192504 1712150473 247201057 kt t Apt soy

Badal

Nair whip

white
ay
forma

Lilacwhom gelatinous peat

Ppt

ain't

NaA02

SodiumAluminate

whitepeddlers

their aqueoussolution to their respe live

tons

 firstfollowedbyanions

chelatingligands

É

o

Closed
sing typestructure

y
M hing chelateling
gt

o ligands chelatingligands
chelation
Phenomenon Priess

chelate

complex
Some multidentateligands when band with CMA

form like structure whish are known as

they

chelates ring
theseligands are chelatingligands and the

Phenomenon is known as chelation

th
Ex
Cha Nka cha
ng
In

Nn Inna cha

T

chelatingligand

I NicNazig
when compared to abovestructure
IsThis is lessstable
Chelates are relatively more stable thanthe complexes
of some metal withMonodendateligands
 É'm
It
a chelation
stability s 4
Hole is the number
greater win be
of chelaterings
formed
the stability of complexformed 3 a gt
Monodantate 31
Bidentate
Ex
a Porphyrincomplex
Fha
1
CA

Ii me D boo2 A forms y

Eat
B
Ising
stability of rings it is
3rem a 4menbasmembebmamb Tmembered Hemoglobin Ride ftp.gatan
E E6 EE
rings chlorophyll
Vitamin B12
My
M
2,7g
Co
Due to steam membered is more in
stable angle ring Q Determine the coordinationnumber of CMA
Following complexes t
T Ic I N as well on S can behave on
Icoenoyl tenge 2 I Fe 10753 Co19197
downatom
C N I 8 C N 5 CN G
an

In M
CO
e N
Hg Sen
4
I CO CEDTal
c N 6
The ligands which form three or 4 memb t
can not undergo chelation and win a it as
lings
Morodertate ligands 1120473
donoralum is presentalso it is not
If tan
Consider as bidentate ligand if its not forming
CN 6
monodendate
5 membling it is considered onlyas
ligand
chelates whichinvolves conjugatedsystem latenate
double and singleband are morestable due to
debialisation

É
I O
Ambidentateligands
Having more team
one of donor site is
one donorsite but at a timeonly
utilised for donation are
ch caned ambidendate ligand
ch
due to chelation and First letter of the formulaof ligand denotes
Resonant it is extra thedonor atom
stable
Itis Ex Ligand Donoralum
it do not
cyanide fin y e
member dei
74
showchelation g
o c m N
Isocyanide Ni I
Althoughcog forms a gamem
but it art as cyanate loin I o
ring may in some cases
bidentateligand Is cyanate N 107 N
 s
Thiocyanate Cscw
Isothiocyanate CN's N
V Nitrito Not Nitro N
O Nite it Cono 7 Nitrite Imp
Fexidentateligands
Ligands which show Variable denticity ale called
flexidendateligands
All can form fourmember with CMA
Can ligands act as a flexidentatesing
generally ligands
Ex 34 3 e
IM
o c
e N t
Eidendatelig

o
c Co Inn 103 C
O
I b Montodendate
o M
ligand
Five or 6 mumbling cannot acts as a

Flexidentate ligand
Sele't the species which can arts as a flexidentah
Q
ligands
No2 No 5035 5042 CNJSentCaztoo
92042
Solution
N
IM
O Flex
NIEM Fuxi
to
of
M
Flex I o
y flexi
o yo
CN Unidendateligand Sin Ambi

cha c
Flexi

o o
Imchelate
VOTE EDTA art as Flexidendateligand and its
a
denticitydepends on the phmedium

C112
cos 42 112 Cor
Chp
f n
É
em oo
T oc
th
ED Tat Dentility 6
I pH Andie
if htimie
Coneincrease
I4ffe ligand
the CMA
donate the elenteenPaid
and accepts it from the
election
o
cnn
KED TA Dentcity 5 in their vacant d orbitals
Ex pH Pfs Pp's l below 2nd periodl while
naming
these ligand re prefixis used
x n cand hepticityof ligand
t d
C tha
Ho atoms involved in
of
donations
Mama PHz camp I e
n
1 i ddonor n
21
2 IT donor and IT acceptorligands t Ge down
y

If
Benzene oh 7
26

m
I theecloudbeam
theligand isdevoted C N Not debiand
tothe CMA
Ex Liese's salt Iet cizleany
orbitan
µÉÉÉÉd CABMO 545 Cyclopentadienyl

a P'E l site candy G donor

or T diner

I 10 are accepted in th Iii E

isms

Freeethylene a
C C B L inelases n
I due to decreases in
clip planar B o The I I B
in thiscomplex is I as
greater than free Ex All 3173
Cary Bondlength
Cly
E
o donor
i a
ÉÉi
tominimise it undergoesgo
c.mn
plane of Pt113and Ex Ferrocene
n it will becomenon
Planet

I Here the ligand has filled t obitals

f e diner
Cor Ielection aloud which overlaps with ye
Vasant d orbital at bad
of CMA giving
I These ligand also accept
elections from
CMA in their TR orbitals IABMol
X
 Oxidationnumber EffectiveAtomicnumber
The Cma in The total number of electrons in the Crea after
charge head be virtual
on
a complex d
s'd
formation
of complex
Ex Icoentgy y3t
Ex k co pun
yep so 3 t 6 2 36
27

EAN Z O S 2X C N
to 21 11 ti l 21 1
31 3 C N 6 Ex ka FITinto
E AN 25 2 6 2 36
In Ks Fe lent The following rules are to be followed while
Atomin number
37 61 17 0 calculating effective
X 3 3 e enfeudonol
Ex Ni lo Ni O R T 95175 Ex

Ageing tc ages83333
Ag ti
Ex

Ag
th É es EI dietoninjugation

t 9 5
a Qe donor
4 team get Ennio
2 u Nhs 327 Cu 2 Ex 2
3 co CI Noa Nh I Nos Co 3 IT 131755 0 93175
en Chatham
Fe IEITA Fe 3 Te amor
becoz of
cha
5 EFE.dz sngnqmIIIEFe t1 conjugation

Fe Iggy
E A N 26 3 2 6 E 35
Echizen if Ennio For ITdonors IT electronsinvolved in donation ale

FFCNHzly Item52 Considered

Q
1 Ferko
Fan 0 6 2 36
24
2 IFecent
26 2 2 1 36

3 Facing 73
26 372 6 E 35

4 I CNN JC's 33
24 3 2 6
5 Ict CioHolz
24 0 2 6 36
 t 27 Oxidising Reducingnature and polymerisation
Ni can Idient lent Tendency of metal carbonyls
28 38
2 2 1
Complex jtsffginsbendmark
37
za
Fn 1075

IIe
Teimerise
21 0 2 5 36 Reducing
ofidising
gifting agent
Icu can 433
36 Ex TMT Cal is it a o A or R A
29 1 4 2
25 to 2 6 37
Fecit Csiii
26 2 t 2 6 36

Tico 5151 Ct 15515 mucus Reducingagent

22 4 2 2 2 6 34 Ex v1 lol
tie I b

I SIGDWIIIC'S EAN RULE

ggÉ y
Thecomplexes inwhich the Ean of He 2
he cma equals the atomicnumber I
are found Ne lo
of the next noble gas
more stable
o be relatively Ar 18
The EAN dulia generally
3d 31 3 To bind metal metal band m
foundto be notvalid ku
polynuclear carbonyls
in case
of mostof the
complexes but in case of 49 Xe 54 peltedAlludingto EAN
etat carbonyls this sale is sd Rn 86 Ey macro 22
found to be valid in almost 1 Actual EAN 2 25 10 2 71
mmmm
Applications of EANRule
1
Monomer Mn 1075
Diff 72 70
Tiffeince
bind the value of X lotband
Fe soy

Fe lol 36 26 0 73C X2 o
ie
91 5
I l
co

Fellas co
Mn Mn Co
Cr f lol find the Vallee of 21 J
According to EAN lull
to 36
or value is equal y Ico
E Co2 lol g Antral EAN 54776 to
Cr f tolie 36 24 0 t c 2
Diff Expected EAN ActualEAN
6 72 70 2
to
Motivationcomplex only me central co do
atom co Co
Poly trailer Complex t more then one
lentealatom CO
1 Arnie metal carbonyls exhibit strong a
tendency to attain Sigdwille Ean values
and therefore the number co molecules
t
attached in a mononuclear of
complexes can be
calculated
 I Fez Ck Expected EAN 52718 5 Fe C1075 ICO CN's7421237
Co C1015 Tetaammine di badge
Diff ActualEAN ExpectedEAN
e
T2 70 2
No special suffix is used
Co
I to Ex T Felin
Compleich anion thenspecial suffix ate
co d Fe 10 is ifund
Heracyanidoferrate
g
co Ex NielsCPPh372
dichloride bis triphenylphosphine nickel CI

IUPAC NOMENCLATURE OF COORDINATIONCOMPND Ex I lo Cla Inna en Channa123T

dichloride bis Cethylenediamine cobalt till
ofComplex
Like Simplesalts in namingwhether compound
cationic is named
part find it is simpleor
g Negativeoeganinligandshavingnot suffix Y
Compline followed by namingofanionic part of hydrocarbonorigins
are replaced
Nafi Suffix
first cation name followedbyanion by o
list Cs eg Hj 7 Cytopentadienge

É
Calia name simply
the complexion is a cation the metal
u
7 If
Agfacials
Nh3 2 ten cation Name firstcomplex named Sami as the element
and
Ex Co in a completecation is called cobalt
In of Completion name ofligands Pt is called Platinum
ale naming
written first in alphabet in orderand
with in oxidation state in Roman numeral in
the parentheses after the name of metal Telvaamminedinhenidoplatinum 114
g If the compere ion is an anion the
man
Ex Cognatic Éteini of of the metal ends with the suffix
ate
9 stuperoxido
Ex I Fa long 4
Ammine bromide chloride cyanide Iodide Hexacyanido ferrate lil

is
ludo metals
used for Some
super Latin names are
Ex Pt Inn Bren C Ch Nz Metal Name
AmmineBromidechloridemethyl iron f fel Ferrate
had 1Pbl Plumbate
3 If thecomplexcompound lontains more than Silver lag argentate
one same type of ligands then prefix s tannate
bi tri tetra ate are used fines aulate
Ex I Ni c 2 1120412 gold can Kalium
potassium 1k

I Feennzly c 2
EX Ini can e Teta ammine dichloride Ison ill
ly 123 Cly is named
The neutral complete molecule
9similar
Jetta diehard to that of complain cation
ICV 113CP473
Thou dnot be
alphabeticalorder
larsideerd as trishinido this I pyridinechromium1171
A o should be followed onlyherligands Ex KI Itg Ic I potassiumtelvatodido
mellulate in
4 If the etc
name
thenligand
already contains
of bis this tetrakis are
bi tri K I Fel 1463 Potassiumhexagon
used t Ferrata I hit
Ex I co 112 Cnn inatnitis a pay
go.mg
dichlnidobrs thyeenediam.ne
T Pt112Cnn 12 Diamminedinhlorido
platinumCill
Cnn 158 eternal s Is
x
coenalitil Hexaammineggind
in Symmetrical
x In oxy potassiumtrioxalatteidate t if thetemples
ypentammineeheomium pin y hydroxidepentamm
Chromium lint thloride
x CoBrConor lengthdiamine
Beomidobis ethylene
nitrite cobalt 21 1h hydroxidebis pentamminechromium
t
chloride
Coal
the name of one sid
X I lo I Nhs 5 so42 Pentammineiodide We could also have written
cobalt in Sulphate of the bridge and then side ofbridge
the name
thebridge
and then the other of
Flo thiammineteiniteo ligand
line this
No21
City Cobalt 1117
Ir CNN315 C 75
INN315 IV GH
x I Fe Fg Hexafluoridefellate i'll pentaamminechromium fine pe hydroxidepent
amminechromiumCint Chloride
X Naz toCNozl Sodiumhexaniteocoballate by
Cin
tg
x I Itzlen72J soy
dichloride bis ethylene
diamine cobalttint
Ex Nasty
to cnn ly pogy

sulphate
201 6 SC 3
221 2 4
É Telvammine
ly PE ly Platinum In Tetra
PFCNa
x nit lo bi s ftetraammine cobalt
M hydroxide p C in sulphate
Chloridoptalinate lil

Pt Tatraamminecobalttint M hydroxide te nitho

x I Cla NH3 y FayJ Tet ammine Tetaammine cobalt tiny sulphate
dichanasplatinum III TetrachlorideMalinak
firmlyto
Ex Cent2
0472
x Icu firmly PE ly Telvammine
Copperin Tetrachlorideplatinate I Tetraumminacobart int M cyanide m hydroxide
biscethylenediamine cobalt 1 Sulphate
n I Écrnz7 Eels I Hexammine
Coal
cobalt in pentachloridocuplateCI Tetra amminecobalt
when X is the flCIIIcyanide te hydwnido
For ITdonorligands m is used bis c diamine
ethylene
cobalt CIII Sulphate
hepticity similar bridgingligand o un more than
GI's
11 If etc
co Colz IT once we use di p trip
cobalt I
23acyltrilabiny Ex

Felt 1511512
cnn.ly YIIPce 2 0412
bis
Il en II Tela amminecobalt tint di M hydroxide
N brs cyclopentadienyl
Cethylenediaminecobalt fail sulphate
Con
0 In case bridgingcomplex compounds M
of for the bridgingligand
prefix is used Di M hydroxideTetraamminecobaltcall bis
on bothsides of the bridgeis I ethylenediamine cobalt tin sulphate
a
If the Situation
Symmetrical then we can write the name of
remainingcompleteat one place
Ea Kol Fe MIÉÉIjo Ily
EX CNN 1 Cr OH er N17375 C's di gu hydroxide bis Pentaagua Iron il
Chenidr
BONDING IN TRANSITION METAL COMPLEXES CO C13 4 N h z

l Werner's Coordination theory

I Nh3

I
coordinationchemistry
Alfred weiner fatherof I
ji
j
Twovalencies are satisfied
CMA those are called
by
P and 20 valencies
i valency 2 valency
Represent i n
IS fTe
Represents
Oxidationstate
Ext Coc skol
coordination
sphere D 2 ggonggte.im
Ionisable pagionisable of
Non directional Diendranal pity
low Polyhad

weened introduced the squarebrailieb

valencyenclose
bynegativein Igt
Responsiblefor
h Ey to thoseatoms
Coordination complies and
makingup
which are
the
therebore

bydottedline mmmm26 Gsgm of complex eretz f 20

when
Colinlife'sqtreated
complex a
Ex with Agnos produied 787 28

i
NH3
NH3
gtatmeeding
polyhedra
satisfied
by
both ve and
wanted mum
an
roading to

Cruz
weenie theory E Mol wt

6h20 t Agnos
of the

Ag
26.65

II
represented

ofAges
Nnp 1h3 3 p
co
IV
if C 12.1120
a 42075
in
pi
e
NH3
i iz Gnh Coelz 5N 173 Col's 4 Nhs
131
In 1893 weaner was the first to attempt to y 21
coordination compound His
bonding in
explainwas
theory built on the bars of chemicalleaction Colly 3mn
and there was no moderninstruments whichcould 4
ele the annal stenture of a complex line Q Increasing order of electrical
conductivity
X diffraction today
lay metal in
According to werner a a completes
Festina conductivity 2 no of ions changed
ions
I Primaryvalency
the the MA I copy Gnn Co 311 Chai't
This corresponds to o s
of ions 4
This is also called as the prinsiple ionisable
no
of charge 73
Oh ionic valency and is non dierational in
ITffin satisfied by the negativeions and its II Co Nhs 9 112 7 to INK3151137
attachment with the central metal ion is shownby 211
no ions 3
dotted lines of
2 secondaryvalency charge t2
This corresponds to the coordinationnumber I Eto CNaziy112 11 I 10 IN1374112
ofCMA
Secondary valency is dolentional
in nature no of ions 2
t
Secondary valency is satisfied
and by
negative
its attachment change tf
Positive and neutral ligands solid lines
to the central metal atom is shown by
 valine band theory I UBT
I Co lizCnh Nanimisable 1 The ema provides required numberof
L a Electricalconductivity variant hybridised orbital alcoeding to its
order Coordination number
Ex ntginmpte.no
O Colligativeproperties etienne t
dilute solution which are
dependent onof no ofparticles in solution
properties
Élan1,34
Thick V p and f p 21 The orbital
dm
4nF ligand containing
withofthe Vasant d
hybridise
pain overlap
orbitals of CMA forming a coordinate bond

noof ins 31 The tan

geometry and hybridisationof a
B P and osmoticpressure compline be its e N
preditted from
B ponder L Ex f 3

it c
F p order S Co covalent innatm
dietetic
7 moles of Age precipitated Na
Square planar contraproper
Geometypisonan
Arrange the following in increasingorderof 1h
electrical conductivity tetrahedral
KI M3125
214
B renigbino my guyup
C Krenn 7 No Cle No216
C N Geometry Hybridisation
3 Mg CoCNN IN0275
g Linear Sp
E c order be at d e e 2
3 Trigonal sp
ktt al
plan
97 K Co1107312 no
ly
socamping
3
No
of inschfgest Tetrahedral St
b No dissociation 4
squareplan dsp2
Cl Tar Inn 3 Nos Co 1 021632 bi SP'd
5 Trigonal pyramidal
3 events Nol t't f ontahadear sp'd
2 lo Noa the type orbital used
Sims Change tb
on the basis of of
daringIbg the.net
D
Mg colonelenoans Mgtat a inn ib.FTcobmepu1No21
52 Octahedralgeometry C N 6
Charge 72
no of rang 2

t
MEIIII I IÉÉ
É
 inner nd in orbital aimed
asps
The complain formed is called as inner orbital themed 2
complete
set
effffiden pets effectivenuclear
are used The charge is highs
Sp 312 Guteed orbital
complene formed is called as outer orbital donati tending i
complex Nn higher
strongfieldligands
Streng of the bar
gads I decided is
by strong
weak find ligand CS.FI
elastins
String fieldligand In presence of stengfieldligands
I High Lewisbase get paired
y character Some importantpoints
µ To the CMA if the ligand but art as a
asf Sfl
formsstronger coordinate
pin
generally
as a
1027
bend and donation tendency WF for ertz Mnt Fetz and
but at's
of e is higher 2 Germany o donor act as WFL
SFL for Cost and int
ant as WFL but for Nit
Weak field ligand's base character 3 F
It Low Lewis generally
it act as a S FL
To the CMA if the ligand and
µ
heal coordinatebond All ligands are S FL for 4d
foe donation
s ee
e is 54 Series nation Reason
of
I Iggy
and tendency
lower due to
intraction
É it i Halogendenn
1 Coordinationnumber 4
on the basis of strength ligandsmay be
classified as field ligands Iwf4
iit
i wean
Is Fil
Ex Nisly 25 with
steng field ligands 3984s 2
but generalligands II
are decidedby CFT
Although Sfl and Wfl in
crystal field theory
Lewis bare charanter are
having greaterThe

It jj
fi donation tendency to s
gunny
hi order Nopairing of
a weak find ligand
The actualorder is
C Y N S o F Y I S Br I orbitals are formed
Itna Bura tha Kaala Shama Nai Faile
hath Aise us ke paan Bhasa to Jaise
Naveen Chandru Saksena Aaltan Aman Pande
in orono canaanite
range
chalillae Kaat haha hai donor Zeometey
Fiji Tetrahedral
logger 3
Hybridisation Sp

On L Ch Wo C 12042
1 I I Due to preseneof 2
iii H2o Palamegnetin in nature
V1 S L ED TA L NH3 Py ten Dipy f

Fitwgendonor
 5
M Fantz Boy I Pt Nhs 292
M A BM If both Sfl and w fl are presents it is
decided based on the number Sfl and Wf
Ini f in of
more no Sfl's are present then
4 present If
wit equalnumb
It Sfl and Wfl in
If
meat
are

win ocing It is a sd series an ligands will

CN S F L pairing behave as a
strong field ligands
Nith
tht Ptt 548

Geometry Squareplanar
dsp
ftp.t T
2
Tybridisation dsp
in nature due to absence of
Diamagnetic peta
unpaired e
TianaHybridisation
dspd
U O pata s geometry

I Zn t
Nh374J 6 I Cuennzly
ant's Tifft I 39104s t
If If cut2 399
t sp 3 sp
Tybridisalia
I tetrahedral
Geometry
Ji magnet in nature M o

IicolyT
sp3 Tetrahedral
Paramagnet due
to one

11 1 I it has bossed
imma
that meant

Co Sfl 147511
pairingof
elections takes dstp2

Free F IF
Sp Hybridisation
tetrahedral
t
due tohigh Left of
Cat
this eleition is
not easy to remove
tamed a spa squarepland
geometry g the valence e and this is also the
season for Axitation of e
flam 3d to gp
 outer orbital complete cop highspin
to
complete v7 Spin free complex
dsp Éecan
sq DianagnTowgpropu 21
as
Mo sp Paramagnets
FetIII Is Dal will be
stringfieldligand
e
CN
chighftiping Paired

do
sp Diamagnet
in
p
C Inner
thing d2sp3
orbital complex
octahedral
or low

Sps Spin compline in spin paired complete

49 M BBM
Ste dsp
3
Fec in
Fett 3dt
Mn
Bry72
Mn 3954s a
Than be paired
Mt2 3d 5
HIIIII
TITI
If d2 p
low spin complex spinpairedcomplexlost
octahedral

Tetrahedral Inner orbital Complain

Sp3
4 I co cent g 4
Paramagnetic
I Complexes with Coordination no 6 Co 397452
Geometry octahedral lost sat

asf Spada
TIFF IF
Fetoys esme
pared
If 391452 ÉI III 1

Fett 7 3ds 2
Sp Hybridisation
II octahedral Paramagnetic
tf tf 4P 5
t
Ni INnzl
2
F m a weak field II
Ni 398
7
ligand
Danamagnetism y Hybridisation
hybrid sp3d2 octahedral
Diamagnetic
4
Sp3d2
octahedron
5511 5 BM
geometry
 Bt
Ter Chao g Mn 345452
Cr
cut
3454s 1
3d HIIIII I
2
sp
paramagnetic highspincomplex

no and d orbital is
Feta 3dB
pairing sp392 paramagnet
empty it is used for
Tybridisation
ybridisation d2sp3
Fuggy
Paramagnetism MITI sp'd paramagnetic
her orbital and Highspincomplex booze
an
it is considered as I f 2 then felt
wi
of in end state
poi If
be diamagnetic which is wrong
er Inns 3t

MidÉF
er wrong
donors art as Sfl
is f For cot all oxygen
No pairing till d Coi 397452
i

III II MIX
a d's
it is paramagnetic Hybridisation p
in nature
t
SFL 7 d2sp3 Diamagnetic
5,5
44 Wfl 10 it g
2

sp3 d2 will ait

with with high Ziff F
10
as S f l
48,9 sp342 Ni 398452

YÉh I a
hybidisation win be d
Hybridisation sp
Sp392 onlytelespiative Diamagnetism
of the nature ligandof Coordination number 5
27
I Mn M3 Fe Inn 1,321 sp3d Get dsp3
Ex Fe 1075
I 10 Nh3 C N 5
wf in case of Fe 3d b 4,2
it will acts as a

Matz cut2 Fet not2 et 1

EFFIELITE
 É547652
É aÉÉt
sasa

Iet 3 546
eybridisation dsp ftp.go midal 420 SfL

ay gasps Diamagnetic
orbital
C inner
T Ni Cini B Nita 348 nhgggtsg.ae a wean field
Vit 398 Myuffa sp'd 2 diamagnetic
outer orbital
cats 393
tIIepmnn
Ithaca.pt
c

sasses paramagnetic
P but t
Inpg
innerorbital
it contain both T B P and
S
in high and it is
of squareaspyramidal
declared squarepyramidal d2sp3 Diamagnetic
tuff Cinnee orbital
CNET yen
Q JEE 2011
Pyramidal Ik P
Ii Ignsquare Among the following complexes
an
Kz Ftcent I co CNA lo Cl
which the following complexes have
of
tetrahedral 3
shape 395
7 acorns 772 By Nicoly
para 1 39 Dia

93 IET on J
Ma
I I Ni
ely 32 I enemy 7 cot behave as S f L
oxygendonor will
cot 396 Diamagnetic
349 s f a hybridisation dspa
it CNMI CL N
348452 Co Stl
Ni
Hybridisation 573 Nith 3 348 what a
with 3d Ces Mhz ants as
atw.fi Paramagnetic

Znt2 3410 3
Ifp K2 PtCanty O
sp
innerorbital Pt 5996s 1
Which of the following is are
complexes as well as diamagnetic ptt2 548
12076337 ni can 7,32T CN Sfl Diamagnet c
Il By
t IZ n 912016 No
312 P
Cr Nh3 Jt Coen 31 Ln723410 Diamagnetic
The diamagnetic complexes are
M O and p
 JEE 2016 CMA and are considered as
ligands
Among Ni lol y Ini any Ilo crazyclayPointcharges
CMA is considered be a positive to
V93 It off Naz02 and 02 The total Point
as
are considered as
no compounds one charge and ligands
of paramagnetic negativepointcharges
a
Neutral ligands are considered as
Vi 398452 these negative end directed
dipoles with
towards CMA
Vi An Diamagnetic
are paired There is no interaction between metal
orbitals and orbitals
Fi 398 Ch W f l No pairing ligand
Paramagnetic The 5 d orbitals in an isolated gaseous
metal atom ion have some energy ie they
are degenerate This degeneracy in maintaine
cot sat cries f l
s Pairing a sperically symmeteilae field ofnegaliv
Diamagnetic if
charges surrounds the metalatomlien keep
in
mind that in presentsof Symmetrilatelithital
cot3 396 fl W f l Nopairing an the orbitals win be
I
field the energyitofwill not remain same as
Paramagnet i Sailed equally
but since all will be at same energy
before
are still degenerate
Va 02 Diamagnetic they
election election tail

t.gg
cso Paramagnetic
repulsion in Symis
Ans 3 find degeneracy
it will
no
Mov
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DRAWBACKS of BT
It doesnt explain the variation of magnets
QQ
moment with temperature
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compounds

Ipsf
It does not give quantitative interpretation
a
the thermodynamic Corl kinkiest abilities
of coordination compounds
ofIt doesnot make exalt peedintions legarding
asymmetrical
Fief It
e tetrahedral and Square planarstructures Fs crystal
4 Coordinatecomplex field
of symmetrical
field still degenerate plitlin
withhigher
eystal field theory
hypomania
energy in
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betweenpoint
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degenerate
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t
tve point I point isolatedgases
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iom
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are same
CMA and ligands dipole
as considered on point positive splitting in octahedral field
hanges Nyt I f 122
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by
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Crea and ligands in purely electrostaticis I É I_gd YIdE.y
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in g nay y
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terse splitting
X weal freedligand
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s se spesteocheminal series
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egging c I filling of
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formationof an octahedral spinoff
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from the direction along
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along the axis feel more depurionand
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orbitals win be at Selatively higher
PgG.s
A
value in presence a f I in less
of
than the Ao value in presents of S f L
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meanenergylevel 11,1111g
in pre
j
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t elastins will not

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azz stoically 7mm 2 Same elections
g g gapp cimaginary filling of
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ve
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M aicitation Ex Tiago tf Ao W o b Ao
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experimentally

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14
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it is below thats it is indicated win
ve
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it is above o 4Ao
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 W F S f L

t st.f a
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o.sao
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in considered is compared to s f l
1 If Pairingenergy
w f e
very less
d even in s f l it will behave as
CFSE 2
2 Aoxntzgt3Aoxnegt a Paramagnetic complex
P X no
of pain Ex Triana Jt
stable win be the complex formula
Cfs 0 410 7 to b Ao x neg
tag
Electron distribution in ontogeny complexes
Distributionin C FSE No of
Wfc
nigh at o 470
d o Mage
Igel 440
d O O Ao
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D O 8 Ao
d
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as
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o
o to d4 D
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FIFI 2 490
d IFT D
d pit HI o ga
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97 TIM
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6A
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i o

99 MIN FI o.la

910