Tª 23ºC

t (min) k (uS) pH 10^14-pH

1 2895 0 12.04 91.20108394
2 2880 0.007334963 12.05 89.12509381
3 2794 0.051556917 12.04 91.20108394
4 2706 0.1010155 12 100
5 2701 0.103965702 11.97 107.1519305
6 2601 0.166477916 11.97 107.1519305
7 2591 0.173120729 11.95 112.2018454
8 2435 0.2875 11.92 120.2264435
9 2450 0.275541796 11.93 117.4897555
10 2450 0.275541796 11.91 123.0268771
11 2407 0.31043257 11.9 125.8925412
12 2320 0.387205387 11.9 125.8925412
13 2323 0.384408602 11.9 125.8925412
14 2316 0.390952059 11.89 128.8249552
15 2292 0.413864104 11.86 138.0384265
17 2229 0.477761836 11.82 151.3561248
19 2188 0.522542498 11.81 154.8816619
21 2153 0.562974203 11.8 158.4893192
23 2107 0.619496855 11.77 169.8243652
25 2069 0.669367909 11.76 173.7800829
27 2044 0.70388751 11.73 186.2087137
29 2008 0.756180733 11.71 194.98446
33 1950 0.847533632 11.64 229.0867653
37 1908 0.919850885 11.67 213.796209
41 1875 0.980769231 11.63 234.4228815
45 1843 1.043650794 11.58 263.0267992
49 1815 1.102040816 11.59 257.0395783
Infinit 835 7.42 3801893.963

Cinética a 25ºC por conductimetría C

1.2 1
f(x) = 0.0250485389186265 x + 0.0642590805596747 f(x) =
R² = 0.984310806669241 0.9 R² = 0
1
0.8
0.7
0.8
(k0 - kt) / (kt - kf)
(k0 - kt) / (kt - kf)

0 0.00733496332518337 0.6
0.6 Linear (0 0.5
0.00733496332518337)
0.4
0.4
0.3
 1.2 1
f(x) = 0.0250485389186265 x + 0.0642590805596747 f(x) =
R² = 0.984310806669241 0.9 R² = 0
1
0.8
0.7
0.8

(k0 - kt) / (kt - kf)

(k0 - kt) / (kt - kf)
0 0.00733496332518337 0.6
0.6 Linear (0 0.5
0.00733496332518337)
0.4
0.4
0.3
0.2
0.2
0.1
0 0
0 5 10 15 20 25 30 35 40 45 50 0 2
t (min)

Cinética a 25ºC por potenciometria C

280 800
f(x) = 4.43073452016721 x + 86.9215960272859
R² = 0.978875514859013 700
230 f(x) =
600 R² =
180 500
91.2010839355912

10^(14-pH)
10^14-pH

89.1250938133744
130 400
Linear (91.2010839355912
89.1250938133744)
300
80
200

30 100

0
-200 5 10 15 20 25 30 35 40 45 0
t (min)

Tª 45-50 ºC
t(min) k (uS) (k0 - kt) / (kt - kf) pH 10^(14-pH)
1 1642 0 10.5 3162.2776601684
2 1628 0.017654477 10.38 4168.6938347034
3 1617 0.031969309 10.38 4168.6938347034
4 1614 0.035943517 10.3 5011.8723362727
5 1610 0.041290323 10.3 5011.8723362727
6 1599 0.056282723 10.3 5011.8723362727
7 1595 0.061842105 10.29 5128.6138399137
8 1590 0.068874172 10.3 5011.8723362727
 9 1586 0.074567244 10.3 5011.8723362727
10 1575 0.090540541 10.3 5011.8723362727
11 1573 0.093495935 10.3 5011.8723362727
12 1575 0.090540541 10.32 4786.3009232264
13 1573 0.093495935 10.33 4677.351412872
Infinito 835 7.42 3801893.9632056
 Tª 31ºC
t (min) k (uS) (k0 - kt) / (kt - kf pH 10^14-pH t(min)
1 2232 0 11.52 301.9951720402 1
2 2223 0.00648414985591 11.51 309.02954325136 2
3 2125 0.08294573643411 11.48 331.13112148259 3
4 2056 0.14414414414415 11.44 363.0780547701 4
5 2010 0.18893617021277 11.44 363.0780547701 5
6 1947 0.25629496402878 11.37 426.57951880159 6
7 1910 0.29953488372093 11.4 398.1071705535 7
8 1872 0.34715525554484 11.35 446.68359215096 8
9 1818 0.42115971515768 11.34 457.08818961488 9
10 1772 0.49092849519744 11.31 489.77881936845 10
11 1757 0.51518438177874 11.31 489.77881936845 11
12 1720 0.57853107344633 11.28 524.80746024977 12
13 1643 0.728960396 11.25 562.34132519035 13
14 1662 0.68923821039903 11.22 602.55958607436 14
15 1642 0.73110285006196 11.23 588.84365535559 15
16 1631 0.75502512562814 11.19 645.65422903466 16
17 1631 0.75502512562814 11.2 630.9573444802 17
18 1595 0.83815789473684 11.19 645.65422903466 18
19 1580 0.8751677852349 11.19 645.65422903466 19
20 1565 0.91369863013699 11.16 691.83097091894 20

La pendiente es la k en la ecuación
en r2 cuando más se aproxima a 1 más lineal es

ABAJO HAY LA TABLA A 50ºC

Cinética a 31ºC por conductimetría Cinética a 35

1 3
f(x) = 0.0494519589419845 x + 0.0641614365784669
0.9 R² = 0.97906553257467 f(x) = 0.1333688480805
2.5 R² = 0.95631353375754
0.8
0.7
2
(k0 - kt) / (kt - kf)

(k0 - kt) / (kt - kf)

6332518337 0.6 0 0.00648414985590778

0.5 Linear (0 1.5
32518337) 0.00648414985590778)
0.4
1
0.3
 1 3
f(x) = 0.0494519589419845 x + 0.0641614365784669
0.9 R² = 0.97906553257467 f(x) = 0.1333688480805
2.5 R² = 0.95631353375754
0.8
0.7
2
(k0 - kt) / (kt - kf)

(k0 - kt) / (kt - kf)

6332518337 0.6 0 0.00648414985590778
0.5 Linear (0 1.5
32518337) 0.00648414985590778)
0.4
1
0.3
0.2
0.5
0.1
0 0
0 2 4 6 8 10 12 14 16 18 20 0 5 10
t (min) t

Cinética a 31ºC por potenciometría Cinética a 35

800 12000

700
f(x) = 21.1361697354646 x + 273.801772054889 10000
600 R² = 0.982094790881278 f(x) = 497.96891933
8000 R² = 0.98440510151
5912 500
10^(14-pH)

10^(14-pH)
3744 Column L
400 6000
0839355912 Linear (Column L)
3744)
300
4000
200
2000
100

0 0
0 5 10 15 20 25 0 5 10
t (min) t

Cinética a 45-50ºC por conductimetría Cinétic

0.1 6000
f(x) = 0.00694435301752409 x + 0.0255013677139489
0.09 R² = 0.952880548903577
5000 f(x) = 85.
0.08
R² = 0.34
0.07
4000
(k0 - kt) / (kt - kf)

0.06
10^(14 - pH)

0 0.0176544766708701
0.05 Linear (0 3000
0.0176544766708701)
0.04
2000
0.03
0.02
1000
0.01
0 0
0 2 4 6 8 10 12 0 2
t (min)
 0.06

10^(14 - pH)
0 0.0176544766708701

(k0 - kt) / (kt -

0.05 Linear (0 3000
0.0176544766708701)
0.04
2000
0.03
0.02
1000
0.01
0 0
0 2 4 6 8 10 12 0 2
t (min)
 Tª 35-36 ºC Tª 42 ºC
k (uS) (k0 - kt) / (kt - kf) pH 10^(14-pH) t(min) k (uS)
1660 0 11.07 851.13803820238 0 1914
1525 0.195652174 10.95 1122.018454302 1 1744
1397 0.46797153 10.85 1412.5375446228 2 1611
1335 0.65 10.77 1698.2436524618 3 1516
1293 0.801310044 10.66 2187.7616239496 4 1440
1270 0.896551724 10.61 2454.708915685 5 1382
1204 1.235772358 10.54 2884.0315031266 6 1335
1183 1.370689655 10.49 3235.9365692963 7 1303
1155 1.578125 10.41 3890.4514499428 8 1272
1129 1.806122449 10.37 4265.7951880159 9 1253
1126 1.835051546 10.32 4786.3009232264 10 1230
1117 1.925531915 10.28 5248.0746024977 11 1210
1108 2.021978022 10.24 5754.3993733716 12 1202
1106 2.044280443 10.19 6456.5422903466 13 1192
1099 2.125 10.15 7079.4578438414 14 1179
1095 2.173076923 10.12 7585.7757502919 15 1171
1078 2.395061728 10.09 8128.305161641 16 1169
1075 2.4375 10.06 8709.6358995608 17 1159
1068 2.540772532 10.02 9549.9258602144 18 1150
1065 2.586956522 9.98 10471.285480509 19 1153
20 1143
Infinito 835

Cinética a 35-36ºC por conductimetría Cinética a 42ºC por c

3
f(x) = 0.114390415627215 x + 0.6571621084
f(x) = 0.133368848080506 x + 0.15399732342026 R² = 0.953965705788449
R² = 0.956313533757542 2.5

2
(k0 - kt) / (kt - kf)

Column P
1.5
Linear (Column P)

1
 3
f(x) = 0.114390415627215 x + 0.6571621084
f(x) = 0.133368848080506 x + 0.15399732342026 R² = 0.953965705788449
R² = 0.956313533757542 2.5

(k0 - kt) / (kt - kf)

Column P
1.5
Linear (Column P)

0.5

0
0 5 10 15 20 25 0 2 4 6 8 10 12 14 16 18
t (min) t (min)

Cinética a 35-36ºC por potenciometría Cinética a 42ºC por p

00 14000

00 12000
f(x) = 497.968919334362 x − 340.057346755513 f(x) = 579.310572369755 x − 289.04252
R² = 0.984405101510305 10000 R² = 0.983271679927435
00

10^(14 - pH)
Column R 8000
00
Linear (Column R)
6000
00
4000

00 2000

0 0
0 5 10 15 20 25 0 5 10 15
t (min) t (min

Cinética a 45-50ºC por potenciometría

6000

5000 f(x) = 85.44610969843 x + 4107.64937514915

R² = 0.349566246471352
4000
10^(14 - pH)

Column G
3000
Linear (Column G)

2000

1000

0
0 2 4 6 8 10 12 14
t (min)
10^(14 - pH) Column G
3000
Linear (Column G)

2000

1000

0
0 2 4 6 8 10 12 14
t (min)
 Tª 42 ºC
(k0 - kt) / (kt - kf) pH 10^(14-pH)
0 11.13 741.31024130092
0.1870187019 11.02 954.99258602144
0.3904639175 10.9 1258.9254117942
0.5844346549 10.8 1584.8931924611
0.7834710744 10.71 1949.8445997581
0.9725776965 10.64 2290.8676527678
1.158 10.56 2754.2287033382
1.3055555556 10.48 3311.3112148259
1.4691075515 10.42 3801.8939632056
1.5813397129 10.36 4365.1583224017
1.7316455696 10.3 5011.8723362727
1.8773333333 10.26 5495.4087385763
1.9400544959 10.21 6165.9500186148
2.0224089636 10.15 7079.4578438414
2.136627907 10.11 7762.4711662869
2.2113095238 10.07 8511.3803820238
2.2305389222 10.03 9332.5430079699
2.3302469136 10.01 9772.3722095581
2.4253968254 9.98 10471.285480509
2.393081761 9.95 11220.18454302
2.5032467532 9.93 11748.975549395
7.42 3801893.9632056

ica a 42ºC por conductimetría

415627215 x + 0.657162108404389
05788449

0 0.187018701870187
Linear (0 0.187018701870187)
415627215 x + 0.657162108404389
05788449

0 0.187018701870187
Linear (0 0.187018701870187)

8 10 12 14 16 18 20
t (min)

ica a 42ºC por potenciometría

10572369755 x − 289.042525414564
271679927435

Column X
Linear (Column X)

10 15 20 25
t (min