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Chapter 13

Magnetic and Electrical Separation

13.1 INTRODUCTION product (“mags”) of a magnetic separator due to


attractive magnetic forces. Examples of paramagnetic
Magnetic and electrical separators are being considered in minerals which are separated in commercial magnetic
the same chapter, as there is often an overlap in the appli- separators are ilmenite (FeTiO3), rutile (TiO2), wol-
cation of the two processes. A classic example of this is framite ((Fe, Mn)WO4), monazite ((Ce, La, Nd, Th)
the processing of heavy mineral sands in which both mag- PO4), xenotime (YPO4), siderite (FeCO3), chromite
netic and electrostatic separation are crucial to achieve (FeCr2O4), and manganese minerals.
separation.
Paramagnetism in a material originates due to the
presence of unpaired electrons which create magnetic
13.2 MAGNETISM IN MINERALS dipoles. When these magnetic dipoles are aligned by an
externally applied magnetic field, the resultant magnetic
Magnetic separators exploit the difference in magnetic
moment causes the material to become magnetized and
properties between the minerals in a deposit and are used
experience a magnetic force along the lines of the applied
to concentrate a valuable mineral that is magnetic (e.g.,
magnetic field. Certain elements have electron configura-
magnetite from quartz), to remove magnetic contaminants,
tions with many unpaired electrons, but the magnetic
or to separate mixtures of magnetic and nonmagnetic
response of a given mineral depends on the structure of
valuable minerals. An example of the latter is the tin-
the mineral as well as its constituent atoms. For example,
bearing mineral cassiterite, which is often associated with
pyrite (FeS2) is very slightly paramagnetic, but the
traces of the valuable minerals magnetite or wolframite,
chemically similar pyrrhotite (Fe12xS) in the monoclinic
which can be removed by magnetic separators.
structural form is actually strongly magnetic, referred to
This text will only briefly introduce the concepts asso-
as ferromagnetic.
ciated with magnetism in mineral separation. For those
Ferromagnetism can be regarded as a special case of
interested in further details there are a number of other
paramagnetism in which the magnetic dipoles of a mate-
sources (Jiles, 1990; Oberteuffer, 1974; Svoboda, 1987;
rial undergo exchange coupling so that they can more
Svoboda and Fujita, 2003).
rapidly align themselves with an applied magnetic field.
All materials are affected in some way when placed in
Examples of diamagnetic, paramagnetic, and ferromag-
a magnetic field, although with many substances the
netic behavior are shown in Figures 13.1 and 13.2
effect is too slight to be easily detected. For the purposes
represented as magnetization (density of magnetic
of mineral processing, materials may be classified into
dipoles) versus applied magnetic field strength. The slope
two broad groups, according to whether they are attracted
of these curves represents the dimensionless magnetic
or repelled by a magnet:
susceptibility of the material. Figure 13.1 shows the para-
1. Diamagnetic materials are repelled along the lines of magnetic susceptibility (shown by a positive linear slope)
magnetic force to a point where the field intensity is of chromite and the diamagnetic susceptibility (negative
smaller. The forces involved here are very small and linear slope) of quartz, while Figure 13.2 shows the ferro-
diamagnetic substances are often referred to as “non- magnetic trend of magnetite. Thanks to exchange cou-
magnetic”, although this is not strictly correct. pling, ferromagnetic materials will have very high initial
Diamagnetic minerals will report to the nonmagnetic susceptibility to magnetic forces until all of the
product (“non-mags”) of a magnetic separator as they exchange coupled magnetic moments have aligned with
do not experience a magnetic attractive force. the applied magnetic force. This results in a rapidly
2. Paramagnetic materials are attracted along the lines of decreasing value of susceptibility with increased applied
magnetic force to points of greater field intensity. magnetic field (Figure 13.2, points 13). Once this
Paramagnetic materials report to the “magnetic” alignment has occurred the material is said to have
Wills’ Mineral Processing Technology.
© 2016 Elsevier Ltd. All rights reserved. 381
382 Wills’ Mineral Processing Technology

3.0
Magnetization
(kA m–1) Paramagnetic
2.0 (Chromite)

1.0
Diamagnetic
(quartz)

–2,000 –1,500 –1,000 –5,00 0 500 1,000 1,500 2,000

Applied magnetic field (kA m–1)


–1.0

–2.0

–3.0

FIGURE 13.1 Magnetization versus applied magnetic field strength for idealized paramagnetic and diamagnetic minerals.

400
Ferromagnetic
Magnetization
(magnetite)
(kA m–1)
300
3
2
200 1 Point Slope, χ
1 1.7
2 0.3
100
3 0.0

–2,000 –1,500 –1,000 –500 0 500 1,000 1,500 2,000


Applied magnetic field (kA m–1)
–100

–200

–300

–400

FIGURE 13.2 Magnetization versus applied magnetic field strength for a ferromagnetic mineral.

reached its saturation magnetization (a characteristic to report to the magnetic product, ferromagnetic materials
value of the material shown in Figure 13.2 as a plateau are recovered in low-intensity magnetic separators.
in magnetization), and any further increase in applied
magnetic field will not be accompanied by a further
increase in magnetization. Measuring Magnetic Properties
Compared to paramagnetic materials, which need The magnetic properties of a material may be measured
high-intensity (high magnetic field) magnetic separators directly via a vibrating sample magnetometer (used to
Magnetic and Electrical Separation Chapter | 13 383

4.0
Magnetization Paramagnetic
(kA m–1) (Chromite)
3.0
0.4

0.2
2.0
0
–500 –300 –100 100 300 500
–0.2
1.0
–0.4 Diamagnetic
(Quartz)

–2,000 –1,500 –1,000 –500 0 500 1,000 1,500 2,000


Applied magnetic field (kA m–1)
–1.0

–2.0

–3.0

–4.0

FIGURE 13.3 Magnetization versus applied magnetic field strength for natural samples.

obtain the data for Figures 13.1 and 13.2) which is


specifically designed to capture the variation of the mag-
netic properties of a material as a function of applied
magnetic field strength. Empirical data for paramagnetic
mineral samples often includes both paramagnetic and
ferromagnetic characteristics due to the presence of impu-
rities in the sample, as mineral grains, or in the mineral’s
crystal structure. Similarly, measurements of a predomi-
nantly diamagnetic sample may show signs of a paramag-
netic impurity. In Figure 13.3, the results are shown for FIGURE 13.4 Diagram of Frantz Isodynamic Separator.
the samples from Figure 13.1 prior to data processing to
isolate the paramagnetic or diamagnetic trend.
Vibrating sample magnetometers are expensive instru- particle it will report to the chute on the right side of
ments and require specialized personnel to operate. As Figure 13.4, and when the magnetic force is insufficient
such, they are typically found only in research settings, to overcome gravity the mineral particle exits the separa-
such as universities. A more practical tool in mineral pro- tor on the left side of the chute. As the current through
cessing labs for determining magnetic properties is the the electromagnetic coil and both θ1 and θ2 may be varied
Frantz Isodynamic Separator, shown diagrammatically in across a wide range, this separator is able to separate
Figure 13.4. In the Frantz separator, mineral particles are minerals of varying magnetic properties. It may even be
fed down a vibrating chute inclined at an angle θ2 which used to concentrate diamagnetic minerals, in which case
is also inclined in the transverse direction at an angle θ1. the side slope is moved past horizontal such that the chute
The force of gravity is opposed by the magnetic force exit on the right of Figure 13.4 becomes the down slope
generated by the electromagnetic coil through which the exit for particles where the diamagnetic force (repulsive
chute passes. The Frantz is referred to as an isodynamic magnetic force) is insufficient to overcome the force of
separator due to the fact that the magnetic force felt by a gravity. The Frantz may also be used to determine the
particle of constant magnetic susceptibility and orienta- magnetic susceptibility of a given mineral, provided other
tion remains constant throughout the length of the separa- materials of known susceptibility are available for proper
tor (McAndrew, 1957). When the attractive magnetic calibration (McAndrew, 1957). Normally operated dry, it
force is stronger than the force of gravity on a mineral can be modified to operate wet (Todd and Finch, 1984).
384 Wills’ Mineral Processing Technology

The Franz is also used to characterize materials, sepa- we can combine Eqs. (13.4) and (13.5) to yield:
rating fractions that can then be identified. These data can
B 5 μμ0 H (13.6)
form the basis of predicting separation in full size mag-
netic separators. For ferromagnetic materials, the Davis For paramagnetic materials, χ is a small positive con-
tube is more suitable and is the common tool for charac- stant, and for diamagnetic materials it is a much smaller
terizing magnetic iron ores (Davis, 1921). negative constant. As examples, from Figure 13.1 the slope
representing the magnetic susceptibility of the material, χ,
is about 0.001 for chromite and 20.0001 for quartz.
13.3 EQUATIONS OF MAGNETISM The magnetic susceptibility of a ferromagnetic mate-
The magnetic flux density or magnetic induction is the rial is dependent on the magnetic field, decreasing with
number of lines of force passing through a unit area of field strength as the material becomes saturated.
material, B. The unit of magnetic induction is the tesla (T). Figure 13.2 shows a plot of M versus H for magnetite,
The magnetizing force, which induces the lines of showing that at an applied field of 80 kA m21, or 0.1 T,
force through a material, is called the field intensity, H the magnetic susceptibility is about 1.7, and saturation
(or H-field), and by convention has the units ampere per occurs at an applied magnetic field strength of about
meter (A m21) (Bennett et al., 1978). 500 kA m21 or 0.63 T. Many high-intensity magnetic
The intensity of magnetization or the magnetization separators use iron cores and frames to produce the
(M, A m21) of a material relates to the magnetization desired magnetic flux concentrations and field strengths.
induced in the material and can also be thought of as the Iron saturates magnetically at about 22.5 T, and its non-
volumetric density of induced magnetic dipoles in the linear ferromagnetic relationship between inducing field
material. The magnetic induction, B, field intensity, H, strength and magnetization intensity necessitates the use
and magnetization, M, are related by the equation: of very large currents in the energizing coils, sometimes
up to hundreds of amperes.
B 5 μ0 ðH 1 MÞ (13.1) The magnetic force felt by a mineral particle is depen-
where μ0 is the permeability of free space and has the dent not only on the value of the field intensity, but also
value of 4π 3 1027 N A22. In a vacuum, M 5 0, and M is on the field gradient (the rate at which the field intensity
extremely low in air and water, such that for mineral pro- increases across the particle toward the magnet surface).
cessing purposes Eq. (13.1) may be simplified to: As paramagnetic minerals have higher (relative) magnetic
permeabilities than the surrounding media, usually air or
B 5 μ0 H (13.2) water, they concentrate the lines of force of an external
so that the value of the field intensity, H, is directly pro- magnetic field. The higher the magnetic susceptibility, the
portional to the value of induced flux density, B (or B- higher the induced field density in the particle and the
field), and the term “magnetic field intensity” is then greater is the attraction up the field gradient toward
often loosely used for both the H-field and the B-field. increasing field strength. Diamagnetic minerals have
However, when dealing with the magnetic field inside lower magnetic susceptibility than their surrounding
materials, particularly ferromagnetic materials that con- medium and hence expel the lines of force of the external
centrate the lines of force, the value of the induced flux field. This causes their expulsion down the gradient of the
density will be much higher than the field intensity. This field in the direction of the decreasing field strength.
relationship is used in high-gradient magnetic separation The equation for the magnetic force on a particle in a
(discussed further in Section 13.4.1). For clarity it must magnetic separator depends on the magnetic susceptibility
be specified which field is being referred to. of the particle and fluid medium, the applied magnetic
Magnetic susceptibility (χ) is the ratio of the intensity field and the magnetic field gradient. This equation, when
of magnetization produced in the material over the considered in only the x-direction, may be expressed as
applied magnetic field that produces the magnetization: (Oberteuffer, 1974):
M dB
χ5 (13.3) Fx 5 Vðχp 2 χm ÞH (13.7)
H dx
Combining Eqs. (13.1) and (13.3) we get: where Fx is the magnetic force on the particle (N), V the
particle volume (m3), χp the magnetic susceptibility of the
B 5 μ0 Hð1 1 χÞ (13.4) particle, χm the magnetic susceptibility of the fluid medium,
If we then define the dimensionless relative permeabil- H the applied magnetic field strength (A m21), and dB/dx
ity, μ, as: the magnetic field gradient (T m21 5 N A21 m22). The
product of H and dB/dx is sometimes referred to as the
μ511χ (13.5) “force factor.”
Magnetic and Electrical Separation Chapter | 13 385

Production of a high field gradient as well as high particles themselves to behave as magnets, thus attracting
intensity is therefore an important aspect of separator each other. Flocculation, or agglomeration, of the parti-
design. To generate a given attractive force, there are an cles can occur if they are small and highly susceptible
infinite number of combinations of field and gradient and if the field is intense. This is important as these mag-
which will give the same effect. Another important factor netic “flocs” can entrain gangue mineral particles as well
is the particle size, as the magnetic force experienced by as bridge the gaps between magnetic poles, reducing the
a particle must compete with various other forces such as efficiency of separation.
hydrodynamic drag (in wet magnetic separations) and the Much of the optimization of high-intensity separators
force of gravity. In one example, considering only these is based on providing as many sites of high field gradient
two competing forces, Oberteuffer (1974) has shown that as possible to improve the magnetic particle carrying
the range of particle size where the magnetic force predo- capacity of the separator. Wet high-intensity magnetic
minates is from about 5 μm to 1 mm.

13.4 MAGNETIC SEPARATOR DESIGN


13.4.1 Magnetic Field Gradient
Certain elements of design are incorporated in all mag-
netic separators, whether they are wet or dry separators
with low- or high-intensity magnetic fields. The prime
requirement is the provision of a high-intensity field in
which there is a steep field strength gradient. In a field of
uniform magnetic flux, such as in Figure 13.5(a), mag- FIGURE 13.5 (a) Field of uniform flux, and (b) converging field gen-
netic particles will orient, but will not move along the erating force on particle.
lines of flux. The most straightforward method for pro-
ducing a converging field is by providing a V-shaped pole
above a flat pole, as in Figure 13.5(b). The tapering of the
upper pole concentrates the magnetic flux into a very
small area, giving high intensity. The lower flat pole has
the same total magnetic flux distributed over a larger
area. Thus, there is a steep field gradient across the gap
by virtue of the different field intensity levels. Another
method of producing a high field gradient is by using a
pole which is constructed of alternating magnetic and
nonmagnetic laminations (Figure 13.6).
The design of field gradient in magnetic separators
may be divided into two types: open-gradient magnetic
separators (OGMSs) and high-gradient magnetic separa-
tors (HGMSs). In an OGMS design, the magnetic gradient
is created by the poles of the magnets themselves, and as
FIGURE 13.6 Production of field gradient by laminated pole.
a result the gradient is relatively weak (Kopp, 1991).
These type of separators include free-fall separators and
drum separators where particles passing by the separator
are deflected into different streams based on their mag-
netic properties (Kopp, 1991). In HGMS, a ferromagnetic
matrix element is introduced into the applied magnetic
field to create many points of high field gradient with the
intention of capturing the magnetic particles and allowing
nonmagnetic particles to flow through the separator.
The introduction of particles with high magnetic sus-
ceptibility into a magnetic field will concentrate the lines
of force so that they pass through the particles themselves
(Figure 13.7). Since the lines of force converge to the par- FIGURE 13.7 Production of filed gradient by strongly magnetic matrix
ticles, a high field gradient is produced, which causes the material, and consequent capture and buildup of magnetic particles.
386 Wills’ Mineral Processing Technology

separators (WHIMSs) will often use a ferromagnetic 13.4.2 Magnetic Field Intensity
matrix material to achieve this, such as those shown in
Figure 13.8. The recently developed Outotec SLon Provision must be incorporated in the separator for regu-
vertically pulsating high-gradient magnetic separator lating the intensity of the magnetic field in order to deal
(VPHGMS) offers improvements in magnetic matrix with various types of material. This is easily achieved in
design via the use of steel rods. electromagnetic separators by varying the current, while
A visual comparison of the effects of different matrix with permanent magnets the interpole distance can be var-
materials on magnetic flux may be seen in Figure 13.9. ied. In the case of laboratory separators, this can also be
The design of the matrix can be further optimized by achieved by interchanging the permanent magnets for
tapering the size and spacing of the rods throughout the magnets of higher magnetic field intensity. A special class
matrix (Figure 13.10) so that coarse magnetic particles of magnetic separators, known as superconducting separa-
are trapped first near the slurry inlet, with additional tors, may be used when very high field intensities are
points of high field gradient introduced further along the required. Additional information on superconducting
direction of slurry flow to capture finer magnetic parti- separators may be found in Section 13.5.4.
cles (Novotny, 2014). Further details on WHIMS and It is important to note that increasing field intensity
VPHGMS may be found in Sections 13.5.2 and 13.5.3, does not necessarily lead to an improved separation.
respectively. Work by Svoboda (1994) with HGMS has shown that the

FIGURE 13.8 Examples of matrix materials used in high-intensity separators: (a) section through Boxmag-Rapid grid assembly showing matrix of
stainless steel bars, (b) grid of expanded ferromagnetic stainless steel used for coarse particle sizes, and (c) ferromagnetic stainless steel wool used for
fine particle sizes (Courtesy Metso).

HIMS ®
al W SLon VPH
on Nonmagnetic particle
G
iti

MS
Trad

Magnetic particle
Magnetic flux line

Wash water Slurry flow Slurry flow


Magnetic pole

Magnetic pole

Magnetic pole

Magnetic pole

Steel matrix Steel matrix

Pulsing Wash
water

FIGURE 13.9 Comparison of effects of magnetic matrix design on magnetic flux in traditional WHIMS and SLon VPHGMS (Courtesy Outotec).
Magnetic and Electrical Separation Chapter | 13 387

TABLE 13.1 Comparison of Product of Magnetic


Susceptibility and Applied Magnetic Field Between
Points Along the Curve in Figure 13.2

Point Applied Magnetic Field χH (kA m21)


(kA m21)
1 80 134
2 160 49
3 320 23

FIGURE 13.10 Design of magnetic matrix to optimize capacity as


well as maximize recovery of fine magnetic particles (Adapted from
Novotny (2014)).
effect of increased field strength can actually be a
decrease in the magnetic force experienced by the parti-
magnetic field strength should be carefully selected cle. It is therefore crucial that the appropriate magnetic
according to the application, as higher field strengths may field is applied for a given separation.
lead to increased capture of weakly magnetic gangue par-
ticles. The field should be sufficient to ensure that a parti- 13.4.3 Material Transport in Magnetic
cle which collides with a matrix element will remain
fixed to that element; any further increase serves only to
Separators
retain particles with weaker magnetic properties. Another Commercial magnetic separators are continuous-process
negative impact of high field strength is that for particles machines, and separation is carried out on a moving
exhibiting some degree of magnetic ordering, a relatively stream of particles passing into and through the magnetic
common situation in mineral processing, increased field field. Close control of the speed of passage of the parti-
strength actually serves to decrease the magnetic suscepti- cles through the field is essential, which typically rules
bility (Svoboda, 1994). Work by Shao et al. (1996) to out free fall as a means of feeding. Belts or drums are
measure the magnetic susceptibility of iron minerals at very often used to transport the feed through the field.
varying field strengths showed that from 0.4 to 0.9 T the As discussed in Section 13.4.1, flocculation of mag-
susceptibility of a hematite sample decreased by more netic particles is a concern in magnetic separators, espe-
than 50%. A similar result is seen in Figure 13.2, where cially with dry separators processing fine material. If the
the susceptibility of magnetite decreases from 1.7 to 0.1 ore can be fed through the field in a monolayer, this effect
as the applied magnetic field strength is increased from is much less serious, but, of course, the capacity of the
0.1 to 0.4 T (80320 kA m21). While such a decrease in machine is drastically reduced. Flocculation is often mini-
magnetic susceptibility is significant, it must be consid- mized by passing the material through consecutive mag-
ered in the context of the increasing applied magnetic netic fields, which are usually arranged with successive
field strength, as both H and χ affect the force experi- reversals of the polarity. This causes the particles to turn
enced by a mineral particle (Eq. (13.7)). The product of through 180 , each reversal tending to free the entrained
the two, χH, should be calculated to capture the effect of gangue particles. The main disadvantage of this method is
both the decreasing magnetic susceptibility and the that flux tends to leak from pole to pole, reducing the
increasing applied magnetic field strength. An example of effective field intensity.
such a calculation for the mineral from Figure 13.2 is Provision for collection of the magnetic and nonmag-
given in Table 13.1. netic fractions must be incorporated into the design of the
As magnetic field strength is increased, the magnetic separator. Rather than allow the magnetics to contact the
field gradient in the separator will also change; this is not pole-pieces, which then requires their detachment, most
considered in the calculations in Table 13.1, although it separators are designed so that the magnetics are attracted
will have a direct effect on the force experienced by the to the pole-pieces, but come into contact with some form
mineral particles. Excess applied field strength may actu- of conveying device, which carries them out of the influ-
ally decrease the field gradient in a given separator ence of the field, into a bin or a belt. Nonmagnetic dis-
(Section 13.4.1) (Svoboda, 1994). Since the magnetic posal presents no problems; free fall from a conveyor into
force on a particle is directly proportional to the magnetic a bin is often used. Middlings are readily produced by
susceptibility of the particle as well as the magnetic field using a more intense field after the removal of the highly
gradient in the separator, as seen in Eq. (13.7), the net magnetic fraction.
388 Wills’ Mineral Processing Technology

13.5 TYPES OF MAGNETIC SEPARATOR separator) in advance of centrifugal gravity concentration


is used to remove tramp iron and prevent damage to the
Magnetic separators are generally classified into low- centrifugal separator, as well as avoiding contamination
and high-intensity machines, but here we include high- of the gravity concentrate with dense iron particles (Bird
gradient and superconducting devices. and Briggs, 2011).
Dry low-intensity magnetic separation is confined
mainly to the concentration of coarse sands which are
13.5.1 Low-Intensity Magnetic Separators strongly magnetic, a process known as “cobbing,” and is
Low-intensity separators are used to treat ferromagnetic often carried out using drum separators. For particles
materials and some highly paramagnetic minerals. below 5 mm, dry separation tends to be replaced by wet
As shown in Figure 13.2, minerals with ferromagnetic methods, which produce less dust loss and usually yield a
properties have high susceptibility at low applied field cleaner product. Low-intensity wet separation is widely
strengths and can therefore be concentrated in low inten- used for recycling (and cleaning) magnetic media in dense
sity (,B0.3 T) magnetic separators. For low-intensity medium separation (DMS) processes (see Chapter 11) and
drum separators (Figure 13.11) used in the iron ore indus- for the processing of ferromagnetic sands.
try, the standard field, for a separator with ferrite-based The general design of drum separators is a rotating,
magnets, is 0.12 T at a distance of 50 mm from the drum hollow, nonmagnetic drum containing multiple stationary
surface (Novotny, 2014). Work by Murariu and Svoboda magnets of alternating polarity. The medium-intensity
(2003) has also shown that such separators have maxi- Permos separator uses many small magnet blocks, whose
mum field strengths on the drum surface of less than direction of magnetization changes in small steps. This is
0.3 T. The principal ferromagnetic mineral concentrated said to generate a very even magnetic field, requiring less
in mineral processing is magnetite (Fe3O4), although magnetic material (Wasmuth and Unkelbach, 1991). The
hematite (Fe2O3) and siderite (FeCO3) can be roasted to spatial arrangement of the magnets within a drum separa-
produce magnetite and hence give good separation in tor may be varied depending on the specific requirements
low-intensity machines. of the application. This is illustrated by the two variants
The removal of “tramp” iron from feed belts can also of magnet configuration offered for Metso’s low-intensity
be regarded as a form of low-intensity magnetic separa- drum separator for DMS applications. The two configura-
tion. However, tramp iron removal is usually accom- tions (Figure 13.13) demonstrate the trade-off between
plished by means of a magnetic pulley at the end of an increasing magnetic loading capacity (Figure 13.13(a)) to
ore conveyor (Figure 13.12) or by a guard magnet sus- capture more particles and increasing field gradient
pended over the conveyor belt (see Chapter 2). Tramp (Figure 13.13(b)) to capture finer or less susceptible parti-
iron removal is important prior to crushing and in certain cles. The high-capacity arrangement has fewer, larger
cases removal of the iron produced from grinding media poles, which results in a lower field gradient but a higher
wear can be important for downstream processing. A magnetic flux of 0.12 T at a distance of 50 mm from the
common example of the latter is processing gold ores, roll surface (Metso, 2014a). The high gradient variant has
where the use of magnetic separation (typically a drum more, smaller poles, resulting in a higher field gradient to
better capture fine magnetic particles, but at reduced
capacity (magnetic flux of only 0.06 T at a distance of
50 mm from the roll surface) (Metso, 2014a).

FIGURE 13.12 Example of magnetic pulley used to remove tramp


FIGURE 13.11 Diagram of a typical drum separator. iron from an ore prior to further processing (Courtesy Eriez).
Magnetic and Electrical Separation Chapter | 13 389

Slurry feed

Separator drum

Concentrate
launder
Feed
box
FIGURE 13.13 Alternate magnet configurations for a wet drum sepa-
rator. (a) High-capacity arrangement, and (b) high-gradient arrangement Mag n e ts
(Courtesy Metso).

Separator tank
Slurry feed

Tailings Magnetic concentrate


Separator drum
Concentrate
launder FIGURE 13.15 Counter-current configuration of a wet drum separator
(Courtesy Metso).
Feed
box
M ag n ets Slurry feed

Separator drum
Separator tank Feed Discharge
box launder

M
gn

a
Tailings Magnetic concentrate ets

FIGURE 13.14 Concurrent configuration of a wet drum separator


(Courtesy Metso). Concentrate Separator tank
launder

Although drum separators initially employed electro- Magnetic concentrate Tailings


magnets, permanent magnets are used in modern devices,
utilizing ceramic or rare earth magnetic alloys, which FIGURE 13.16 Counter-rotation configuration of a wet drum separator
retain their intensity for an indefinite period (Norrgran (Courtesy Metso).
and Marin, 1994). Separation in a drum separator occurs
by the “pick-up” principle, wherein magnetic particles are
lifted by the magnets and pinned to the drum and are con- also be configured with counter-current and counter-
veyed out of the field, leaving the nonmagnetics (usually rotation arrangements (Figures 13.15 and 13.16).
the gangue) in the tailings compartment. Water is intro- In a counter-current separator, the tailings are forced
duced to provide flow, which keeps the pulp in suspen- to travel in the opposite direction to the drum rotation and
sion. Field intensities of up to 0.7 T at the pole surfaces are discharged into the tailings chute. This type of separa-
can be obtained in this type of separator. tor is designed for finishing operations on relatively fine
The drum separators shown in Figures 13.11 and material, of particle size less than about 800 μm. Pulp
13.14 are of the concurrent type (as shown by the separa- densities in this type of separator are typically lower than
tor tank flow pattern in Figure 13.14), whereby the con- in the concurrent configuration.
centrate is carried forward by the drum and passes The third possible configuration is the counter-rotation
through a gap, where it is compressed and dewatered type, where the feed flows in the opposite direction to the
before leaving the separator. This design is most effective rotation. This type is used in roughing operations, where
for producing a clean magnetic concentrate from rela- occasional surges in feed must be handled, and where
tively coarse feeds (up to 68 mm) and is widely used in magnetic material losses are to be held to a minimum
dense medium recovery systems. In addition to the con- when high solids loading is encountered, while an
current arrangement (Figure 13.14), drum separators may extremely clean concentrate is not required.
390 Wills’ Mineral Processing Technology

Drum separators are widely used to treat low-grade iron


ores, which contain 4050% Fe, mainly as magnetite, but
in some areas with hematite, finely disseminated in bands in
hard siliceous rocks. Very fine grinding is necessary to free
the iron minerals that produce a concentrate requiring pellet-
izing before being fed to steelmaking blast furnaces.
At the Iron Ore Company of Canada’s Carol Project,
low-intensity magnetic separation is used as an initial
cobbing step on the cyclone overflow of the ball mill dis-
charge to remove magnetite. This magnetite concentrate
is then combined with the tailings of spiral gravity con-
centrators to be fed to a rougher wet drum low-intensity
separator where magnetite is removed and sent directly to
the pellet plant, with the tailings from the drum being
sent for further gravity processing to concentrate any
remaining hematite (Damjanović and Goode, 2000). FIGURE 13.17 Cross-belt separator.
The mechanism by which ferromagnetic particles are
captured by low-intensity drum separators has been inves-
tigated for both high solids content (1017% solids by
weight) and low solids content (2%) (Rayner and Napier-
Munn, 2000). For the high feed solids case, magnetic
recovery occurs primarily via the formation of magnetic
flocs, which are then captured. At lower feed solids, mag-
netic capture is not contingent on floc formation, as the
increased distances between particles make it more diffi-
cult for flocs to form. These findings are significant as
they provide information on the dominant variable affect-
ing ferromagnetic losses to the tailings. At high feed
solids content, particles with low magnetic susceptibility
are lost to the tailings (higher magnetic susceptibility pro-
motes floc formation), while at low feed solids content
tailings losses are primarily fine ferromagnetic particles FIGURE 13.18 Schematic of rare earth roll separator (Adapted from
(Rayner and Napier-Munn, 2000). Dobbins et al. (2009)).
At Palabora, the tailings from copper flotation (see
Section 12.17.1) are deslimed, after which the 1105 μm
material is treated by wet low-intensity drum separators Rare earth roll separators use alternate magnetic and
to recover 95% of the magnetite at a grade of 62% Fe. nonmagnetic laminations (like those illustrated in
Another example of wet low-intensity magnetic sepa- Figure 13.6). Feed is carried onto the magnetic roll by a
ration is the treatment of flotation tailings at the Niobec belt as shown in Figure 13.18 to limit bouncing or scatter-
mine in Quebec, Canada (Section 12.17.7). The Niobec ing of particles and to ensure they all enter the magnetic
mine employs multiple flotation stages to produce a pyro- zone with the same horizontal velocity. In a rare earth roll
chlore concentrate including carbonate, pyrochlore, and separator, the variables affecting separation are the mag-
sulfide flotation circuits. The deslimed tails from the car- netic field strength, the feed rate, the linear speed of the
bonate flotation bank are fed to low-intensity drum mag- roll surface, and the particle size of the material (Eriez,
netic separators to remove approximately 1 t h21 of 2003). Most importantly, the centrifugal force applied to
magnetite assaying 68.30% Fe, 0.08% Nb2O5, 0.80% the mineral particles by the roll surface must be optimized
SiO2, and 0.16% P2O5. The nonmagnetic product (con- to achieve a sharp separation (Eriez, 2003). To control the
taining the bulk of the Nb) is then sent to the pyrochlore centrifugal force, roll speed can be adjusted over a wide
flotation circuit for upgrading (Biss and Ayotte, 1989). range, allowing the product quality to be “dialed in.”
The cross-belt separator (Figure 13.17) and disc Dry rare earth drum separators provide a “fan” of sepa-
separators, once widely used in the mineral sands indus- rated particles, which can often be seen as distinct streams
try, are now considered obsolete. They are being replaced (Figure 13.18). The fan can be separated into various grades
with rare earth roll magnetic separators and rare earth of magnetic product and a nonmagnetic tailing. In some
drum magnetic separators (Arvidson, 2001). mineral sands applications, drum separators have been
Magnetic and Electrical Separation Chapter | 13 391

integrated with one or more rare earth rolls, arranged to treat pole (to create a higher effective magnetic field strength)
the middlings particles from the drum. In any dry magnetic to take off successively more weakly magnetic products.
separator, the careful control of feed moisture is critical to The primary variables affecting separation using an
avoid smaller particles sticking to larger particles IRM separator are the magnetic susceptibility of the min-
(Oberteuffer, 1974). While increasing particle size increases eral particles, the applied magnetic field intensity, the size
the acceptable moisture limits, even at a particle size of of the particles, and the speed of the roll (Singh et al.,
90% passing 20 mm, the recommended moisture limit for 2013).The setting of the splitter plates cutting into the tra-
Metso’s dry drum separators is only 3% (Metso, 2014b). jectory of the discharged material is also of importance.
In most cases, IRM separators have been replaced by
the more recently developed (circa 1980) rare earth drum
13.5.2 High-Intensity Magnetic Separators and roll separators, which are capable of field intensities
Weakly paramagnetic minerals can only be effectively of up to 0.7 and 2.1 T, respectively (Norrgran and Marin,
recovered using high-intensity (B-fields of 2 T or greater) 1994). The advantages of rare earth roll separators over
magnetic separators (Svoboda, 1994). Until the 1960s, IRM separators include: lower operating costs due to
high-intensity separation was confined solely to dry ore, decreased energy requirements, less weight leading to
having been used commercially since about 1908. This is lower construction and installation costs, higher through-
no longer the case, as many new technologies have been put, fewer required stages, and increased flexibility in roll
developed to treat slurried feeds. configuration which allows for improved separation at
Induced roll magnetic (IRM) separators (Figure 13.19) various size ranges (Dobbins and Sherrell, 2010).
are widely used to treat beach sands, wolframite and tin Dry high-intensity separation is largely restricted to
ores, glass sands, and phosphate rock. They have also been ores containing little, if any, material finer than about
used to treat weakly magnetic iron ores, principally in 75 μm. The effectiveness of separation on such fine mate-
Europe. The roll, onto which the ore is fed, is composed of rial is severely reduced by the effects of air currents, par-
phosphated steel laminates compressed together on a non- ticleparticle adhesion, and particlerotor adhesion.
magnetic stainless steel shaft. By using two sizes of lami- Without doubt, the greatest advance in the field of
nations, differing slightly in outer diameter, the roll is magnetic separation was the development of continuous
given a serrated profile, which promotes the high field WHIMSs (Lawver and Hopstock, 1974). These devices
intensity and gradient required. Field strengths of up to have reduced the minimum particle size for efficient mag-
2.2 T are attainable in the gap between feed pole and roll. netic separation compared to dry high-intensity methods.
Nonmagnetic particles are thrown off the roll into the tail- In some flowsheets, expensive drying operations, neces-
ings compartment, whereas magnetics are held, carried out sary prior to a dry separation, can be eliminated by using
of the influence of the field and deposited into the mag- an entirely wet concentration system.
netics compartment. The gap between the feed pole and Perhaps the most well-known WHIMS machine is the
rotor is adjustable and is usually decreased from pole to Jones separator, the design principle of which is utilized
in many other types of wet separators found today. The
machine has a strong main frame (Figure 13.20(a)) made
of structural steel. The magnet yokes are welded to this
frame, with the electromagnetic coils enclosed in air-
cooled cases. The separation takes place in the plate
boxes, which are on the periphery of the one or two rotors
attached to the central roller shaft and carried into and out
of the magnetic field in a carousel (Figure 13.20(b)). The
feed, which is thoroughly mixed slurry, flows through the
plate boxes via fitted pipes and launders into the plate
boxes (Figure 13.21), which are grooved to concentrate
the magnetic field at the tip of the ridges. Feeding is con-
tinuous due to the rotation of the plate boxes on the rotors
and the feed points are at the leading edges of the mag-
netic fields (Figure 13.20(b)). Each rotor has two feed
points diametrically opposed to one another.
The weakly magnetic particles are held by the plates,
whereas the remaining nonmagnetic particle slurry passes
through the plate boxes and is collected in a launder.
FIGURE 13.19 Schematic of an induced roll separator. Before leaving the field any entrained nonmagnetics are
392 Wills’ Mineral Processing Technology

FIGURE 13.20 The Jones high-intensity wet magnetic separator in cross section: (a) plan view, and (b) top view.

type of matrix material (Eriez, 2008). The selection of


matrix type has a direct impact on the magnetic field gra-
dient present in the separation chamber. As explained in
Section 13.4.2, increasing magnetic field can in some
applications actually cause decreased performance of the
magnetic separation step and it is for this reason that
FIGURE 13.21 Jones plate box showing grooved plates and spacer improvements in the separation of paramagnetic materials
bars. focus largely on achieving a high magnetic field gradient.
The Eriez model SSS-I WHIMS employs the basic princi-
ples of WHIMS with improvements in the matrix material
washed out by low-pressure water and are collected as a (to generate a high field gradient) as well as the slurry
middlings product. feeding and washing steps (to improve separation effi-
When the plate boxes reach a point midway between ciency) (Eriez and Gzrinm, 2014). While this separator is
the two magnetic poles, where the magnetic field is referred to as a WHIMS, it is in fact more similar to the
essentially zero, the magnetic particles are washed out SLon VPHGMS mentioned in Sections 13.4.1 and 13.5.3.
using high-pressure scour water sprays operating at up Further discussion on high-gradient magnetic separation
to 5 bar. Field intensities of over 2 T can be produced in (HGMS) may be found in Section 13.5.3.
these machines, although the applied magnetic field Wet high-intensity magnetic separation has its greatest
strength should be carefully selected depending on the use in the concentration of low-grade iron ores containing
application (see Section 13.4.2). The production of a hematite, where they are an alternative to flotation or grav-
1.5 T field requires electric power consumption in the ity methods. The decision to select magnetic separation for
coils of 16 kW per pole. the concentration of hematite from iron ore must balance
There are currently two types of WHIMS machines, the relative ease with which hematite may be concentrated
one that uses electromagnetic coils to generate the required in such a separator against the high capital cost of such
field strength, the other that employs rare earth permanent separators. It has been shown by White (1978) that the
magnets. They are used in different applications; the weak- capital cost of flotation equipment for concentrating
er magnetic field strength produced by rare earth perma- weakly magnetic ore is about 20% that of a Jones separator
nent magnets may be insufficient to concentrate some installation, although flotation operating costs are about
weakly paramagnetic minerals. The variables to consider three times higher (and may be even higher if water treat-
before installing a traditional horizontal carousel WHIMS ment is required). Total cost depends on terms for capital
include: the feed characteristics (slurry density, feed rate, depreciation; over 10 years or longer the high-intensity
particle size, magnetic susceptibility of the target magnetic magnetic separator may be more attractive than flotation.
mineral), the product requirements (volume of solids to be In addition to recovery of hematite (and other iron oxi-
removed, required grade of products), and the cost of des such as goethite), wet high-intensity separators are
power (Eriez, 2008). From these considerations the design now in operation for a wide range of duties, including
and operation of the separator can be tailored by changing removal of magnetic impurities from cassiterite concen-
the following: the magnetic field intensity and/or configu- trates, removal of fine magnetic material from asbestos,
ration, the speed of the carousel, the setting of the mid- removal of iron oxides and ferrosilicate minerals from
dling splitter, the pressure/volume of wash water, and the industrial minerals such as quartz and clay, concentration
Magnetic and Electrical Separation Chapter | 13 393

FIGURE 13.22 Flowsheet from CliffsWabush iron ore mine (Adapted from Damjanović and Goode (2000)).

of ilmenite, wolframite, and chromite, removal of mag- via WHIMS can reduce the consumption of oxidizing
netic impurities from scheelite concentrates, purification agents by removing a large portion of this iron prior to
of talc, the recovery of non-sulfide molybdenum-bearing leaching (Corrans and Svoboda, 1985).
minerals from flotation tailings, and the removal of Fe- At the CliffsWabush iron ore mine in Labrador,
oxides and FeTi-oxides from zircon and rutile in heavy Canada (Figure 13.22), the cyclone overflow from the
mineral beach sands (Corrans and Svoboda, 1985; Eriez, tailings of a rougher spiral bank is sent to a magnetic
2008). In the PGM-bearing Merensky Reef (South scavenger circuit utilizing both low-intensity drum separa-
Africa), WHIMS has been used to remove much of the tion and WHIMS. This circuit employs the low-intensity
strongly paramagnetic orthopyroxene gangue from the (0.07 T) drum separators to remove fine magnetite parti-
PGM-containing chromite (Corrans and Svoboda, 1985). cles lost during the spiral gravity concentration step, fol-
WHIMS has also been successfully used for the recovery lowed by a WHIMS step using 100 t h21 Jones separators
of gold and uranium from cyanidation residues in South which are operated at field strengths of 1 T to concentrate
Africa (Corrans, 1984). Magnetic separation can be used fine hematite. Cleaning of only the gravity tailings by
to recover some of the free gold, and much of the silicate- magnetic separation is preferred, as relatively small
locked gold, due to the presence of iron impurities and amounts of magnetic concentrate have to be handled, the
coatings. In the case of uranium leaching, small amounts bulk of the material being essentially unaffected by the
of iron (from milling) may act as reducing agents and magnetic field. The concentrate produced from this mag-
negatively affect the oxidation of U41 to U61; treatment netic scavenging step is eventually recombined with the
394 Wills’ Mineral Processing Technology

spiral concentrate before feeding to the pelletizing plant more importantly, each pole produces, in its immediate
(Damjanović and Goode, 2000). vicinity, high field gradients of up to 14 T/mm. Thus, a
The paramagnetic properties of some sulfide minerals, multitude of high gradients across numerous small gaps,
such as chalcopyrite and marmatite (high Fe form of centered on each of the secondary poles, is achieved.
sphalerite), have been exploited by applying wet high- The solenoid can be clad externally with an iron frame
intensity magnetic separation to augment differential flo- to form a continuous return path for the magnetic flux,
tation processes (Tawil and Morales, 1985). Testwork thus reducing the energy consumption for driving the coil
showed that a Chilean copper concentrate could be by a factor of about 2. The matrix is held in a canister
upgraded from 23.8% to 30.2% Cu, at 87% recovery. into which the slurry is fed. Both continuous and batch-
type HGMS are available, with batch-type HGMS requir-
ing periodic demagnetization in order to remove accumu-
13.5.3 High-Gradient Magnetic Separators
lated magnetic particles, while the continuous HGMS
As noted in Eq. (13.7), in order to separate paramagnetic (Figure 13.23) operates in a carousel-type configuration
minerals of low magnetic susceptibility and/or fine size, similar to the Jones WHIMS (Metso, 2014c,d).
high field gradients are required. These are generated by An inherent disadvantage of high-gradient separators
exploiting the ferromagnetic properties of iron to generate a is that in producing an increase in field gradient, the
high B-field (induced field) many hundreds of times greater working gap between secondary poles is reduced, so that
than the applied H-field. This, however, requires that the the magnetic force has a short reach of no more than
iron be in the volume where separation takes place. The about 1 mm. It is therefore necessary to use gaps of only
steel plates in a Jones separator, for example, occupy up to about 2 mm between poles, such that the matrix separa-
60% of the process volume. Thus, high-intensity magnetic tors are best suited to the treatment of very fine particles.
separators using conventional iron circuits tend to be very They are used mainly in the kaolin industry for removing
massive and heavy in relation to their capacity. A large sep- iron-containing particles which lower brightness.
arator may contain over 200 t of iron to carry the flux, hence In order to address some of the deficiencies in the
capital and installation costs are high. design of HGMS, new horizontally fed vertical carousel
Instead of using one large convergent field in the gap separators have been designed that incorporate a pulsating
of a magnetic circuit, as in the Jones separator, in HGMS a feed system to ensure particle dispersion (i.e., avoid floc-
solenoid is used to generate a uniform field with a solenoid culation) and prevent nonmagnetic entrainment. The
core, or working volume, filled with a matrix of secondary SLon VPHGMS (Figures 13.24 and 13.25) employs a
ferromagnetic poles, such as ball bearings, or wire wool, unique matrix of steel rods oriented perpendicular to the
the latter filling only about 10% of the working volume. applied magnetic field (Section 13.4.1) as well as flushing
Each secondary pole, due to its high permeability, can pro- of trapped magnetic particles (Figure 13.26) in the reverse
duce maximum field strengths of 2 T at their surface, but direction to the feed in order to reduce particle

Feed Rinse water

Matrix

Magnetics
Ring

Flush station

Magnetic coil

Magnet head

Flush water

Nonmagnetics

FIGURE 13.23 Metso HGMS operating principle (Courtesy Metso).


Magnetic and Electrical Separation Chapter | 13 395

FIGURE 13.24 SLon VPHGMS (Courtesy Outotec).

Flush water Vertical ring confusingly referred to as WHIMS, while using a rod
matrix to produce high magnetic field gradients in a man-
Feed ner similar to HGMS (Eriez and Gzrinm, 2014). The Eriez
separator has been successfully applied to the following:
Magnetics the concentration of Fe-bearing minerals (hematite, limo-
nite, siderite, chromite), the cleaning of nonferrous ores
Slurry bath (quartz, cassiterite, garnet), the recovery of rare earth
level
minerals, and the purification of nonmetallic ores (quartz,
feldspar, kaolin, alusite, kyanite) (Eriez and Gzrinm, 2014).
Active separation zone
13.5.4 Superconducting Separators
FIGURE 13.25 Plan view of separation zone in SLon VPHGMS
(Courtesy Outotec). Future developments and applications of magnetic separa-
tion in the mineral industry lie in the creation and use of
increasingly higher product of field and field gradient,
momentum, maximize particle trapping, and improve sep- that is, the “force factor.” Matrix separators with very
aration (Outotec, 2013). The rod diameter in the matrix high field gradients and multiple small working gaps can
may be tailored for the given application to vary the max- draw little benefit from field strengths above the satura-
imum particle size that can pass through the separator tion levels of the secondary poles (B2 T for an iron/steel
from 0.6 up to 3.0 mm (Outotec, 2013). The averaged matrix material). As discussed in Section 13.4.1, the alter-
magnetic field intensity across the entire VPHGMS is no native to HGMS is OGMS, where separators with large
greater than 1.3 T; however, as the steel rod matrix working volumes deflect coarser particles at high capac-
becomes saturated, intensities up to 1.8 T can be achieved ity, rather than capture particles, as in HGMS. As the gra-
at the matrix surface with an applied magnetic field of dient in OGMS is relatively low, these separators need to
only 1 T (Outotec, 2013). The SLon separator has been use the highest possible field strengths to generate the
applied in the concentration of fine particles such as high magnetic forces required to treat weakly paramag-
hematite and ilmenite, and for desulfurization and dephos- netic particles. Field strengths in excess of 2 T can only
porization of iron ore feeds prior to steelmaking (Xiong, be generated economically by the use of superconducting
1994, 2004). Eriez also offers a vertical carousel-type magnets (Kopp, 1991; Watson, 1994).
WHIMS with similar innovations to the SLon VPHGMS, Certain alloys have the property of presenting no resis-
such as pulsating feed and high capacity due to improved tance to electric currents at extremely low temperatures.
matrix washing (Eriez and Gzrinm, 2014). The recently An example is niobiumtitanium at 4.2 K, the tempera-
developed version of the Eriez separator is somewhat ture of liquid helium. Once a current is established
396 Wills’ Mineral Processing Technology

FIGURE 13.26 Buildup on the matrix in the SLon separator (Courtesy Outotec).

through a coil made from a superconducting material, it colored) contaminants from kaolinite clay for operations
will continue to flow without being connected to a power in the United States. This machine used only about
source, and the coil will become, in effect, a permanent 0.007 kW in producing 5 T of flux, the ancillary equip-
magnet. Superconducting magnets can produce extremely ment needed requiring another 20 kW. In comparison, a
intense and uniform magnetic fields, of up to 15 T. The conventional 2 T high-gradient separator of similar
main problem, of course, is in maintaining the extremely throughput would need about 250 kW to produce the flux,
low temperatures. In 1986, a Ba/La/Cu oxide composite and at least another 30 kW to cool the magnet windings.
was made superconductive at 35 K, promoting a race to The 5 T machine is an assembly of concentric compo-
prepare ceramic oxides with much higher superconducting nents (Figure 13.27). A removable processing canister is
temperatures (Malati, 1990). Unfortunately, these materials installed in a processing chamber located at the center of the
are of a highly complex crystal structure, making them dif- assembly. This is surrounded by a double-walled, vacuum-
ficult to fabricate into wires. They also have a low current- insulated container that accommodates the superconductive
carrying capacity, so it is likely that for the foreseeable niobium/titaniumtantalum winding and the liquid helium
future superconducting magnets will be made from ductile coolant. A thermal shield, cooled with liquid nitrogen to
niobium alloys, embedded in a copper matrix. 77 K, limits radiation into the cryostat. In operation, the sup-
The main advantage of superconducting separators is ply of slurry is periodically cut off, the magnetic field is
that elevated magnetic field strength increases the maxi- shut down, and the canister backwashed with water to clear
mum feed slurry velocity with a corresponding increase in out accumulated magnetic contaminants.
capacity (Kopp, 1991). In order to fully utilize this capac- A picture of a superconducting magnetic separator in
ity, downtime for removal of accumulated magnetic parti- a horizontal arrangement installed in a plant is shown in
cles from the working volume of the separator must be Figure 13.28.
minimized through the use of a reciprocating or continu- An open-gradient drum magnetic separator with a
ously cycling matrix (Kopp, 1991). Another advantage of superconducting magnet system has been operating com-
these separators is the reduced weight of the separators mercially since the 1980s (Unkelbach and Kellerwessel,
(smaller coils and windings along with much less iron 1985; Wasmuth and Unkelbach, 1991). Although separa-
required compared to the heavy frames and matrix materi- tion is identical to that in conventional drum separators,
als used in HGMS) (Gillet and Diot, 1999). The factors the magnetic flux density at the drum surface can reach
limiting the adoption of superconducting separators are over 4 T.
the difficulties in maintaining the very low temperatures The development of HGMS and superconducting
necessary for the material to retain its superconducting separators capable of concentrating very fine or very
properties against heat leaks, and the high energy costs weakly magnetic mineral particles has prompted the
associated with maintaining this refrigeration (Kopp, application of magnetic separation techniques to treat
1991). Superconducting magnets are generally only viable many waste streams from mineral processing operations.
when large field volumes and magnetic fields greater than Fine (,10 μm), weakly magnetic hematite and limonite
2 T are required (Kopp, 1991). have been recovered by a combination of selective floccu-
In 1986, a superconducting HGMS was designed and lation using sodium oleate and kerosene followed by
built by Eriez Magnetics to remove magnetic (and HGMS (Song et al., 2002). HGMS has been used to
Magnetic and Electrical Separation Chapter | 13 397

Liquid
DC Bipolar
helium 3 Φ AC input
power supply

Vent
Liquid

Fill
nitrogen

Vent
Canister

Fill Vacuum space

Iron enclosure

Supercon ducting coil


and liquid helium

Liquid nitrogen Matrix

Feed

FIGURE 13.27 Diagram of a superconducting magnetic separator.

ions. Multiple authors have developed processes where


the metal ions to be removed are coprecipitated with Fe
ions to form a fine, dispersed magnetite phase which can
be easily extracted through the use of HGMS (Gillet
et al., 1999; Karapinar, 2003).

13.6 ELECTRICAL SEPARATION


Electrical separation exploits the differences in electrical
conductivity between different minerals in a feed. Since
almost all minerals show some difference in conductivity,
it would appear to represent the universal concentrating
method. In practice, however, the method has fairly lim-
ited applications due to the required processing conditions
(notably a perfectly dry feed), and its greatest use is in sep-
FIGURE 13.28 Superconducting magnetic separator (Courtesy
arating some of the minerals found in heavy mineral sands
Imerys). from beach or stream placer deposits (Dance and
Morrison, 1992). Electrical separation also suffers from a
similar disadvantage to dry magnetic separation—the
recover fine gold-bearing leach residues from uranium capacity is very small for finely divided material. For most
processing, and fine Pb minerals containing V and Zn efficient operation, the feed to most electrical separators
from a mining waste dump (Watson and Beharrell, 2006). should be in a layer, one particle deep, which reduces the
A single-stage extraction of ilmenite from highly mag- throughput if the particle size is small (,75 μm).
netic gangue minerals has been developed using a super- There are two distinct forces which may be considered
conducting HGMS system (the difference in magnetic in the context of electrical separation. The electrophoretic
susceptibility between ilmenite and gangue is only signifi- force is the force experienced by a charged particle under
cant at very high magnetic field strength). However, this the influence of an electric field, and the dielectrophoretic
process is still faced with the typical challenges associated force is the force experienced by a neutral particle in a
with an industrial installation of a superconducting sepa- fluid when subjected to a nonuniform electric field. The
rator (Watson and Beharrell, 2006). Another interesting, dielectrophoretic force is somewhat analogous to mag-
and potentially significant, application of HGMS is in the netic force as it relies on the polarization of a neutral par-
treatment of wastewater streams containing heavy metal ticle into an electric dipole as well as a nonuniform
398 Wills’ Mineral Processing Technology

applied field (Lockhart, 1984). The deliberate use of die- dense high-voltage discharge. The fine wire tends to dis-
lectrophoresis is almost nonexistent in mineral processing charge readily, whereas the large electrode tends to have
however, as the electrophoretic force is much stronger a short range, dense, nondischarging field. This combina-
(Lockhart, 1984). tion creates a strong discharge pattern that may be
In order to exploit the electrophoretic force for min- “beamed” in a definite direction and concentrated to a
eral separation, a treatment step prior to separation is very narrow arc. The voltage supplied should be such that
required in all electrical separators to selectively charge ionization of the air takes place. Arcing between the elec-
the mineral particles. This selective development of trode and the roll must be avoided, as this destroys the
charges on particles relies on conductivity differences ionization.
between the minerals. As most electrical conduction When ionization occurs, the mineral particles receive
occurs in the surface layers of atoms (Dance and a spray discharge of ions which gives all particles in the
Morrison, 1992), electrical separation may be thought of corona field a surface charge. As the HTR drum rotates
as a surface-based separation, similar to flotation, as and particles are moved outside of the corona field,
opposed to magnetic and gravity separation which rely on weakly conductive particles maintain a high surface
differences in bulk properties (magnetic susceptibility, charge, causing them to be attracted to and pinned to the
specific gravity). rotor surface. This is often referred to as pinning by the
There are three main mechanisms by which minerals image force (Figure 13.30), and it may be explained by
are charged: ion bombardment (corona charging), conduc- the charged mineral particle inducing a charge of opposite
tive induction, and frictional charging (tribocharging or sign on the rotor (Dance and Morrison, 1992). Pinned par-
contact electrification). Each of these three mechanisms ticles are removed from the rotor surface either through
has a corresponding separator type, the details of which the eventual decay of their surface charge or mechanically
are described in the following sections. To understand by means of a brush.
electrical separation methods, knowledge of the electrical Particles of relatively high conductivity lose their sur-
properties of materials is required. Introduction to the rel- face charge as the charge rapidly dissipates to the earthed
evant concepts, as they apply to mineral processing, along rotor. The centrifugal force of the rotor, along with
with detailed descriptions of many industrial separators,
may be found in the comprehensive reviews by Kelly and
Spottiswood (1989ac) and Manouchehri et al. (2000). Feed Electrode assembly

13.6.1 Ion Bombardment


Charging via ion bombardment occurs as a high voltage Earthed roll
is applied between two electrodes so that the gas near the
electrodes ionizes and forms a corona discharge, a contin-
uous flow of gaseous ions. Mineral particles passing Brush
through this corona are bombarded with the flow of ions
and develop a charge. A similar mechanism of charge
application is employed in electrostatic precipitators used Nonconductors Conductors
to remove fine particulate matter from flowing gas
streams. In mineral separation applications, different con- FIGURE 13.29 Diagram of HTR separator.
ductivities of the charged mineral particles then result in
different rates of charge decay and correspondingly differ-
ent forces experienced by the particles.
The typical separator relying on corona charging is the
high-tension roll (HTR) separator (Figure 13.29). In this
separator the feed, a mixture of ore minerals of varying
susceptibilities to surface charging, is fed to a rotating
drum made from mild steel, or some other conducting
material, which is grounded through its support bearings.
An electrode assembly, comprising a brass tube in front
of which is supported a length of fine wire, spans the
complete length of the roll and is supplied with a fully
rectified DC supply of up to 50 kV, usually of negative FIGURE 13.30 Representation of pinning force experienced by non-
polarity. Together these two electrodes act to create a conducting particle in a HTR separator (Courtesy OreKinetics).
Magnetic and Electrical Separation Chapter | 13 399

(lifted from the rotor surface) and nonconductive particles


TABLE 13.2 Typical Conductivity and Behavior of (pinned to the rotor surface).
Minerals in a High-Tension Separator High-tension separators operate on feeds containing
particle sizes of 60500 μm. Particle size influences sep-
Nonconductive Minerals Conductive Minerals
aration behavior, as surface charges on a coarse particle
(Pinned) (Thrown)
are lower in relation to its mass than on a fine particle.
Apatite Cassiterite Thus, a coarse particle is more readily thrown from the
Barite Chromite roll surface, and the conducting fraction (particles thrown
Calcite Diamond
from the rotor) often contains a small proportion of coarse
nonconductors. Similarly, the finer the particles the more
Coal Feldspar
they are influenced by the surface charge, and the non-
Corundum Galena conducting fraction often contains some fine conducting
Garnet Gold particles. This cross-contamination may also be inter-
preted in terms of the interplay between the centrifugal
Gypsum Hematite
force on a particle and the image force acting to pin a
Kyanite Ilmenite charged particle to a grounded surface. The centrifugal
Monazite Limonite force varies with particle mass, while the image force var-
Quartz Magnetite
ies with surface area (as charge is accumulated on the par-
ticle surface) so, consequently, the centrifugal force is
Scheelite Pyrite dominant at coarse particle sizes (Dance and Morrison,
Sillimonite Rutile 1992; Svoboda, 1993).
Spinel Sphalerite Some machine factors affecting the operation of an
HTR separator include: geometry of the electrode assem-
Tourmaline Stibnite
bly, electrode voltage and polarity, rotor speed, rotor
Zircon Tantalite diameter, and splitter position (Dance and Morrison,
Wolframite 1992). Larger rotor diameters help to increase recovery,
while a smaller rotor diameter improves the grade of the
conducting fraction (Svoboda, 1993). A similar depen-
dence exists for particle density, rotor speed, and the coef-
ficient of friction between the particle and rotor surface,
gravitational and frictional forces, is then able to throw so that separation selectivity is maximized at low particle
these particles from the roll and away from the relatively density, small rotor diameter, high rotor speed, and high
low-conductivity particles that remain pinned so that two coefficient of friction (Svoboda, 1993). The effect of rotor
streams of particles develop which may be collected sepa- speed on separation is complex and dependent on the con-
rately through the use of a splitter. The separation can be ductivity of a given particle, as the act of increasing rotor
optimized by varying the splitter position. However, pre- speed decreases the time available for charge decay. In
dicting particle trajectories from an HTR separator is this way, increased rotor speed increases the chance that a
challenging, as Edward et al. (1995) have shown that par- conductive mineral particle will report to the nonconduc-
ticles do not instantaneously accelerate to the roll speed, tor fraction, while high rotor speeds will also increase the
due to slip on the rotor surface. centrifugal force on a nonconductive particle so that it is
The primary industrial use of HTR separators is in the more likely to incorrectly report to the conductive fraction
processing of heavy mineral sands (Dance and Morrison, (Svoboda, 1993). Stated another way, increased rotor
1992). Other uses include coal cleaning (Butcher and speed simultaneously increases the minimum particle size
Rowson, 1995), and recycling metals from plastic waste necessary for a conductive particle to be thrown from the
(Dascalescu et al., 1993). Table 13.2 shows typical miner- rotor while decreasing the maximum nonconductive parti-
als which are either pinned to or thrown from the rotor cle size that will be pinned to the rotor (Svoboda, 1993).
during HTR separation. While HTR separation primarily exploits the differ-
A combination of pinning and lifting can be created ences in conductivities between minerals, an equally
by using a third “static” electrode following the corona important criteria for successful operation is the presence
discharge electrodes with a diameter large enough to pre- of at least one strongly conductive (on an absolute basis)
clude corona discharge. The conducting particles, which mineral species in the separator feed. It has been shown by
are thrown from the rotor, are attracted to this third elec- Svoboda (1993) that very large differences in mineral con-
trode, and the combined process produces a very wide ductivities (up to an order of magnitude) will not result in
and distinct separation between conductive particles a sharp separation if both minerals are weak conductors.
400 Wills’ Mineral Processing Technology

Conversely, two strongly conducting minerals can be sepa- results when an uncharged particle develops an opposite
rated with only a small difference in their conductivities. charge, relative to the electrode creating the electric field,
HTR separators have been one of the mainstays of the at the surface closest to the electrode and a corresponding
mineral sands industry for decades. Very little develop- like charge to the electrode on the particle surface furthest
ment of the machines has occurred in that period; their from the electrode. Conductive particles are able to redis-
generally poor single pass separation has been tolerated, tribute these induced charges across the particle surface,
and overcome by using multiple machines and multiple while nonconductive particles are unable to redistribute
recycle streams. However, in the last few years innovative these charges and will remain polarized. The electric
new designs have started to appear, from new as well as force on a polarized particle is a function of the degree to
established manufacturers. Roche Mining (MT) have which it polarizes, which is in turn affected by both the
developed the Carara HTR separator, which incorporates size and shape of the particle (Manouchehri et al., 2000).
an additional insulated plate static electrode to help When a polarized particle contacts a conductive surface it
deflect the path of conductive particles thrown from the may conduct charge of one polarity to the surface, leaving
rotor (Germain et al., 2003). Outokumpu Technology a net charge on the particle. In such a situation noncon-
developed the eForce HTR separator, which also incorpo- ductive particles (with no net charge) will experience no
rates additional static electrodes, as well as an electro- attraction from an applied electric field, whereas
static feed classifier (Elder and Yan, 2003).
OreKinetics has introduced the new CoronaStat
Feed
machine (Figure 13.31), which is a significant improve-
ment on existing HTR designs as it employs additional
static electrodes to improve the efficiency of separation.
Corona
Unlike existing machines, the static electrodes are not electrode
exposed, making the machines much safer to operate. The Pr
im
key improvement in the CoronaStat design relative to tra- ar
yi
ditional HTR separators is the presence of induction elec- nd
uc
tio
trodes, which simultaneously increase the pinning force ne
lec
on nonconducting particles and increase the rate of charge Brush
tro
de
decay for conductive particles (Figure 13.32). This results
in a larger distance between the two particle streams and
therefore an improved separation.
Evo lll
electrode

13.6.2 Conductive Induction


The second charging mechanism used in electrical separa-
tors is conductive induction, in which polarization of a
mineral particle occurs upon exposure to an electric field. Mids 2 Mids 1
Similar to charge decay in HTR separators, the ability of Nonconductors Conductors
the mineral particle to respond to this induced polariza-
FIGURE 13.31 Diagram of CoronaStat separator (Courtesy OreKinetics).
tion is directly related to its conductivity. Polarization

FIGURE 13.32 Effect of induction electrode in CoronaStat separator (Courtesy OreKinetics).


Magnetic and Electrical Separation Chapter | 13 401

conductive particles will be attracted to an oppositely separators, system humidity is intentionally kept low, as
charged electrode (Kelly and Spottiswood, 1989a). excess moisture may alter the conductivity of the fluid
Conductive induction can therefore be thought of as a medium of the separator (the air) as well as affecting the
process in which charges are induced on uncharged con- conductivity of the particle surface through the dual effects
ductive particles, leaving nonconductive particles with no of water molecules themselves and dissolved ions in the
net charge. A graphical representation of conductive water (Kelly and Spottiswood, 1989b).
induction may be seen in Figure 13.33. Similar to the CoronaStat for HTR separation,
Separators exploiting this charging mechanism are OreKinetics has also developed an improved ESP separator
typically used to separate strongly conductive particles known as the UltraStat separator (Figure 13.35). The pri-
from weakly conductive particles and employ static elec- mary improvements in this separator are different geome-
trodes to “lift” charged conductive particles from a tries of the electrode and particle feed path, the presence of
grounded surface while nonconductive particles remain secondary induction electrodes to further increase the lifting
pinned to that surface. The most common such separator force on charged conductive particles as well as a secondary
is the electrostatic plate (ESP) separator. In an ESP sepa- roll to clean the primary roll surface.
rator, material is gravity fed through the separator and the
force on the charged particles acts to counteract the force
of gravity. In contrast to HTR separators, coarse particles 13.6.3 Triboelectric Charging
will tend to report to the nonconducting fraction, which is
The final charging mechanism used in mineral processing
why final cleaning of the products of HTR separation is
is triboelectrification, or contact electrification, in which
often carried out in purely electrostatic separators.
two materials of dissimilar electrical properties exchange
Modern electrostatic separators are of the plate or
electrons upon coming into contact with one another. As
screen type (Figure 13.34), the former being used to clean
most minerals are semi-conductors, with volume conduc-
small amounts of nonconductors from a predominantly con-
tivities between 105 and 1028 Ω m21 (Manouchehri et al.,
ducting feed (Figure 13.34(a)), while the screen separators
2000), the charge acquired by two minerals after contact-
remove small amounts of conductors from a mainly non-
ing one another may be predicted by the relative Fermi
conducting feed (Figure 13.34(b)). The principle of opera-
levels (energy level at which 50% of the energy states in
tion is the same for both types of separator. The feed
a material are occupied by electrons) of the two minerals
particles gravitate down a sloping, grounded plate into an
(Kelly and Spottiswood, 1989c). An alternative measure
electrostatic field induced by a large, oval-shaped, high-
also used to predict triboelectric charging behavior is the
voltage electrode. Fine particles are most affected by the
lifting force, and so fine conductive particles are preferen-
Feed plate
tially lifted to the electrode, whereas coarse nonconductors Feed
+
are most efficiently rejected. Machine parameters affecting – Electrode
ESP separators include: electrode geometry, electrode volt-
age and polarity, plate curvature, and position of the split-
ters (Dance and Morrison, 1992). For both HTR and ESP Splitter

tors
duc
Con
Conductor particle
Nonconductors
(a)
+
HV

Feed plate
M

+
ind
in

+
– Electrode
er

uc

+ Feed
al

tio

++
fa
l

+ ++ +
np
ld
ire

lat
ct

ee
io

+
n

Screen
lec

+
tro

Induced positive charge


tors
ed

+ duc
+ Con Duct work
+ +
+ + +
Roll surface Electrostatic lifting force Nonconductors
(b)
FIGURE 13.33 Representation of conductive induction (Courtesy
OreKinetics). FIGURE 13.34 (a) Plate, and (b) screen electrostatic separators.
402 Wills’ Mineral Processing Technology

Feed

n Pr
tio im
uc a
d el ry i
in e ec nd
y od tro uc
ar ctr de tio
im le
Pr e n
Secondary Secondary
induction induction
electrode electrode

Mid
Non-conductor

Conductor
Mid
Conductor

Non-conductor

Separation roll Cleaning roll

FIGURE 13.35 Diagram of UltraStat separator (Courtesy OreKinetics).

work function of a material, which is a measure of the Teflon, have large differences in work function and will
energy required to bring an electron from the Fermi level therefore produce corresponding differences in the
of a given material to a free electron state (Kelly and charges produced on a given mineral particle (Dwari
Spottiswood, 1989c). A mineral with a low Fermi level et al., 2009). Even if the charge induced on a mineral
must therefore have a higher work function than a mineral surface using different charging materials is of the same
with a higher Fermi level. When two mineral particles sign, the amount of the charge transfer between two
come into frictional contact their Fermi levels will equal- materials is dependent on the differences between the
ize, with the mineral with the highest Fermi level losing Fermi levels of the two materials.
electrons to the mineral with the lower Fermi level Charge acquisition of mineral particles in triboelectric
(Manouchehri et al., 2000). The mineral with the highest separation may also be controlled through the use of a
work function (lower Fermi level) becomes negatively surface treatment prior to tribocharging such as: surface
charged and the opposing mineral becomes positively cleaning, chemical pretreatment, thermal pretreatment,
charged. The potential applications of triboelectric separa- irradiation, changes in the atmospheric humidity, or sur-
tion are immense, as separation does not require large dif- face doping (Manouchehri, 2010). Such surface treat-
ferences in mineral conductivity and virtually every ments are used to increase the difference in work function
binary mixture of minerals will possess a difference in between two minerals to be separated. An example is the
work function. treatment of industrial minerals with H3BO3 at alkaline pH,
Once the minerals have acquired a charge, they are which has been shown to increase the charge differences
often separated using a free-fall design consisting of two of feldsparquartz and feldsparcalcite mixtures
charged electrodes which deflect mineral particles based (Manouchehri et al., 1999). Another important variable in
on their surface charge with the mineral particles col- triboelectric separation is particle size, as small particles
lected in different bins. Such separators have been used have higher work functions than coarse particles of the
on a lab scale to separate quartz from wollastonite and same mineral (Manouchehri and Fawell, 2002). While mea-
calcite, calcite from insoluble silicates (Manouchehri and suring the charge on mineral particles, and even separating
Fawell, 2002), and on an industrial scale to beneficiate a binary mixture, can be readily accomplished in a con-
potash (Lockhart, 1984). trolled laboratory setting, the wide range of variables
In all triboelectric charging devices, mineral particles affecting triboelectric separation has limited the applica-
come into contact with not just one another, but also the tions of this technology in industrial settings where separa-
material from which the conveying device is con- tors must treat a feed consisting of multiple mineral types.
structed. It is therefore important to take this into con- One of the explanations for continued research interest
sideration, as different materials, such as brass and in triboelectric separation is the minimal effect of gravity
Magnetic and Electrical Separation Chapter | 13 403

FIGURE 13.36 Diagram of ST separator (Adapted from Bittner et al. (2014)).

on the separation process, which may in the future be setting up a high particle number density, counter cur-
very beneficial in developing extraterrestrial or lunar min- rent flow within the electrode gap. Particles must travel
ing operations (Li et al., 1999). In one such study, focused across only a small fraction of the electrode gap (across
on the beneficiation of ilmenite from a synthetic lunar the zone of high shear and lower velocities) under elec-
soil, ilmenite was found to report to both positive and trostatic forces to be separated into the oppositely flow-
negative electrodes in binary mixture separations depend- ing streams (Figure 13.38). The counter current highly
ing on the gangue mineral chosen for the feed mixture turbulent flow enables multiple stages of separation to
(Li et al., 1999). When the full synthetic ore, four differ- occur within a single pass through the separator, increas-
ent gangue minerals along with the ilmenite, was pro- ing both grade and recovery of the product streams
cessed through the triboelectric separation unit ilmenite (Bittner et al., 2014). This multistage separation zone
was found to be concentrated (by a factor of 23) in the requires that the particles maintain their charge, which is
neutral particle collection bin, evidently acquiring little made possible due to the high degree of interparticle
net charge due to the presence of gangue minerals with contacts occurring throughout the separation zone
both higher and lower work functions than the ilmenite (Bittner et al., 2014). This separator can process particles
(Li et al., 1999). This finding is illustrative of the inherent from 1 to 300 μm, which is much smaller than conven-
difficulties in predicting mineral behavior through tribo- tional free-fall and HTR separators. It has been widely
electric separations in an industrial setting. employed industrially in removing unburned coal char
Recently a new triboelectric separator, the ST separa- from fly ash (1020 μm median diameter) generated by
tor, has been developed by Separation Technologies coal-fired power plants (Bittner et al., 2014). On a pilot
which employs conventional interparticle contact to tri- plant scale (36 t h21), it has also been shown to be
bocharge mineral particles and a continuous loop open- effective at beneficiating industrial minerals such as sep-
mesh belt that travels at high speeds (520 m s21) arating quartz from calcite (89% recovery, 99% grade)
between positive and negative electrodes for particle and magnesite from talc (77% recovery, 95% grade)
separation (Figure 13.36) (Bittner et al., 2014). Feed (Bittner et al., 2014).
enters from the top of the unit (at feed rates of up to
40 t h21) with positive and negative charged particles
exiting from opposite ends of the separator
13.6.4 Example Flowsheets
(Figure 13.37). The separation occurs within a narrow Earlier in this chapter the possibility of combined mag-
gap (,1.5 cm) between the electrodes. The top and bot- netic and electrical separation was noted, particularly in
tom sections of the belt move in opposite directions, the processing of heavy mineral sand deposits. Table 13.3
404 Wills’ Mineral Processing Technology

Feed ports

Separation zone

+ –

FIGURE 13.37 Industrial installation of ST separator (Adapted from Bittner et al. (2014)).

FIGURE 13.38 Separation zone of ST separator (Adapted from Bittner et al. (2014)).

TABLE 13.3 Magnetic and Electrical Behavior of Typical Heavy Mineral Sands Components
Magnetics Magnetite—C Ilmenite—C Garnet—NC Monazite—NC
Nonmagnetics Rutile—C Zircon—NC Quartz—NC

C, conductor; NC, nonconductor.

shows some of the common minerals present in such allu- up to 20% heavy mineral in some cases. The gravity pre-
vial deposits, along with their properties, related to mag- concentrate is then transferred to the separation plant for
netic and electrical separation. Mineral sands are recovery of heavy minerals by a combination of gravity,
commonly mined by floating dredges, feeding floating magnetic, and electrical (typically HTR) separation.
concentrators at up to 2,000 t h21. Such concentrators, Mineral sands flowsheets vary according to the
consisting of a complex circuit of sluices, spirals, or properties of the minerals present, wet magnetic separa-
Reichert cones, upgrade the heavy mineral content to tion often preceding high-tension separation where mag-
around 90%, the feed grades varying from less than 2%, netic ilmenite is the dominant mineral, for example.
Magnetic and Electrical Separation Chapter | 13 405

FIGURE 13.39 Typical heavy mineral sand flowsheet.

A generalized flowsheet is shown in Figure 13.39. Low- South-East Asia for the treatment of alluvial cassiterite
intensity drum separators remove any magnetite from the deposits, which are also sources of minerals such as
feed, after which high-intensity wet magnetic separators ilmenite, monazite, and zircon.
separate the monazite and ilmenite from the zircon and In the case of the CliffsWabush mine (discussed in
rutile. Drying of these two fractions is followed by HTR Section 13.5.2), the gravity concentrate from the spirals
separation to produce final products, although further bank is cleaned by a series of HTR separators
cleaning is sometimes carried out by ESP separators. (Damjanović and Goode, 2000). The spiral concentrate
For example, screen electrostatic separators (Figure 13.34 is first filtered and dried before being fed to 54 primary
(b)) may be used to clean the zircon and monazite Carpco HTR separators (with a total of 288 rotors),
concentrates, removing fine conducting particles from with the tailings from the rougher HTR separators fed
these fractions. Similarly, plate electrostatic separators to six scavenger HTR separators (total of 24 rotors).
(Figure 13.34(a)) could be used to reject coarse noncon- Each rotor is 10 ft long with a roll diameter of 14 in.
ducting particles from the rutile and ilmenite and is operated at a rotor speed of 100 rpm, electrode
concentrates. voltage of 2325 kV, and a feed rate of 2.54 t h21.
Figure 13.40 shows a simplified circuit used to process Through this separation, the nonconductive quartz
heavy minerals, on the west coast of Australia (Benson gangue is pinned to the roll, with the valuable iron
et al., 2001). oxide mineral thrown from the roll. Cleaning of the
The heavy mineral concentrate is first divided into gravity concentrate with HTR separators is preferred as
conductive and nonconductive streams using HTR separa- relatively little material is pinned to the rotor in the
tors. The conductors are treated using cross-belt and roll high-tension treatment of the gravity concentrate (Fe-
magnetic separators to remove the ilmenite as a magnetic oxides are conductive). The rougher bank of HTR
product. The nonmagnetic stream is cleaned with high- separators produces a final concentrate, a middlings
intensity roll and rare earth magnets to separate the stream that is recycled to the HTR feed and a tailings
weakly paramagnetic leucoxene from diamagnetic rutile. stream sent to the HTR scavenger circuit. The scaven-
The nonconductors undergo another stage of wet gravity ger concentrate goes to the final concentrate (65.50%
separation to remove quartz and other low-specific- Fe, 2.55% SiO2, 1.95% Mn), with the scavenger tailings
gravity contaminants, before sizing and cleaning using sent to the final tailings. The HTR concentrate is then
HTR, ESP and Ultrastat separators to produce fine and blended with the magnetic concentrate prior to being
coarse zircon products. Similar flowsheets are used in sent to pelletization.
406 Wills’ Mineral Processing Technology

FIGURE 13.40 Simplified mineral sands circuit used by Tronox Limited (formerly Tiwest Joint Venture) at the Chandala processing plant, Western
Australia (Adapted from Benson et al. (2001)).

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