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, Chap 4
Homework 1:
1. How would you prepare the following from the solid and pure water
a. 0.400 L of 0.155 M Sr(OH)2
3. You are asked to prepare a 0.8500 M solution of aluminum nitrate. You find that you
only have 50.00 g of the solid.
a. What is the maximum volume of solution that you can prepare?
b. How many milliliters of this prepared solution are required to furnish 0.5000 mol of
aluminum nitrate to a reaction?
c. If 2.500 L of the prepared solution is required, how much more aluminum nitrate would
you need?
2.500 L soln x 0.8500 mol Al(NO3)3 x 243.07 g Al(NO3)3 = 516.52 g Al(NO3)3 total needed
1 L soln 1 mol Al(NO3)3
d. Fifty milliliters of a 0.450 M solution of aluminum nitrate is needed. How would you
prepare the required solution of the solution prepared in part a?
0.050 L soln d x 0.450 mol Al(NO3)3 x 1 L soln A = 26.5 mL of soln a are required
1 L soln d 0.85 mol Al(NO3)3 it is then diluted to 50 mL
13. a. NR
b. 2 Ag+ (aq) + CO32- (aq) --> Ag2CO3 (s)
c. 2 Co3+ (aq) + 3 CO32- (aq) --> Co2(CO3)3 (s)
d. 3 Ba2+ (aq) + 2 PO43- (aq) --> Ba3(PO4)2 (s)
e. NR
17. What volume of 0.2500 M cobalt(III) sulfate is required to react completely with
a. 25.00 mL of 0.0315 M Ca(OH)2
0.025 L Ca(OH)2 soln x 0.0315 mol Ca(OH)2 x 2 mol OH- x 1 mol Co3+ x 1 mol Co2(SO4)3 x 1 L Co2(SO4)3 =
1 L of soln 1 mol Ca(OH)2 3 mol OH- 2 mol Co3+ 0.25 mol Co2(SO4)3
or
b. 5.00 g Na2CO3
0.0125 L K3PO4 soln x 0.1249 mol K3PO4 x 1 mol Co2(SO4)3 x 1 L Co2(SO4)3 soln =
1 L K3PO4 soln 2 mol K3PO4 0.25 mol Co2(SO4)3