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Structural controls, temperature–pressure conditions and fluid evolution of


orogenic gold mineralisation at the Betam mine, south Eastern Desert, Egypt

Article  in  Mineralium Deposita · January 2008


DOI: 10.1007/s00126-007-0156-0

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Miner Deposita (2008) 43:79–95
DOI 10.1007/s00126-007-0156-0

ARTICLE

Structural controls, temperature–pressure conditions


and fluid evolution of orogenic gold mineralisation
at the Betam mine, south Eastern Desert, Egypt
Basem A. Zoheir

Received: 16 February 2006 / Accepted: 4 June 2007 / Published online: 17 July 2007
# Springer-Verlag 2007

Abstract The Betam gold deposit, located in the southern granular trails. Clathrate melting temperatures indicate
Eastern Desert of Egypt, is related to a series of milky low salinities of the fluid (3–8 wt.% NaCl eq.). Homog-
quartz veins along a NNW-trending shear zone, cutting enisation temperatures of the aqueous–carbonic inclusions
through pelitic metasedimentary rocks and small masses of range between 297 and 323°C, slightly higher than those
pink granite. This shear zone, along with a system of of the intra-granular and inter-granular aqueous inclusions
discrete shear and fault zones, was developed late in the (263–304°C), which are likely formed during grain
deformation history of the area. Although slightly sheared boundary migration. Homogenisation temperatures of the
and boudinaged within the shear zone, the auriferous quartz trans-granular H2O–NaCl inclusions are much lower
veins are characterised by irregular walls with a steeply (130–221°C), implying different fluids late in the shear
plunging ridge-in-groove lineation. Shear geometry of zone formation. Fluid densities calculated from aqueous–
rootless intra-folial folds and asymmetrical strain shadows carbonic inclusions along a single trail are between 0.88 and
around the quartz lenses suggests that vein emplacement 0.98 g/cm3, and the resulting isochores suggest trapping
took place under a brittle–ductile shear regime, clearly post- pressures of 2–2.6 kbar. Based on the arsenopyrite–pyrite–
dating the amphibolite-facies regional metamorphism. pyrrhotite cotectic, arsenopyrite (30.4–30.7 wt.% As) asso-
Hydrothermal alteration is pervasive in the wallrock ciated with gold inclusions indicates a temperature range of
metapelites and granite including sericitisation, silicifica- 325–344°C. This ore paragenesis constrains fS2 to the range
tion, sulphidisation and minor carbonatisation. Ore miner- of 10−10 to 10−8.5 bar. Under such conditions, gold was likely
alogy includes pyrite, arsenopyrite and subordinate galena, transported mainly as bisulphide complexes by low salinity
chalcopyrite, pyrrhotite and gold. Gold occurs in the quartz aqueous–carbonic fluids and precipitated because of varia-
veins and adjacent wallrocks as inclusions in pyrite and tions in pH and fO2 through pressure fluctuation and CO2
arsenopyrite, blebs and globules associated with galena, effervescence as the ore fluids infiltrated the shear zone,
fracture fillings in deformed arsenopyrite or as thin, wire- along with precipitation of carbonate and sericite. Wallrock
like rims within or around rhythmic goethite. Presence of sulphidation also likely contributed to destabilising the gold–
refractory gold in arsenopyrite and pyrite is inferred from bisulphide complexes and precipitating gold in the hydro-
microprobe analyses. Clustered and intra-granular trail- thermal alteration zone adjacent to the mineralised quartz
bound aqueous–carbonic (LCO2 +Laq ±VCO2) inclusions veins.
are common in cores of the less deformed quartz crystals,
whereas carbonic (LCO2 ±VCO2) and aqueous H2O–NaCl Keywords Gold . Betam . Egypt . Shear zone .
(L+V) inclusions occur along inter-granular and trans- Orogenic gold . Fluid inclusions

Editorial handling: R. Moritz


Introduction
B. A. Zoheir (*)
Department of Geology, Benha Faculty of Science,
13518 Benha, Egypt The Arabian-Nubian Shield (ANS) is a large geological
e-mail: basem.zoheir@gmail.com ensemble covering several countries, i.e. Egypt, Eritrea,

DO00156; No of Pages
80 Miner Deposita (2008) 43:79–95

Ethiopia, Saudi Arabia, Somalia, Sudan and Yemen (2,200 km 34°30′31″ E, about 7 Km west of Gebel El Adrag. The
NS×1,200 km EW). These different areas, accreted during the mineralisation occurs in gold-bearing quartz veins and
Neoproterozoic (950–450 Ma), share a similar geological veinlets along a shear zone cutting through metapelites. The
evolution and several mineral resources (i.e. gold deposits). area has little mineralisation on surface but dumps of the ore
The Eastern Desert of Egypt has long been a mining district for derived from shafts in the mine area grade 6 g/t Au on
gold, with more than 95 gold occurrences mostly confined to average, which indicates economic potential at depth (United
the Neoproterozoic basement rocks (El Ramly et al. 1970; Nations Development Program, UNDP compilation report by
Kröner 1984; Pohl 1988; Abdel Tawab 1992). Mining activity the Egyptian Geological Survey and Mining Authority 1986).
was extensive during the Pharaonic and Roman times and
exploitation of the major gold deposits, e.g. E1 Sid, Barramiya
and Sukari, continued until 1958 (Sabet and Bordonosov 1984 Geologic setting
and references therein).
In most of the gold occurrences in the Eastern Desert, Regional geology
gold occurs in hydrothermal quartz veins cutting through
basement rocks of variable composition (schists, metavol- The basement rocks cropping out in the Betam mine area are
canic rocks, serpentinite and granitoids) and age (pre-, syn- part of a curvilinear ophiolitic belt, associated with the 750–
and late-orogenic). Mineralogy of these veins commonly 720 Ma Allaqi-Heiani suture, in the extreme south of Egypt.
includes fine disseminations of native gold, As-bearing It extends for more than 250 km in an east–west direction
pyrite, arsenopyrite and chalcopyrite together with subor- and merges into a late NNE-trending shear zone, Hamisana
dinate sphalerite, galena, tetrahedrite and stibnite (Azer Zone (Fig. 1). The Allaqi-Heiani suture was formed when
1966). They are interpreted collectively as products of the Gerf terrane (in the north) overrode the Gabgaba terrane
hydrothermal activity (Garson and Shalaby 1976) induced (in the south) before closure of the Mozambique ocean
either by metamorphism or cooling of Lower Palaeozoic (Abdelsalam and Stern 1996; El Kazzaz and Taylor 2001;
magmatic rocks (Almond et al. 1984; Pohl 1988) or Kusky and Ramadan 2002; Abdelsalam et al. 2003). The
subduction-related calc–alkaline magmatic rocks (El Gaby Gerf terrane encompasses volcanic, volcaniclastic and
et al. 1988). Other authors relate gold mineralisation to the sedimentary successions along with ophiolitic and granitic
emplacement of granitoid rocks that intrude mafic/ultra- rocks, generally metamorphosed under greenschist to am-
mafic rocks (Hume 1937; Amin 1955; El Shazly 1957). phibolite facies conditions (Camp 1984; Stern and Hedge
Klemm et al. (2001) further added that gold was deposited 1985). The Gabgaba terrane occupies the western part of the
at 300–400°C and 1–2 kbar, a conclusion supported by Red Sea Hill in Sudan and is made up of immature arc-
Harraz (2000, 2002) for the deposits at the El-Sid and Atud volcanic assemblages (Stern et al. 1990).
mines, Central Eastern Desert. Almond et al. (1984) Geology of the Wadi Allaqi district includes three major
suggested that gold deposition was linked to an episode of tectonic units, namely: dismembered ophiolites, island arc
shearing post-dating the emplacement of all batholithic volcano–sedimentary–plutonic assemblage and syn- and
intrusions and coeval with regional cooling. On the other late-orogenic granitic intrusions (Kröner et al. 1987; Berhe
hand, Hussein (1990) argued that most of these hydrother- 1990; Taylor et al. 1993; Greiling et al. 1994; Sadek 1994;
mal vein deposits were epithermal rather than mesothermal. Abdelsalam and Stern 1996; Shackleton 1996; El Nisr
In all cases, gold is considered to have been leached either 1997; Abdeen et al. 2002; Kusky and Ramadan 2002;
from metabasaltic or ultramafic rocks through the circula- Abdelsalam et al. 2003). The central part of the Allaqi-
tion of metamorphic or mixed metamorphic–magmatic Heiani suture, where the Betam mine is located, consists of
fluids (e.g. Hassaan and El-Mezayen 1995; Harraz 2000; imbricate thrust-bounded sheets and slices of ophiolitic
Klemm et al. 2001; Botros 2004). serpentinite, amphibolite and metabasalt, embedded in a
Spatial and temporal relationships between gold mineral- highly tectonised matrix of talc carbonate, collectively
isation and the tectonic structures in the Nubian Shield have forming an elongate belt (Fig. 2). Successions of pelitic to
been recognised by many authors (e.g. Sabet and Bordonosov psammopelitic metasedimentary rocks, basaltic to basaltic
1984; Harraz and Ashmawy 1994; Loizenbauer and Neumayr andesite layered metavolcanic, metavolcanoclastic units are
1996). This relationship was recently confirmed by the work ductily deformed and tectonically underlay the ophiolitic
of Loizenbauer et al. (2002), who concluded a genetic thrust sheets. These rocks have island arc affinities (Zoheir
relationship between gold mineralisation at the Fawakhir mine 2004). The syn-orogenic intrusions are mainly calc–alkaline
area (26°16′N, 33°38′E) and transpressional tectonics of Late granitoids, covering vast areas north of the mine area
Pan-African age. (Fig. 2). Late to post-orogenic intrusions mainly of olivine
The Betam gold deposit is located along Wadi Um Tenedib gabbro and pink-coloured granite occur as sporadic small
within the Wadi Allaqi district, at Lat. 22°16′42″ N and Long. bodies intruding most of the pre-existing rock units.
Miner Deposita (2008) 43:79–95 81

Fig. 1 a Distribution of the


Achaean–Paleoproterozoic and
Neoproterozoic rocks in north-
east Africa; b tectonic sketch map
of the Allaqi-Heiani Suture and
the northern part of the Hamisana
Shear Zone (modified after Stern
1994; Abdelsalam et al. 2003 and
references therein)

Geology of the mine area ing on the proximity to the mineralised shear zone. The
metasedimentary rocks are brown to yellowish green and
The Betam mine area is underlain mainly by pelitic have a fine-grained schistose structure. The primary,
metasedimentary rocks (i.e. garnet − biotite ± muscovite metamorphic mineralogy includes quartz−biotite−garnet−
schist), metagabbro and pink granite (Fig. 3). These rocks feldspar±muscovite±hornblende±chlorite±epidote. These
display variable degrees of hydrothermal alteration depend- rocks are locally intercalated with alternate quartz-rich and

Fig. 2 Geological map of


the central part of the Allaqi-
Heiani Suture. Inset showing the
location of this part of the
suture in Egypt
82 Miner Deposita (2008) 43:79–95

Fig. 3 Geological map of the


Betam mine area

chlorite+epidote-rich bands. Along the shear zone, both Structural setting


brittle faulting and ductile shearing post-date the metamor-
phic layering. Biotite flakes are preferably oriented parallel As a part of the central Allaqi-Hieani suture, the mine area
to the main northwest-oriented foliation, whereas chlorite has experienced a multi-stage deformation history charac-
commonly occupies late NNW-trending fractures defining a terised by several overprinted folding, transpression and
cleavage foliation. Quartz ribbons with stretched ends are faulting events (Fig. 2). A summary of the structural
aligned parallel to the cleavage foliation. Adjacent to the evolution of the central part of the Allaqi-Heiani suture is
granite masses and along the shear zone, the altered given in Table 1.
metasedimentary wallrocks are iron-stained schists and The metasedimentary rocks form blocks of a disrupted
thickly seamed with a quartz stockwork. fold mosaic extending in a NW-oriented direction in the
In the southwestern part of the mine area, the metasedi- central part of the mine area (Fig. 3). They exhibit abundant
mentary rocks are intruded by slightly foliated medium- to asymmetric folds and contiguous faults and shear zones at
coarse-grained metagabbro. The latter is granoblastic in different scales. These rocks have a well-developed S2
texture and heterogeneous in terms of grain size and schistosity (N45–59°W/44–63°NE), axial planar to F2
proportions of mafic to felsic minerals. It exhibits variable folds. This fabric is defined by preferred alignment of
degrees of alteration approaching the mineralised shear biotite and muscovite flakes. S2 foliation is overprinted by
zones. In the central part of the mine area, close to the shear NNW-trending crenulations and its related S3 foliation. The
zone, small elongated stocks and offshoots of pink-coloured latter varies from an intense mineral foliation overprinting
granite cut mainly through the metasedimentary rocks. This and transposing S2 to a spaced cleavage foliation mainly in
granite unit is composed essentially of quartz, biotite, mi- the hinge zones of F3 folds. Asymmetric dilational bends
crocline, oligoclase, ±muscovite, with accessory zircon and produced by superimposition of S3 on S2 planes accommo-
sphene. Within and adjacent to the mineralised shear zone, date quartz lenses with elongated ends (Fig. 4). The mine
granite suffered intensive sericitisation, subordinate albit- area is cut by several faults with different directions.
isation and kaolinitisation. Significant displacement, up to 2 km, is common along
Miner Deposita (2008) 43:79–95 83

Table 1 Summary of the deformation, metamorphic and magmatic event sequence of the central part of the Allaqi-Heiani belt

Stern (1994) Modified after Zoheir (2004)

Deformation Related fabrics Metamorphism Magmatism

Greater Weak brittle WNW–ESE, NNE–SSW and Emplacement of late- to post-


Gondwanaland deformation N–S joint/fracture systems orogenic intrusions of
break-up (Crustal traverse the syn- and late- gabbroic and alkali-
shortening and orogenic intrusions and the feldspar-rich granite with
escape tectonics; pre-existing rocks with no sharp irregular contacts
∼640–550 Ma) obvious offset
D3: E–W NNW–SSE strike slip faults Retrogressed mineralogy and
compressional crosscutting the former fabrics rock fabrics point out to low
regime (late- and dislocate the ophiolitic grade, greenschist facies
stage blocks, commonly with metamorphic event
shortening) dextral sense of displacement overprinted the peak
Discrete NNW–SSE shear metamorphic fabrics
zones, locally associated with
C–S structures, mortar
texture, pressure-shadows,
etc.
S3 (NNW–SSE) crenulation
cleavage and kinks, coaxial
with F3 axial planes
F3 major and minor folds, best
developed in the island arc
metavolcanics/volcanoclastics
and metasediments
D2: SW–NE Abundant km-scale NW–SE Development of the garnet+ Emplacement of syn-orogenic
compressional strike slip faults, commonly staurolite+hornblende± intrusions (mainly
regime with a sinistral sense of shear. sillimanite assemblage granodiorite). Marginal sub-
(roughly Genetically, these faults are indicates peak metamorphism horizontal intrusive contacts
perpendicular affiliate to the Najd fault under amphibolite facies flat-lying structures
on D1 system conditions including schistosity planes
structures) Rotated garnet, stretched biotite and thrust faults
and staurolite porphyroclasts
with sinistral asymmetry in
the pelitic metasediments
Early, penetrative slate foliation
(S2) striking roughly NW–SE,
by far the most common
minor structure in the area
NW–SE asymmetric upright
folds (F2), overturned to the
NE in places
Greater D1: Fold and Left lateral transpression Upper green schist facies
Gondwanaland thrust system superimposed on the thrust metamorphic event indicated
assembly (750– formation planes as inferred from the by chlorite-garnet-albite
650 Ma) (ophiolite A-type porphyroblasts and assemblage in the metapelites
emplacement) detached quartz ribbons
Major thrust faults led to
juxtaposition of rocks from
different crustal levels,
Ophiolite and island arc rocks
Overturned to recumbent folds
(F1) commonly verging to
S or SE
84 Miner Deposita (2008) 43:79–95

Fig. 4 a Equal area projections


of poles to planes of S2 and S3
foliations in the country meta-
pelites with mean great circles;
b schematic sketch illustrating
the relationship between S3 and
S2 in the eastern part of the
mine area. The shaded zone in
the close up view is intensely
sericitised

the NW-trending sinistral strike slip faults (Fig. 3). Dextral normal to the shear zone. Fault-fill quartz veins are
NNW-trending faults displace the NW-trending faults and relatively thicker in the curved segments of the shear zone
are attributed to a third D3 ductile deformation increment. compared with the straight segments. This might be
NE- and NS-trending faults are also abundant in the mine attributed to development of zones of enhanced permeabil-
area and clearly overprint the NW and NNW-oriented ity (e.g. Gaboury et al. 2001) or preferential quartz veining
structures. along Riedel shear planes (Fig. 6). A “ridge-in-groove”
The gold-bearing quartz veins are confined to a brittle- type lineation (Lin and Williams 1992) is developed along
ductile shear zone (striking N27–36°W/∼70–80°NE, 160 the quartz vein walls. This lineation has the classical
cm wide at average). This shear zone is characterised by appearance of slickensides and striae along the quartz vein
intense fracturing, asymmetric shearing and stretching walls. Sericite as minute flakes together with recrystallised
lineation development (Fig. 5). Grain size reduction, quartz gives the slickensides a shiny appearance at the
sigmoidal deflection of the pre-shear foliation planes outcrop scale. Microscopic investigations showed that
adjacent to the shear zone along with asymmetric micro- quartz along the slickensides is strongly deformed, recrys-
folds and strain shadows collectively imply ductile defor- tallised and fine-grained, typical for deformation under
mation, whereas local brecciation and abrupt displacement greenschist facies conditions (e.g. Lin and Corfu 2002).
of markers in the wallrock at the centre of the shear zone Analysis of structural fabrics, including a consistent top-
denote brittle deformation. Most mineralisation occurs in to-SE-oriented stretching lineation, asymmetries and slick-
the central-shear quartz veins, and little is related to discrete ensides along the shear planes, suggests composite dextral
quartz lenses sub-parallel to the shear zone. An oblique strike-slip and reverse dip-slip components (Fig. 7).
stretching lineation along the shear planes, defined by
chlorite flakes and quartz rods and boudins, pitches
moderately towards the southeast, denoting a significant, Quartz veins
dextral strike slip component. If parallel to the shear planes,
quartz bodies within the NNW-trending shear zone are lens- Three main types of quartz veins with different directions
shaped. This observation suggests a significant shortening have been observed in the mine area, noted as types I, II
and III, in a chronological sequence. Generally, most of the
quartz veins cut through the metasedimentary rocks and
granite. The gold-bearing quartz veins are commonly
confined to the sheared metasedimentary rocks next to
altered granite masses.
Type I veins are the largest among the different vein sets
in the area and are considered as the principal ore bodies,
where most mining activity was localized. Quartz veins
belonging to this type strike NNW and NW are more or less
parallel to the host shear zone (Fig. 8a). They are mainly
dilated, branched milky quartz veins and lenses with a
maximum width of about 150 cm. A 10- to 30-cm-wide
zone of quartz vein-rich wallrocks bounds the main veins.
In the southern part of the mine area, this type occurs as
Fig. 5 Exposure of fault gouge and crushed metasediments along a boudins and lenses with stretched ends along a crenulated
D3-related shear zone at the main entrance of the Betam mine foliation in intensively altered metasedimentary rocks. A
Miner Deposita (2008) 43:79–95 85

Fig. 6 Geometry of the Au-


mineralised shear zone at Betam
mine. In the inset, the R-type
and P-type veins cut the folia-
tion at small acute angles. The
shear, transposed veins and
quartz boudins result from con-
tinuous shearing and deforma-
tion of R-type veins with a
dextral shear. Great circles of
quartz veins along the shear
zone are shown

steeply-plunging ridge-in-groove lineation is developed of coarse-grained quartz, variably fractured and recrystal-
along the walls of these quartz veins. The veins are slightly lised (Fig. 9). Mixtures of calcite, sulphide minerals and
boudinaged within the shear zone (Fig. 8b), implying minor sericite and kaolinite are locally common in zones of
formation before, at least, the last increment of movement intense fracturing and brecciation. Next to these veins, the
along the shear zone. These veins are composed essentially metasedimentary rocks and granite are bleached, forming a

Fig. 7 a Stereographic projec-


tion of poles to planes of mean
foliation of the host rocks, Au–
quartz veins, faults accommo-
dating the Au–quartz veins with
great circles and stretching line-
ation; b sketch block diagram
illustrating the orientation of the
principal stress directions with
regards to the auriferous shear
zone and distribution of quartz
vein types
86 Miner Deposita (2008) 43:79–95

Fig. 8 a Rose diagram of azi-


muths of the different quartz
veins encountered in Betam
mine area. The arrow points to
trend of the auriferous quartz
veins and lenses; b hand speci-
men of intensely sericitised host
rock with a slightly boudinaged
Au–quartz vein

distinct pale halo varying from a few centimetres to metres alteration mineralogy, replacement textures and destruction
in width. There are abundant millimetre- to centimetre-thick of metamorphic fabrics indicate a post-S2 low-temperature
selvages of wallrocks in these veins, especially near the metasomatic assemblage. The mineralogical composition
margins. In the southern part of the mine area, the veins are and intensity of the alteration are dependent on the host
smaller and form a stockwork in granite, especially where rock composition and proximity to the mineralised shear
the shear zone crosscuts the contact with metasedimentary zone. The hydrothermal alteration halo is classified into
rocks at acute angles. three alteration zones, including: (a) proximal pyrite–
Type II veins are drusy quartz bodies, commonly stained sericite zone (quartz+pyrite+sericite±albite), (b) interme-
with iron hydroxides. These veins occur as about 5- to 15- diate sericite–chlorite zone (quartz+sericite+pyrite±chlo-
cm-wide discontinuous lenses and veinlets, crosscutting the rite) and (c) distal chlorite–calcite zone (chlorite+calcite±
metasedimentary rocks in a NNW–SSE direction. These epidote±biotite). These zones pass gradually into each
veins commonly enclose euhedral crystals of glassy quartz, other (Fig. 10).
with their long axes pointing upwards. At the vicinity of Granite shows considerable variations in colour, chem-
these veins, the metasedimentary rocks are altered into a ical and mineralogical composition close and within the
fine-grained quartz–albite–muscovite–biotite rock. shear zone. Potassic–feldspar is replaced by sericite, quartz
Type III veins are deep brown to smoky quartz sheets, and iron oxides, imparting a reddish violet colouration to
rich in empty or limonite-filled vugs especially near the the rock. Andesine plagioclase crystals are altered into
surface. They are commonly 20–30 cm thick but attain a 3-m aggregates of sericite and kaolinite. In other places,
thickness in the central part of the mine area. These veins plagioclase crystals are completely albitised. Biotite is
extend in a N69°W direction, cutting across the aforementioned partially to completely altered into chlorite and hematite
quartz vein types causing slight to no lateral displacement. with minor rutile. Next to the mineralized quartz veins,
biotite and plagioclase are completely altered into sericite,
chlorite, calcite and epidote, and the original magmatic
Hydrothermal alteration texture is completely obliterated. Near the shear zone,
metagabbro shows spotty appearance with chlorite patches
Slight sericitisation characterises zones adjacent to the embedded in a yellowish white background. Albite devel-
barren quartz veins, whereas, an elongated halo of bleach- ops at the expense of plagioclase. Augite and amphibole are
ing and abundant disseminated Fe–As sulphides bounds the altered into chlorite and subordinate calcite and epidote.
type I gold-bearing quartz-veins. The intensity of bleaching Chlorite is commonly associated with fine-grained quartz,
correlates with the thickness of the quartz veins. The pyrite and chalcopyrite.

Fig. 9 Microphotographs show-


ing quartz textures of the aurif-
erous quartz veins in Betam
gold mine: a deformation la-
mellae in a large quartz por-
phyroblast (down-right side of
the photo); b undulating quartz
ribbons with sub-grain devel-
oped along boundaries (grain
boundary migration)
Miner Deposita (2008) 43:79–95 87

Fig. 10 Sketch drawing show-


ing the distribution of alteration
assemblages around the Au–
quartz veined shear zone. Notice
granite is intensively altered into
quartz–sericite–pyrite assem-
blage adjacent or within the
shear zone

Ore mineralogy cases, arsenopyrite crystals have inclusions of electrum (10–


40 μm long) and rare pyrrhotite. Various inter-growth textures
The type I gold-bearing quartz veins are composed of pyrite, suggest coexistence of pyrrhotite inclusions, euhedral pyrite
arsenopyrite, subordinate chalcopyrite and galena, and dis- and arsenopyrite in the quartz veins (Fig. 11). Chalcopyrite
crete gold grains. In quartz veins, gold and sulphide minerals occurs as dispersed anhedral particles in the quartz veins,
are common in domains rich in altered wallrock selvages. commonly associated with galena±gold grains. Blebs and
Arsenopyrite and pyrite are ubiquitous in the mineralised globules of free gold occur along grain boundaries and filling
veins and wallrocks, occurring as disseminated individual microfissures in deformed arsenopyrite and pyrite crystals.
subhedral grains (70 μm–2 mm) or aggregates usually Free gold occurs also as 10- to 20-μm-thick rims within or
confined to quartz grain boundaries or microfissures. In few surrounding altered arsenopyrite and/or pyrite crystals.

Fig. 11 Reflected light photo-


micrograph of a mineralised
quartz vein from Betam mine
shows intergrown pyrite (py)
and arsenopyrite (aspy) and
inclusions of pyrrhotite (po),
chalcopyrite (ccpy) and gold
(Au) inclusions
88 Miner Deposita (2008) 43:79–95

Arsenopyrite geothermometry standardized charts (e.g. Shepherd et al. 1985) with an error of
±10 vol.%. The accuracy of the measurements is estimated as
Arsenopyrite, pyrite and gold in quartz veins and wallrocks ±1°C at 374°C at a heating rate of 5°C/min and ±0.2°C below
were analysed using a JEOL JSM-6310 SEM equipped 0°C at a heating rate of 1°C/min. Measurements were
with a Microspec wavelength dispersive spectrometer at the corrected by linear interpolation between temperature devia-
Institute of Mineralogy and Petrology, Graz, Austria. The tions at the calibration temperatures (MacDonald and Spooner
operating conditions were 20 kV accelerating voltage and 1981). Molar volumes, compositions and isochores were
0.5 ηA beam current. Arsenopyrite crystals were initially
checked for Co, Ni, Bi, Sb and Au, but only traces of Co
and Au were detected. Emphasis was placed on arsenopy-
rite crystals in mutual contact with pyrite and/or pyrrhotite
and containing gold inclusions. Generally, the variation
within a single grain is less than the variation among
different grains from the same sample. The difference in As
contents in a single grain does not exceed 1 wt.%. Traces of
Au were detected in zones with relatively higher at.% of As
and inversely correlated with Fe concentrations in arseno-
pyrite (Fig. 12). Johan et al. (1989) proposed a substitution
mechanism in arsenopyrite: [2As[Fe] (Au,Sb)+Fe], where
As[Fe] is As in Fe sites. Similarly, Wu and Delbove (1989)
reported a negative correlation between Fe and Au in
synthetic arsenopyrite, suggesting substitution of Fe by Au.
Fleet and Mumin (1997) provided a review of earlier work
on arsenopyrite and suggested that invisible Au in
arsenopyrite represents Au removed from ore fluids by
chemisorption at As-rich, Fe-deficient sites and incorporat-
ed as a metastable solid-solution.
If arsenopyrite is buffered with respect to sulphur
activity, the As/S ratio of arsenopyrite is mainly a function
of the temperature (Clark 1960) and therefore can be used
as a geothermometer (Kretschmar and Scott 1976; Sharp et al.
1985). Using the fS2-buffered arsenopyrite–pyrite–pyrrhotite
assemblage in the studied deposit (30.4–30.7 wt.% As in
arsenopyrite), a temperature range of 325–344°C is inferred
(Fig. 13).

Fluid inclusions

Fluid inclusion petrography and microthermometry were


aimed at assessing the nature and evolution of the ore fluids
and constraining the physico-chemical parameters that
controlled gold deposition. The data were collected from
fluid inclusions trapped in the type I gold-bearing quartz
veins. Freezing–heating runs were conducted on inclusions
in nine vein quartz wafers using a fully automated Linkam
THMSG 600 heating–freezing stage with a TMS 93 tem-
perature programmer. The stage was calibrated with syn-
thetic inclusions supplied by Synflinc. Measurements were
carried out at the Mineralogisches Institut, Universität
Fig. 12 a Frequency of As at.% in arsenopyrite crystals from Betam
Karlsruhe, Germany. Fluid inclusions were cooled until deposit; b gold concentrations as wt.% in auriferous arsenopyrite
complete freezing and then heated at rates of 20, 5 and 1°C/min. crystals; c bivariant correlation between gold and arsenic contents in
The liquid/vapour phase ratios were estimated with the aid of the auriferous arsenopyrites
Miner Deposita (2008) 43:79–95 89

H2O–NaCl inclusions (Fig. 14). All inclusions lack any


daughter mineral phase. Microthermometric data were
collected from inclusions in the less deformed vein quartz.
The obtained data, including temperatures of total homog-
enisation (Th total), melting of CO2 (Tm CO2), homogenisa-
tion of CO2 (Th CO2), melting of clathrate (Tm Clath) and
final melting of ice (Tm ice), are summarised in Fig. 15. As
the investigated gold-bearing quartz veins are spatially and
temporally associated with a shear zone, inclusions are
classified into isolated, clustered and fluid inclusions in
intra-granular, inter-granular and trans-granular trails (e.g.
Simmons and Richter 1976; Touret 1981; Kranz 1983; Van
Fig. 13 Activity of S2 temperature projection of the stability field of den Kerkhof and Hein 2001).
arsenopyrite (Barton 1969), with atomic wt.% As arsenopyrite- The carbonic inclusions, approximately 75% of the
buffered curves from Kretschmar and Scott (1976). The hatched area whole population, range from 7 to 15 μm in diameter.
depicts the temperature range and fS2 conditions of precipitation the
auriferous sulphides. As, arsenic, aspy, arsenopyrite, bn, bornite, l, They are commonly oval to negative crystal shaped
liquid, lö, loellingite, po, pyrrhotite, py, pyrite monophase inclusions (LCO2) at room temperature with a
vapour bubble nucleating upon cooling (LCO2 +VCO2).
calculated using the ‘‘Fluids’’ software package (Bakker They occur as isolated, inter-granular and trans-granular
2003). Salinities from ice melting were obtained using the inclusion trails. In the coarse-grained quartz and close to
equation given by Bodnar (1993). Salinities from final arsenopyrite and pyrite, this inclusion type is associated
clathrate melting were based on Diamond’s (1992) equation. with discrete aqueous and aqueous–carbonic inclusions.
For the CO2-bearing inclusions (carbonic and aqueous– These inclusions yielded Th CO2 to the liquid phase ranging
carbonic), the density of H2O and CO2 were calculated by between 20.4 and 29.2°C, corresponding to densities of
applying the equation of state by Saxena and Fei (1987). 0.62–0.77 g/cm3. Generally, the final melting of CO2 (Tm CO2)
Equations of state used for isochore calculations were from occurred between −56.6 and −57.3°C. Lowering of Tm CO2
Bowers and Helgeson (1983) and Zhang and Franz (1987) for below the −56.6 is attributed to the presence of incompressible
the carbonic and aqueous inclusions, respectively. gases, e.g. CH4 or N2. If only CH4 is considered, a maximum
of 0.10 mole fraction (XCH4) is estimated using the graphical
Petrography and microthermometry method of Heyen et al. (1982). Trails of carbonic inclusions
along the sub-grain boundaries are interpreted as having been
The investigated gold-bearing quartz veins are rich in fluid trapped during grain boundary migration and dynamic re-
inclusions. Petrographic observations and heating/freezing crystallisation (e.g. Johnson and Hollister 1995). Other, late-
measurements helped to define three compositionally paragenic, planar arrays of tiny monophase and biphase
different types of inclusions, namely: carbonic CO2 ±CH4, carbonic inclusions (mostly <4 μm long) with elongated to
aqueous–carbonic H2O–NaCl–CO2 ± CH4 and aqueous rounded shapes crosscut populations of the aqueous–carbonic

Fig. 14 A hand-drawn sketch,


based on microscopic observa-
tions, shows the distribution of
fluid inclusion types in the au-
riferous quartz veins of Betam
deposit. Numbers indicate the
total homogenisation tempera-
tures of the adjacent
inclusions
90 Miner Deposita (2008) 43:79–95

Fig. 15 Summary of microther-


mometric data and geometric
characteristics of the different
types of fluid inclusions in Au–
quartz veins from Betam deposit

inclusions and grain boundaries. The abundance of these DF. Generally, a range of CO2 contents of 10–15 mol% was
inclusions is directly related to the proximity to fractured calculated for the examined aqueous–carbonic inclusions.
domains and sealed cracks. Inclusions along trans-granular Total homogenisation temperature took place between
trails showed higher homogenisation temperatures and pure 297.1 and 323.3°C commonly into liquid.
CO2 composition compared to those in clusters and along The aqueous inclusions (H2O–NaCl) are commonly
intra-granular trails (Fig. 15). biphase (L+V), ranging in size from 7 to 40 μm. These
The aqueous–carbonic inclusions occur as isolated inclusions occur preferentially in isolated, inter-granular
singles or clusters showing a random three-dimensional and/or trans-granular trails. In very few cases, aqueous
distribution typically throughout less deformed large quartz inclusions are associated with carbonic inclusions along
crystals. Close to the clustered inclusions, groups of these inter-granular trails. Isolated aqueous inclusions showed
inclusions occur along intra-granular trails. They exhibit a final ice melting (Tm ice) at temperatures ranging from −5.4
variety of polygonal forms and range in size from ∼10 to 50 to −1.2°C, indicating salinities of 8.4–2.1 wt.% NaCl eq.
μm. These inclusions are commonly bi-phase at room tem- (Bodnar 1993). Inclusions along trans-granular trails
perature and a third phase appears during cooling (LH2O + showed Tm ice between −2.1 and −0.3°C, indicating salin-
LCO2 +VCO2). The degree of fill (volumetric proportion of ities between 0.3 and 3.6 wt.% NaCl eq. Total homogeni-
aqueous phase relative to the total inclusion volume; DF= sation (Th H2O), consistently into liquid, took place
VH2O /Vt) varies from 0.6 up to 0.9 within a single trail. differentially within two temperature ranges, 263.4–303.7°C
Assemblages of aqueous–carbonic, carbonic and aqueous for the intra-granular and inter-granular trail-bound inclu-
inclusions occur also along inter-granular trails. Tm CO2 sions and 130.1–221.1°C for inclusions along the trans-
ranges from −56.6 to −57.4°C but is commonly −56.6°C. granular trails. The different modes of occurrence, lower
Homogenisation (Th CO2) occurred commonly into liquid at homogenisation temperatures and low salinities of aque-
18.4–23.6°C, implying a range of 0.79–0.68 g/cm3 for CO2 ous inclusions along trans-granular trails indicate a later
densities. Upon heating of the bubble-dominated inclu- dilute fluid. Calculated bulk densities of the isolated and
sions, the CO2 bubble expanded instead of shrinking, in- intra-granular trail bound inclusions range from 0.83 to
dicating homogenisation into vapour (e.g. Roedder 1984). 0.86 g/cm3, whereas those trapped along the inter-granular
Although variable, densities of the CO2 fractions were and trans-granular trails have 0.89–0.94 g/cm3.
consistently higher in the water-rich inclusions than in the
vapour-rich ones. Clathrate melting temperatures (Tm Clath) Interpretation of fluid inclusion data and P–T constraints
ranged between 8.4 and 5.7°C, corresponding to salinities
of ∼3.2–7.9 wt.% NaCl eq., respectively (Diamond 1992). Relationships among the three inclusions types, along with
Inclusions with high DF showed low clathrate melting their microthermometric data, indicate that the aqueous,
temperatures compared to those that have relatively low carbonic and aqueous–carbonic fluid inclusions in isolation,
Miner Deposita (2008) 43:79–95 91

clusters and in intra-granular trails are early-entrapped yields an intersection with the fluid inclusion isochore of the
fluids (e.g. Roedder 1979, 1984). On the other hand, highest bulk density aqueous–carbonic inclusions at 3 kbar
aqueous and carbonic inclusions along inter-granular and (conditions defined by point 1 in Fig. 16). This might be the
trans-granular trails were trapped later. The spatial association upper limit of P–T conditions of the overall hydrothermal
of the early inclusion groups and gold–sulphide concentra- system. The inter-granular, trail-bound aqueous inclusions
tions together with the absence of any later higher-temperature have comparable salinities but slightly lower homogenisation
event suggests that the aqueous–carbonic inclusions likely temperatures compared to the aqueous–carbonic inclusions
represent the ore fluids. Although a complete quantum of fluid along intra-granular trails. They likely represent residual
inclusions with variable degrees of filling is missing, and total fluids entrapped through grain boundary migration and CO2
homogenisation into vapour is rare, textures of post- effervescences (probably began at conditions defined by
entrapment modifications induced re-equilibrium (e.g. neck- point 4 in Fig. 16). Variation in Th total, densities and
ing down and decrepitated inclusions, Vityk and Bodnar compositions of the aqueous–carbonic and aqueous inclu-
1995) are generally absent. Similar salinities of the aqueous– sions might reflect the variation of the physico-chemical
carbonic and aqueous inclusions as well as comparable CO2 conditions during the mineralising process (e.g. Schmidt
densities in the carbonic and aqueous–carbonic inclusions, Mumm et al. 1997). Spread of the isochores and pressure
along with the preferential fractionation of salt into the data may also account for pressure fluctuations, a common
aqueous-rich inclusions, suggest unmixing of an initially feature in the shear zone-hosted gold deposits, in which fluid
homogeneous H2O–CO2–NaCl fluid (e.g. Ramboz et al. pressure often exceeds the lithostatic conditions (Sibson
1982; Robert and Kelly 1987; Huizenga and Touret 1999). 1987; Robert and Kelly 1987; Cox et al. 1995).
Accordingly, the aqueous–carbonic inclusions provide the
best approximation of the P–T–X of the mineralising fluid (e.g.
Touret and Dietvorst 1983). The highest homogenisation Discussion
temperature of these inclusions (323.3°C) could therefore
provide a minimum temperature of the original trapping Gold transport and deposition
conditions. At this temperature, the isochores of the
aqueous–carbonic inclusions indicate a pressure range of The Betam deposit is similar to many orogenic lode-gold
2–2.6 kbar (conditions defined by points 2 and 3 in Fig. 16). deposits formed under comparable temperature and pres-
The arsenopyrite–pyrite–pyrrhotite geothermometer indi- sure conditions in the greenschist-facies terranes (Ho et al.
cates a temperature of 344°C, based on 30.7 wt.% As, and 1992). These deposits are commonly characterised by low
salinity aqueous–carbonic ore fluids, weakly alkaline to
neutral and slightly reducing in most cases (Mikucki and
Ridley 1993; Mikucki 1998). Under these conditions, the
gold–thio complexes are generally considered the most
important gold-transporting species (Wood and Sampson
1998; Kerrich 1999). In Betam deposit, the temporal and
spatial association of gold with arsenopyrite and pyrite, low
salinity fluid inclusions, the sericite–carbonate alteration
assemblage and scarcity of Cu–Pb minerals are consistent
with the conclusion that bisulphide complexes were
responsible for gold transport. The presence of microscopic
and sub-microscopic gold particles in the altered wallrock
commonly associated with Fe–sulphides points towards the
importance of the wallrock alteration (sulphidation) in
depositing gold through breakdown of the S-complex and
gold precipitation (e.g. Klein et al. 2005). Changes in the
Fig. 16 P–T diagram with isochores A and B (thick lines) covering fluid pH might have been caused by sericite alteration,
the range in composition of isolated H2O–CO2 inclusions in
populations showing intimate relation to gold grains. Isochores
which should have added H+ to the circulating fluid,
represented by the dotted lines constrain the range of total density of whereas precipitation of carbonate removed CO2 from the
the aqueous inclusions (type III). The highest Th total of the aqueous– fluid (e.g. Buchholz et al. 1998). Effervescence of CO2
carbonic inclusions (323°C) is considered as the minimum entrapment triggered by pressure fluctuations along the shear zone
temperature and gold deposition. The P–T fields given the letters 1, 2,
3 and 4, with the obvious path of retrogression, represent the total
might have also raised both pH and fO2 (Bowers 1991). As
fluid regime imposed from sulphide mineralisation to local exhuma- these two processes were operating in parallel, gold was
tion. For more details, see the text deposited in the quartz veins and adjacent wallrocks.
92 Miner Deposita (2008) 43:79–95

Mineralisation controls and timing relative brittle–ductile shear zones mostly developed during late
to the tectono-thermal evolution of the Eastern Desert deformational stages of the evolution history of the Eastern
Desert. Loizenbauer et al. (2002) concluded that Late Pan-
According to Kerrich and Cassidy (1994), Goldfarb et al. African transpressional tectonics controlled gold minerali-
(2001) and Groves et al. (2003), the orogenic lode gold sation at the Fawakhir mine area. One isochron model
deposits were formed typically during the late stages of the based on Pb isotope data of galena associated with gold in
deformational–metamorphic–magmatic history of an evolv- quartz veins at the Fawakhir mine indicates an age of 480
ing orogen, synchronously with at least one main penetrative Ma (Delevaux et al. 1967). Helmy et al. (2004) suggested
deformation stage of the host rocks. In the investigated that gold mineralisation at the El Sukari mine area, took
deposit, gold occurs as free-milling inclusions and refractory place during late stage extension and strike-slip tectonics
Au in arsenopyrite and pyrite. A similar bimodal distribution (∼580 Ma) because of a combined strike-slip and vertical
of gold is described in many orogenic gold deposits (e.g. the motion along flower type shear zones.
Ashanti belt of Ghana, Oberthür et al. 1994). Refractory gold
is considered as a characteristic of mesothermal/orogenic Fluid evolution and fluid sources in comparison
gold deposits (Cabri et al. 1989, 2000). with similar gold deposits in the Eastern Desert
The occurrence of most mineralisation in the central-shear
quartz veins along slip surfaces and discrete sub-parallel The occurrence of aqueous, carbonic and aqueous–carbonic
quartz lenses, strong steeply plunging ridge-and-groove fluid inclusion assemblages as isolated, clustered and along
lineations along the vein walls parallel to the mylonitic intra-granular trails in quartz indicates that these fluids were
lineation and abundant asymmetric quartz bends along the trapped early during the vein formation. Moreover, the
shear zone indicate that emplacement of the gold-bearing abundance of these inclusions along intra-granular trails close
quartz veins at the Betam mine was syn-kinematic with the to auriferous sulphide crystals suggests that gold mineralisa-
shear zone formation. This shear zone is related to D3, late in tion occurred late in the history of the vein formation. Based
the tectonic evolution of the Betam mine area and on the absence of the aqueous–carbonic inclusions in
surroundings. Replacement of the metamorphic mineralogy secondary sites, absence of the aqueous phase in the carbonic
by hydrothermal alteration assemblages, within and adjacent inclusions and variable CO2 densities in carbonic and
to the shear zone, indicates that the mineralisation is post- aqueous–carbonic inclusions, it is proposed that low-density
peak metamorphism. The peak metamorphic event occurred CO2 might have been separated from an initially miscible
under amphibolite facies conditions along the Allaqi Heiani aqueous–carbonic ore fluid because of changes in tempera-
belt and is dated at 630–550 Ma (Abd El Naby et al. 2000). ture or pressure or both (Bowers and Helgeson 1983; Walsh
In the central part of the Allaqi-Heiani belt, the peak et al. 1988). Cooling is unlikely as the main depositional
metamorphic conditions were attained during D2 (SW–NE mechanism in view of the variable fluid densities in both
compressional regime). This deformation increment was aqueous and aqueous–carbonic inclusions. Pressure could
terminated by a northwest-trending transpression, leading to have fluctuated widely between lithostatic and hydrostatic
the formation of abundant kilometre scale sinistral NW- conditions in response to possible fluid overpressure and
oriented strike slip faults. These faults are common in the movement along the shear zone (e.g. Sibson et al. 1988).
central Eastern Desert of Egypt, known as Wadi Hodein– Alternatively, interplay of pressure drop and temperature
Wadi Kharit shear system (Stern 1985, 1994; Greiling et al. decrease is more appropriate to explain variations in
1994) and in Arabia as Najd Fault System (NFS; Stoesser homogenisation temperatures and bulk density of coexisting
and Camp 1985). The NFS imparted deep-seated regional fluid inclusions. Similar fluid evolution histories are de-
fabrics that controlled the locus of later episodes of scribed in other mesothermal gold deposits worldwide and
deformation (e.g. Agar 1987). In the Wadi Allaqi region, from the Eastern Desert of Egypt. Loizenbauer and Neumayr
gold mineralisation was chiefly controlled by a system of (1996) described pseudosecondary liquid-rich, vapour-rich
discrete NNW-trending, brittle–ductile shear zones (e.g. El and low salinity CO2–H2O in the auriferous quartz veins
Shimi 1996; El Kazzaz 1996) formed during a D3 trancurrent from the El Sid gold deposit, for which they proposed a
shearing event, post-dating the late Proterozoic NFS (∼640– range of 1.8–2.3 kbar for the formation conditions.
530 Ma). Accordingly, D3 and the related mineralisation Harraz (2002) suggested that conditions of gold deposi-
should be younger than 640–530 Ma. According to Stern tion in the Atud gold deposit were similar to many
et al. (1989), the magmatic and metamorphic events in the mesothermal vein systems and likely occurred because of
region ceased at 510±40 Ma. a sharp decrease in sulphur activity through un-mixing
Botros (2004) described 16 gold deposits and occur- because of an abrupt drop in fluid pressure (from 272 to
rences in the Eastern Desert of Egypt in which gold 160 MPa). Further, he concluded that low salinity (2.8–8.2
mineralisation is clearly spatially and genetically related to wt.% NaCl eq.) and homogenisation temperatures of the
Miner Deposita (2008) 43:79–95 93

H2O–CO2-rich inclusions suggest a metamorphic source, Comparison between the Betam deposit and other
such as devolatilisation of the metasedimentary rocks and important mesothermal gold deposits from the Eastern
serpentinites at depth and migrated upward along dilational Desert of Egypt, Atud, El Sukari and Um El-Tuyor suggests
structures. The ore fluids leached the metals from the that comparable ore fluids were involved in them with
country rocks. Furthermore, similar assemblages of aque- similar gold-forming P–T regimes, suggesting that orogenic
ous, aqueous–carbonic and carbonic fluid inclusions have lode–gold mineralisation in the Egyptian basement was an
been described in gold-bearing quartz veins from the El integral part of a regional-scale event during the evolution
Sukari mine (Helmy et al. 2004). The authors assumed that of the Arabian-Nubian Shield late in the Neoproterozoic at
early CO2-rich fluids caused alteration along the shear ca. 510±40 Ma.
zones and these fluids were mixed with meteoric water
during exhumation. They suggested a long-term, cyclic Acknowledgements This work is made possible by the assistance
and expertise of Prof. J. Walter, Institute of Mineralogy and
crack–seal mechanism during pressure fluctuations (be- Geochemistry, Karlsruhe (Germany), during the fluid inclusion
tween 210 and 1,890 bar) along with host-rock because of microthermometric measurements and interpretation. Interpretations
alteration. The authors suggested that similar gold deposits benefited greatly from discussions with Reinhard Kaindl (Graz) and
within the Eastern Desert of Egypt, located at the contact Van den Kerkhof (Göttingen). Appreciation should extend to the
journal editor, Prof. Dr. Lawrence Meinert, associate editor, Dr. Robert
between granitoids and mafic–ultramafic rocks and along Moritz and to the reviewers, Drs. Jean Vallance and Damien Gaboury.
shear-zones, are the result of similar formation processes. Their criticism and suggestions greatly improved the initial version of
At 20 km east of the Betam mine, in the Um El Tuyor this manuscript.
gold deposit, an initial gold/bisulphide-bearing ore fluid
(H2O−6 wt.% NaCl−21 mol% CO2 ±1−2 mol% CH4 or
N2) started to separate into two phases and precipitated gold
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