. b. Explain material balance in an absorption tower. What is molecular weight? What is the molecular weight of CaCO;? Time- 3 Hrs c. 1f20 grams of caustic soda are dissolved in water to prepare 500ml 5 of solution. Find the normality and molarity of solution. d. Ethanol and water form an azeotrope containing 96 % of ethanol by 5 weight, Find the composition of azeotrope by mole %? e. A sample of gas having volume of 0.5 m’ is compressed in such a 3 manner so that pressure is increased by 60%. The operation is done for a fixed mass of gas at constant temperature. Find the final volume of the gas. fA mixture of CH, and C,H has the average molecular weight of 22.4. 5 find the mole % CH, and C,H, in the mixture.g Calculate the density of air containing 21% O,, 79% Nz by volume at 5 a temperature of 313 K and pressure of 1519.875 kPa. The ground nut seeds containing 45% oil and 45% solid are fedto ‘10 expeller, cake coming out from the expeller is found to contain 80% solid and 5% oil. Find the percentage recovery of oil. An evaporator is fed with 15000 kg/hr of a solution containing 10% 10 NaCl,15% NaOH and rest water. In the operation, water is evaporated and NaCl is precipitated as crystal. The thick Liquor leaving evaporator contains 2% NaCi,45% NaOH and rest water. Calculate a) Kg/hr of water evaporated. b) Kg/hr of salt precipitated. rss) c) Kg/hr thick liquor. wy Calculate the number of cubic meter of acetylene gas at a temperature 10 of 313 K and a pressure of 100kPa that may be produced from 5 kg of Calcium Carbide. The dilute acid containing 25% H,SO, is concentrated by commercial 10 grade sulphuric acid containing 98% H,SO, to obtain the desired acid containing 65% H;SO,. Find the quantity of commercial grade acid required to make 1000 kg of desired acid. Ammonia gas is produced by following reaction. 10 NN; + 3H) — 2NH3 Calculate (a) the molar flow rate of hydrogen corresponding to BH nitrogen feed rate of 25 kMoW/hr if they are fed in stoichiometric proportion. EF (b) the kg of ammonia produced per hour if the % conversion is25 [5 | and N; feed rate is 25 kMol/hr A feed to a continuous fractionating column analysis by weight 28 10 percent Benzene and 72 % Toluene. The analysis of the distillate shows 52 weight percent Benzene and 5 weight % Toluene was found in bottom product. Calculate the amount of distillate and bottom product per 1000 kg of feed per hour. Also calculate % recovery of Benzene. We