AP Chemistry Exercise 13.5 Equilibrium & ICE Tables ‘The equilibrium constant (A) isthe ratio ofthe equilibrium concentration (or pressure) of product(s) tothe equilibrium concentration (or pressure) of reactant(s). The same expression can be used to calculate the reaction quotient, (Q): INO) +7 Hay # 2M) + 4D wis °° HoFUP ‘The coefficients from the balanced equation become exponents. Liquids and solids never appear in the expressions, because il "oh their concentrations (or pressures) do not change throughout the reaction, (at equltram) (at any mament/pint) DIRECTIONS: Write an equilibrium expression for each of the following. Not all equations are balanced. 1. CaSO, (s) # Ca” (ag) + SO,* (aq) Ke 2 CMTE aut 2. YHCI(g) + _Or(g) = 2H0() + ZCh(e) Lows Thetford 3. Sn(3) + 260 (g) # SnOa() + 2C0(@) = Uses est” a 4. 280) = 280,(@) + 10,() ke Loortoc} “TBosl= 5. Mg(s) + 2Ag" (aq) = Mg” (aq) + 2Ag(s) ve = Be © Taal 6. ZNO(®) + ACh () = ZNOCI() 2 Toor] {Ro}Teuy 2HBr(g) & H:@) + Bri 2 Lie], ee ue CG) + HO@ # COW + hE Yq = Scontnel Theo} 2O@ # 201g ve + Soa < ” oate O2(@) + NOs(@) = O5(@) + NO® Ke = Lositre}__ Cor}i nos Calcul DIRECTIONS: Complete the following in the space provided: 11, Determine the equi ‘equilibrium concentrations (or pressures) into the equilibrium expression. If K. (or K,) is known, the concentration (or ing K- (or K,) from a known set of equilibrium concentrations (or pressures) simply requires substituting the pressure) of one missing species may be found ifthe others are known, rum constant (K,) for the following reaction ifthe equilibrium concentrations of [N01] = 0.00150 and [NO] = 0.571. Write the equilibrium expression and solve forthe value of K. N,0{g) = 2NOx@) = Good [o-szi)’ Me ocd teow © 754 12, For the reaction CH4(g) + HO(g) = CO(g) + 3H; (g) at 1500°C, an equilibrium mixture of these gases was found to have the following concentrations [CO] = equilibrium concentration of HO in this mixture. = Gol)? fcvdlitzol = fe Hoo XT 300M, [Hs] = 0.800M and [CH,] = 0.4004. K, at 1500°C = 5.67. Determine the 2 selboeen eee > cena leeteeey - ovate [p-do0] s-6¥ Revised 2018-10-02 aa TT ATR TTT 3}{00)"ea (0284) [C0)"oSar a0 2704) ode. (M0 e260} = f= [eode) Boo TITRE SPST ASA TTT TNT TOTOAP Chemistry Exercise 13.5 ae Equilibrium & ICE Tables Date:_____ Per: 1, Nitrogen and hydrogen react together ina 4.00 liter container at 450°C. At equilibrium, [Ns] = 0.130, [Ha] = 0.220, and [NE] = 0.650. Calculate the equilibrium constant (K,) for this reaction. NG) eMelQy S 2NBL) Cast g Re ag? Leese TNrSCweY fowl eww? 14, A reaction vessel is charged with hydrogen iodide, which partially decomposes to molecular hydrogen and iodine according to the equation: 2seg2 Kee | 2HI (2) When the system comes to equilibrium at 425 °C, Py = H,@ + L@ 708 atm, and Py, = Pi, = 0.0960 atm, Calculate the value of K,. Ke # (UNCTAD _—z (©. 0940)(0.09)_ = 5.01878 @ wae (e-z68* K ABH \.B4 KU 15. For the reaction Hy (g) + Cl, (g) =* 2HCI (g), the following equilibrium concentrations are determined: [H:] = 0.42 M, cages Sea er meal 16, Write the equilibrium expression K, forthe reaction: No (g) + 03(g) = 2NO(@) 2 ee OD PY Np goa 17. The Koy forthe equilibrium of 2NO (g) + Os (g) = 2NOz (g) is 5.4 » 10” at 480. reaction 4NO (g) + 20> (g) = 4NOz (g)? 2 UwOLg) ¥ 202g % MMOL) = 2 (241g) + O41) = 2068) 7 iva = genes faa 18. Write the expression for K, for the reaction 4Cu@{s) + CHy(g) = COs(8) + Seutsy + 2H,0(8). - (ReDdgrot (poed 19. Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC,H,0,(aq) = C,1,0,"€q) + H(@q) jes 2 {urltew) (eaz}fecrs) Suet, toss 2 29.45 Ke 0°C, What isthe value of Keg for the At cqulibriugy at 25 °C a 0.100 M solution of acetic acid has the following concentrations: [HC3H.0; [CH:0: L513 * 10° M, and [H'] 5 1.33 = 10° M, Calculate the equilibrium constant, Ky fr the acid at 25% ge Cesborttwd Dsseto M2980) 2 | 3G nF THCctyoe) fo.0%40) me eS all ETS TNT OTST ae 2)(C} ow suc (C= Revised: 2018-1002 FTAA TS TTT Ee Pico) eam (ol ossee f= fcoJ~ ose 20m 201E £ & 5 & Name: Date: Per: Exercise 13.5 Equilibrium & ICE Tables 20. Phosphorus trichloride and phosphorus pentachloride equilibrate in the presence of molecular chlorine according to the reaction: PCh(e) +Clx(g) = PCIs(g), Ifan equilibrium mixture at 450 K contains PCI; = 0.124 atm, PCl; = 0.157 atm, and ra = 1,30 atm, What is the value of K, at this temperature? = (pPus) Gx Gras) 4®) oa (PRAY “Cro. cy = Vag? be® \aras lly deompose according tothe equlbrium: NsO4(g) = 2NO(@). A LODO sk charged 21. Dinitrogen tetroxide pa with 3.00 x 107 mol of NOx. At equilibrium, 2.36. 10” mol of N:0, remains. Keg for this reaction is “ANzd4(d & ZNOr(s) _ foul? TE Vworwide — 2 Wtexwtl 2 yeureie? “Tia e ~fud stort) seb 0") eerercoo| : Ceaenw hy b.2e807) [eee cana | ICE Tables equilibrium concentrations are not known, the problem requires using stoichiometric relationships to determine the ‘equilibrium concentrations from given information. These are organized using an ICE table. For the reaction CO(g) + H.0(8) = CO,(g) + Hag) calculate the jum concentrations of all species i 1.000 mol of each reactant is mixed in @1,000L flask. K.~ 5.10 at the temperature of this reaction. COs 0.000 initial T [Change] c wilibrium] —E [CO,)| He) ae gee a Ke TES, 10-226" mo 226-226 0.693 CO) 1,0) COxg) Fag) [ [Equilibrium] —E | 1.000—0.693 0307 | 1.000—0.693 = 0307 W7 0.693 M 0.693. A7 22, When wine spoils, ethanol is oxidized to acetic acid as O, from the air dissolves in the wine: C3HsOH (aq) + O3(aq) == CH,COOH (ag) + H;0()) The value of K. for this reaction at 25°C is 1.2.x 10%. Will much ethanol remain when the reaction has reached equilibrium? Explain. 1.2 ¥ (082 16 AP CHrREMELY LARK HOMEER TERING WE Bt) Gog? vo COPE Teh (BAREALY) , 60 NOT MUCK VE ANY OF THE Cadsalk wus Ferrenet: CHHORN MUL Cog th wo Corsieiaee “© teervers. 23, An equilibrium mixture of Os, SO: and SOs contains equal concentrations of SO; and SO. Calculate the concentration of 0, if K,= 270, forthe reaction: 2 $Os(g) + O2(g) #2 SOs(g) Ca0st* [4023* Con) At s Pe: 30,4 Cxy Con Cates [oud teen Sess aye RETA RT TE TPIT TT AGT ATT ST TOY SRT Ta TT at NO) =o BNL y= teOA AON 2mm ZIMA) = Leen (“cea 38(CO} oes By) oer co) “om Revised: 2018-10402 FamaName: Exercise 13.5 Date Per: Equilibrium & ICE Tables AP Chemistry 24, The value of Ke for the equilibrium N,Oq(g) = 2NOs() is 4.64 x 10° at 25°C. Ifthe initial concentrations of NO is 0.0367M and the initial concentration of NO» is zero, what will be the concentration of both gases at equilibrium? B% Nudge) & 2Noalg) Ke-= Coste Heat chin’ -tZoLsiod 2 X 0.0%Kt ° Ws} x 2 Heh a0? Gate eH ( e7 a ay Cas 62x quew?s fxd we nae £2 F809107 ge TO Lg eae Hoses) Be) 2 Bee Dee mnen P= O-ONAF [O.8N9 Crowe ox 2 O.03G- S.IGB B15 0.050% = 25. AL680°C the reaction blow haa Ku yl of 0.77. 1F2.00 mal ofboth yarogen and erbon dase are placed ina | 2304] 4.00 L container and allowed to react, what will be the equilibrium concentrations of all four gases? rE. = Leolw % Ha(g) + COn(g) + CO®) + H2O(@) i ae ie ae I b.5001 [o50, oo ° 0.498 - 0.8980" ) = Key & -x x eX OK DMB € 1-8480K ae © smd fomen x « 20.098 Gao de sd < Teele pedy 2 0. 7940 2 ta me 7 N —_ «ett +» = ew 2 0.26L < Gens PIER Gawd TORE Goebel tee 26, Find the equilibrium constant, Ku, forthe following equilibrium. The inital con aiid ASD are 0.30 M before they are mixed and when equilibrium is reached, the equilibrium concentration of AxD is 0.20 M._Be sure To show an ICE table for your caleulation. % 2B) +GDEH3ADW) +20) Yo = Chl _ x 040 0.20 oa © +020 0.10 Suace Craven & E o.60 0.20 Produk? ore presark Koatoke b & peat ERGs ese ld wit 100ml fH 0 mel an. mol fH Ky 0K) 2, Clare the equilibrium concentrations of Ha, Ip and HI at SOOK given the reaction: Ha(g) + la(g) ==2HI(g). HE belo LMM) & HiQe sud a) Gyo = 2sore i Wete6h [o.00a (0.500) Coney Cp.vod} 6.500} ar sao ebe ~ Lest Cc -x oe ate + S:OTEK yas Kew OE S omioma omens CHT a ce Bi . Yet Loser te}! ida teeaoel LATS= ©,600-2(0.132) = To.see) zo! esx] .500 ¥ FOAM | Testo TY tpn cons hy ) Jewro-xy" BAYNE 0.500425 28. Cabom pombe COBEEA SE RARITY Racing CO with Br, A mise of 2400 moO, 0300 mol Br and £20200 mol COBrs sealed ina 5.00. fas, Calle equilram concentrations forall eases, K= 0.680 =e % CO(e) + Br(g) COBN(g) os COD © BAD Buon E (e.cG0a) (orev Gouceweg — 6B + eRstx ~opects4 =O Te.ct0d} —. ; tk kK =k qa “lease t Terme ower 0) 2 Sete) pee Pe sieanear ———v Ke? Tertec} ene Hs OE ee Z(o.6ee) . feeoned Ye alten’ Hee GAH KW oF el LAN, gaint Boalt Ans py outos (p.0ekee-% [ests o.cbo0 + vatMiniett 2 0.080% 2 fo an Loqlz0.0w0 btn = 0.0007" oF abo = Le-denco-*! __- 2 * Got Porceee OO aT aHDR TE \_Lesta}e o.cnea-tAAneit 0.0078 e.0O8UE + 0.0952. +O. (GOR" = DCOMEDA ST TSH ITs AN OO NO ToT HET TT ean ove 28 (Co|= ou bn) = ecb) 000 2s asome 2708) vised 2018 aa TAT TTT TTT reed: 2016 10.0 year dam puol= ODA