Scribd Logo
Upload

Welcome to Scribd!

  • Crystal Field Theory - 4 Marks in 10 Minutes For NEET Exam

    Uploaded by

    mesati6896
    6 views3 pages
    The document discusses ligand donor strength in coordination complexes. It presents the spectrochemical series, which ranks ligands based on their donor strengths from weak to strong. It also shows how metal ion charge and d-orbital electron configuration affects which ligands can coordinate in tetrahedral or square planar geometries. The 3d transition metals form complexes with carbon or nitrogen/carbon donors as the metal oxidation state increases, while 4d and 5d metals can form complexes with all ligand types.

    Original Description:

    Original Title

    Crystal Field Theory || 4 Marks in 10 Minutes For NEET Exam

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    The document discusses ligand donor strength in coordination complexes. It presents the spectrochemical series, which ranks ligands based on their donor strengths from weak to strong. It also shows how metal ion charge and d-orbital electron configuration affects which ligands can coordinate in tetrahedral or square planar geometries. The 3d transition metals form complexes with carbon or nitrogen/carbon donors as the metal oxidation state increases, while 4d and 5d metals can form complexes with all ligand types.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    6 views3 pages

    Crystal Field Theory - 4 Marks in 10 Minutes For NEET Exam

    Uploaded by

    mesati6896
    The document discusses ligand donor strength in coordination complexes. It presents the spectrochemical series, which ranks ligands based on their donor strengths from weak to strong. It also shows how metal ion charge and d-orbital electron configuration affects which ligands can coordinate in tetrahedral or square planar geometries. The 3d transition metals form complexes with carbon or nitrogen/carbon donors as the metal oxidation state increases, while 4d and 5d metals can form complexes with all ligand types.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 3

    Octahedral Terahedral

    Spectrochemical Series

    Halogen donors Oxygen donors Nitrogen donors Carbon donors

    I– Br – SCN– Cl– S2– F– OH– C2O42– H2O NCS– EDTA4– NH3 en CN – CO

    3d Series 4d / 5d Series
    Metal (+2) : C Donors Metal (+2)

    Metal (+3) : N / C Donors Metal (+3)

    Metal (+4) : All ligands are SFL Metal (+4)

    Co+3 [ O / N / C Donors ]
    Tetrahedral & Square Planar
    ZnCl42–
    MnO4– d0 d7 d8 d9 d10 Ni(CO)4

    3d series (+2 Metal) C.N. = 4 d 8 d9

    [ I– to H2O ] [ NH3 to CO ] [Cu(NH3)4]2+


    NiCl42– Ni(CN)42–
    [Ni(en)2]2+
    All Ligands of
    3d series (+3/ +4)

    4d / 5d series (+2/+3/+4) PtCl42–

    You might also like