Professional Documents
Culture Documents
3.0
Magnetization
(kA m–1) Paramagnetic
2.0 (Chromite)
1.0
Diamagnetic
(quartz)
–2.0
–3.0
FIGURE 13.1 Magnetization versus applied magnetic field strength for idealized paramagnetic and diamagnetic minerals.
400
Ferromagnetic
Magnetization
(magnetite)
(kA m–1)
300
3
2
200 1 Point Slope, χ
1 1.7
2 0.3
100
3 0.0
–200
–300
–400
FIGURE 13.2 Magnetization versus applied magnetic field strength for a ferromagnetic mineral.
reached its saturation magnetization (a characteristic to report to the magnetic product, ferromagnetic materials
value of the material shown in Figure 13.2 as a plateau are recovered in low-intensity magnetic separators.
in magnetization), and any further increase in applied
magnetic field will not be accompanied by a further
increase in magnetization. Measuring Magnetic Properties
Compared to paramagnetic materials, which need The magnetic properties of a material may be measured
high-intensity (high magnetic field) magnetic separators directly via a vibrating sample magnetometer (used to
Magnetic and Electrical Separation Chapter | 13 383
4.0
Magnetization Paramagnetic
(kA m–1) (Chromite)
3.0
0.4
0.2
2.0
0
–500 –300 –100 100 300 500
–0.2
1.0
–0.4 Diamagnetic
(Quartz)
–2.0
–3.0
–4.0
FIGURE 13.3 Magnetization versus applied magnetic field strength for natural samples.
The Franz is also used to characterize materials, sepa- we can combine Eqs. (13.4) and (13.5) to yield:
rating fractions that can then be identified. These data can
B 5 μμ0 H (13.6)
form the basis of predicting separation in full size mag-
netic separators. For ferromagnetic materials, the Davis For paramagnetic materials, χ is a small positive con-
tube is more suitable and is the common tool for charac- stant, and for diamagnetic materials it is a much smaller
terizing magnetic iron ores (Davis, 1921). negative constant. As examples, from Figure 13.1 the slope
representing the magnetic susceptibility of the material, χ,
is about 0.001 for chromite and 20.0001 for quartz.
13.3 EQUATIONS OF MAGNETISM The magnetic susceptibility of a ferromagnetic mate-
The magnetic flux density or magnetic induction is the rial is dependent on the magnetic field, decreasing with
number of lines of force passing through a unit area of field strength as the material becomes saturated.
material, B. The unit of magnetic induction is the tesla (T). Figure 13.2 shows a plot of M versus H for magnetite,
The magnetizing force, which induces the lines of showing that at an applied field of 80 kA m21, or 0.1 T,
force through a material, is called the field intensity, H the magnetic susceptibility is about 1.7, and saturation
(or H-field), and by convention has the units ampere per occurs at an applied magnetic field strength of about
meter (A m21) (Bennett et al., 1978). 500 kA m21 or 0.63 T. Many high-intensity magnetic
The intensity of magnetization or the magnetization separators use iron cores and frames to produce the
(M, A m21) of a material relates to the magnetization desired magnetic flux concentrations and field strengths.
induced in the material and can also be thought of as the Iron saturates magnetically at about 22.5 T, and its non-
volumetric density of induced magnetic dipoles in the linear ferromagnetic relationship between inducing field
material. The magnetic induction, B, field intensity, H, strength and magnetization intensity necessitates the use
and magnetization, M, are related by the equation: of very large currents in the energizing coils, sometimes
up to hundreds of amperes.
B 5 μ0 ðH 1 MÞ (13.1) The magnetic force felt by a mineral particle is depen-
where μ0 is the permeability of free space and has the dent not only on the value of the field intensity, but also
value of 4π 3 1027 N A22. In a vacuum, M 5 0, and M is on the field gradient (the rate at which the field intensity
extremely low in air and water, such that for mineral pro- increases across the particle toward the magnet surface).
cessing purposes Eq. (13.1) may be simplified to: As paramagnetic minerals have higher (relative) magnetic
permeabilities than the surrounding media, usually air or
B 5 μ0 H (13.2) water, they concentrate the lines of force of an external
so that the value of the field intensity, H, is directly pro- magnetic field. The higher the magnetic susceptibility, the
portional to the value of induced flux density, B (or B- higher the induced field density in the particle and the
field), and the term “magnetic field intensity” is then greater is the attraction up the field gradient toward
often loosely used for both the H-field and the B-field. increasing field strength. Diamagnetic minerals have
However, when dealing with the magnetic field inside lower magnetic susceptibility than their surrounding
materials, particularly ferromagnetic materials that con- medium and hence expel the lines of force of the external
centrate the lines of force, the value of the induced flux field. This causes their expulsion down the gradient of the
density will be much higher than the field intensity. This field in the direction of the decreasing field strength.
relationship is used in high-gradient magnetic separation The equation for the magnetic force on a particle in a
(discussed further in Section 13.4.1). For clarity it must magnetic separator depends on the magnetic susceptibility
be specified which field is being referred to. of the particle and fluid medium, the applied magnetic
Magnetic susceptibility (χ) is the ratio of the intensity field and the magnetic field gradient. This equation, when
of magnetization produced in the material over the considered in only the x-direction, may be expressed as
applied magnetic field that produces the magnetization: (Oberteuffer, 1974):
M dB
χ5 (13.3) Fx 5 Vðχp 2 χm ÞH (13.7)
H dx
Combining Eqs. (13.1) and (13.3) we get: where Fx is the magnetic force on the particle (N), V the
particle volume (m3), χp the magnetic susceptibility of the
B 5 μ0 Hð1 1 χÞ (13.4) particle, χm the magnetic susceptibility of the fluid medium,
If we then define the dimensionless relative permeabil- H the applied magnetic field strength (A m21), and dB/dx
ity, μ, as: the magnetic field gradient (T m21 5 N A21 m22). The
product of H and dB/dx is sometimes referred to as the
μ511χ (13.5) “force factor.”
Magnetic and Electrical Separation Chapter | 13 385
Production of a high field gradient as well as high particles themselves to behave as magnets, thus attracting
intensity is therefore an important aspect of separator each other. Flocculation, or agglomeration, of the parti-
design. To generate a given attractive force, there are an cles can occur if they are small and highly susceptible
infinite number of combinations of field and gradient and if the field is intense. This is important as these mag-
which will give the same effect. Another important factor netic “flocs” can entrain gangue mineral particles as well
is the particle size, as the magnetic force experienced by as bridge the gaps between magnetic poles, reducing the
a particle must compete with various other forces such as efficiency of separation.
hydrodynamic drag (in wet magnetic separations) and the Much of the optimization of high-intensity separators
force of gravity. In one example, considering only these is based on providing as many sites of high field gradient
two competing forces, Oberteuffer (1974) has shown that as possible to improve the magnetic particle carrying
the range of particle size where the magnetic force predo- capacity of the separator. Wet high-intensity magnetic
minates is from about 5 μm to 1 mm.
separators (WHIMSs) will often use a ferromagnetic 13.4.2 Magnetic Field Intensity
matrix material to achieve this, such as those shown in
Figure 13.8. The recently developed Outotec SLon Provision must be incorporated in the separator for regu-
vertically pulsating high-gradient magnetic separator lating the intensity of the magnetic field in order to deal
(VPHGMS) offers improvements in magnetic matrix with various types of material. This is easily achieved in
design via the use of steel rods. electromagnetic separators by varying the current, while
A visual comparison of the effects of different matrix with permanent magnets the interpole distance can be var-
materials on magnetic flux may be seen in Figure 13.9. ied. In the case of laboratory separators, this can also be
The design of the matrix can be further optimized by achieved by interchanging the permanent magnets for
tapering the size and spacing of the rods throughout the magnets of higher magnetic field intensity. A special class
matrix (Figure 13.10) so that coarse magnetic particles of magnetic separators, known as superconducting separa-
are trapped first near the slurry inlet, with additional tors, may be used when very high field intensities are
points of high field gradient introduced further along the required. Additional information on superconducting
direction of slurry flow to capture finer magnetic parti- separators may be found in Section 13.5.4.
cles (Novotny, 2014). Further details on WHIMS and It is important to note that increasing field intensity
VPHGMS may be found in Sections 13.5.2 and 13.5.3, does not necessarily lead to an improved separation.
respectively. Work by Svoboda (1994) with HGMS has shown that the
FIGURE 13.8 Examples of matrix materials used in high-intensity separators: (a) section through Boxmag-Rapid grid assembly showing matrix of
stainless steel bars, (b) grid of expanded ferromagnetic stainless steel used for coarse particle sizes, and (c) ferromagnetic stainless steel wool used for
fine particle sizes (Courtesy Metso).
HIMS ®
al W SLon VPH
on Nonmagnetic particle
G
iti
MS
Trad
Magnetic particle
Magnetic flux line
Magnetic pole
Magnetic pole
Magnetic pole
Pulsing Wash
water
FIGURE 13.9 Comparison of effects of magnetic matrix design on magnetic flux in traditional WHIMS and SLon VPHGMS (Courtesy Outotec).
Magnetic and Electrical Separation Chapter | 13 387
Slurry feed
Separator drum
Concentrate
launder
Feed
box
FIGURE 13.13 Alternate magnet configurations for a wet drum sepa-
rator. (a) High-capacity arrangement, and (b) high-gradient arrangement Mag n e ts
(Courtesy Metso).
Separator tank
Slurry feed
Separator drum
Separator tank Feed Discharge
box launder
M
gn
a
Tailings Magnetic concentrate ets
integrated with one or more rare earth rolls, arranged to treat pole (to create a higher effective magnetic field strength)
the middlings particles from the drum. In any dry magnetic to take off successively more weakly magnetic products.
separator, the careful control of feed moisture is critical to The primary variables affecting separation using an
avoid smaller particles sticking to larger particles IRM separator are the magnetic susceptibility of the min-
(Oberteuffer, 1974). While increasing particle size increases eral particles, the applied magnetic field intensity, the size
the acceptable moisture limits, even at a particle size of of the particles, and the speed of the roll (Singh et al.,
90% passing 20 mm, the recommended moisture limit for 2013).The setting of the splitter plates cutting into the tra-
Metso’s dry drum separators is only 3% (Metso, 2014b). jectory of the discharged material is also of importance.
In most cases, IRM separators have been replaced by
the more recently developed (circa 1980) rare earth drum
13.5.2 High-Intensity Magnetic Separators and roll separators, which are capable of field intensities
Weakly paramagnetic minerals can only be effectively of up to 0.7 and 2.1 T, respectively (Norrgran and Marin,
recovered using high-intensity (B-fields of 2 T or greater) 1994). The advantages of rare earth roll separators over
magnetic separators (Svoboda, 1994). Until the 1960s, IRM separators include: lower operating costs due to
high-intensity separation was confined solely to dry ore, decreased energy requirements, less weight leading to
having been used commercially since about 1908. This is lower construction and installation costs, higher through-
no longer the case, as many new technologies have been put, fewer required stages, and increased flexibility in roll
developed to treat slurried feeds. configuration which allows for improved separation at
Induced roll magnetic (IRM) separators (Figure 13.19) various size ranges (Dobbins and Sherrell, 2010).
are widely used to treat beach sands, wolframite and tin Dry high-intensity separation is largely restricted to
ores, glass sands, and phosphate rock. They have also been ores containing little, if any, material finer than about
used to treat weakly magnetic iron ores, principally in 75 μm. The effectiveness of separation on such fine mate-
Europe. The roll, onto which the ore is fed, is composed of rial is severely reduced by the effects of air currents, par-
phosphated steel laminates compressed together on a non- ticleparticle adhesion, and particlerotor adhesion.
magnetic stainless steel shaft. By using two sizes of lami- Without doubt, the greatest advance in the field of
nations, differing slightly in outer diameter, the roll is magnetic separation was the development of continuous
given a serrated profile, which promotes the high field WHIMSs (Lawver and Hopstock, 1974). These devices
intensity and gradient required. Field strengths of up to have reduced the minimum particle size for efficient mag-
2.2 T are attainable in the gap between feed pole and roll. netic separation compared to dry high-intensity methods.
Nonmagnetic particles are thrown off the roll into the tail- In some flowsheets, expensive drying operations, neces-
ings compartment, whereas magnetics are held, carried out sary prior to a dry separation, can be eliminated by using
of the influence of the field and deposited into the mag- an entirely wet concentration system.
netics compartment. The gap between the feed pole and Perhaps the most well-known WHIMS machine is the
rotor is adjustable and is usually decreased from pole to Jones separator, the design principle of which is utilized
in many other types of wet separators found today. The
machine has a strong main frame (Figure 13.20(a)) made
of structural steel. The magnet yokes are welded to this
frame, with the electromagnetic coils enclosed in air-
cooled cases. The separation takes place in the plate
boxes, which are on the periphery of the one or two rotors
attached to the central roller shaft and carried into and out
of the magnetic field in a carousel (Figure 13.20(b)). The
feed, which is thoroughly mixed slurry, flows through the
plate boxes via fitted pipes and launders into the plate
boxes (Figure 13.21), which are grooved to concentrate
the magnetic field at the tip of the ridges. Feeding is con-
tinuous due to the rotation of the plate boxes on the rotors
and the feed points are at the leading edges of the mag-
netic fields (Figure 13.20(b)). Each rotor has two feed
points diametrically opposed to one another.
The weakly magnetic particles are held by the plates,
whereas the remaining nonmagnetic particle slurry passes
through the plate boxes and is collected in a launder.
FIGURE 13.19 Schematic of an induced roll separator. Before leaving the field any entrained nonmagnetics are
392 Wills’ Mineral Processing Technology
FIGURE 13.20 The Jones high-intensity wet magnetic separator in cross section: (a) plan view, and (b) top view.
FIGURE 13.22 Flowsheet from CliffsWabush iron ore mine (Adapted from Damjanović and Goode (2000)).
of ilmenite, wolframite, and chromite, removal of mag- via WHIMS can reduce the consumption of oxidizing
netic impurities from scheelite concentrates, purification agents by removing a large portion of this iron prior to
of talc, the recovery of non-sulfide molybdenum-bearing leaching (Corrans and Svoboda, 1985).
minerals from flotation tailings, and the removal of Fe- At the CliffsWabush iron ore mine in Labrador,
oxides and FeTi-oxides from zircon and rutile in heavy Canada (Figure 13.22), the cyclone overflow from the
mineral beach sands (Corrans and Svoboda, 1985; Eriez, tailings of a rougher spiral bank is sent to a magnetic
2008). In the PGM-bearing Merensky Reef (South scavenger circuit utilizing both low-intensity drum separa-
Africa), WHIMS has been used to remove much of the tion and WHIMS. This circuit employs the low-intensity
strongly paramagnetic orthopyroxene gangue from the (0.07 T) drum separators to remove fine magnetite parti-
PGM-containing chromite (Corrans and Svoboda, 1985). cles lost during the spiral gravity concentration step, fol-
WHIMS has also been successfully used for the recovery lowed by a WHIMS step using 100 t h21 Jones separators
of gold and uranium from cyanidation residues in South which are operated at field strengths of 1 T to concentrate
Africa (Corrans, 1984). Magnetic separation can be used fine hematite. Cleaning of only the gravity tailings by
to recover some of the free gold, and much of the silicate- magnetic separation is preferred, as relatively small
locked gold, due to the presence of iron impurities and amounts of magnetic concentrate have to be handled, the
coatings. In the case of uranium leaching, small amounts bulk of the material being essentially unaffected by the
of iron (from milling) may act as reducing agents and magnetic field. The concentrate produced from this mag-
negatively affect the oxidation of U41 to U61; treatment netic scavenging step is eventually recombined with the
394 Wills’ Mineral Processing Technology
spiral concentrate before feeding to the pelletizing plant more importantly, each pole produces, in its immediate
(Damjanović and Goode, 2000). vicinity, high field gradients of up to 14 T/mm. Thus, a
The paramagnetic properties of some sulfide minerals, multitude of high gradients across numerous small gaps,
such as chalcopyrite and marmatite (high Fe form of centered on each of the secondary poles, is achieved.
sphalerite), have been exploited by applying wet high- The solenoid can be clad externally with an iron frame
intensity magnetic separation to augment differential flo- to form a continuous return path for the magnetic flux,
tation processes (Tawil and Morales, 1985). Testwork thus reducing the energy consumption for driving the coil
showed that a Chilean copper concentrate could be by a factor of about 2. The matrix is held in a canister
upgraded from 23.8% to 30.2% Cu, at 87% recovery. into which the slurry is fed. Both continuous and batch-
type HGMS are available, with batch-type HGMS requir-
ing periodic demagnetization in order to remove accumu-
13.5.3 High-Gradient Magnetic Separators
lated magnetic particles, while the continuous HGMS
As noted in Eq. (13.7), in order to separate paramagnetic (Figure 13.23) operates in a carousel-type configuration
minerals of low magnetic susceptibility and/or fine size, similar to the Jones WHIMS (Metso, 2014c,d).
high field gradients are required. These are generated by An inherent disadvantage of high-gradient separators
exploiting the ferromagnetic properties of iron to generate a is that in producing an increase in field gradient, the
high B-field (induced field) many hundreds of times greater working gap between secondary poles is reduced, so that
than the applied H-field. This, however, requires that the the magnetic force has a short reach of no more than
iron be in the volume where separation takes place. The about 1 mm. It is therefore necessary to use gaps of only
steel plates in a Jones separator, for example, occupy up to about 2 mm between poles, such that the matrix separa-
60% of the process volume. Thus, high-intensity magnetic tors are best suited to the treatment of very fine particles.
separators using conventional iron circuits tend to be very They are used mainly in the kaolin industry for removing
massive and heavy in relation to their capacity. A large sep- iron-containing particles which lower brightness.
arator may contain over 200 t of iron to carry the flux, hence In order to address some of the deficiencies in the
capital and installation costs are high. design of HGMS, new horizontally fed vertical carousel
Instead of using one large convergent field in the gap separators have been designed that incorporate a pulsating
of a magnetic circuit, as in the Jones separator, in HGMS a feed system to ensure particle dispersion (i.e., avoid floc-
solenoid is used to generate a uniform field with a solenoid culation) and prevent nonmagnetic entrainment. The
core, or working volume, filled with a matrix of secondary SLon VPHGMS (Figures 13.24 and 13.25) employs a
ferromagnetic poles, such as ball bearings, or wire wool, unique matrix of steel rods oriented perpendicular to the
the latter filling only about 10% of the working volume. applied magnetic field (Section 13.4.1) as well as flushing
Each secondary pole, due to its high permeability, can pro- of trapped magnetic particles (Figure 13.26) in the reverse
duce maximum field strengths of 2 T at their surface, but direction to the feed in order to reduce particle
Matrix
Magnetics
Ring
Flush station
Magnetic coil
Magnet head
Flush water
Nonmagnetics
Flush water Vertical ring confusingly referred to as WHIMS, while using a rod
matrix to produce high magnetic field gradients in a man-
Feed ner similar to HGMS (Eriez and Gzrinm, 2014). The Eriez
separator has been successfully applied to the following:
Magnetics the concentration of Fe-bearing minerals (hematite, limo-
nite, siderite, chromite), the cleaning of nonferrous ores
Slurry bath (quartz, cassiterite, garnet), the recovery of rare earth
level
minerals, and the purification of nonmetallic ores (quartz,
feldspar, kaolin, alusite, kyanite) (Eriez and Gzrinm, 2014).
Active separation zone
13.5.4 Superconducting Separators
FIGURE 13.25 Plan view of separation zone in SLon VPHGMS
(Courtesy Outotec). Future developments and applications of magnetic separa-
tion in the mineral industry lie in the creation and use of
increasingly higher product of field and field gradient,
momentum, maximize particle trapping, and improve sep- that is, the “force factor.” Matrix separators with very
aration (Outotec, 2013). The rod diameter in the matrix high field gradients and multiple small working gaps can
may be tailored for the given application to vary the max- draw little benefit from field strengths above the satura-
imum particle size that can pass through the separator tion levels of the secondary poles (B2 T for an iron/steel
from 0.6 up to 3.0 mm (Outotec, 2013). The averaged matrix material). As discussed in Section 13.4.1, the alter-
magnetic field intensity across the entire VPHGMS is no native to HGMS is OGMS, where separators with large
greater than 1.3 T; however, as the steel rod matrix working volumes deflect coarser particles at high capac-
becomes saturated, intensities up to 1.8 T can be achieved ity, rather than capture particles, as in HGMS. As the gra-
at the matrix surface with an applied magnetic field of dient in OGMS is relatively low, these separators need to
only 1 T (Outotec, 2013). The SLon separator has been use the highest possible field strengths to generate the
applied in the concentration of fine particles such as high magnetic forces required to treat weakly paramag-
hematite and ilmenite, and for desulfurization and dephos- netic particles. Field strengths in excess of 2 T can only
porization of iron ore feeds prior to steelmaking (Xiong, be generated economically by the use of superconducting
1994, 2004). Eriez also offers a vertical carousel-type magnets (Kopp, 1991; Watson, 1994).
WHIMS with similar innovations to the SLon VPHGMS, Certain alloys have the property of presenting no resis-
such as pulsating feed and high capacity due to improved tance to electric currents at extremely low temperatures.
matrix washing (Eriez and Gzrinm, 2014). The recently An example is niobiumtitanium at 4.2 K, the tempera-
developed version of the Eriez separator is somewhat ture of liquid helium. Once a current is established
396 Wills’ Mineral Processing Technology
FIGURE 13.26 Buildup on the matrix in the SLon separator (Courtesy Outotec).
through a coil made from a superconducting material, it colored) contaminants from kaolinite clay for operations
will continue to flow without being connected to a power in the United States. This machine used only about
source, and the coil will become, in effect, a permanent 0.007 kW in producing 5 T of flux, the ancillary equip-
magnet. Superconducting magnets can produce extremely ment needed requiring another 20 kW. In comparison, a
intense and uniform magnetic fields, of up to 15 T. The conventional 2 T high-gradient separator of similar
main problem, of course, is in maintaining the extremely throughput would need about 250 kW to produce the flux,
low temperatures. In 1986, a Ba/La/Cu oxide composite and at least another 30 kW to cool the magnet windings.
was made superconductive at 35 K, promoting a race to The 5 T machine is an assembly of concentric compo-
prepare ceramic oxides with much higher superconducting nents (Figure 13.27). A removable processing canister is
temperatures (Malati, 1990). Unfortunately, these materials installed in a processing chamber located at the center of the
are of a highly complex crystal structure, making them dif- assembly. This is surrounded by a double-walled, vacuum-
ficult to fabricate into wires. They also have a low current- insulated container that accommodates the superconductive
carrying capacity, so it is likely that for the foreseeable niobium/titaniumtantalum winding and the liquid helium
future superconducting magnets will be made from ductile coolant. A thermal shield, cooled with liquid nitrogen to
niobium alloys, embedded in a copper matrix. 77 K, limits radiation into the cryostat. In operation, the sup-
The main advantage of superconducting separators is ply of slurry is periodically cut off, the magnetic field is
that elevated magnetic field strength increases the maxi- shut down, and the canister backwashed with water to clear
mum feed slurry velocity with a corresponding increase in out accumulated magnetic contaminants.
capacity (Kopp, 1991). In order to fully utilize this capac- A picture of a superconducting magnetic separator in
ity, downtime for removal of accumulated magnetic parti- a horizontal arrangement installed in a plant is shown in
cles from the working volume of the separator must be Figure 13.28.
minimized through the use of a reciprocating or continu- An open-gradient drum magnetic separator with a
ously cycling matrix (Kopp, 1991). Another advantage of superconducting magnet system has been operating com-
these separators is the reduced weight of the separators mercially since the 1980s (Unkelbach and Kellerwessel,
(smaller coils and windings along with much less iron 1985; Wasmuth and Unkelbach, 1991). Although separa-
required compared to the heavy frames and matrix materi- tion is identical to that in conventional drum separators,
als used in HGMS) (Gillet and Diot, 1999). The factors the magnetic flux density at the drum surface can reach
limiting the adoption of superconducting separators are over 4 T.
the difficulties in maintaining the very low temperatures The development of HGMS and superconducting
necessary for the material to retain its superconducting separators capable of concentrating very fine or very
properties against heat leaks, and the high energy costs weakly magnetic mineral particles has prompted the
associated with maintaining this refrigeration (Kopp, application of magnetic separation techniques to treat
1991). Superconducting magnets are generally only viable many waste streams from mineral processing operations.
when large field volumes and magnetic fields greater than Fine (,10 μm), weakly magnetic hematite and limonite
2 T are required (Kopp, 1991). have been recovered by a combination of selective floccu-
In 1986, a superconducting HGMS was designed and lation using sodium oleate and kerosene followed by
built by Eriez Magnetics to remove magnetic (and HGMS (Song et al., 2002). HGMS has been used to
Magnetic and Electrical Separation Chapter | 13 397
Liquid
DC Bipolar
helium 3 Φ AC input
power supply
Vent
Liquid
Fill
nitrogen
Vent
Canister
Iron enclosure
Feed
applied field (Lockhart, 1984). The deliberate use of die- dense high-voltage discharge. The fine wire tends to dis-
lectrophoresis is almost nonexistent in mineral processing charge readily, whereas the large electrode tends to have
however, as the electrophoretic force is much stronger a short range, dense, nondischarging field. This combina-
(Lockhart, 1984). tion creates a strong discharge pattern that may be
In order to exploit the electrophoretic force for min- “beamed” in a definite direction and concentrated to a
eral separation, a treatment step prior to separation is very narrow arc. The voltage supplied should be such that
required in all electrical separators to selectively charge ionization of the air takes place. Arcing between the elec-
the mineral particles. This selective development of trode and the roll must be avoided, as this destroys the
charges on particles relies on conductivity differences ionization.
between the minerals. As most electrical conduction When ionization occurs, the mineral particles receive
occurs in the surface layers of atoms (Dance and a spray discharge of ions which gives all particles in the
Morrison, 1992), electrical separation may be thought of corona field a surface charge. As the HTR drum rotates
as a surface-based separation, similar to flotation, as and particles are moved outside of the corona field,
opposed to magnetic and gravity separation which rely on weakly conductive particles maintain a high surface
differences in bulk properties (magnetic susceptibility, charge, causing them to be attracted to and pinned to the
specific gravity). rotor surface. This is often referred to as pinning by the
There are three main mechanisms by which minerals image force (Figure 13.30), and it may be explained by
are charged: ion bombardment (corona charging), conduc- the charged mineral particle inducing a charge of opposite
tive induction, and frictional charging (tribocharging or sign on the rotor (Dance and Morrison, 1992). Pinned par-
contact electrification). Each of these three mechanisms ticles are removed from the rotor surface either through
has a corresponding separator type, the details of which the eventual decay of their surface charge or mechanically
are described in the following sections. To understand by means of a brush.
electrical separation methods, knowledge of the electrical Particles of relatively high conductivity lose their sur-
properties of materials is required. Introduction to the rel- face charge as the charge rapidly dissipates to the earthed
evant concepts, as they apply to mineral processing, along rotor. The centrifugal force of the rotor, along with
with detailed descriptions of many industrial separators,
may be found in the comprehensive reviews by Kelly and
Spottiswood (1989ac) and Manouchehri et al. (2000). Feed Electrode assembly
Conversely, two strongly conducting minerals can be sepa- results when an uncharged particle develops an opposite
rated with only a small difference in their conductivities. charge, relative to the electrode creating the electric field,
HTR separators have been one of the mainstays of the at the surface closest to the electrode and a corresponding
mineral sands industry for decades. Very little develop- like charge to the electrode on the particle surface furthest
ment of the machines has occurred in that period; their from the electrode. Conductive particles are able to redis-
generally poor single pass separation has been tolerated, tribute these induced charges across the particle surface,
and overcome by using multiple machines and multiple while nonconductive particles are unable to redistribute
recycle streams. However, in the last few years innovative these charges and will remain polarized. The electric
new designs have started to appear, from new as well as force on a polarized particle is a function of the degree to
established manufacturers. Roche Mining (MT) have which it polarizes, which is in turn affected by both the
developed the Carara HTR separator, which incorporates size and shape of the particle (Manouchehri et al., 2000).
an additional insulated plate static electrode to help When a polarized particle contacts a conductive surface it
deflect the path of conductive particles thrown from the may conduct charge of one polarity to the surface, leaving
rotor (Germain et al., 2003). Outokumpu Technology a net charge on the particle. In such a situation noncon-
developed the eForce HTR separator, which also incorpo- ductive particles (with no net charge) will experience no
rates additional static electrodes, as well as an electro- attraction from an applied electric field, whereas
static feed classifier (Elder and Yan, 2003).
OreKinetics has introduced the new CoronaStat
Feed
machine (Figure 13.31), which is a significant improve-
ment on existing HTR designs as it employs additional
static electrodes to improve the efficiency of separation.
Corona
Unlike existing machines, the static electrodes are not electrode
exposed, making the machines much safer to operate. The Pr
im
key improvement in the CoronaStat design relative to tra- ar
yi
ditional HTR separators is the presence of induction elec- nd
uc
tio
trodes, which simultaneously increase the pinning force ne
lec
on nonconducting particles and increase the rate of charge Brush
tro
de
decay for conductive particles (Figure 13.32). This results
in a larger distance between the two particle streams and
therefore an improved separation.
Evo lll
electrode
conductive particles will be attracted to an oppositely separators, system humidity is intentionally kept low, as
charged electrode (Kelly and Spottiswood, 1989a). excess moisture may alter the conductivity of the fluid
Conductive induction can therefore be thought of as a medium of the separator (the air) as well as affecting the
process in which charges are induced on uncharged con- conductivity of the particle surface through the dual effects
ductive particles, leaving nonconductive particles with no of water molecules themselves and dissolved ions in the
net charge. A graphical representation of conductive water (Kelly and Spottiswood, 1989b).
induction may be seen in Figure 13.33. Similar to the CoronaStat for HTR separation,
Separators exploiting this charging mechanism are OreKinetics has also developed an improved ESP separator
typically used to separate strongly conductive particles known as the UltraStat separator (Figure 13.35). The pri-
from weakly conductive particles and employ static elec- mary improvements in this separator are different geome-
trodes to “lift” charged conductive particles from a tries of the electrode and particle feed path, the presence of
grounded surface while nonconductive particles remain secondary induction electrodes to further increase the lifting
pinned to that surface. The most common such separator force on charged conductive particles as well as a secondary
is the electrostatic plate (ESP) separator. In an ESP sepa- roll to clean the primary roll surface.
rator, material is gravity fed through the separator and the
force on the charged particles acts to counteract the force
of gravity. In contrast to HTR separators, coarse particles 13.6.3 Triboelectric Charging
will tend to report to the nonconducting fraction, which is
The final charging mechanism used in mineral processing
why final cleaning of the products of HTR separation is
is triboelectrification, or contact electrification, in which
often carried out in purely electrostatic separators.
two materials of dissimilar electrical properties exchange
Modern electrostatic separators are of the plate or
electrons upon coming into contact with one another. As
screen type (Figure 13.34), the former being used to clean
most minerals are semi-conductors, with volume conduc-
small amounts of nonconductors from a predominantly con-
tivities between 105 and 1028 Ω m21 (Manouchehri et al.,
ducting feed (Figure 13.34(a)), while the screen separators
2000), the charge acquired by two minerals after contact-
remove small amounts of conductors from a mainly non-
ing one another may be predicted by the relative Fermi
conducting feed (Figure 13.34(b)). The principle of opera-
levels (energy level at which 50% of the energy states in
tion is the same for both types of separator. The feed
a material are occupied by electrons) of the two minerals
particles gravitate down a sloping, grounded plate into an
(Kelly and Spottiswood, 1989c). An alternative measure
electrostatic field induced by a large, oval-shaped, high-
also used to predict triboelectric charging behavior is the
voltage electrode. Fine particles are most affected by the
lifting force, and so fine conductive particles are preferen-
Feed plate
tially lifted to the electrode, whereas coarse nonconductors Feed
+
are most efficiently rejected. Machine parameters affecting – Electrode
ESP separators include: electrode geometry, electrode volt-
age and polarity, plate curvature, and position of the split-
ters (Dance and Morrison, 1992). For both HTR and ESP Splitter
tors
duc
Con
Conductor particle
Nonconductors
(a)
+
HV
Feed plate
M
+
ind
in
+
– Electrode
er
uc
+ Feed
al
tio
++
fa
l
+ ++ +
np
ld
ire
lat
ct
ee
io
+
n
Screen
lec
+
tro
+ duc
+ Con Duct work
+ +
+ + +
Roll surface Electrostatic lifting force Nonconductors
(b)
FIGURE 13.33 Representation of conductive induction (Courtesy
OreKinetics). FIGURE 13.34 (a) Plate, and (b) screen electrostatic separators.
402 Wills’ Mineral Processing Technology
Feed
n Pr
tio im
uc a
d el ry i
in e ec nd
y od tro uc
ar ctr de tio
im le
Pr e n
Secondary Secondary
induction induction
electrode electrode
Mid
Non-conductor
Conductor
Mid
Conductor
Non-conductor
work function of a material, which is a measure of the Teflon, have large differences in work function and will
energy required to bring an electron from the Fermi level therefore produce corresponding differences in the
of a given material to a free electron state (Kelly and charges produced on a given mineral particle (Dwari
Spottiswood, 1989c). A mineral with a low Fermi level et al., 2009). Even if the charge induced on a mineral
must therefore have a higher work function than a mineral surface using different charging materials is of the same
with a higher Fermi level. When two mineral particles sign, the amount of the charge transfer between two
come into frictional contact their Fermi levels will equal- materials is dependent on the differences between the
ize, with the mineral with the highest Fermi level losing Fermi levels of the two materials.
electrons to the mineral with the lower Fermi level Charge acquisition of mineral particles in triboelectric
(Manouchehri et al., 2000). The mineral with the highest separation may also be controlled through the use of a
work function (lower Fermi level) becomes negatively surface treatment prior to tribocharging such as: surface
charged and the opposing mineral becomes positively cleaning, chemical pretreatment, thermal pretreatment,
charged. The potential applications of triboelectric separa- irradiation, changes in the atmospheric humidity, or sur-
tion are immense, as separation does not require large dif- face doping (Manouchehri, 2010). Such surface treat-
ferences in mineral conductivity and virtually every ments are used to increase the difference in work function
binary mixture of minerals will possess a difference in between two minerals to be separated. An example is the
work function. treatment of industrial minerals with H3BO3 at alkaline pH,
Once the minerals have acquired a charge, they are which has been shown to increase the charge differences
often separated using a free-fall design consisting of two of feldsparquartz and feldsparcalcite mixtures
charged electrodes which deflect mineral particles based (Manouchehri et al., 1999). Another important variable in
on their surface charge with the mineral particles col- triboelectric separation is particle size, as small particles
lected in different bins. Such separators have been used have higher work functions than coarse particles of the
on a lab scale to separate quartz from wollastonite and same mineral (Manouchehri and Fawell, 2002). While mea-
calcite, calcite from insoluble silicates (Manouchehri and suring the charge on mineral particles, and even separating
Fawell, 2002), and on an industrial scale to beneficiate a binary mixture, can be readily accomplished in a con-
potash (Lockhart, 1984). trolled laboratory setting, the wide range of variables
In all triboelectric charging devices, mineral particles affecting triboelectric separation has limited the applica-
come into contact with not just one another, but also the tions of this technology in industrial settings where separa-
material from which the conveying device is con- tors must treat a feed consisting of multiple mineral types.
structed. It is therefore important to take this into con- One of the explanations for continued research interest
sideration, as different materials, such as brass and in triboelectric separation is the minimal effect of gravity
Magnetic and Electrical Separation Chapter | 13 403
on the separation process, which may in the future be setting up a high particle number density, counter cur-
very beneficial in developing extraterrestrial or lunar min- rent flow within the electrode gap. Particles must travel
ing operations (Li et al., 1999). In one such study, focused across only a small fraction of the electrode gap (across
on the beneficiation of ilmenite from a synthetic lunar the zone of high shear and lower velocities) under elec-
soil, ilmenite was found to report to both positive and trostatic forces to be separated into the oppositely flow-
negative electrodes in binary mixture separations depend- ing streams (Figure 13.38). The counter current highly
ing on the gangue mineral chosen for the feed mixture turbulent flow enables multiple stages of separation to
(Li et al., 1999). When the full synthetic ore, four differ- occur within a single pass through the separator, increas-
ent gangue minerals along with the ilmenite, was pro- ing both grade and recovery of the product streams
cessed through the triboelectric separation unit ilmenite (Bittner et al., 2014). This multistage separation zone
was found to be concentrated (by a factor of 23) in the requires that the particles maintain their charge, which is
neutral particle collection bin, evidently acquiring little made possible due to the high degree of interparticle
net charge due to the presence of gangue minerals with contacts occurring throughout the separation zone
both higher and lower work functions than the ilmenite (Bittner et al., 2014). This separator can process particles
(Li et al., 1999). This finding is illustrative of the inherent from 1 to 300 μm, which is much smaller than conven-
difficulties in predicting mineral behavior through tribo- tional free-fall and HTR separators. It has been widely
electric separations in an industrial setting. employed industrially in removing unburned coal char
Recently a new triboelectric separator, the ST separa- from fly ash (1020 μm median diameter) generated by
tor, has been developed by Separation Technologies coal-fired power plants (Bittner et al., 2014). On a pilot
which employs conventional interparticle contact to tri- plant scale (36 t h21), it has also been shown to be
bocharge mineral particles and a continuous loop open- effective at beneficiating industrial minerals such as sep-
mesh belt that travels at high speeds (520 m s21) arating quartz from calcite (89% recovery, 99% grade)
between positive and negative electrodes for particle and magnesite from talc (77% recovery, 95% grade)
separation (Figure 13.36) (Bittner et al., 2014). Feed (Bittner et al., 2014).
enters from the top of the unit (at feed rates of up to
40 t h21) with positive and negative charged particles
exiting from opposite ends of the separator
13.6.4 Example Flowsheets
(Figure 13.37). The separation occurs within a narrow Earlier in this chapter the possibility of combined mag-
gap (,1.5 cm) between the electrodes. The top and bot- netic and electrical separation was noted, particularly in
tom sections of the belt move in opposite directions, the processing of heavy mineral sand deposits. Table 13.3
404 Wills’ Mineral Processing Technology
Feed ports
Separation zone
+ –
FIGURE 13.37 Industrial installation of ST separator (Adapted from Bittner et al. (2014)).
FIGURE 13.38 Separation zone of ST separator (Adapted from Bittner et al. (2014)).
TABLE 13.3 Magnetic and Electrical Behavior of Typical Heavy Mineral Sands Components
Magnetics Magnetite—C Ilmenite—C Garnet—NC Monazite—NC
Nonmagnetics Rutile—C Zircon—NC Quartz—NC
shows some of the common minerals present in such allu- up to 20% heavy mineral in some cases. The gravity pre-
vial deposits, along with their properties, related to mag- concentrate is then transferred to the separation plant for
netic and electrical separation. Mineral sands are recovery of heavy minerals by a combination of gravity,
commonly mined by floating dredges, feeding floating magnetic, and electrical (typically HTR) separation.
concentrators at up to 2,000 t h21. Such concentrators, Mineral sands flowsheets vary according to the
consisting of a complex circuit of sluices, spirals, or properties of the minerals present, wet magnetic separa-
Reichert cones, upgrade the heavy mineral content to tion often preceding high-tension separation where mag-
around 90%, the feed grades varying from less than 2%, netic ilmenite is the dominant mineral, for example.
Magnetic and Electrical Separation Chapter | 13 405
A generalized flowsheet is shown in Figure 13.39. Low- South-East Asia for the treatment of alluvial cassiterite
intensity drum separators remove any magnetite from the deposits, which are also sources of minerals such as
feed, after which high-intensity wet magnetic separators ilmenite, monazite, and zircon.
separate the monazite and ilmenite from the zircon and In the case of the CliffsWabush mine (discussed in
rutile. Drying of these two fractions is followed by HTR Section 13.5.2), the gravity concentrate from the spirals
separation to produce final products, although further bank is cleaned by a series of HTR separators
cleaning is sometimes carried out by ESP separators. (Damjanović and Goode, 2000). The spiral concentrate
For example, screen electrostatic separators (Figure 13.34 is first filtered and dried before being fed to 54 primary
(b)) may be used to clean the zircon and monazite Carpco HTR separators (with a total of 288 rotors),
concentrates, removing fine conducting particles from with the tailings from the rougher HTR separators fed
these fractions. Similarly, plate electrostatic separators to six scavenger HTR separators (total of 24 rotors).
(Figure 13.34(a)) could be used to reject coarse noncon- Each rotor is 10 ft long with a roll diameter of 14 in.
ducting particles from the rutile and ilmenite and is operated at a rotor speed of 100 rpm, electrode
concentrates. voltage of 2325 kV, and a feed rate of 2.54 t h21.
Figure 13.40 shows a simplified circuit used to process Through this separation, the nonconductive quartz
heavy minerals, on the west coast of Australia (Benson gangue is pinned to the roll, with the valuable iron
et al., 2001). oxide mineral thrown from the roll. Cleaning of the
The heavy mineral concentrate is first divided into gravity concentrate with HTR separators is preferred as
conductive and nonconductive streams using HTR separa- relatively little material is pinned to the rotor in the
tors. The conductors are treated using cross-belt and roll high-tension treatment of the gravity concentrate (Fe-
magnetic separators to remove the ilmenite as a magnetic oxides are conductive). The rougher bank of HTR
product. The nonmagnetic stream is cleaned with high- separators produces a final concentrate, a middlings
intensity roll and rare earth magnets to separate the stream that is recycled to the HTR feed and a tailings
weakly paramagnetic leucoxene from diamagnetic rutile. stream sent to the HTR scavenger circuit. The scaven-
The nonconductors undergo another stage of wet gravity ger concentrate goes to the final concentrate (65.50%
separation to remove quartz and other low-specific- Fe, 2.55% SiO2, 1.95% Mn), with the scavenger tailings
gravity contaminants, before sizing and cleaning using sent to the final tailings. The HTR concentrate is then
HTR, ESP and Ultrastat separators to produce fine and blended with the magnetic concentrate prior to being
coarse zircon products. Similar flowsheets are used in sent to pelletization.
406 Wills’ Mineral Processing Technology
FIGURE 13.40 Simplified mineral sands circuit used by Tronox Limited (formerly Tiwest Joint Venture) at the Chandala processing plant, Western
Australia (Adapted from Benson et al. (2001)).
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