Attachment 9.

Chemical Analysis of Carbon and Low-Alloy Steel by Spark Atomic Emission

Spectrometry.
ASTM E415
Scope:
The ASTM E415 is a standard test technique for spark atomic emission spectrometry
examination of carbon and low-alloy steel. This test method applies to specimens with a
diameter large enough to overlap and seal the bore of the spark stand hole. This test technique
covers routine control analysis in iron and steelmaking activities as well as material analysis. It is
intended for specimens that have been chill-cast, rolled, or forged.
The spectrometric analysis of metals and alloys in this test method is primarily aimed to ensure
that such materials meet compositional standards. All users of this test technique are presumed
to be analysts capable of completing conventional laboratory operations skillfully and securely.
Test Procedure:
A capacitor discharge is created between the flat, ground surface of the disc specimen and a
conically shaped electrode in accordance with the ASTM E415 test protocol. The discharge is
stopped at a predetermined intensity time integral of one of the iron lines, or at a
predetermined time, and the relative radiant energies of the analytical lines are recorded. The
vacuum ultraviolet area contains the most sensitive lines of arsenic, boron, carbon, nitrogen,
phosphorus, sulphur, and tin. By vacating the spectrometer and flushing the spark chamber
with argon, the absorption of the radiation by air in this location is overcome.
Specimen Size:
The specimen thickness might vary considerably depending on the design of the spectrometer
stand, according to ASTM E415; however, a thickness between 10 mm and 38 mm has been
determined to be most practical.
Data:
When reference materials and specimens are of similar metallurgical condition and
composition, according to the ASTM E415 test procedure, better results are expected. It is not,
however, needed in all cases where this standard is used.