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114 IEEE JOURNAL OF PHOTOVOLTAICS, VOL. 13, NO. 1, JANUARY 2023
Fig. 1. PPC design schematics for (a) InGaAsP/InP and (b) MM-GaInAs/GaAs. ARC: anti-reflection coating; FSF: front surface field; BSF: back surface field.
(c) Visualization of the experimental setup. (d), (e) Knife-edge profiles and (f), (g) beam intensity profiles for two different beam widths. The 1/e2 beam diameters
(2 w) and the average irradiance (Iavg ) relative to the peak beam intensity for a nominal designated area of 0.054 cm2 are indicated. (h) Electrical circuit diagram
for the PPC device DCM. The photocurrent (Jph ), two-diode parameters (J01 and J02 ), and relevant resistances are indicated.
and much better transmission efficiencies than 850 nm light for In this article, we analyze high-performance O-band PPCs
distances beyond a few hundred meters [3]. Here, we explore based on both InP and GaAs substrates. We examine the impact
O-band PPCs, for which the comparatively larger photon energy of the illumination profile on device performance and employ a
leads to larger output voltages than could be produced for distributed circuit model (DCM) to better understand the mecha-
comparable C-band PPCs. nisms responsible for reduced performance of the 6.4-mm2 PPCs
O-band PPCs have been less studied than their 850-nm-band under nonuniform illumination with average irradiance in the
counterparts. To date, only a handful of O-band PPC devices range of 2–10 W/cm2 .
have been experimentally characterized and reported in the lit-
erature [31], [32], [33], [34], based on InP and GaAs substrates. II. METHODS
Other studies have investigated pathways to increased power
conversion efficiencies in O-band PPCs [35], [36]. For InP- A. Design and Fabrication of PPC Devices
based devices, high-quality lattice-matched quaternary materials The design and fabrication of PPCs for operation under
such as InGaAsP or InAlGaAs can provide high absorptance 1310-nm laser illumination was carried out at Fraunhofer
in the O-band. For GaAs-based PPCs, there is no convenient ISE [32]. The devices were grown by metal–organic vapor phase
lattice-matched absorber material for O-band operation and epitaxy (MOVPE) using an AIXTRON G4 2800TM reactor.
lattice-mismatched growth processes are required [32], [37]. Two designs were considered, similar to existing literature [39],
Highly efficient GaAs-based devices represent a path toward [40], [41], both using an n–p homojunction architecture for
large-scale manufacturing of O-band PPCs, as GaAs substrates the active layers sandwiched between wider bandgap front and
are less expensive and available in larger sizes than InP. Noting back surface field layers, which prevent the loss of minority
that materials with smaller bandgaps yield lower efficiencies carriers generated in the absorber region through electrical
than their larger-bandgap counterparts, detailed-balance mod- passivation. The first design, shown in Fig. 1(a), was grown on
eling of O-band devices predicts theoretical power conversion a 4-inch p-type InP substrate making use of lattice-matched
efficiencies exceeding 67% in the radiative limit [36]. This In0.32 Ga0.68 As0.69 P0.31 (InGaAsP/InP) with a measured
compares to the predicted efficiency of 73.7% for a comparable bandgap of Eg = 0.890 eV for the absorber material. The
GaAs PPC operating at 830 nm in the radiative limit at room second design, shown in Fig. 1(b), was grown on a 4-inch
temperature [38]. n-type GaAs substrate. Lattice-mismatched Ga0.56 In0.44 As
BEATTIE et al.: INP- AND GAAS-BASED PPCS UNDER O-BAND LASER ILLUMINATION 115
Fig. 2. (a), (b) J–V characteristics measured under O-band laser illumination at five different incident powers for (a) InGaAsP/InP and (b) MM-GaInAs/GaAs
PPCs. The solid and dashed lines correspond to PARs of 2.8 and 7.6, respectively. Average irradiance values are given for each measurement. (c) WOC as a
function of JSC,avg for the InGaAsP/InP and MM-GaInAs/GaAs PPCs. Measured data is shown for three of the five O-band laser illumination profiles and for
broad spectrum uniform illumination. Dotted lines are fits to (4), see Table III for fitting parameters.
for the InGaAsP/InP device, averaging over 20 measurements absorption in the O-band. The smaller bandgap of the MM-
under average laser irradiance below 0.57 W/cm2 , well below GaInAs/GaAs PPC also gives rise to smaller (VOC ) values
the threshold of ∼ 2 W/cm2 above which nonuniform illumi- in general compared to the InGaAsP/InP PPC. By adjusting
nation effects were observed. The large value obtained for RSH the alloy compositions, the bandgaps of both InGaAsP and
signifies that shunting was insignificant for this device. The n–p MM-GaInAs can be tuned to optimize the trade-off between
junction unit cells were interconnected with resistive elements absorptance and voltage. In the case of the MM material,
in the lateral and vertical directions to form a complete circuit smaller bandgaps correspond to greater lattice mismatch be-
model representing the device [43], [44], shown in Fig. 1(h). The tween GaInAs and the GaAs substrate, increasing the difficulty
sheet resistances and the top contact resistance listed in Table II in maintaining high material quality [39].
were measured experimentally. The bottom contact resistance is For the MM-GaInAs/GaAs PPC, its TD [see Fig. 1(b)] im-
an estimate based on other devices and had a negligible impact pacts the shape of the J–V curves and each maximum power
on the simulated I–V curve. Resistances in the metal busbars and point. TDs are characterized by a peak tunneling current density,
gridlines were approximated using the resistivity of silver (ρAg ). above which tunneling is no longer possible and the TD switches
from low-resistance tunneling to higher-resistance thermal dif-
III. RESULTS AND DISCUSSION fusion (the dominant electrical transport mechanism in standard
pn-junction diodes) [45]. When embedded in a photovoltaic de-
A. Current–Voltage Characteristics vice, the switch from tunneling to thermal diffusion significantly
Sample current–voltage (J–V ) characteristics are shown in increases the device’s total series resistance [46], [47], [48],
Fig. 2(a) and (b) for the InGaAsP/InP and MM-GaInAs/GaAs [49], [50], [51], [52]. Fig. 2(b) shows this effect for the MM-
PPCs, respectively, where the current density Javg is averaged GaInAs/GaAs PPC, where a dip in total current is observed for
over the total device area. We measured the devices under a range bias voltages > 0.1 V. Note that the J–V curves were measured
of incident laser powers between 7 and 526 mW, corresponding in the forward direction from JSC to VOC , and hysteresis is often
to average irradiance between 0.13 and 9.74 W/cm2 . For clarity, observed in the J–V curves of photovoltaic cells that contain
only five incident powers and two beam diameters are shown in TDs [47], [50], [51]. Measuring in the forward direction gives a
Fig. 2(a) and (b). more accurate assessment of the threshold beyond, which the TD
For both PPCs, the short-circuit current density (JSC ) scales begins to influence the cell performance [47]. In Fig. 2(b), we
linearly with increasing incident power, regardless of the beam observe that the dip in the J–V curve becomes more pronounced
diameter, with average responsivities of 0.912 and 0.957 A/W with increasing illumination power and is more significant for
for the InGaAsP/InP and MM-GaInAs/GaAs PPCs, respectively. smaller beam sizes, which are characterized by higher PAR
Smaller spot sizes are associated with reduced fill factors (FF) values and correspondingly higher peak illumination intensities
and open-circuit voltages (VOC ) compared to the larger spot (and peak current densities) at the center of the laser spot. The
sizes for both PPCs. TD begins to impact the J–V curves for the lattice-mismatched
The larger responsivity of the lattice-mismatched device is MM-GaInAs PPC on GaAs when the peak illumination intensity
due to its smaller bandgap and correspondingly larger optical Ipeak 20 W/cm2 .
BEATTIE et al.: INP- AND GAAS-BASED PPCS UNDER O-BAND LASER ILLUMINATION 117
Fig. 3. (a) VOC as a function of JSC,avg from the DCM and experiment for the InGaAsP/InP PPC under uniform and Gaussian illumination. Inset: schematic
of the modeled cell geometry. (b) Difference in experimental VOC compared to simulation and estimated change in effective temperature (ΔTeff ) to account for
ΔVOC , calculated from (6). Dotted lines in (a) and (b) are extrapolated trend lines. (c), (d) Voltage vs. position at the top of the PPC cell along a line perpendicular
to the gridlines and equidistant between the busbars, as calculated by the DCM at the maximum power point for (c) uniform and (d) Gaussian illumination when
JSC,avg = 10A/cm2 . VMP is indicated by the dashed lines and the shading indicates the shape of the incident illumination profile. (e), (f) 2D map showing the
modelled voltage as a function of position at the maximum power point for (e) uniform and (f) Gaussian illumination. The busbars and gridlines are shown in
white, and the cross-sections for (c) and (d) are indicated by the cyan dashed lines through the center (perpendicular to gridlines).
Considering the difference in voltage between the model and highly nonuniform illumination condition, the total difference
experiment, ΔVOC , and using dVdTOC from (6), we found an in voltage between the central peak and VMP is 61.7 mV, a factor
effective difference in average cell temperature (ΔTeff ) that of four larger than the maximum voltage gradient under uniform
increased with JSC,avg . The result is shown in Fig. 3(b). Given illumination.
the significant nonuniformity in the illumination profile, local- Despite the significantly larger peak voltage simulated un-
ized heating from the laser is expected to produce a similar der Gaussian illumination, the value of VMP is largest under
nonuniformity in the temperature profile across the device, with uniform illumination [see Fig. 3(c) and (d)]. This is because
more significant heating at the center of the illumination spot. lateral conduction losses are more significant under nonuniform
ΔTeff does not account for this nonuniformity, which depends illumination, and the darker regions at the cell’s periphery bring
on the thermal and electrical conductivities of the cell materials down VMP . Given that the DCM does not account for localized
and the thermal contact efficiency between the cell and the heating, the temperature-induced voltage drop [see Fig. 3(a) and
temperature-controlled chuck. (b)] may be even more significant than lateral conduction losses
In Fig. 3(c)–(f), the simulated voltage at the maximum power in a physical device, resulting in a larger drop in VMP under
point is shown for uniform (c) and Gaussian (d) illumination nonuniform illumination than predicted by the model.
conditions as a function of position when JSC,avg = 10 A/cm2 . Fig. 2(c) shows that deviations from the logarithmic trend
The profiles in 3(c) and (d) follow a line through the center of in WOC at higher illumination powers are more significant for
the modeled device, perpendicular to the gridlines. The extracted the lattice-mismatched MM-GaInAs/GaAs PPC compared to
voltage at maximum power (VMP ) is the simulated voltage at the lattice-matched InGaAsP/InP PPC. This suggests that the
the outer edge of the busbars. Full 2-D voltage maps across MM-GaInAs material has lower lateral conductivity compared
the entire device surface are shown in Fig. 3(e) and (f). Under to the lattice-matched InGaAsP, resulting in more significant
uniform illumination, small dips in voltage are found beneath resistive losses. This observation is consistent with the sheet
each gridline, where the cell is shaded. Across the entire device, resistances measured in the window layers of each device, which
a voltage deviation of only 15.3 mV is calculated, with the peak are 7.7 − 8 Ω/ and 39 − 49 Ω/ for the InGaAsP/InP and the
voltage in the center and the lowest voltage in the shaded regions MM-GaInAs/GaAs PPCs, respectively. Improving the lateral
beneath the busbars. A more significant voltage gradient is conductivity within the metamorphic device may help to en-
simulated under Gaussian illumination. The peak voltage occurs hance its voltage under nonuniform illumination. Lower thermal
at the center of the device where the illumination intensity is conductivity within the MM-GaInAs/GaAs PPC compared to
largest. The lowest voltage is found at the edges of the device, the lattice-matched device may also contribute to its increased
which are not illuminated, and beneath the busbars. Under this WOC , but this effect has not been quantified.
BEATTIE et al.: INP- AND GAAS-BASED PPCS UNDER O-BAND LASER ILLUMINATION 119
IV. CONCLUSION
We measured two 6.4-mm2 O-band PPCs under laser illu-
mination. The lattice-matched InGaAsP/InP device exhibited a
record power conversion efficiency for the O-band of 52.8% ±
1.2% (abs). A robust efficiency of 48.7% ± 1.1% (abs.) was
measured for the MM-GaInAs/GaAs PPC, demonstrating the
potential for GaAs as a more cost-effective, scalable alternative
to InP for O-band PPCs. Even higher efficiencies could likely be
achieved for both material systems through design optimization
and the integration of a back-reflector.
For both PPCs, the nonuniformity of the illumination
profiles had minimal impact on device performance for
Iavg < 2 W/cm2 and, for JSC,avg < 1 A/cm2 , a logarithmic re-
lation was observed between the WOC and JSC,avg in accordance
with the nonideal diode equation. A deviation from this trend un-
Fig. 4. Efficiency as a function of average irradiance for the InGaAsP/InP and
MM-GaInAs/GaAs PPCs. Measured data is shown for the five laser spot sizes. der nonuniform illumination occurred for JSC,avg > 1 A/cm2 ,
The shaded regions indicate the uncertainty on the datasets with PAR = 2. which can be explained by: 1) lateral conduction losses, as shown
by the DCM, and 2) localized heating. Overall, both PPCs are
suitable for powering sensors and other devices requiring
250 mW, with an appropriate illumination profile. Better perfor-
C. Optical-to-Electrical Conversion Efficiency mance at higher illumination powers could be achieved by engi-
Though analysis of the VOC is critical to understanding neering a more uniform illumination profile, optimizing the front
PPC performance, it is not the only factor influencing device metallization, or adopting multi-junction device architectures.
efficiency. The optical-to-electrical conversion efficiency is
plotted in Fig. 4 as a function of average irradiance for the APPENDIX
five laser beam diameters. The largest efficiency for the UNCERTAINTY IN MEASURED EFFICIENCY
InGaAsP/InP PPC was 52.8% ± 1.3% (abs.), measured at
The dominant source of error in the determination of PPC
an average irradiance of 5.94 ± 0.14 W/cm2 . The largest
optical-to-electrical conversion efficiencies is uncertainty in the
efficiency for the MM-GaInAs/GaAs PPC was 48.7% ± 1.1%
incident illumination power. During the experiment, the incident
(abs.) at 8.84 ± 0.20 W/cm2 . The primary source of error
laser power was determined from the laser diode current, which
is uncertainty in the incident beam power (see Appendix).
was controlled directly. The relationship between optical power
The maximum efficiency measurements for both devices were
and diode current was established through a calibration exper-
recorded for the largest beam diameter of 2w = 2.3 mm with
iment in which the current was stepped up in discrete intervals
the correspondingly smallest nonuniformity with PAR = 2.
from the threshold current and the resultant laser power was
Further efficiency enhancements could be obtained through
measured using a Newport 918D-IR-OD2 photodiode detector.
design optimization and the integration of a back-reflector
Neutral density (ND) filters were used to attenuate the beam
to enhance the output voltage through photon recycling and
power and their transparencies were measured experimentally.
optical resonance effects [16], [35].
The measured efficiencies are shown in Fig. 5 along with the
In general, both PPCs were tolerant to nonuniform illumi-
associated error bars, which account for the following sources
nation profiles up to an average irradiance of ∼ 2 W/cm2 .
of error.
Efficiency losses observed for smaller beam diameters at higher
1) ±2% calibration uncertainty for the photodiode detector.
incident powers can be explained by the reduction in VOC
2) ±0.1 mW uncertainty for power meter precision.
and fill factor observed with increasing PAR. Note that, like
3) Uncertainty in the filter transparency T :
VOC , fill factor is also impacted by localized heating effects
and series resistance losses. The observed trends indicate that – ND1: T = 10.05 ± 0.04%
more uniform laser illumination profiles would improve PPC – ND2: T = 1.373 ± 0.004%
performance under high illumination powers. Transitioning to 4) ±0.02% uncertainty in laser diode current to account for
multijunction device structures would also improve the tolerance power fluctuations.
to nonuniform illumination by lowering the current density 5) Uncertainty of ±(0.012% + 1.3 mV) in the VMP .
through the device structure, mitigating resistive losses [43]. 6) Range-dependent uncertainties in IMP of:
These measures have the potential to enhance the performance of IMP < 10 mA: ±(0.035% + 5.6 μA)
PPCs at any operation wavelength, but are especially important 10 mA ≤ IMP < 100 mA: ±(0.055% + 56 μA)
for long-wavelength PPCs that operate in the O- or C-bands 100 mA ≤ IMP < 1 A: ±(0.066% + 1.57 mA)
120 IEEE JOURNAL OF PHOTOVOLTAICS, VOL. 13, NO. 1, JANUARY 2023