D and F Block

D and F block
Test / Exam Name: Test Standard: 12th Science Subject: Chemistry

Student Name: Section: Roll No.:
Questions: 428 Time: 01:00 hh:mm Marks: 753
Section A - 1 mark
Q1. Which one of the following ion exhibits colour in aqueous solution ? 1 Mark
1. Sc3+
2. Ni2+
3. Ti4+
4. Zn+2
Q2. Why do Zr and Hf exhibit almost similar properties? 1 Mark
Q3. ____________ is used in gas lamp material. 1 Mark

1. MnO2
2. CeO2
3. N2O5
4. Fe2O3
Q4. Which of the following species do not exist? 1 Mark

1. PbF4
2. PbCl4
3. PbO2
4. Pbl4
Q5. On the basis of lanthanoid contraction, explain the following: 1 Mark

Trends in the stability of oxo salts of lanthanoids from La to Lu.
Q6. Why are lanthanoids called f-block elements? 1 Mark
Q7. Describe the oxidising action of potassium dichromate and write the ionic equations for its reaction 1 Mark
with:
iron(II) solution
Q8. Write down the electronic configuration of: 1 Mark

Ce4+
Q9. Which of the following is paramagnetic as well as coloured ion? 1 Mark

1. Cu+
2. Cu2+
3. Sc3+
4. Zn2+
Q10. hich of the following statement is not correct? 1 Mark

1. La(OH)3 is less basic than Lu(OH)3.
2. In Lanthanide series ionic radius of Ln+3 ions decreases.
3. La is actually an element of transition series rather Lanthanide.
4. Aomic radius of Zr and Hf are same because of Lanthanide contraction.
Q11. Name the lanthanoid element which exhibits +4 oxidation state besides +3 oxidation state. 1 Mark
Q12. The Lanthanide contraction relates to:
1. Oxidation states. 1 Mark
2. Magnetic state.
3. Atomic radius.
4. Valence electrons.
Q13. A compound where the transition metal is in the +7 oxidation state. 1 Mark
Q14. Fuel used in nuclear power plants is: 1 Mark

1. Uranium - 235
2. Plutonium - 235
3. Plutonium - 238
4. Uranium - 238
Q15. What would be magnetic moment of Gd+3 (Z = 64)? 1 Mark

1. 7.9 BM
2. 3.62 BM
3. 10.60 BM
4. 9.72 BM
Q16. Which of the following ions show higher spin only magnetic moment value? 1 Mark
1. Ti3+
2. Mn2+
3. Fe2+
4. Co3+
Q17. Which of the following actinoids show oxidation states upto +7? 1 Mark
1. Am
2. Pu
3. U
4. Np
Q18. Which of the following statements is not correct about magnetic behaviour of substances? 1 Mark
1. Diamagnetic substances are repelled by an applied magnetic field.
2. Paramagnetic substances are attracted by an applied magnetic field.
3. Magnetic moment of n unpaired electrons is given by μ√n(n-2)B.M.
4. Magnetic moment increases as the number of unpaired electrons increases.
Q19. Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals. 1 Mark
Which of the following is not the characteristic property of interstitial compounds?
1. They have high melting points in comparison to pure metals.
2. They are very hard.
3. They retain metallic conductivity.
4. They are chemically very reactive.
Q20. Smallest ionic radius is: 1 Mark

1. La3+
2. U3+
3. Yb3+
4. Cf3+
Q21. Which is the most common oxidation state of lanthanoids? 1 Mark
Q22. The highest magnetic moment is shown by the transition metal ion with which of the following 1 Mark
outermost electronic configuration?
1. 3d2
2. 3d5
3. 3d7
4. 3d9
Q23. The tendency towards complex formation is maximum in: 1 Mark

1. S-block elements.
2. P-block elements.
3. D-block elements.
4. None of the above.
Q24. In these questions, a statement of assertion followed by a statement of reason is given. Choose the 1 Mark
correct answer out of the following choices.
1. Assertion and reason both are correct statements and reason is correct explanation for
assertion.
2. Assertion and reason both are correct statements but reason is not correct explanation for
assertion.
3. Assertion is correct statement but reason is wrong statement.
4. Assertion is wrong statement but reason is correct statement.
Assertion: [Ti(H2O)6]3+ is a coloured ion.
Reason: Ti shows +2, +3, +4 oxidation states.
Q25. Which of the following is used as Catalyst in the hydrogenation of oil? 1 Mark
1. V2O5
2. Pd
3. Fe
4. Ni
Q26. What is the maximum oxidation state shown by actinoids? 1 Mark
Q27. Transition elements show positive oxidation state, generally, due to: 1 Mark
1. Large atomic size.
2. Low ionization energy.
3. Low electronegativity.
4. High electronegativity.
Q28. Identify a 'Chemical twin' among the followings. 1 Mark

1. Zr - Ta
2. Nb - Tc
3. Hf - Re
4. Nb - Ta
Q29. How would you account for the following: 1 Mark

Although Zr belongs to 4d and Hf belongs to 5d transition series but it is quite difficult to separate
them.
Q30. Discuss the relative stability in aqueous solutions of +2 oxidation state among the elements: Cr, Mn, Fe 1 Mark
and Co. How would you justify this situation?
(At. Nos. Cr = 24, Mn = 25, Fe = 26, Co = 27)
Q31. Transition metals show paramagnetism due to: 1 Mark

1. Characteristic configuration.
2. High lattice energy.
3. Variable oxidation states.
4. Unpaired electrons.
Q32. Iron sheets are covered with a layer of zinc i.e., galvanized mainly to: 1 Mark
1. Harden the surface.
2. Increase the surface.
3. Prevent action of water only.
4. Prevent action of oxygen and water.
Q33. In the form of dichromate, Cr(VI) is a strong oxidising agent in acidic medium but Mo (VI) in MoO3 and 1 Mark
W(VI) in WO3 are not because ___________.
1. Cr(VI) is more stable than Mo(VI) and W(VI).
2. Mo(VI) and W(VI) are more stable than Cr(VI).
3. Higher oxidation states of heavier members of group-6 of transition series are more stable.
4. Lower oxidation states of heavier members of group-6 of transition series are more stable.
Q34. Highest oxidation state of manganese in fluoride is +4 (MnF4) but highest oxidation state in oxides is 1 Mark
+7 (Mn2O7) because ____________.
1. Fluorine is more electronegative than oxygen.
2. Fluorine does not possess d-orbitals.
3. Fluorine stabilises lower oxidation state.
4. In covalent compounds fluorine can form single bond only while oxygen forms double bond.
Q35. Which one of the following ionic species will impart colour to an aqueous solution? 1 Mark
1. Sc+3
2. Cd+2
3. Zn+2
4. Cr+3
Q36. The Lanthanoid contraction refers to: 1 Mark

1. Vlence electrons of the Lanthanide series.
2. Ionic radius of the series.
3. The density of the series.
4. Nuclear mass of the series.
Q37. Colour of Fe2+ ions is: 1 Mark

1. Blue.
2. Light green.
3. Very dark green.
4. Yellow.
Q38. General electronic configuration of actionoids is (n − 2)f1−14 (n − 1)d0−2 ns2 .Which of the following 1 Mark
actinoids have one electron in 6d orbital?
1. U (Atomic no. 92)
2. Np (Atomic no.93)
3. Pu (Atomic no. 94)
4. Am (Atomic no. 95)
Q39. Variable valency of transition elements is on account of: 1 Mark

1. Incomplete s - orbitals.
2. Incomplete d - orbitals.
3. Completely filled d - orbitals.
4. Incomplete p - orbitals.
Q40. The atomic and ionic radii (M3+ ions) of Lanthanide elements decrease with increase in atomic 1 Mark
number. This effect is called as:
1. Lanthanoid contraction.
2. Lanthanoid expansion.
3. Actinoid contraction.
4. None of these.
Q41. Fe has higher melting point than Cu. Why? 1 Mark
Q42. When acidified K2Cr2O7 solution is added to Sn2+ salts then Sn2+ changes to 1 Mark
1. Sn
2. Sn3+
3. Sn4+
4. Sn+
Q43. What are the two important oxidation states of Group 6 elements of the periodic table? 1 Mark
assertion.
assertion.
Assertion: Mn2+ is more stable than Mn3+.
Reason: Mn2+ has half-filled configuration.
Q45. Which one of the following elements forms compounds that are all coloured? 1 Mark
1. Magnesium.
2. Aluminium.
3. Iron.
4. Chromium.
Q46. Zinc chromate and lead chromate are used as: 1 Mark
1. Lakes
2. Lacquers
3. Mordants
4. Pigments
Q47. Actinoids belongs to following type of elements: 1 Mark

1. S - block element
2. D - block element
3. F - block element
4. P - block element
assertion.
assertion.
Assertion: Cu2+ is paramagnetic.
Reason: Cu2+ is less stable than Cu2+.
Q49. The Lanthanoids contraction relates to: 1 Mark

1. Atomic radii.
2. Atomic as well as M3+ radii.
3. Valence electrons.
4. Oxidation states.
Q50. In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomisation of zinc is the lowest, i.e., 126 kJ 1 Mark
mol–1. Why?
Q51. The magnetic moment is associated with its spin angular momentum and orbital angular momentum. 1 Mark
Spin only magnetic moment value of Cr3+ ion is ___________.
1. 2.87 B.M.
2. 3.87 B.M.
3. 3.47 B.M.
4. 3.57 B.M.
Q52. Differentiating electron in inner transition elements enters the ________ orbital. 1 Mark
1. s
2. p
3. d
4. f
Q53. What is the atomic number of the element with M2+ ion having electronic configuration [Ar]3d8? 1 Mark
1. 25
2. 28
3. 27
4. 26
Q54. The first and last elements of actinides are: 1 Mark

1. Actinium and Thorium.
2. Actinium and Nobelium.
3. Actinium and Mendelevium.
4. Actinium and Lawrencium.
Q55. Account for the following: 1 Mark

Actinoids show wide range of oxidation states.
Q56. Which metal oxide is used to obtain blue coloured glass? 1 Mark
1. Ferric oxide.
2. Chromium oxide.
3. Manganese oxide.
4. Cobalt oxide.
Q57. Identify the metal that forms colourless compounds. 1 Mark

1. Iron (Z = 26)
2. Chromium (Z = 24)
3. Vanadium (Z = 23)
4. Scandium (Z = 21)
Q58. Chemically Zinc group elements closely resemble ______. 1 Mark

1. I A group
2. II A group
3. III A group
4. IV A group
Q59. Which of the following pairs of atom have the most similar radii ? 1 Mark
1. Zr, Hf
2. Cu, Ag
3. Sc, Ti
4. Pd, Pt
Q60. Which of the following statements is not correct? 1 Mark

1. Copper liberates hydrogen from acids.
2. In its higher oxidation states, manganese forms stable compounds with oxygen and fluorine.
3. Mn3+ and Co3+ are oxidising agents in aqueous solution.
4. Ti2+ and Cr2+ are reducing agents in aqueous solution.
assertion.
assertion.
Assertion: Chromium is hard but mercury is soft.
Reason: Chromium is a 3d transition element.
Q62. Metal cation which is coloured in its aqueous solution is: 1 Mark
1. Sc3+
2. Zn2+
3. V3+
4. Ti4+
Q63. Which of the following belongs to the actinide series of elements? 1 Mark
1. Y
2. Ta
3. U
4. Lu
Q64. Which of the following is not an actinide? 1 Mark

1. Uranium
2. Curium
3. Californium
4. Erbium
assertion.
assertion.
+ 2+
Assertion: The correct order of oxidising power is: VO2 < VO < VO .
Reason: The oxidation state of Mn is +7.
Q66. In the following electronic configuration ns2(n - 1)d0-1(n - 2)f1-14. If value of (n - 1) = 6 the configuration 1 Mark
will be of:
1. lanthanides
2. d - block
3. actinides
4. s - block
with:
Iodide
Q68. The number of elements in the transition metal series Sc through Zn that have four unpaired electrons 1 Mark
in their +2 state are:
1. 2
2. 4
3. 5
4. 6
Q69. Choose the correct statement. 1 Mark

1. Only few transition metal complexes are coloured.
2. d-orbital are degenerated hence, they form complexes.
3. Transition metal complexes reflect the complimentary colour of absorbed colour.
4. Energy difference between t2(g) and tg level is very large.
Q70. Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct 1 Mark
electronic configuration of gadolinium?
1. [Xe] 4f7 5d1 6s2
6
2. [Xe] 4f 5d2 6s2
3. [Xe] 4f8 6d2
9
4. [Xe] 4f 5s1
Q71. Most of the radio active elements are present in: 1 Mark
1. Lanthanoids
2. Actinoids
3. Representative elements
4. Second transition series
Q72. KMnO4 acts as an oxidising agent in alkaline medium. When alkaline KMnO4 is treated with KI, iodide 1 Mark
ion is oxidised to ____________.
1. I2
−
2. IO
−
3. IO3
4. IO−4
assertion.
assertion.
Assertion: Transition metals form a large number of interstitial compounds.
Reason: They have high melting point and boiling point.
Q74. Transition metals are often para magnetic owing to ____________. 1 Mark
1. High melting point and boiling point.
2. The presence of vacant orbitals.
3. The presence of unpaired electrons.
4. Malleability and ductility.
Q75. Variable valency is characteristic of: 1 Mark

1. Halogen.
2. Transition elements.
3. Alkali metals.
4. Noble gas.
Q76. Magnetic moment of X3+ion od 3d series is √35BM What is atomic number of X3+? 1 Mark
1. 25
2. 26
3. 27
4. 28
Q77. On the basis of lanthanoid contraction, explain the following: 1 Mark

Radii of 4d and 5d block elements.
Q78. Generally transition elements and their salts are coloured due to presence of ___________? 1 Mark
1. Coloured compounds and ions.
2. Coloured anions and cations.
3. Coloured particles and ions.
4. Unpaired electrons.
Q79. IP values of Sc, Y and La are in the order: 1 Mark

1. Sc > Y > La
2. Sc < Y < La
3. Sc = Y = La
4. La > Sc > Y
Q80. Which of the following is not an interstitial compound? 1 Mark

1. TiC
2. MoC
3. Fe0.82O
4. Cr2O3

Pm3+
Q82. Although +3 is the characteristic oxidation state for lanthanoids but cerium also shows +4 oxidation 1 Mark
state because ___________.
1. It has variable ionisation enthalpy
2. It has a tendency to attain noble gas configuration
3. It has a tendency to attain f0 configuration
4. It resembles Pb4+
+ 2−
Q83. How would you account for the increasing oxidising power in the series VO2 < Cr2O7 < MnO−4 1 Mark
assertion.
assertion.
Assertion: In transition elements, ns orbital is filled up first and (n - 1)d afterwards, during ionization
ns electrons are lost prior to (n - 1)d electrons.
Reason: The effective nuclear charge felt by (n - 1)d electrons is higher as compared to that by ns
electrons.
Q85. Which of the following elements belongs to actinide series? 1 Mark

1. Lu
2. Gd
3. Th
4. La

Lu2+
Q87. The separation of Lanthanides by ion exchange method is based on: 1 Mark

1. Asicity of the hydroxides.
2. Size of the ions.
3. The solubility of their nitrates.
4. Oxidation state of the ion.
Q88. Which one of the following statements about lanthanides is false ? 1 Mark
1. Lanthanides are seperated from one another by ion exchange method.
2. The ionic radii of trivalent lanthanides steadily increases with increase in atomic number.
3. All lanthanides are highly dense metals.
4. Most typical oxidation state of lanthanides is +3
Q89. Analysis shows that FeO has a non-stoichiometric composition with formula Fe0.95O. Give reason. 1 Mark
Q90. Lanthanoid contraction occurs because: 1 Mark

1. The 4f electrons, which are gradually added, create strong shielding effect.
2. The 4f orbitals are greater in size than the 3d and 3f orbitals.
3. The 5f orbitals strongly penetrate into the 4f orbitals.
4. The poor shielding effect of 4f electrons is coupled with increased attraction between the
nucleus and the added electrons.
Q91. Write any one use of pyrophoric alloys. 1 Mark
Q92. How many electron present in penultimate shell of d-block element? 1 Mark

1. 9 - 18
2. 8 - 18
3. 1 - 10
4. 1 - 32
assertion.
assertion.
Assertion: Members of 4d and 5d series of transition elements have nearly same atomic radii.
Reason: Atomic and ionic radii for transition elements are smaller than their corresponding s-
block elements.
Q94. The atomic numbers of elements of second inner transition elements lie in the range of: 1 Mark
1. 88 to 101
2. 89 to 102
3. 90 to 103
4. 91 to 104
Q95. What are the different oxidation states exhibited by the lanthanoids? 1 Mark
Q96. The catalytic activity of the transition metals and their compounds is ascribed to their 1 Mark
1. Chemical reactivity.
2. Magnetic behaviour.
3. Unfilled d-orbitals.
4. Ability to adopt multiple oxidation states and their complexing ability.
Q97. The E⊖ (M2+ /M) value for copper is positive (+0.34V). What is possibly the reason for this? (Hint: 1 Mark
consider its high Δa H⊖ and low Δhyd H⊖ ).
Q98. The adsorption of hydrogen by platinum black is called: 1 Mark

1. Hydrogenation
2. Reduction
3. Occlusion
4. Hydration
Q99. What is meant by 'lanthanoid contraction'? 1 Mark
Q100. Metals are usually used as catalysts belong to: 1 Mark

1. S-block
2. P-block
3. D-block
4. F-block
Q101. The following belongs to d-block but it is not transition element: 1 Mark

1. Mn
2. Fe
3. Zn
4. Cr
Q102. The transition metal used in X-rays tube is: 1 Mark

1. Mo
2. Ta
3. Tc
4. Pm
Q103. There are 14 elements in actinoid series. Which of the following elements does not belong to this 1 Mark
series?
1. U
2. Np
3. Tm
4. Pm
Q104. Why do transition elements show similarities along the horizontal period? 1 Mark
Q105. Out of the following transition elements, the maximum number of oxidation states are shown by: 1 Mark
1. Sc (Z = 21)
2. Cr (Z = 24)
3. Mn (Z = 25)
4. Fe (Z = 26)

Th4+
Q107. When KMnO4 solution is added to oxalic acid solution, the decolourisation is slow in the beginning but 1 Mark
becomes instantaneous after some time because
1. CO2 is formed as the product.
2. Reaction is exothermic.
3. MnO−4 catalyses the reaction.
4. Mn2+ acts as autocatalyst.
Q108. Among the following metals, interatomic forces are probably the weakest in: 1 Mark
1. Cu
2. Ag
3. Zn
4. Hg
with:
H 2S
Q110. Explain why Cu+ ion is not stable in aqueous solutions? 1 Mark
Q111. D-block elements form complexes because they have: 1 Mark

1. Vacant orbitals.
2. Small sizes.
3. Higher nuclear charge.
4. All of the above.
Q112. Which of the following types of metals forms the most efficient catalysts: 1 Mark
1. Alkali metals.
2. Alkaline earth metals.
3. Transition metal.
4. All of these.
Q113. Raney nickel, which is used as a catalyst, is obtained: 1 Mark

1. By grinding solid nickel.
2. By treating nickelaluminium alloy with dilute NaOH.
3. By treating nickelaluminium alloy with dilute HCl.
4. By heating nickel tetracarbonyl.
Q114. Which of the following is ferromagnetic. 1 Mark

1. Cu, Ag, Au
2. Fe, Co, Ni
3. Zn, Cd, Hg
4. Ca, Sr, Ba
assertion.
assertion.
Assertion: Fe2+ is paramagnetic.
Reason: Fe2+ contains four unpaired electrons.
Q116. Which of the following statements concerning lanthanide elements is false? 1 Mark
2. The characteristic oxidation state of lanthanide elements is +3.
3. Lanthanides are separated from one another by ion exchange method.
4. Ionic radii of trivalent lanthanides steadily increase with an increase in the atomic number.
2−
Q117. Number of Cr−O bonds in dichromate ion (Cr2 O7 ) is: 1 Mark
1. 6
2. 7
3. 8
4. 4
Q118. Transition elements show magnetic moment due to spin and orbital motion of electrons. Which of the 1 Mark
following metallic ions have almost same spin only magnetic moment?
1. Co2+
2. Cr2+
3. Mn2+
4. Cr3+
Q119. Which one is false in the following statement: 1 Mark

1. A catalyst is specific in its action.
2. A very small amount of the catalyst alters the rate of a reaction.
3. The number of free valencies on the surface of the catalyst increases on subdivision.
4. Ni is used as catalyst in the manufacture of ammonia in the redox reaction.
Q120. Which lanthanide compound is used as a pigment? 1 Mark

1. CeO2
2. Ce(OH)3
3. Lu(OH)3$
4. Tb(OH)3
Q121. Name a transition element which does not exhibit variable oxidation state 1 Mark
Q122. Which is the last element in the series of the actinoids? Write the electronic configuration of this 1 Mark
element. Comment on the possible oxidation state of this element.

Cu+
Q124. A transition metal which does not exhibit variation in oxidation state in its compounds. 1 Mark
Q125. The following is not a noble metal: 1 Mark

1. Au
2. Cu
3. Ag
4. Pt
Q126. Why does a transition series contain 10 elements? 1 Mark
Q127. ll Cu(II) halides are known except the iodide. The reason for it is that: 1 Mark
1. iodide is a bulky ion.
2. Cu2+ oxidizes iodide to iodine.
2+
3. Cu(aq) has much more negative hydration enthalpy.
4. Cu2+ ion has smaller size.
Q128. Transition metals are often paramagnetic owing to: 1 Mark

1. High m.p. and b.p. of transition metals.
2. Presence of vacant d-orbitals.
3. Presence of one or more unpaired d-electrons.
4. Their less electropositive nature as compared to the elements of groups IA and IIA.
Q129. A reduction in atomic size with increase in atomic number is a characteristic of elements of: 1 Mark
1. D-block.
2. F-block.
3. Radioactive series.
4. High atomic masses.
Q130. Gallium is in __________ state at room temperature. 1 Mark

1. Plasma.
2. Liquid.
3. Solid.
4. Gaseous.
Q131. Write the formula of an oxo-anion of Manganese (Mn) in which it shows the oxidation state equal to 1 Mark
its group number.
Q132. When MnO2 is fused with KOH in the presence of air, a coloured compound is formed, the product 1 Mark
and its colour is:
1. K2MnO4, dark green
2. KMnO4, purple
3. Mn2O3, brown
4. Mn3O4, black.
Q133. Which is a stronger reducing agent Cr2+ or Fe2+ and why? 1 Mark
Q134. Oil is converted into fat by using ____ as a catalyst. 1 Mark
1. Ni
2. Fe
3. Mn
4. V2O5

Q135. Why is the highest oxidation state of a metal exhibited in its oxide or fluoride only? 1 Mark
assertion.
assertion.
Assertion: Zinc is used in the galvanisation of iron.
Reason: Its coating on iron articles increases their life by protecting them from rusting.
Q137. Which of following ion has the maximum theoretical magnetic moment? 1 Mark
1. Cr3+
2. Fe3+
3. Ti3+
4. Co3+
Q138. Magnetic moment of diamagnetic substance in Bohr Magnetons is: 1 Mark

1. 1.73
2. 2.83
3. 50
4. 0
assertion.
assertion.
Assertion: Reduction potential of Mn (+3 to +2) is more positive than Fe (+3 to +2).
Reason: Ionisation potential of Mn is more than that of Fe.
Q140. The electronic configuration of Cu(II) is 3d9 whereas that of Cu(I) is 3d10. Which of the following is 1 Mark
correct?
1. Cu(II) is more stable
2. Cu(II) is less stable
3. Cu(I) and Cu(II) are equally stable
4. Stability of Cu(I) and Cu(II) depends on nature of copper salts
Q141. What is the general formula by which the electronic configuration of the transition elements is 1 Mark
represented?
Q142. The transition metals are mostly: 1 Mark

1. Diamagnetic.
2. Paramagnetic.
3. Neither diamagnetic nor paramagnetic.
4. Both diamagnetic and paramagnetic.
Q143. A member of the lanthanoid series which is well known to exhibit +4 oxidation state. 1 Mark
Q144. Why are transition elements so named? 1 Mark
Q145. The catalytic activity of the transition metals and their compounds is ascribed to their: 1 Mark
1. Chemical reactivity.
2. Magnetic behaviour.
3. Unfilled d-orbitals.
4. Ability to adopt multiple oxidation states and their complexing ability.
Q146. Which of the following is diamagnetic ion? 1 Mark

1. Zn2+
2. Ni2+
3. Co2+
4. Cu2+
Q147. Transition metals are less reactive because of their: 1 Mark

1. High ionization potential and low melting point.
2. High ionization potential and high melting point.
3. Low ionization potential and low melting point.
4. Low ionization potential and high melting point.
Q148. If each one of the above ionic species is in turn kept in a magnetic field, which one will get attracted ? 1 Mark
1. Co+2
2. Mn+7
3. Sc+3
4. Ti+4
Q149. The property seen in f-block elements is: 1 Mark

1. Lanthanoid contraction.
2. Actinide contraction.
3. Both (A) and (B).
4. Lanthanoid expansion.
Q150. Which of the following becomes paramagnetic on heating? 1 Mark

1. MnO
2. Fe3O4
3. ZnFe2O4
4. B and C both

Cr3+
Q152. Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then they 1 Mark
show similar physical and chemical properties because ___________.
1. Both belong to d-block.
2. Both have same number of electrons.
3. Both have similar atomic radius.
4. Both belong to the same group of the periodic table.
Q153. Which compound is volatile on heating? 1 Mark

1. MgCl2
2. HgCl2
3. ZnCl2
4. none of these
Q154. The Lanthanoid contraction refers to decrease in the: 1 Mark
1. Valence electrons of the Lanthanide series.
2. Ionic radius of the series.
3. The density of the series.
4. Nuclear mass of the series.
Q155. Actinoid contraction is greater from element to element than lanthanoid contraction. Why? 1 Mark
assertion.
assertion.
Assertion: Transition metals form substitutional alloys.
Reason: Alloys are made to develop some useful properties which are absent in the constituent
elements.
Q157. The magnetic nature of elements depends on the presence of unpaired electrons. Identify the 1 Mark
configuration of transition elements which shows highest magnetic moment?
1. 3d2
2. 3d8
3. 3d7
4. 3d5
Q158. The color of CoCl3.5NH3.H2O is: 1 Mark

1. Red
2. Orange
3. Orange-yellow
4. Pink
Q159. Transition metal compounds are usually colored. This is due to the electronic transition: 1 Mark
1. From p-orbital to s-orbital.
2. From d-orbital to s-orbital.
3. From d-orbital to p-orbital.
4. Within the d-orbitals.
Q160. Name one ore each of manganese and chromium. 1 Mark
assertion.
assertion.
Assertion: Promethium is a manmade element.
Reason: It is radioactive and has been prepared by artificial means.
Q162. Which of the following statement regarding transition elements is incorrect? 1 Mark
1. Their atoms contain partially filled d orbitals.
2. They are capable of showing variable valencies.
3. All of their ions are colourless.
4. They form complexes readily.
Q163. An atom of element has 2K, 8L and 3M electrons. Then the element belongs to: 1 Mark
1. IA group
2. IIA group
3. IIIA group
4. IVA group
Q164. Titanium oxide is added in interior paints for walls of rooms, halls and galleries to give: 1 Mark
1. A whiter 'white'
2. Agreener 'green'
3. Aredder 'red'
4. Silver-white
Q165. Elements which generally exhibit variable oxidation states and form colored ions are ___________. 1 Mark
1. Metalloids.
3. Non-metals.
4. Gases.
Q166. Write the outer electronic configuration of lanthanoids. 1 Mark
Q167. Why is HCl not used to make the medium acidic in oxidation reactions of KMnO4 in acidic medium? 1 Mark
1. Both HCl and KMnO4 act as oxidising agents.
2. KMnO4 oxidises HCl into Cl2 which is also an oxidising agent.
3. KMnO4 is a weaker oxidising agent than HCl.
4. KMnO4 acts as a reducing agent in the presence of HCl.
Q168. Some compounds turn dark when exposed to light. They are, therefore, used in photography. A metal 1 Mark
used for making such compounds is:
1. Aluminium.
2. Nickel.
3. Chromium.
4. Silver.
Q169. Transitional elements exhibit variable valencies because they release electrons from the following 1 Mark
orbits:
1. Ns orbit
2. Ns and np orbits
3. (n−1)d and ns orbits
4. (n−1)d orbit
Q170. Of the following metals, the most reactive metal is: 1 Mark
1. Fe
2. Ni
3. Pt
4. Au
assertion.
assertion.
Assertion: Zinc becomes dull in moist air.
Reason: Zinc is coated by a thin film of its basic carbonate in moist air.
Q172. Which of the following belongs to actinoid series of elements?
1. Nd 1 Mark
2. U
3. Sm
4. Au
Q173. The elements which exhibit both vertical and horizontal similarities are _______. 1 Mark
1. Inert gas elements.
2. Representative elements.
3. Rare elements.
Q174. The element californium belongs to a family of: 1 Mark

1. Actinide series.
2. Alkali metal family.
3. Alkaline earth family.
4. lanthanide series.
Q175. An aqueous solution containing Vx+ ion has magnetic moment equal to √15BM Therefore, the x is: 1 Mark
1. 5
2. 2
3. 3
4. 4
Q176. It is sometimes necessary to remove colouring matter contained as an impurity in glass. Glass is 1 Mark
decolourised by:
1. Wood charcoal.
2. Manganese dioxide.
3. Bleaching powder.
4. Hydrogen.
Q177. Atomic number of three elements A, B, and C are respectively, 1 Mark

Pm (Z = 61), Sm (Z = 62), Eu (Z = 63).
Which one has a maximum atomic radius?
1. A
2. B
3. C
4. All have the same radius.

Mn2+
Q179. Most copper (I) compounds are found to be colourless. This is due to: 1 Mark
1. Presence of low oxidation state of copper.
2. Completely filled d-level in Cu(I).
3. Diamagnetic nature of the compound.
4. High polarizability of Cu(I) ion.
Q180. Which of the following transition metal ions has highest magnetic moment? 1 Mark
1. cu2+
2. Ni2+
3. Co2+
4. Fe2+
Q181. Compare the chemistry of actinoids with that of the lanthanoids with special reference to: 1 Mark
Electronic configuration
Q182. Which of the following is true regarding derivation of the name of californium? 1 Mark
1. The name of californium was derived from the name of the place.
2. The name of californium was derived from its color.
3. The name of californium was derived from the name of the scientist who discovered it.
4. The name of californium was derived from mythological character name.
Q183. The first ionisation potential of N, P, O and S are in the order of: 1 Mark
1. S > P < O > N
2. N > O > P > S
3. N > O < P > S
4. N < O < P < S
Q184. The radius of La3+ (atomic number of La = 57) is 1.06A. Which one of the following given values will 1 Mark
be closest to the radius of Lu3+? (atomic number of Lu = 71)
1. 1.40A
2. 1.06A
3. 0.85A
4. 1.60A
Q185. Silver atom has completely filled d orbitals (4d10) in its ground state. How can you say that it is a 1 Mark
transition element?
Q186. 5f series elements are known as_______? 1 Mark

1. Lanthanides.
2. Representative elements.
4. Actinides.
Q187. Which divalent metal ion has maximum paramagnetic character among the first transition metals? 1 Mark
Why?
assertion.
assertion.
Assertion: Co (IV) is known but Ni (IV) is not.
Reason: Ni (IV) has d6 electronic configuration.
Q189. KMnO4 acts as an oxidising agent in acidic medium. The number of moles of KMnO4 that will be 1 Mark
needed to react with one mole of sulphide ions in acidic solution is
1. 25
3
2. 5
4
3. 5
1
4. 5
Q190. Give the general electronic configuration of actinoids. 1 Mark
Q191. Transuranic elements begin with: 1 Mark

1. Np
2. Cm
3. Pu
4. U
Q192. Which of the following reactions are disproportionation reactions? 1 Mark

1. Cu+ → Cu2+ + Cu
2. 3MnO4– + 4H+ → 2MnO4– + MnO2 + 2H2O
3. 2KMnO4 → K2MnO4 + MnO2 + O2
4. 2MnO4– + 3Mn2+ + 2H2O → 5MnO2 + 4H+
1. a, b
2. a, b, c
3. b, c, d
4. a, d

Q193. Which sub shell is filled up progressively in actinoids? 1 Mark

1. 4f
2. 5f
3. 6d
4. 7s
Q194. Monazite is an ore of: 1 Mark

1. Titanium.
2. Throium.
3. Zirconium.
4. Iron.
Q195. The only radioactive element among the lanthanoids is: 1 Mark
1. Gadolinium.
2. Holmium.
3. Promethium.
4. Neodynium.
Q196. Chromium - plated steel is a material of popular use. During its process of manufacture, the effluent 1 Mark
contains chromate and cyanide ions as impurities. After these are chemically removed, carbon dioxide
and salt (sodium chloride) still remain as impurities. This salt solution is purified electrolytically by
adding carbonaceous matter which acts as:
1. A microcell.
2. An electrode.
3. A cathode.
4. Asalt absorber.
Q197. Experimental value of magnetic momentum of Mn2+ complex is 5.96 B.M. This indicates: 1 Mark
1. Axial and orbital motion of electron in same direction.
2. Axial and orbital motion of electron in opposite direction.
3. Electron does not exhibit orbital motion, it only exhibits axial motion.
4. Electron does not exhibit axial motion, it only exhibits orbital motion.
Q198. Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state 1 Mark
+3 of lanthanoids?
1. Ce
2. Eu
3. Yb
4. Ho
assertion.
assertion.
Assertion: When Zn is placed in a magnetic field, it is feebly magnetised in a direction opposite to that
of the magnetising field.
Reason: Zn has completely filled atomic orbitals.
assertion.
assertion.
Assertion: Most of the trivalent lanthanide ions are coloured both in the solid state and in aqueous
solution.
Reason: The elements with xf electrons have a similar colour to those of (14 - x)f electrons.
Q201. How many elements are present in the d-block of the periodic table? 1 Mark
Q202. Transition elements form binary compounds with halogens. Which of the following elements will form 1 Mark
MF3 type compounds?
1. Cr
2. Co
3. Cu
4. Ni
Q203. The magnetic moment of [Cu(NH3)4]2+ was found to be 1.73 B.M. The number of unpaired electrons in 1 Mark
the complex is:
1. 0
2. 1
3. 2
4. 3
Q204. Which of the following group belongs to actinide series ? 1 Mark

1. Th, Pa, U
2. Ce Pr, Nd
3. Ba, La, Hf
4. Pt, Au, Ag
Q205. Which of the 3d series of the transition metals exhibits the largest number of oxidation states and 1 Mark
why?
Q206. Arrange the following in increasing order of acidic character: CrO3, CrO, Cr2O3. 1 Mark
Q207. There are 14 elements in actinoid series. Which of the following elements does not belong to this 1 Mark
series?
1. U
2. Np
3. Tm
4. Fm
Q208. On addition of small amount of KMnO4 to concentrated H2SO4, a green oily compound is obtained 1 Mark
which is highly explosive in nature. Identify the compound from the following.
1. Mn2O7
2. MnO2
3. MnSO4
4. Mn2O3
Q209. 1 Mark
Metallic radii of some transition elements are given below. Which of these elements will have highest
density?
Element Fe Co Ni Cu
Metallic radii/pm 126 125 125 128
1. Fe
2. Ni
3. Co
4. Cu
Q210. Catalytic activity of transition elements and their compounds is due to their _______. 1 Mark
1. Small size.
2. Vacant d-orbitals.
3. Higher densities.
4. Colour.
Q211. The metal capable of gaining as well as losing an electron is: 1 Mark
1. Hg
2. Ca
3. Ag
4. Au
Q212. Why are transition elements known as d-block elements? 1 Mark
Q213. In which pair highest oxidation states of transition metals are found? 1 Mark
1. Nitrides and Chlorides.
2. Fluorides and Chlorides.
3. Fluorides and Oxides.
4. Nitrides and Oxides.
Q214. Which of the following has smallest ionic radius ? 1 Mark

1. Nd3+
2. Dy3+
3. Lu3+
4. Pm3+
Q215. Which of the following compounds will not give +ve chromyl chloride test? 1 Mark
1. CuCl2
2. HgCl2
3. ZnCl2
4. C6H5NH2HCl
Q216. Which of the following will not act as oxidising agents? 1 Mark
1. CrO3
2. MoO3
3. WO3
4. CrO2−
4
Q217. What is the common oxidation state of Cu, Ag and Au? 1 Mark
Q218. Many Lanthanoid elements are used to prepare: 1 Mark

1. Ceramic materials.
2. Water softener.
3. Superconducting materials.
4. Enzyme catalysts.
Q219. Maximum ferromagnetism is found in? 1 Mark

1. Fe
2. Ni
3. Co
4. None
Q220. Which forms coloured salts? 1 Mark

1. Metals
2. Non-metals
3. p-block elements
4. Transitional elements
Q221. Which of the following oxidation state is common for all lanthanoids? 1 Mark
1. +2
2. +3
3. +4
4. +5
Q222. The ionic charges on chromate ion and dichromate ion respectively is: 1 Mark
1. -2, -2
2. -3, -2
3. -2, -4
4. -4, -2
Q223. The magnetic nature of elements depends on the presence of unpaired electrons. Identify the 1 Mark
configuration of transition element, which shows highest magnetic moment.
1. 3d7
2. 3d5
3. 3d8
4. 3d2
assertion.
assertion.
Assertion: Europium (II) is more stable than cerium (II).
Reason: Cerium salts are used as a catalyst in petroleum cracking
Q225. Which one of the following paramagnetic in nature? 1 Mark

1. CuCl2
2. CaCl2
3. CdCl2
4. All of these.
Q226. Generally transition elements and their salts are coloured due to the presence of unpaired electrons 1 Mark
in metal ions. Which of the following compounds are coloured?
1. KMnO4
2. Ce (SO4)2
3. TiCl4
4. Cu2Cl2
Q227. Transition metals are good electrical conductor because ___________. 1 Mark

1. They are metals.
2. They are solids.
3. They have free electrons in outer energy levels.
4. They are hard.
Q228. Which of the following is amphoteric oxide? 1 Mark
Mn2O7, CrO3, Cr2O3, CrO, V2O5, V2O4
1. V5 O5 , Cr2 O3
2. Mn2 O7 , CrO3
3. CrO, V2 O5
4. V2 O5 , V2 O4
Q229. Colour in transition metal compounds is attributed to: 1 Mark

1. Small size of metal ions.
2. Absorption of light in UV region.
3. Complete (ns) subshell.
4. Incomplete (n−1)d subshell.
Q230. Generally transition elements form coloured salts due to the presence of unpaired electrons. Which of 1 Mark
the following compounds will be coloured in solid state?
1. Ag2SO4
2. CuF2
3. ZnF2
4. Cu2Cl
Q231. Which of the following has highest value of magnetic moment? 1 Mark
1. Fe2+
2. Co3+
3. V3+
4. Ti3+

CO2+
Q233. Cholrine gas is produced from HCI by the addition of: 1 Mark
1. K2SO4
2. KCl
3. KNO3
4. KMnO4

Q234. Which element among the Lanthanides has the smallest atomic radius? 1 Mark
1. Cerium.
2. Lutetium.
3. Europium.
4. Gadolinium.
Q235. The color of Cu+ compounds is? 1 Mark

1. White
2. Blue
3. Orange
4. Yellow
Q236. Which ine of the following statement about lanthanides is false? 1 Mark
1. Lanthanides are sepearated from one another by ion exchange method.
2. The ionic radii of trivalent lanthanides steadily increases with increase in atomic number.
4. Most typical oxidation state of lanthanides is +3
Q237. Transition metals make the most efficient catalysts because of their ability to: 1 Mark
1. Adopt multiple oxidation states and to form complexes.
2. Form coloured ions.
3. Show paramagnetism due to unpaired electrons.
4. Form a large number of oxides.
Q238. Lanthanides and actinides resemble in: 1 Mark

1. Electronic configuration.
2. Oxidation state.
3. Ionization energy.
4. Formation of complexes.
assertion.
assertion.
Assertion: Transition metals are good catalysts.
Reason: V2O5 or Pt is used in the preparation of H2SO4 by Con tact process.
assertion.
assertion.
Assertion: Fe3+ is more stable than Fe2+.
Reason: Fe2+ ions are easily oxidised to Fe3+ ions.
Q241. Uranium is a radioactive element but it is also a typical metal. What is not a property of uranium? 1 Mark
1. It can be hammered into shape.
2. It conducts heat.
3. It is used as a source of energy.
4. It forms covalent compounds.
Section B - 2 mark
Q242. When chromite ore FeCr2O4 is fused with NaOH in presence of air, a yellow coloured compound (A) is 2 Marks
obtained which on acidification with dilute sulphuric acid gives a compound (B). Compound (B) on
reaction with KCl forms a orange coloured crystalline compound (C).
1. Write the formulae of the compounds (A), (B) and (C).
2. Write one use of compound (C).
Q243. Why do transition elements show variable oxidation states? How is the variability in oxidation states 2 Marks
of d-block different from that of the p-block elements?
Q244. Calculate the number of unpaired electrons in the following gaseous ions: Mn3+, Cr3+, V3+ and Ti3+. 2 Marks
Which one of these is the most stable in aqueous solution?
Q245. Compare the stability of +2 oxidation state for the elements of the first transition series. 2 Marks
Q246. Name the oxometal anions of the first series of the transition metals in which the metal exhibits the 2 Marks
oxidation state equal to its group number.
Q247. For M2+/M and M3+/M2+ systems the values for some metals are as follows: 2 Marks
Cr2+/Cr - 0.9 V Cr3/Cr2+ - 0.4 V
Mn2+/Mn - 1.2 V Mn3+/Mn2+ + 1.5 V
Fe2+/Fe - 0.4 V Fe3+/Fe2+ + 0.8 V
Use this data to comment upon:

1. The stability of Fe3+ in acid solution as compared to that of Cr3+ or Mn3+.
2. The ease with which iron can be oxidised as compared to a similar process for either chromium
or manganese metal.
Q248. Compare the chemistry of actinoids with that of the lanthanoids with special reference to: 2 Marks
Atomic and ionic sizes
Q249. Note: In the following questions a statement of assertion followed by a statement of reason is given. 2 Marks
Choose the correct answer out of the following choices.
1. Both assertion and reason are true, and reason is the correct explanation of the assertion.
2. Both assertion and reason are true but reason is not the correct explanation of assertion.
3. Assertion is not true but reason is true.
4. Both assertion and reason are false.
Assertion: Cu cannot liberate hydrogen from acids.
Reason: Because it has positive electrode potential.
Q250. What may be the stable oxidation state of the transition element with the following d electron 2 Marks
configurations in the ground state of their atoms: 3d3,
3d5, 3d8 and 3d4?
Q251. Explain the following observations: 2 Marks

The enthalpies of atomisation of transition metals are quite high.
Q252. Compare the chemistry of the actinoid with that of lanthanoids with reference to: 2 Marks
Electronic configuration:
Q253. Out of Cu2Cl2 and CuCl2, which is more stable and why? 2 Marks
Q254. In the following ions: 2 Marks

Mn3+, V3+, Cr3+, Ti4+
(Atomic no. : Mn = 25, V = 23, Cr = 24, Ti = 22)
1. Which ion is most stable in an aqueous solution?
2. Which ion is the strongest oxidising agent?
3. Which ion is colourless?
4. Which ion has the highest number of unpaired electrons?
Q255. How is the variability in oxidation states of transition metals different from that of the non transition 2 Marks
metals? Illustrate with examples.
Q256. Assign reasons for the following: 2 Marks

K2[PtCl6] is a well-known compound whereas the corresponding Ni compound is not known.

The second and third rows of transition elements resemble each other much more than they
resemble the first row.
Q258. Write complete chemical equations for: 2 Marks

2−
1. Oxidation of Fe2+ by Cr2 O7 in acid medium.
2− −
2. Oxidation of S2 O3 by MnO4 in neutral aqueous medium.
Q259. On the basis of the standard electrode potential values stated for acid solution, predict whether Ti4+ 2 Marks
species may be used to oxidise FeII to FeIII.
Reaction Eo/V
TiIV + e- → Ti3+: +0.01
Fe3 + e- → Fe2+: +0.77
Q260. How would you account for the following: 2 Marks

Cobalt(II) is stable in aqueous solution but in the presence of complexing reagents it is easily oxidised.

1. Cr2+ is reducing in nature while with the same d-orbital configuration (d4) Mn3+ is an oxidising
agent.
2. In a transition series of metals, the metal which exhibits the greatest number of oxidation states
occurs in the middle of the senes.
Q262. Explain giving reason: 2 Marks

The enthalpies of atomisation of the transition metals are high.
Q263. Give reasons for the following: 2 Marks

Copper (I) has d10 configuration, while copper (II) has d9 configuration, still copper (II) is more stable in
aqueous solution than copper (I).
Q264. In what way is the electronic configuration of the transition elements different from that of the non 2 Marks
transition elements?
Q265. What are the characteristics of the transition elements and why are they called transition elements? 2 Marks
Which of the d-block elements may not be regarded as the transition elements?
Q266. Explain why does colour of KMnO4 disappear when oxalic acid is added to its solution in acidic 2 Marks
medium.
Q267. Why first ionisation enthalpy of Cr is lower than that of Zn? 2 Marks
Oxidation states.
Q269. 1. Which metal in the first transition series (3d series) exhibits +1 oxidation state most frequently 2 Marks
and why?
2. Which of the following cations are coloured in aqueous solutions and why?
Sc ,V ,Ti ,Mn2+
3+ 3+ 4+
(At. nos. Sc = 21, V = 23, Ti = 22, Mn = 25).
⊕
Q270. Why E V values for Mn, Ni and Zn are more negative than expected? 2 Marks

The enthalpies of atomisation of transition elements are high.
Q272. Compare the general characteristics of the first series of the transition metals with those of the 2 Marks
second and third series metals in the respective vertical columns. Give special emphasis on the
following points:
Oxidation states
Chemical reactivity.
Q274. When Cu2+ ion is treated with KI, a white precipitate is formed. Explain the reaction with the help of 2 Marks
chemical equation.

The transition elements have great tendency for complex formation.
Q276. Assign reasons for the following:
The E0 value for the Mn3+/Mn2+ couple is much more positive than that of Cr3+/Cr2+. 2 Marks
Q277. Transition metals can act as catalysts because these can change their oxidation state. How does Fe(III) 2 Marks
catalyse the reaction between iodide and persulphate ions?
Q278. Transition elements show high melting points. Why? 2 Marks
Q279. For the first row transition metals the values are: 2 Marks
E° V Cr Mn Fe Co Ni CU
(M2+/ -1.1 -0.9 -1.1 -0.4 -0.2 -0.2 +0.
M) 8 1 8 4 8 5 34
Explain the irregularity in the above values.
Q280. Why is the +2 oxidation state of manganese quite stable, while the same is not true for iron? [Mn = 2 Marks
25, Fe = 26].
Q281. Complete the following chemical equations: 2 Marks

1. MnO−4 (aq) + S2 O2−
3 (aq) + H2 O(l) →
2. Cr2 O7 (aq) + Fe (aq) + H+ (aq) →
2− 2+

Among the lanthanoids, Ce(III) is easily oxidised to Ce(IV).

The transition metals generally form coloured compounds.
Q284. Silver atom has completely filled d-orbitals (4d10) in its ground state yet silver is a transition element. 2 Marks
Q285. The second and third rows of transition elements resemble each other much more than they 2 Marks
resemble the first row. Explain why?
Q286. Although Zr belongs to 4d and Hf belongs to 5d transition series but it is quite difficult to separate 2 Marks
them. Why?

Transition metals have high enthalpies of atomisation.
Q288. Explain briefly how +2 state becomes more and more stable in the first half of the first row transition 2 Marks
elements with increasing atomic number?
following points:
Atomic sizes.
Q290. How would you account for the irregular variation of ionisation enthalpies (first and second) in the 2 Marks
first series of the transition elements?
Q291. State reasons for the following: 2 Marks

1. Cu (I) ion is not stable in an aqueous solution.
2. Unlike Cr3+, Mn3+, Fe3+ and the subsequent other M3+ ions of the 3d series of elements, the 4d
and the 5d series metals generally do not form stable cationic species.
Q292. Why does copper not replace hydrogen from acids? 2 Marks
Q293. Complete the following chemical reaction equations:
Cr2 O2− − + 2 Marks
7 +I +H →
MnO−4 + NO−2 + H+ →

2−
Q294. When orange solution containing Cr2 O7 ion is treated with an alkali, a yellow solution is formed and 2 Marks
when H+ ions are added to yellow solution, an orange solution is obtained. Explain why does this
happen?
Assertion: Actinoids form relatively less stable complexes as compared to lanthanoids.
Reason: Actinoids can utilise their 5f orbitals along with 6d orbitals in bonding but lanthanoids do not
use their 4f orbital for bonding.
Q296. What are inner transition elements? Decide which of the following atomic numbers are the atomic 2 Marks
numbers of the inner transition elements: 29, 59, 74, 95, 102, 104.
Assertion: The highest oxidation state of osmium is +8.
Reason: Osmium is a 5d-block element.

The atomic radii of the metals of the third (5d) series of transition elements are virtually the same as
those of the corresponding members of the second (4d) series.
Q299. Give examples and suggest reasons for the following features of the transition metal chemistry: 2 Marks
A transition metal exhibits highest oxidation state in oxides and fluorides.
Q300. Complete the following chemical reaction equations: 2 Marks

1. MnO4- (aq) + C2 O2− +
4 (aq) + H (aq) →
2. Cr2 O2− 2+ +
7 (aq) + Fe (aq) + H (aq) →

Cr2 O2− +
7 +H +I →
−
MnO−4 + NO−2 + H+ →

1. 8MnO−4+3S2O2−3+H2O→
2. Cr2O2−7+3Sn2++14H+→
Q303. Mention any three processes where transition metals act as catalysts. 2 Marks
Q304. Name the members of the lanthanoid series which exhibit +4 oxidation states and those which exhibit 2 Marks
+2 oxidation states. Try to correlate this type of behaviour with the electronic configurations of these
elements.
Q305. 2 Marks
Write chemical equations for the reactions involved in the manufacture of potassium permanganate
from pyrolusite ore.
Q306. When a brown compound of manganese: 2 Marks

1. Is treated with HCl it gives a gas
2. The gas taken in excess, reacts with NH3 to give an explosive compound
3. Identify compounds A, B and C.
Q307. Write the electronic configurations of the elements with the atomic numbers 61, 91, 101, and 109. 2 Marks
Q308. Give examples and suggest reasons for the following features of the transition metal chemistry: 2 Marks
The highest oxidation state is exhibited in oxoanions of a metal.
Q309. What is meant by ‘disproportionation’? Give two examples of disproportionation reaction in aqueous 2 Marks
solution.
Q310. Highest oxidation state of a metal exhibited in its oxide or fluoride only. 2 Marks
Q311. Reactivity of transition elements decreases almost regularly from Sc to Cu. Explain. 2 Marks

Transition metals and many of their compounds show paramagnetic behaviour.

1. Copper (I) ion is not known in aqueous solution.
2. Actinoids exhibit greater range of oxidation states than lanthanoids.
Oxidation state
Q315. Complete and balance the following chemical equations: 2 Marks

−
1. Fe2+ + MnO4 + H+ −−→

− −
2. MnO4 + H2 O + I −−→
following points:
Ionisation enthalpies.

The d1 configuration is very unstable in ions.

Fe3+ | Fe2+ redox couple has less positive electrode potential than Mn3+ | Mn2+ couple.
Q319. Account for the following: 2 Marks

Mn2O7 is acidic whereas MnO is basic.
Q320. Give examples and suggest reasons for the following features of the transition metal chemistry 2 Marks
The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.

The second and third transition series elements have almost similar atomic radii.

Transition metals and their many compounds act as good catalyst.
Q323. Explain the following observations:
1. Generally there is an increase in density of elements from titanium (Z= 22) to copper (Z=29) in 2 Marks
the first series of transition elements.
2. Transition elements and their compounds are generally found to be good catalysts in chemical
reactions.
Assertion: Cu2+ iodide is not known.
Reason: Cu2+ oxidises I– to iodine.

Scandium (Z = 21) does not exhibit variable oxidation states and yet it is regarded as a transition
element.
Q326. When an oxide of manganese (A) is fused with KOH in the presence of an oxidising agent and 2 Marks
dissolved in water, it gives a dark green solution of compound (B). Compound (B) disproportionates in
neutral or acidic solution to give purple compound (C). An alkaline solution of compound (C) oxidises
potassium iodide solution to a compound (D) and compound (A) is also formed. Identify compounds A
to D and also explain the reactions involved.

From element to element, the actinoid contraction is greater than the lanthanoid contraction.
Q328. What are interstitial compounds? Why are such compounds well known for transition metals? 2 Marks

Of the d4 species, Cr2+ is strongly reducing while manganese(III) is strongly oxidising.

Though copper has completely filled d-orbital (d10) yet it is considered as a transition metal.
Assertion: Separation of Zr and Hf is difficult.
Reason: Because Zr and Hf lie in the same group of the periodic table.
Q332. Predict which of the following will be coloured in aqueous solution? Ti3+, V3+, Cu+, Sc3+, Mn2+, Fe3+ 2 Marks
and CO2+. Give reasons for each.
Q333. Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and 2 Marks
why?
Q334. Answer the following questions: 2 Marks

What can be inferred from the magnetic moment of the complex K4[Mn(CN)6], Magnetic moment: 2.2
BM?
Q335. On the basis of lanthanoid contraction, explain the following: 2 Marks

Nature of bonding in La2O3 and Lu2O3.
Q336. Why are Mn2+ compounds more stable than Fe2+ towards oxidation to their +3 state? 2 Marks
Q337. What are the transition elements? Write two characteristics of the transition elements. 2 Marks
Q338. The halides of transition elements become more covalent with increasing oxidation state of the metal. 2 Marks
Why?
Q339. How do the oxides of transition elements in lower oxidation states differ from those in higher 3 Marks
oxidation state in the nature of metal-oxygen bonding and why?
Section C- 3 mark
Q340. Although Cr3+ and Co2+ ions have same number of unpaired electrons but the magnetic moment of 3 Marks
Cr3+ is 3.87 B.M. and that of Co2+ is 4.87 B.M. Why?
Q341. How would you account for the following situations? 3 Marks
1. The transition metals generally form coloured compounds.
2. With 3d4 configuration, Cr2+ acts as a reducing agent but Mn3+ acts as an oxidising agent.
(Atomic Numbers, Cr = 24, Mn = 25).
3. The actinoids exhibit a larger number of oxidation states than the corresponding lanthanoids.
Q342. The halides of transition elements become more covalent with increasing oxidation state of the metal. 3 Marks
Q343. A violet compound of manganese (A) decomposes on heating to liberate oxygen and compounds (B) 3 Marks
and (C) of manganese are formed. Compound (C) reacts with KOH in the presence of potassium
nitrate to give compound (B). On heating compound (C) with conc. H2SO4 and NaCl, chlorine gas is
liberated and a compound (D) of manganese along with other products is formed. Identify compounds
A to D and also explain the reactions involved.
Q344. Lanthanum, gadolinium and lutetium are extraordinarily stable in +3 oxidation state. Explain. 3 Marks
(Atomic number: La = 57, Gd = 64, Lu = 71)
Q345. 1. Write the electronic configuration of the element with atomic number 102. 3 Marks
2. What is lanthanoid contraction? What is its effect on the chemistry of the elements which follow
the lanthanoids?
Q346. Ionisation enthalpies of Ce, Pr and Nd are higher than Th, Pa and U. Why? 3 Marks
Chemical reactivity
Q348. Give reasons: 3 Marks

1. E° value for Mn3+/ Mn2+ couple is much more positive than that for Fe3+/ Fe2+.
2. Iron has higher enthalpy of atomization than that of copper.
3. Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.
Q349. The chemistry of the actinoid elements is not so smooth as that of the lanthanoids. Justify this 3 Marks
statement by giving some examples from the oxidation state of these elements.

Compare non transition and transition elements on the basis of their.
1. Variability of oxidation states.
2. Stability of oxidation states.

1. MnO−4 + C2 O2−
4 + H+ →
heated
2. KMnO4 −−−−→
3. Cr2 O2− +
4 + H2 S + H + →
Q352. E⊖ V of Cu is + 0.34V while that of Zn is – 0.76V. Explain. 3 Marks
Q353. On what basis can you say that scandium (Z = 21) is a transition element but zinc (Z = 30) is not? 3 Marks

The transition metals and many of their compounds act as good catalysts.

Cr2+ is reducing in nature while with the same d-orbital configuration (d4) Mn3+ is an oxidising agent.

The E° value for the Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+ couple or
Fe3+/Fe2+couple.
Q357. How would you account for the following? 3 Marks

1. The atomic radii of the metals of the third (5d) series of transition elements are virtually the
same as those of the corresponding members of the second (4d) series.
2. The Eo value for the Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+ couple or
Fe3+/Fe2+ couple.
3. The highest oxidation state of a metal is exhibited in its oxide or fluoride.
Q358. [Ti(H2O)]3+ is coloured while [Sc(H2O)6]3+ is colourless. 3 Marks

1. Transition metals form alloys.
2. Mn2O3 is basic whereas Mn2O7 is acidic.
3. Eu2+ is a strong reducing agent.
Q360. While filling up of electrons in the atomic orbitals, the 4s orbital is filled before the 3d orbital but 3 Marks
reverse happens during the ionisation of the atom. Explain why?
Q361. Describe the trends in the following properties of the first series of the transition elements: 3 Marks
1. Oxidation states.
2. Atomic sizes.
3. Magnetic behaviour of dipositive gaseous ions (M2+).

1. Among lanthanoids, Ln (III) compounds are predominant. However, occasionally in solutions or
in solid compounds, +2 and +4 ions are also obtained.
2. The EoM2+/M for copper is positive (0.34V). Copper is the only metal in the first series of transition
elements showing this behaviour.
3. The metallic radii of the third (5d) series of transition metals are nearly the same as those of the
corresponding members of the second series.
Q363. Indicate the steps in the preparation of: 3 Marks

K2Cr2O7 from chromite ore.

In the titration of FeSO4 with KMnO4 in the acidic medium, why is dil. H2SO4 used instead of dil. HCl?

Transition metals sometimes exhibit very low oxidation state such as +1 and 0.

1. The transition elements have high enthalpies of atomisation.
2. The transition metals and their compounds are found to be good catalysts in many processes.
Q367. 1. How would you account for the following: 3 Marks

1. Actinoid contraction is greater than lanthanoid contraction.
2. Transition metals form coloured compounds.
2. Complete the following equation:
2MnO−4 + 6H+ + 5NO−2 →

1. Many of the transition elements and their compounds can act as good catalysts.
2. The metallic radii of the third (5d) series of transition elements are virtually the same as those of
the corresponding members of the second series.
3. There is a greater range of oxidation states among the actinoids than among the lanthanoids.

1. Transition metals exhibit variable oxidation states.
2. Zr(z=40) and Hf (Z=72) have almost identical redii.
3. Transition metals and their compounds act as catalyst.
Q370. A solution of KMnO4 on reduction yields either a colourless solution or a brown precipitate or a green 3 Marks
solution depending on pH of the solution. What different stages of the reduction do these represent
and how are they carried out?

1. CuCl2 is more stable than Cu2Cl2.
2. Atomic radii of 4d and 5d series elements are nearly same.
3. Hydrochloric acid is not used in permanganate titrations.
Q372. Calculate the magnetic moment of a divalent ion in aqueous solution if its atomic number is 25. 3 Marks
Q373. What is lanthanoid contraction? What are the consequences of lanthanoid contraction? 3 Marks
Q374. Ionisation enthalpies of Ce, Pr and Nd are higher than Th, Pa and U. 3 Marks

1. The transition metals generally form coloured compounds.
2. Eo value for (Mn3+|Mn2+) is highly positive than that for (Cr3+|Cr2+) couple.
3. The chemistry of actinoids elements is not so smooth as that of the lanthanoids.
Q376. Giving a suitable example for each, explain the following: 3 Marks
1. Crystal field splitting.
2. Linkage isomerism.
3. Ambidentate ligand.

1. Many of the transition elements are known to form interstitial compounds.
2. The metallic radii of the third (5d) series of transition metals are virtually the same as those of
the corresponding group members of the second (4d) series.
3. Lanthanoids form primarily +3 ions, while the actinoids usually have higher oxidation states in
their compounds, +4 or even +6 being typical.
Q378. What are alloys? Name an important alloy which contains some of the lanthanoid metals. Mention its 3 Marks
uses.

Give reasons:
1. Among transition metals, the highest oxidation state is exhibited in oxoanions of a metal.
2. Ce4+ is used as an oxidising agent in volumetric analysis.
3. Zn2+ salts are white while Cu2+ salts are blue.
Q380. Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 3 Marks
oxidation state also. Why?
Q381. What can be inferred from the magnetic moment values of the following complex species? 3 Marks
Example Magnatic Moment (BM)
K4[Mn(CN)6] 2.2
[Fe(H2O)6]2+ 5.3
K2[MnCl4] 5.9
Q382. Indicate the steps in the preparation of: 3 Marks

KMnO4 from pyrolusite ore.

E° of Cu is +0.34 V while that of Zn is -0.76 V.
Q384. 1. E0 value for the Mn3+/Mn2+ couple is positive (+ 1.5V) whereas that of Cr3+/Cr2+ is negative (-0.4 3 Marks
V). Why?
2. Transition metals form coloured compounds. Why?

2MnO−4 + 16H+ + 5C2 O2−
4 −−−−→

MnO−4 (aq) + C2 O2− +
4 (aq) + H (aq) −
−→
following points:
Electronic configurations:

There is a gradual decrease in the atomic sizes of transition elements in a series with increasing
atomic numbers.

1. Transition elements and their compounds act as catalysts.
2. E0 value for (Mn2+|Mn) is negative whereas for (Cu2+|Cu) is positive.
3. Actinoids show irregularities in their electronic configuration.
Q389. Explain the following observations: 3 Marks

There is a close similarity in physical and chemical properties of the 4d and 5d series of the transition
elements, much more than expected on the basis of usual family relationship.
Q390. Write down the number of 3d electrons in each of the following ions: Ti2+, V2+, Cr3+, Mn2+, Fe2+, Fe3+, 3 Marks
Co2+, Ni2+ and Cu2+. Indicate how would you expect the five 3d orbitals to be occupied for these
hydrated ions (octahedral).
Q391. Identify the metal and justify your answer. 3 Marks

1. Carbonyl M (CO)5
2. MO3F
Q392. E° values of Mn, Ni and Zn are more negative than expected. 3 Marks
Q393. A green solution of potassium manganate turns purple when CO2 gas is passed through the solution. 3 Marks
Q394. Although fluorine is more electronegative than oxygen, but the ability of oxygen to stabilise higher 3 Marks
oxidation states exceeds that of fluorine. Why?
Q395. Match the properties given in Column I with the metals given in Column II. 3 Marks
Column II (Me
Column I (Property)
tal)
An element which can show +8 oxidation stat
(i) (a) Mn
e
3d block element that can show upto +7 oxid
(ii) (b)Cr
ation state
(ii
3d block element with highest melting point (c) Os
i)
(d)Fe
Q396. To what extent do the electronic configurations decide the stability of oxidation states in the first 3 Marks
series of the transition elements? Illustrate your answer with examples.
Q397. When a chromite ore (A) is fused with sodium carbonate in free excess of air and the product is 3 Marks
dissolved in water, a yellow solution of compound (B) is obtained. After treatment of this yellow
solution with sulphuric acid,compound (C) can be crystallised from the solution. When compound (C)
is treated with KCl, orange crystals of compound (D) crystallise out. Identify A to D and also explain the
reactions.
Q398. Give reasons: 3 Marks

1. Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest
oxidation state of +4.
2. Transition metals show variable oxidation states.
3. Actinoids show irregularities in their electronic configurations.

Cr2 O2−
7 (aq)
2+ +
+ Fe (aq) + H (aq) −−→
Q400. Colour of KMnO4 disappears when oxalic acid is added to its solution in acidic medium. 3 Marks
Section D - 4 marks
Q401. A mixed oxide of iron and chromium, FeOCr2O3 is fused with sodium carbonate in the presence of air 4 Marks
to form a yellow coloured compound (A). On acidification the compound (A) forms an orange coloured
compound (B), which is a strong oxidising agent.
1. Identify the compounds (A) and (B).
2. Write balanced chemical equation for each step.
Q402. Identify A to E and also explain the reactions involved. 4 Marks
Q403. Match the properties given in Column I with the metals given in Column II. 4 Marks
Column II (Me
Column I (Property)
tal)
Element with highest second ionisation
(i) (a) Co
enthalpy
Element with highest third ionisation e
(ii) (b)Cr
nthalpy
(ii
M in M (CO)6 is (c) Cu
i)
(i Element with highest heat of atomisati
(d)Zn
v) on
(e)Ni

For M2+/M and M3+/M2+ systems, E° values for some metals are as follows:
Cr2+/Cr = - 0.9 V Cr3+/Cr2+ = - 0.4 V
Mn2+/Mn = 0 1.2 V Mn3+/Mn2+ = +1.5 V
Fe2+/Fe = - 0.4 V Fe3+/Fe2+ = +0.8 V
Use this data to comment upon:

1. The stability of Fe3+ in acid solution as compared to that of Cr3+ and Mn3+.
2. The ease with which iron can be oxidised as compared to the similar process for either Cr or Mn
metals.
Q405. Match the statements given in Column I with the oxidation states given in Column II. 4 Marks
Column I Column II
(i) Oxidation state of Mn in MnO2 is (a) +2
(ii) Most stable oxidation state of Mn is (b) +3
(iii) Most stable oxidation state of Mn in oxides is (c) +4
(iv) Characteristic oxidation state of lanthanoids is (d) +5
(e) +7

Draw the structures of chromate and dichromate ions.

Write balanced equations to represent what happens when.
1. Cu2+ is treated with KI.
2. Acidified potassium dichromate solution is reacted with iron (II) solution. (ionic equation).

1. The figure given alongside illustrates the first ionization enthalpies of first, second and third
series of transition elements. Answer the question that follows:
2. Which series amongst the first, second and third series of transition elements have the highest
first ionization enthalpy and why?
3. Separation of lanthanoid elements is difficult. Explain.
4. Sm2+, Eu2+ and Yb2+ ions in solutions are good reducing agents but an aqueous solution of Ce4+ is
a good oxidising agent. Why?
Section E- 5 marks
Q409. 1. A blackish brown coloured solid ‘A’ when fused with alkali metal hydroxides in presence of air, 5 Marks
produces a dark green coloured compound ‘B’, which on electrolytic oxidation in alkaline
medium gives a dark purple coloured compound C. Identify A, B and C and write the reactions
involved.
2. What happens when an acidic solution of the green compound (B) is allowed to stand for some
time? Give the equation involved. What is this type of reaction called?
Q410. Comment on the statement that elements of the first transition series possess many properties
different from those of heavier transition elements. 5 Marks
Q411. 1. Account for the following: 5 Marks

1. Mn2O7 is acidic whereas MnO is basic.
2. Though copper has completely filled d-orbital (d10) yet it is considered as a transition metal.
3. Actinoids show wide range of oxidation states.
2. Write the preparation of potassium permanganate from pyrolusite ore (MnO2).
Q412. 1. 5 Marks
1. How is the variability in oxidation states of transition metals different from that of the p-block
elements?
2. Out of Cu+ and Cu2+, which ion is unstable in aqueous solution and why?
3. Orange colour of Cr2O72– ion changes to yellow when treated with an alkali. Why?
2. Chemistry of actinoids is complicated as compared to lanthanoids. Give two reasons.

2. Zn, Cd and Hg are soft metals.
3. Eo value for the Mn3+/Mn2+ couple is highly
positive (+ 1·57 V) as compared to Cr3+/Cr2+.
2. Write one similarity and one difference between the chemistry of lanthanoid and actinoid
elements.
Q414. 1. Describe the general trends in the following properties of the first series of the transition 5 Marks
elements:
1. Stability of +2 oxidation state.
2. Formation of oxometal ions.
2. Assign reason for each of the following:
1. Transition elements exhibit variable oxidation states.
2. Transition metal ions are usually coloured.

1. Copper (I) compounds are white whereas Copper (II) compounds are coloured.
2. Chromates change their colour when kept in an acidic solution.
3. Zn, Cd, Hg are considered as d-block elements but not as transition elements.
2. Calculate the spin-only moment of Co2+ (Z = 27) by writing the electronic configuration of Co and
Co2+.
Q416. 1. Give three points of difference between lanthanoids and actinoids. 5 Marks
2. Give reason and select one atom/ion which will exhibit asked property:
1. Sc3+ or Cr3+ (Exhibit diamagnetic behaviour).
2. Cr or Cu (High melting and boiling point).

Is the variability in oxidation number of transition elements different from that of non–transition
elements? Illustrate with examples.

1. Transition metals form large number of complex compounds.
2. The lowest oxide of transition metal is basic whereas the highest oxide is amphoteric or acidic.
3. E° value for the Mn3+/Mn2+ couple is highly positive (+1.57 V) as compare to Cr3+/Cr2+. 56/1/1 9.
2. Write one similarity and one difference between the chemistry of lanthanoid and actinoid
elements.

Give reasons:
1. d-block elements exhibit more oxidation states than f-block elements.
2. Orange solution of potassium dichromate turns yellow on adding sodium hydroxide to it.
3. Zirconium (Z = 40) and Hafnium (Z = 72) have almost similar atomic radii.

Give chemical reactions for the following observations:
1. Potassium permanganate is a good oxidising agent in basic medium.
2. Inter convertibility of chromate ion and dichromate ion in aqueous solution depends upon pH of
the solution.
3. Potassium permanganate is thermally unstable at 513K.

1. Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the
highest oxidation state of +4.
2. Cr2+ is a strong reducing agent.
3. Cu2+ salts are coloured while Zn2+ salts are white.
2. Complete the following equations:
Δ
1. 2MnO2 + 4KOH + O2 → −
2−
2. Cr2 O7 + 14H+ + 6I− →.
Q422. Describe the preparation of potassium permanganate. How does the acidified permanganate solution 5 Marks
react with (i) iron(II) ions (ii) SO2 and (iii) oxalic acid? Write the ionic equations for the reactions.

Assign reasons for the following:
1. In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomisation of Zn is the lowest.
2. Zr and Hf have almost identical radii.
4. The E°M2+/M value for copper is positive (+0.34 V).

Describe the preparation of potassium permanganate from pyrolusite ore. Write balanced chemical
equation for one reaction to show the oxidizing nature of potassium permanganate.
Q425. 1. Why do transition elements show variable oxidation states? 5 Marks

1. Name the element showing maximum number of oxidation states among the first series of
transition metals form Sc (Z=21) to Zn (Z=30).
2. Name the element which shows only +3 oxidation state.
2. What is lanthanoid contraction? Name an important alloy which contains some of the
lanthanoid metals.

1. The enthalpies of atomisation of transition elements are high.
2. The transition metals and many of their compounds act as good catalyst.
3. From element to element the actinoid contraction is greater than the lanthanoid contraction.
4. The E0 value for the Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+.
5. Scandium (Z = 21) does not exhibit variable oxidation states and yet it is regarded as a transition
element.
Q427. The elements of 3d transition series are given as: 5 Marks

Sc Ti V Cr Mn Fe Co Ni Cu Zn.
Answer the following:
1. Write the element which shows maximum number of oxidation states. Give reason.
2. Which element has the highest m.p?
3. Which element shows only + 3 oxidation state?
4. Which element is a strong oxidizing agent in + 3 oxidation state and why?
Q428. 5 Marks
1. Name the element of 3d transition series which shows maximum number of oxidation states.
Why does it show so?
2. which transition metal of 3d series has positive Eo(M2+/M) value and why?
3. Out of Cr3+ and Mn3+, which is a stronger oxidizing agent and why?
4. Name a member of the lanthanoid series which is well known to exhibit +2 oxidation state.
MnO-4+8H++5e-→

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Test / Exam Name: Test Standard: 12th Science Subject: Chemistry

Q2. Why do Zr and Hf exhibit almost similar properties? 1 Mark

Q3. ____________ is used in gas lamp material. 1 Mark

Q4. Which of the following species do not exist? 1 Mark

Q5. On the basis of lanthanoid contraction, explain the following: 1 Mark

Q6. Why are lanthanoids called f-block elements? 1 Mark

Q8. Write down the electronic configuration of: 1 Mark

Q9. Which of the following is paramagnetic as well as coloured ion? 1 Mark

Q10. hich of the following statement is not correct? 1 Mark

Q14. Fuel used in nuclear power plants is: 1 Mark

Q15. What would be magnetic moment of Gd+3 (Z = 64)? 1 Mark

Q20. Smallest ionic radius is: 1 Mark

Q21. Which is the most common oxidation state of lanthanoids? 1 Mark

Q23. The tendency towards complex formation is maximum in: 1 Mark

Q26. What is the maximum oxidation state shown by actinoids? 1 Mark

Q28. Identify a 'Chemical twin' among the followings. 1 Mark

Q29. How would you account for the following: 1 Mark

Q31. Transition metals show paramagnetism due to: 1 Mark

Q36. The Lanthanoid contraction refers to: 1 Mark

Q37. Colour of Fe2+ ions is: 1 Mark

Q39. Variable valency of transition elements is on account of: 1 Mark

Q41. Fe has higher melting point than Cu. Why? 1 Mark

Q47. Actinoids belongs to following type of elements: 1 Mark

Q49. The Lanthanoids contraction relates to: 1 Mark

Q54. The first and last elements of actinides are: 1 Mark

Q55. Account for the following: 1 Mark

Q57. Identify the metal that forms colourless compounds. 1 Mark

Q58. Chemically Zinc group elements closely resemble ______. 1 Mark

Q60. Which of the following statements is not correct? 1 Mark

Q64. Which of the following is not an actinide? 1 Mark

Q69. Choose the correct statement. 1 Mark

Q75. Variable valency is characteristic of: 1 Mark

Q77. On the basis of lanthanoid contraction, explain the following: 1 Mark

Q79. IP values of Sc, Y and La are in the order: 1 Mark

Q80. Which of the following is not an interstitial compound? 1 Mark

Q81. Write down the electronic configuration of: 1 Mark

Q85. Which of the following elements belongs to actinide series? 1 Mark

Q86. Write down the electronic configuration of: 1 Mark

Q87. The separation of Lanthanides by ion exchange method is based on: 1 Mark

Q90. Lanthanoid contraction occurs because: 1 Mark

Q91. Write any one use of pyrophoric alloys. 1 Mark

Q92. How many electron present in penultimate shell of d-block element? 1 Mark

Q98. The adsorption of hydrogen by platinum black is called: 1 Mark

Q99. What is meant by 'lanthanoid contraction'? 1 Mark

Q100. Metals are usually used as catalysts belong to: 1 Mark

Q101. The following belongs to d-block but it is not transition element: 1 Mark

Q102. The transition metal used in X-rays tube is: 1 Mark

Q106. Write down the electronic configuration of: 1 Mark

Q111. D-block elements form complexes because they have: 1 Mark

Q113. Raney nickel, which is used as a catalyst, is obtained: 1 Mark

Q114. Which of the following is ferromagnetic. 1 Mark

Q119. Which one is false in the following statement: 1 Mark

Q120. Which lanthanide compound is used as a pigment? 1 Mark

Q123. Write down the electronic configuration of: 1 Mark

Q125. The following is not a noble metal: 1 Mark

Q126. Why does a transition series contain 10 elements? 1 Mark

Q128. Transition metals are often paramagnetic owing to: 1 Mark

Q130. Gallium is in __________ state at room temperature. 1 Mark

Q138. Magnetic moment of diamagnetic substance in Bohr Magnetons is: 1 Mark

Q142. The transition metals are mostly: 1 Mark

Q144. Why are transition elements so named? 1 Mark

Q146. Which of the following is diamagnetic ion? 1 Mark

Q158. The color of CoCl3.5NH3.H2O is: 1 Mark