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Solutions to JEE Main - 14 | JEE-2022

PHYSICS
SECTION-1

2
 1 
1.(C) Impedance, Z  R2     1250 
 C 
Solving, we get R  750 
So, at angular frequency 400 rad/s,
2
 
1
Z   750       750 2  500 2
2
 250 13  901.4 
 
  400  5  106  

2.(B) In the situation of minimum deviation, the ray travelling inside the prism is parallel to its base, and
A
hence the angle of refraction is  30o
2
sin 45o
By Snell’s law,  prism   2
sin 30o
3.(B) Let the amplitude of the voltage source be V
dQ V 2 R V 2R
 
 
Rate of heat dissipation is given by
dt 2 Z 2 2 R 2   L 2

dQ
So, if the frequency is increases, decreases continuously
dt

4.(D) We know that if the voltage source is V  t   V0 cos  t  , then the current is given by
V0
I t   cos  t  
Z
100
So, by comparing the given equations, we get 2  Z  50 
Z
R
Also,   60o Now, since  cos  , R  50 cos60o  25 
Z

5.(D) Fringe width, 

D


500  109  4  
 2 cm
d 104
6.(A) We know that the combination of a lens and mirror behaves like a mirror, and hence we must apply
mirror equations
The focal length of this mirror is given by
1 2 1
  F  20 cm
F 40 
We are given that the magnification is –2
v
   2  v  2u
u
1 1 1
Mirror equation:    u  30 cm
2u u 20

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7.(C) At a point at a distance y from the central maximum, the intensity is

    y 
I  I M cos2    I M cos2  
 2    
 5 3I
So, for y = 0, I  I M and for y  , , I  M
6 6 4
 
So, for the minimum distance between any two such points, we must choose y  and y  
6 6
   
Therefore, the distance is y    
6  6 3

1 1 1 1 1
8.(D) Mirror formula:     v  15 cm
v f u 20 60
v 1
Magnification, M  
u 4
9.(B) The amplitudes of VC , VL and I can be anything as they depend on the values of R, L and C
But the phase relationship between VC , VL and I is always the same:
 
VC must be behind I by a phase angle of , and V L must be ahead of I by a phase angle of
2 2
10.(C) Because the incidence on face AB is normal, the ray suffers no deviation at face AB and strikes the
face AC at an angle of incidence 30 o (  A )
Now, the ray suffers TIR at face AC if
1
sin 30o  i.e. if   2

Therefore, in both the given cases, TIR does not take place and the ray emerges into air from face AC
itself
For   3 , the angle of emergence e is given by
sin 30o 1
  e  60o
sin e 3
The deviation suffered in any refraction is | i  r |
Since no deviation is suffered by the ray in crossing face AB, the net deviation is equal to the
deviation suffered at face AC, i.e.   60o  30o  30o

1  1.5  1 1   1  1 
11.(A) Lens Makers’ Formula:   1         f  160 cm
f  4 / 3  30 60   8  20 
12.(C) We know that   180o  2    60o
 5
13.(B) At the point where the third order minimum is formed, the phase difference is  2  3  1 
2 2
At a point on the screen located at a distance y from the central maxima, the path difference,

 yd 
P  
D 
y    P  
2
 
   500  10
9
   1.25 cm
 So, 
 D d  0.2  103   2 
 

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 1  1   
14.(D) First refraction:    v1   R
v1   R   1 
 2  
Object distance for the second refraction, u2  v1  2 R   R
  1 
So, for the second refraction:
1  1  1    1   1 2   R
      v2 
v2  2    R v2  2    R R 2   1
  1  R
 

So, the distance of the final image from the centre of the sphere is D  v2  R  R
2   1
 
15.(C) Angular fringe width  
D d
So,   
  5  104 1.2  103  600 nm

     1    I
2 2 2
16.(B) We know that I MAX  I1  I 2 I  I

I MIN   I2    I   1    I
2 2 2
And, I1  I
2
I MAX  1   
So,  
I MIN  1   

17.(B) Since the final image is the same size as the object, and the net magnification produced by the lenses
is M 1M 2 (if M 1 and M 2 are the magnification produced by the individual lenses),
1
M 1M 2  1  M2 
M1
We know that the magnification by a lens becomes its reciprocal if the object distance and image
distance are interchanged. So, since the focal length of the lenses is the same, it is clear that if the
image distance for lens 1 is X, then the object distance for lens 2 will be X too. And since the sum of
these quantities, i.e. 2X, must be equal to the distance between the lenses, we get 2 X  120 cm ,
i.e. X  60 cm
So, the image distance for the first lens is 60 cm
1 1 1
Applying the lens formula on the first lens,    u  180 cm
60 u 45
R
18.(A) Power factor at frequency f 
Zf
1/2
  1  
2
(where Z f   R 2    2fL   is the impedance at frequency f)
  2fC  

V 2R
Power consumed at frequency f, P 
2 Z 2f
At resonance, the impedance is Z 0  R , so the power consumed is
V 2R V 2
P0  
2R2 2R
1/2
P R2 R P
So,    
P0 Z 2f Z f  P0 

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1  1   1 1 
19.(A) Convex lens:    1   
f1  1   R1  
1  2  1 1 
Concave lens:   1   
f2  1    R2 R2 
1 1 1  1  1 2   2  1
Combination:    
F f1 f 2 R1 R2
The combination behaves like a converging lens if the equivalent focal length is positive
1  1  2 2  1
So,
R1 R2
R1 R2
i.e. 
1  1 2 2  1
1 1 1 1 1
20.(B) Lens Formula:    
v f u f  2 f  

 v
2 f   f
f 
1
v f   
So, the magnification is M    1    1
u f   f  f

SECTION-2

1 L 1 20  103
21.(0.01) Quality factor, Q    0.01
R C 5 103 8 106
Dt    1 1  2 104  1.5  1
22.(2) Shift on screen due to introduction of sheet, S    2 cm
d 5 103
V
23.(400) We know that I RMS 
2Z
Z 2 I RMS ,1 3
Since the amplitude V of the voltage source remains the same,  
Z1 I RMS ,2 4
  
 
2
2 
9 6    200  0.04    16 6  
1
   200  0.04   
2
 2

   200  C  
1 1
  12.5  C   400 μF
 200  C  200 12.5

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24.(80) The water “lens” and the mirror behave together like a concave mirror
If the focal length of the original concave mirror is –X, its radius of curvature is 2X
Now, the focal length of the water “lens” is given by
1  4 / 3  1 1  1
  1   
fWL  1     2 X   6 X
So, the equivalent focal length of the combination of the water “lens” and the original concave mirror
is given by
1 2 1 3X
   F 
F 6X  X 4

For the image to be coincident with the object, the object should be at the centre of curvature of the
combination mirror
So, 2 F  120  X  80 cm

 
25.(9) When the experiment is performed inside water, the wavelength of the light becomes 
n 4/3
D
Fringe width of the first experiment, 1   6 mm
d
  
   2D  3
Therefore, the fringe width of the second experiment, 2   4 / 3
 1  9 mm
d 2

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Chemistry

SECTION-1

1.(D) I.

Intramolecular Williamson’s ether synthesis

II.

Intramolecular E2

2.(C)

3.(C)

4.(B)
5.(B)

6.(C) Light corresponding to the energy of red region is absorbed by the complex.

7.(B) Wilkinson’s catalyst is  Rh(PPh 3 )3 Cl .

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8.(C) I.

II.

III.

IV.

9.(B) It is diamagnetic complex

10.(B)

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11.(D)

12.(A)

13.(C) B2 H6  6ROH 
 2B(OR)3  6H2
Isomer of THF is cyclobutanol.

14.(D) Picric acid is prepared by treating phenol first with concentrated H 2SO 4 which converts it to phenol-
2, 4-disulphonic acid, and then with conc. HNO 3 to get 2, 4, 6-trinitrophenol.

15.(C)

16.(D) Most of the methanol is produced by catalytic hydrogenation of carbon monoxide at high pressure and
temperature in the presence of ZnO  Cr2 O3 catalyst.

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17.(C)

18.(A)

19.(A) Metal carbonyl shows synergic bonding

20.(D)

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SECTION-2
21.(90) (NH 4 ) 2 [Ce(NO3 )6 ] : Here NO3 is bidentate ligand.
EAN  (58  4)  24  78
22.(6) (a) Neither (b)
Neither (c) Reduction (d) Neither
(e) Neither (f)
Neither (g) Oxidation (h) Oxidation
(i) Oxidation (j)
Neither
3
23.(3) Average bond order for C  O bond  ; Aromatic having 2 - electrons (n  0)
2
24.(19) X1  5; X 2  5; X 3  9

*  Chiral carbon atoms

*  Saturated tertiary carbon atoms
25.(27) Z1  5; Z2  16; Z3  6

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Mathematics

SECTION-1
1.(D) ( a  b )  V  u  (d  a )  [a c d ] b
(a V ) b  (b V )a  (u  a )d  (u  d )a  [a c d ] b
[a c d ]b  [b c d ]a  [b c a ]d  [b c d ]a  [a c d ]b
[b c a]d  0  a, b , c are coplanar

2.(A) Vector perpendicular to 2iˆ  ˆj  kˆ and iˆ  3 ˆj  kˆ is

iˆ ˆj kˆ
2 1 1  2iˆ  ˆj  5kˆ
1 3 1
Any general point on the line is (1  2, 1  , 1   ) at their point of intersection. This point satisfies
equation of plane.
(1  2)  3(1  )  1(1  )  9    1  Point of intersection is (3, 2, 0).
x 3 y 2 z
Hence required line is r  (3iˆ  2 ˆj )  k (2iˆ  ˆj  5kˆ)   
2 1 5
3.(B) M  (4, 5, 6)
Plane passes through 4, 5, 6
 A( x  4)  B ( y  5)  C ( z  5)  0
A, B , C are 4, 4,4
 equation is x  4  y  5  z  6  0
 x  y  z  15

4.(C) L1 through Point A(1, 1, 1) and dir  1, 1, 1 

L2 through point B(1,  1, 0) and dir  1, 1,  1 
0 2 1
1 1 1
1 1 1 2 1
 S.D   
440 2 2 2

5.(A) Line joins P (3,  4, 1) & Q(2  3, 3  1, 2   ) and PQ  n  0

  2, 3  3, 1    2, 1,  1 
 4  3  3  1    0  2  2  0
   1
 P (3,  4, 1) and Q(1, 2, 3)
x  3 y  4 z 1 x  3 y  4 z 1
     
1 3 2  4 3 1 2 6 2
x  3 y  4 z 1
 line is  
1 3 1

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6.(B)  is x  2 y  3 z  2  0

2 2
 P 
1 4  9 14

7.(D) L1 and L2 are intersecting lines

The position vector of their point of intersection is 5iˆ  7 ˆj  6kˆ (For   2 or   1)
70
Also, angle between L1 and L2 
11 42

8.(A) Solving the equation of planes, we get equation of line containing planes
x y z
  …(1)
0 10 5
Any point P on (1) is (0,  10,  5).
Now, direction ratios of the line joining P and M is  1, 1  10, 1  5 
1 2
So, d.r’s of MP are 1, ,
5 5

x 1 y 1 z 1
So, equation of required line is  
5 1 2

9.(A) z-axis is r  0  (kˆ)

Line is r  (2iˆ  5 ˆj  kˆ)  (3iˆ  2 ˆj  5kˆ)

(2iˆ  5 ˆj  kˆ)  ((3iˆ  2 ˆj  5kˆ)  kˆ) 11

 shortest distance  
| (3iˆ  2 ˆj  5kˆ)  kˆ | 13

x 1 y  5 z  9
10.(C) Equation of line parallel to given line through P is   
1 1 1
Its point of intersection with plane is Q (  1,   5,   9)
 (  1)  (  5)  (  9)  5
   10
 Q  (9,  15,  1)
 PQ  10 3

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11.(D) | r [a b c ]|  | r |[a b c ]  2  3  6  36

12.(D) n1  (4,  3, 4)
n2  (3,  2, 1)
n1  n2  (5, 8, 1)
(n1  n2 )  n  0
 10  8  a  0  a  2

13.(D) Let the ratio t :1

 3t  2 5t  4 8t  7 
 point P   , ,  lies on plane
 t 1 t 1 t 1 
 3t  2   5t  4   8t  7  3
  1  2    3   17  t  10
 t 1   t 1   t 1 
2 2 2
1  k2   k2   k2  k2
14.(A) Area          
2  lm   mn   nl  2lmn

l 2  m2  n 2
  (l 2m2 n2 )1/3
3
1 1 1 k2 3 3 k2
  (l m n) 2/3   l mn  3 3  
3 3 3 lmn 2 lmn 2

a  1 1 0 a 1 0
15.(D) 1 1 3 0  0 1 3 0
1 1 2 0 1 2
 a (3  2)  0  a  0

16.(C) r  (a  b )sin x  (b  c )cos y  2(c  a )

r  (a  b  c )  0
 [a b c ] (sin x  cos y  2)  0  [a b c ]  0  sin x  cos y  2
This is possible only when sin x  1 and cos y  1

For x 2  y 2 to be minimum x   and y  
2
2 52
 minimum value of ( x 2  y 2 ) is   
2
4 4
17.(C) b  d  0  b  d
a  b c & c d  0  ad  b d c d
or ad  b d
d  (a  d ) ( d  d ) a  ( d  a )d (b  d )d (d  d )d
Now 2
 2
a 2
a  a  d  a  b  c
d d d d2

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18.(A) The given planes can be written as 2 x  y  z  2  0 and  x  2 y  z  3  0

Here, (2) ( 1)  (1) ( 2)  ( 1) (1)  1  0
(2 x  y  z  2) ( x  2 y  z  3)
Equation of bisectors 
(4  1  1) 1 4 1
 Acute angle bisector is
(2 x  y  z  2)  ( x  2 y  z  3)  x  3 y  2 z  1  0

19.(C) a  (a  (a  (a  (a  (a  b )))))  a  (a  (a  (a  (0  4b ))))

in similar manner  (4)3 b  64b

20.(A) Equation of plane 2 x  3 y  5 z  7  0

Equation of plane, parallel to the plane 2 x  3 y  5 z  7  0 is 2 x  3 y  5 z  
Pass through (3, 4, 1) then 6  12  5      1
 equation of plane 2 x  3 y  5 z  1  0

SECTION-2
21.(3.50) Clearly minimum value of a 2  b 2  c 2

2
 | (3(0)  2(0)  (0)  7 | 
   49  7 units.
 (3)  (2)  (1) 
2 2 2 14 2

(This is possible when P ( a , b, c ) is foot of perpendicular from O (0, 0, 0) on the plane.)

1
22.(6) We have [ aˆ bˆ aˆ  bˆ] 
4
1 1
 (aˆ  bˆ)  (aˆ  bˆ)   | aˆ  bˆ |2 
4 4
1 1
 sin 2    sin  
4 2

Hence   (As | a |  1  | b |)
6

23.(58) Since, both the planes are parallel

P1 : 4 x  6 y  12 z  10  0
P2 : 4 x  6 y  12 z  d  0
b  6, c  12

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 Vidyamandir Classes: Innovating For Your Success

d  10
Now, 3
2 4  9  36
| d  10 |  42  d  52 or  32
 P2 is 4 x  6 y  12 z  52  0
or 4 x  6 y  12 z  32  0
Point (3, 0,  1) is lying between planes P1 and P2
 On substituting the point in the equation of the planes both expressions must be of opposite sign.
From P1 : 4  (3)  6  0  12(1)  10   ve
From P2 : 4  (3)  6  0  12(1)  52   ve
 d must be 52 Hence, (b  c  d )  6  12  52  58

24.(15) | c  a |  2 2  | c  a |2  8
 | c |2  9  2 c  a  8  | c |2 2 | c | 1  0  | c |  1
iˆ ˆj kˆ
 a  b  2 1 2  2iˆ  2 ˆj  kˆ
1 1 0
1
 10 | (a  b )  c | 10 | a  b | | c | sin 30  10  3 1  15
2

25.(8) ( xiˆ  yjˆ)  ( xiˆ  yjˆ  8iˆ  10 ˆj )  41  0

x 2  y 2  8 x  10 y  41  0
Centre (-4, 5), r  16  25  41  0
So, minimum value of | 4iˆ  5 ˆj  2iˆ  3 ˆj |2  | 2iˆ  2 ˆj |2  ( 4  4)2  8

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