Lectura - The Impact of Corrosion On Society

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The Impact of Corrosion on Society

C.M. HANSSON

Almost all metals and alloys are unstable in the Earth’s atmosphere and will always be sus-
ceptible to corrosion. The basic principles of corrosion are briefly described in order to explain
the observations of corrosion, which render our personal items as well as industrial machinery
and public property dysfunctional, aesthetically displeasing, and potentially dangerous. This is
followed by a discussion, with case study examples, of three aspects of the impact of corrosion
on society: (1) direct effects resulting in injury or death, (2) contamination of the environment,
and (3) the financial costs.

DOI: 10.1007/s11661-011-0703-2
 The Minerals, Metals & Materials Society and ASM International 2011

I. INTRODUCTION very simply as an anodic electrochemical reaction in


which the metal atom, M, gives up one or more electrons
ALMOST all metals and alloys are unstable in the to become a cation:
Earth’s atmosphere and will always be susceptible to
corrosion, i.e., conversion to a lower energy inorganic M ! Mnþ þ ne ½1
compound, such as carbonate, sulfide, or oxide. Thus,
the metals and alloys used by engineers today are all in a This reaction will only happen if there is a corre-
metastable state and will corrode, at a rate dependent on sponding cathodic reactant available to receive the
the environment, unless steps are taken to minimize the electrons; in aqueous solutions, this is usually one of
risk of corrosion for the expected service life of the the following:
component. Unfortunately, while this fact is known by
the majority of engineers, corrosion resistance is often 2Hþ þ 2e ! H2 in acidic solutions ½2
relegated to a lower priority when materials are selected
on the basis of those properties essential to the specific 1=2O þ H2 O þ 2e ! 2ðOHÞ
2
application, such as strength, stiffness, and electrical ½3
conductivity. The result is that corrosion is ubiquitous, in neutral or basic solutions
occurring in all forms of engineering materials from
microelectronics to orthopaedic implants to major civil The metal ions may remain dissolved in the solution
infrastructures and to the everyday objects in our lives, or may react with other ions and precipitate as solid
as illustrated by the collage of images in Figure 1. compounds.
While the images in Figure 1 show the breadth of As in any other electrical circuit, the passage of
corrosion, the examples illustrate the waste and loss of electrons between the anode and cathode constitutes a
functionality corrosion causes, but they do not consti- current. Electrochemical corrosion measurements are
tute major hazards. However, there are instances where based on directly or indirectly measuring this current
seemingly trivial amounts of corrosion can have major and using Faraday’s law to convert this to a corrosion
impacts, and three aspects of these are considered rate, for example, in material loss expressed as lm/
subsequently: (1) direct effects resulting in injury or year.[1]
death, (2) contamination of the environment, and (3) the Fortunately, instead of continuing to actively corrode,
financial costs. These will be illustrated by case histories several metals and alloys form a thin (nanometer thick),
of some of the worst corrosion-related disasters reported passive film in certain environments, which reduces the
in the last half century. corrosion rate to a negligible level. For solutions in the
neutral pH range, these include aluminum and its alloys,
titanium and its alloys, and stainless steel, as long as the
II. CORROSION PRINCIPLES chromium content of the steel is in excess of ~12 wt pct,
at which level a protective film of Cr2O3 will form. In
Most corrosion occurs in aqueous solutions, including highly alkaline environments, plain carbon steel also
the very thin film of condensate moisture on the surface becomes passivated. The regions of pH and electro-
of metals exposed to the atmosphere. It can be described chemical potential for which metals are passivated are
given in the ‘‘Atlas of Electrochemical Equilibria in
Aqueous Solutions.’’[2]
C.M. HANSSON, Professor, is with the Department of Mechanical The rate of corrosion can be increased significantly,
and Mechatronics Engineering, University of Waterloo, Waterloo, ON
N2L 3G1, Canada. Contact e-mail: chansson@uwaterloo.ca
either overall or locally, by a number of factors, which
Manuscript submitted September 20, 2010. has led to a classification of corrosion forms, some of
Article published online April 29, 2011 which are described subsequently.

2952—VOLUME 42A, OCTOBER 2011 METALLURGICAL AND MATERIALS TRANSACTIONS A


Fig. 1—Everyday examples of corrosion: (a) corrosion of a computer circuit board (courtesy: oldcomputers.net); (b) crevice corrosion on the
underside of the author’s washroom sink; (c) corrosion of a food can (courtesy: Cesar Mejar); (d) pitting corrosion of a silver-plated water jug
(courtesy: Corrosion Doctors); (e) corrosion of brass plate (courtesy: Corrosion Doctors); and (f) deicing salt-induced corrosion of reinforcing
steel corrosion in reinforced concrete bridge.

A. General Corrosion contaminants from the atmosphere such as sulfates or


General corrosion is sometimes known as uniform chlorides.[3]
corrosion, because it occurs over the entire exposed The worst example of this kind of corrosion observed
surface. However, once it progresses, there are always by this author is illustrated in Figure 2(a). This ship
variations in the degree of corrosion so ‘‘uniform’’ as carried 130 passengers and ‘‘crew’’ for 58 days from
not completely accurate. If the corrosion products are China to Canada in 1999 and, amazingly, all survived.
soluble, then the result is a general thinning of the In this case, the ‘‘rust’’ would have incorporated
metal and can result in structural failure or in perfora- chlorides and possible sulfates and gave rise to a very
tion of the part. The most common form of general nonuniform attack, as shown in Figure 2(b).
corrosion is the atmospheric rusting of steel. In this case,
the corrosion product is insoluble but is porous and
poorly adherent and is, therefore, not protective.[3] B. Galvanic Corrosion
There are many forms of oxides of iron, and rust is Contact between two different metals (galvanic cor-
often considered to be simply Fe2O3. However, it is rosion) enhances the protection of one (which becomes
generally a hydrated form of the oxide incorporating more cathodic) at the expense of more rapid dissolution

METALLURGICAL AND MATERIALS TRANSACTIONS A VOLUME 42A, OCTOBER 2011—2953


of the other (which becomes more anodic). A classic disintegrated over the years, allowing contact between
example of the detrimental effects is the perforation of the two metals. The steel corroded and its expansive
the copper skin of the Statue of Liberty.[4] The gaskets corrosion products perforated the copper, as shown in
isolating the copper skin from the steel support structure Figure 3. Galvanic corrosion leads to failures in many
fields, some of the most common of which are in
electronic components and household pipe components.
The following guidelines are given to mitigate gal-
vanic corrosion:[5]
(1) use one metal or alloy throughout the system;
(2) if this is not possible, use metals that are as close
as possible in the galvanic series;[1]
(3) avoid a surface area ratio in which the more active
(anodic) metal is smaller than the more noble
(cathodic) metal;
(4) isolate the dissimilar metals; and
(5) design for easy replacement of the anodic part.
The beneficial exploitation of galvanic corrosion is
exemplified by the widespread processes of galvanizing
steel and of cathodic protection using ‘‘sacrificial
anodes.’’ The latter are used extensively in applications
ranging from household water heater tanks to offshore
oil platforms and thousands of kilometers of oil, gas,
and water pipelines. The principle is shown schemati-
cally in Figure 4.

C. Pitting Corrosion
Pitting usually occurs in passivated metals and alloys
and is often associated with saline environments. Chlo-
rides cause local breakdown of the passive film, the actual
mechanisms of breakdown being a matter of debate. The
various theories[6] include (1) penetration through the
point defects in the passive oxide film by chlorides and
Fig. 2—(a) Refugee ship from China. (b) Close up of the corrosion
of the ship in (a), showing general corrosion with additional local-
subsequent aggressive dissolution,[6] (2) competitive
ized corrosion below the water line, attributable to the chlorides in absorption of chloride and oxygen ions, and (3) dynamic
sea water. depassivation-repassivation. However, what is agreed is

Fig. 3—Galvanic corrosion-induced perforation of the copper skin on the statue of Liberty.[4]

2954—VOLUME 42A, OCTOBER 2011 METALLURGICAL AND MATERIALS TRANSACTIONS A


Fig. 6—Schematic representation of crevice corrosion.

D. Crevice Corrosion
Local stagnant conditions often develop in confined
spaces, such as under a lap joint or a washer, and can lead
to that area becoming anodic with respect to the remain-
ing area of the metal, which remains exposed to aerobic
conditions and becomes cathodic. Since the number of
electrons consumed by the cathodic reaction (Eq. [3])
Fig. 4—Schematic diagram of cathodic protection of a buried pipe must, at all times, equal those released by the anodic
using magnesium as a sacrificial anode. reaction (Eq. [1]), and the area in the confined space is
usually significantly smaller than the rest of the part, the
result is more rapid corrosion of the metal in the confined
space, illustrated schematically in Figure 6. An example,
in practice, is shown in Figure 1(b) in which corrosion was
initiated between a cast iron bathroom washbasin and the
metal straps supporting it. The electrolyte, in this case,
was just the moist air in the bathroom.
Stainless steels seem to be particularly susceptible to
crevice corrosion, because when oxygen becomes
depleted in the crevice, the passive film of Cr2O3 cannot
be maintained. Molybdenum in the stainless steel
enhances the resistance to crevice corrosion as it does
to pitting corrosion.

E. Microbially Induced Corrosion


Fig. 5—Schematic representation of chloride-induced pitting corro-
sion of a passivated metal. Another factor that must be taken into account in
evaluating or predicting corrosion is the role of bacteria:
microbes can radically change the environment in terms
of both pH and access to oxygen, often creating acidic
that, where the passive film is locally destroyed, active
conditions.[7] Sulfate reducing bacteria, such as the
corrosion is initiated and that area becomes more anodic
Desulfovibrio species, are believed[8] to be responsible
with respect to the remaining passivated surface. The
for the cathodic reaction, producing H2S, which dis-
sequence of reactions is as follows:
solves to form sulfuric acid and decreases the pH.[9,10] A
M ! Mnþ þ ne great number and variety of bacteria can influence
corrosion, some of which are described in Reference 11.
Olszewski[12] described the problems associated with
Mnþ þ nCl ! MCln identifying this form of corrosion and distinguishing it
from other forms such as crevice corrosion and pitting.
MCln þ nH2 O ! MðOHÞn þnHþ þ nCl However, as emphasized by Lane,[11] microbially in-
duced corrosion is not accurately a form of corrosion:
The electrons released by the metal travel through the the bacteria and fungi change the environment and,
metal, as indicated in Figure 5, and react with water and thereby, create the conditions for different forms of
dissolved oxygen to form hydroxide ions, according to corrosion. Bacteria have played a major role in many
Eq. [3]. Consequently, the remaining passive area serious corrosion-related failures and warrant careful
becomes more alkaline and the anodic area in the pit monitoring.[7] They are a well known cause of failure in
becomes more acidic; because the chloride ions are not oil, gas, and sewage pipelines but can also cause
consumed, the process becomes autocatalytic. The local corrosion of more personal items such as intrauterine
corrosion rate increases, and the anodic area tends to devices[13] and household appliances.[12]
grow in depth rather than laterally. This can lead to
perforation of containers, such as that shown in
Figure 1(d), with no readily visible warning and can, F. Intergranular Corrosion
therefore, be more dangerous than general corrosion of In many alloys, minor constituents segregate to the
the metal surface. grain boundaries. When these constituents are less noble

METALLURGICAL AND MATERIALS TRANSACTIONS A VOLUME 42A, OCTOBER 2011—2955


Fig. 7—Intergranular corrosion of a 7075-T6 failed aircraft compo-
nent (Courtesy: Corrosion Doctors).
Fig. 8—Burnt out pesticide plant in Bhopal, India after explosion in
1984.
than the alloy matrix, preferential dissolution can occur
along the grain boundary, for example, in the aluminum
alloy in Figure 7. This can be a particular problem in
stainless steels if they are heated within a critical range
of 723 K to 1073 K (450 C to 800 C) in which
chromium reacts to form Cr23C6, particularly at the
grain boundaries, leaving the steel adjacent to the grain
boundary depleted in chromium and, therefore, unable
to form the protective passive film of Cr2O3. The heat-
affected zones of welds in stainless steels are particularly
susceptible to this problem. This problem can be
avoided by suitable heat treatment after welding, by
the use of steels with a low carbon content or those
containing alloying elements such as titanium, niobium,
or tantalum, which have a greater affinity for carbon
than has chromium.
Fig. 9—Sunken ferry ‘‘Princess Ashika’’ in which 78 people lost their
G. Corrosion-Induced Fracture lives.

Corrosion can also lead to environmental cracking


methylisocyanate, the iron corrosion products provided
which may take the form of stress corrosion cracking,
a catalyst for a reaction, which blew apart the plant
hydrogen embrittlement, or corrosion fatigue.[14] In
allowing the methylisocyanate and other toxic gases to
these cases, there is usually no observable corrosion
escape, killing over 8000 people. Since then, an addi-
and, instead of a gradual dissolution of material, the
tional 15,000 have died as a result of the explosion
consequence is usually fracture without any prior
and an estimated 500,000 others are suffering from gas-
deformation.
related disorders.[15–18]

III. CORROSION RESULTING IN INJURY B. Sinking of the Tongan Inter-Island Ferry ‘‘Princess
AND LOSS OF LIFE Ashika’’
Barely a month after being commissioned in 2009, the
A. Chemical Plant Explosion, Bhopal India, 1984
ferry ‘‘Princess Ashika’’ sank, resulting in the death of
There are many cases of injuries and deaths (of both all passengers and crew (a total of 74) (Figure 9). During
humans and animals) related to corrosion. By far the the Royal Commission established to investigate the
worst corrosion-related disaster, in terms of human cause of the disaster, a marine engineer who inspected
death, injury, and subsequent health problems was the the vessel prior to its sailing presented photos showing
explosion at a chemical plant in Bhopal, India in 1984 doors and entrances on the Ashika unable to fully close
(Figure 8). This plant was part of India’s ‘‘Green due to corrosion and had advised against the sailing.[19]
Revolution’’ intended to provide fertilizer and pesticides
to boost grain production. However, a number of design
flaws and management problems converged to cause a C. Berlin Congress Hall Collapse, 1980
catastrophic explosion. It is reported that, when steel In 1957, the Berlin Congress Hall, shown in
pipes corroded and water leaked into tanks containing Figure 10(a), was hailed as a spectacular building with

2956—VOLUME 42A, OCTOBER 2011 METALLURGICAL AND MATERIALS TRANSACTIONS A


Fig. 11—(a) Illustration of the correct placement of the duct and
post-tensioned steel within the concrete. (b) The duct and steel are
resting on the support and are not completely coated in the highly
alkaline concrete and grout required for passivation.

Fig. 10—(a) Prize-winning Berlin Congress Hall built in 1957.[22]


(b) The Berlin Congress Hall after collapse in 1980.[22]
Fig. 12—Aloha Flight 243 after landing safely in 1988 following
fracture of part of the fuselage. One person was killed as a result.[23]

unique design and construction. One of its features was


a curved canopy constructed of post-tensioned concrete
panels. In such systems, a metal or plastic duct is
positioned in the formwork and a high strength rod or
7-wire steel strand is inserted in the duct and anchored
at one end. After the concrete is placed and has
hardened, the nonfixed end of the steel is pulled in
tension and anchored. The duct is then filled with grout
to allow transfer of load between the concrete and the
post-tensioned steel, as illustrated schematically in Fig. 13—Schematic illustration of cracks, initiated by stress corro-
Figure 11(a). The steel is protected from active corro- sion cracking after moisture seeped under epoxy at the rivets and
propagating to form a critical crack.
sion by the highly alkaline (pH > 13) concrete and
grout, which induce a passive film on the steel.[20,21] In
1980, the building collapsed (Figure 10(b)), killing one
person. Analysis of the failure[22] showed the ducts in D. Failure of Aloha Airline Flight
several of the post-tensioned panels to have been placed In 1988, a Boeing 737 passenger liner ‘‘experienced an
incorrectly in a manner illustrated schematically in explosive decompression and structural failure at 24,000
Figure 11(b). In these cases, the ducts and the post- feet…. Approximately 18 feet from the cabin skin and
tensioned steel were not completely surrounded by structure aft of the cabin entrance door and above the
concrete and grout and, therefore, were not passivated passenger floor line separated from the airplane during
over the entire surface. Consequently, the cathodic half- flight’’[23] (Figure 12). A flight attendant was swept
cell reaction was that given by Eq. [2], rather than that overboard and presumed dead; eight others received
in Eq. [3]. Fractography showed corrosion along prior- serious injuries. The cause of this failure is believed to
austenite grain boundaries, and numerous inner cracks have been initiated by crevice corrosion. The skin of the
and the failure were attributed to hydrogen embrittle- fuselage was joined by rivets, as illustrated in Figure 13,
ment.[22] Once the embrittled panels had failed, the and these were reinforced by a two-component epoxy. It
remaining panels failed in a ductile manner due to is believed that the epoxy did not adhere well and that
overload. moisture got under the epoxy and resulted in crevice

METALLURGICAL AND MATERIALS TRANSACTIONS A VOLUME 42A, OCTOBER 2011—2957


Fig. 14—Swine barn at Innerkip, ON after corrosion-induced
collapse.[3,5]

corrosion, leading to stress corrosion cracking. Small Fig. 15—Remains of farm buildings after fire initiated at corroded
electrical wiring (#921).
cracks formed at several adjacent rivet joints and
propagated by fatigue to form one large critical crack.

more such contamination can be expected. Corrosion


E. Failure of Livestock Facilities
can occur on both the inside wall and the outside surface
Corrosion-related failures leading to deaths of ani- of a pipeline, but is more common on the inside.
mals receive far less publicity than those involving Papavinasam et al.[28] report that internal corrosion
human tragedies. Nevertheless, these deaths are tragic accounted for 15 pct of all pipeline incidents in the
and many could be avoided. United States between 1994 and 2000 and that those
Many livestock facilities integrate manure storage occurring in Alberta, Canada amounted to almost
with livestock housing. Animal manure contains sulfates 1 per day over the last 20 years. In many cases, the
and sulfides, which, in high concentration, are known to cause is MIC, such as sulfate reducing bacteria, which
cause corrosion of reinforcement in concrete.[24] Anal- produced the pit and perforation in a carbon steel heavy
ysis of the chemicals in waste from poultry, dairy cattle, oil pipe in Figure 16.[29]
and swine[25] indicates that there are also relatively high The impact of oil leaks on wildlife is horrific, as
levels of chlorides and ammonia, and of course, the illustrated in Figure 17. Note that there are more than
waste contains significant levels of bacteria. Most 160,000 such images on Google. Sewage also contains
structural metals, with the exception of stainless steel bacteria, ammonia, and sulfur compounds, and sewage
and batch galvanized steel, exhibit severe corrosion in pipe leaks can be equally harmful to the environment.
these wastes. One example of the consequences of such
corrosion is illustrated in Figure 14: a reinforced con-
crete support column in a swine barn in Ontario, A. Prudhoe Bay Oil Pipeline Leak
Canada failed, causing the barn to collapse and killing One of the worst oil leaks occurred on March 2, 2006,
250 hogs. This is, unfortunately, not an isolated case.[26] when approximately 1 million liters of crude oil leaked
In addition to structural collapse caused by corrosion, from a corroded transit pipeline in Northern Alaska and
many barn fires, such as that shown in Figure 15, are covered two acres of snow-covered tundra. The location
attributed to corrosion of electrical wiring by the moist of the leak, shown in Figure 18, was in a culvert
and corrosive atmosphere inside the barn. The heat surrounding the transit line as it passes under a caribou
generated by an electrical current is directly propor- crossing.[30] According to the company’s corrosion
tional to the resistance of the conductor. Thus, when the authority, the pipeline was designed for a 25-year service
cross section of the wire is reduced, its electrical life, and at the time of leaking, it had been in service for
resistance increases and the wire heats up.[27] 29 years. The cause was internal corrosion of the
pipeline steel.[31] The company spent 72 million dollars
to fight corrosion in the previous year and 60 million
IV. IMPACT OF CORROSION dollars in the year prior to that. The effort, according to
ON THE ENVIRONMENT the company spokesman, included corrosion inhibition,
X-ray runs, and ultrasonic tests.
Most corrosion-related contamination of the environ- The U.S. Department of Transportation ordered
ment can be traced to leaks from perforated tanks, smart pig inspections in response to the leakage report.
containers, and pipelines. As the number and length of The inspection record noted that the steel had corroded
pipelines for oil, gas, water, and sewage grow, more and in 12 places on the eastern side of Prudhoe Bay up to

2958—VOLUME 42A, OCTOBER 2011 METALLURGICAL AND MATERIALS TRANSACTIONS A


Fig. 16—Pit and perforation of 6.3-cm internal diameter carbon steel
pipe carrying heavy oil. The pit morphology is typical of sulfate
reducing MIC attack.[22]

Fig. 18—(a) Source of the leak at the Prudhoe Pipeline in 2006.[23]


(b) Transit line spill.[23]

Corrosion Engineers (NACE), the Federal Highway


Fig. 17—Result of oil leak from corroded pipeline. Administration (FHWA), and CC Technologies, and
the report was published in 2002.[34] The following data
70 to 81 pct of the original thickness, which was less are reproduced from the presentation of the report data
than company standard. by permission of CC Technologies. The sectors studied
were as follows.
B. Sewage Spill into Buena Vista Lagoon Infrastructure:
In 2007, a 25-year-old, 0.6-m- (24-in.-) diameter sewage Highway bridges
pipe running adjacent to the Buena Vista Lagoon in Gas and liquid transmission pipelines
California (Figure 19) and buried 4.8 m (16 ft.) below Waterways and ports
ground developed a 24 cm (10 in) diameter hole (Fig- Hazardous materials storage
ure 20). Although the pipe was repaired within a record Airports
time (less than 24 hours after the leak was discovered),[32] Railroads
it is estimated that 7.3 million gallons of raw sewage
Utilities:
spilled into the lagoon.[33] The problem was attributed to
erosion-corrosion due to the high velocity of flow and Gas distribution
strong sulfuric acid vapors in the pipe. Drinking water and sewer systems
Electrical utilities
Telecommunications
V. FINANCIAL COSTS OF CORROSION Transportation:
In 1999, the U.S. Government funded a study of the Motor vehicles
direct and indirect costs of corrosion in 26 sectors. The Ships
study was carried out by the National Association of Aircraft

METALLURGICAL AND MATERIALS TRANSACTIONS A VOLUME 42A, OCTOBER 2011—2959


Railroad cars The indirect costs of corrosion include plant down-
Hazardous materials transport time, loss of product, environmental contamination, loss
of efficiency, over design, user costs, and insurance costs.
Production and manufacturing:
When these are added to the direct costs, the total
Oil and gas exploration—production amount rises to $276 billion and contributes more than
Mining 3 pct to the U.S. Gross Domestic Product
Petroleum refining (GDP)—more than those of the mining and agriculture
Chemical, petrochemical, and pharmaceutical sectors combined (Figure 22).
Pulp and paper As mentioned previously, one of the major costs is
Agriculture corrosion prevention, which was calculated to be $121.4
Food processing B, almost 90 pct of the direct costs of corrosion. Of this,
Electronics almost 90 pct is spent on protective coatings. For the
Home appliances organic coatings, the materials accounted for 4 to 20 pct
of the cost, depending on the complexity of the project,
Government:
the remainder being the application costs. The most
Defense widely used metallic coating is zinc, used mostly as hot-
Nuclear waste storage dip galvanizing of steel, but also, with aluminum, as
sprayed or electroplated coating.
The overall annual direct costs of corrosion, illustrated in
The very small amount of funds being spent on
the pie chart in Figure 21, were considered to be (1) the
research and development and on education and train-
additional or more expensive materials needed to prevent
ing is noted in the report. It is stated that, ‘‘It has been
corrosion damage, (2) the labor for corrosion manage-
observed that over the past few decades less funding has
ment, (3) equipment required for corrosion-related
been made available for corrosion related research and
activities, (4) loss of reliability, and (5) loss of capital
development, which is significant in light of the cost and
due to corrosion-induced deterioration. The total of all
inconvenience of dealing with leaking and exploding
sectors was calculated to be $137.9 billion per year.
underground pipelines, bursting water mains, corroding
storage tanks, aging aircraft and deteriorating highway
bridges. In fact, several government and corporate

Fig. 19—Buena Vista Lagoon. Fig. 21—Direct costs of corrosion in the five major sectors.[27]

Fig. 20—(a) Damaged pipeline and (b) close up of the 25-cm (10-in.) hole in the 61-cm (24-in.) diameter pipe.[3,5]

2960—VOLUME 42A, OCTOBER 2011 METALLURGICAL AND MATERIALS TRANSACTIONS A


Fig. 22—Contribution of total direct and indirect corrosion costs to the U.S. gross domestic product relative to the other major contributing
sectors.[27]

research laboratories have significantly reduced their other technologies, corrosion research has much to
corrosion research staff or even have closed down their contribute to delivering social services more efficiently
research facilities.’’[34] and more reliably while lowering the costs of many of
the products and services purchased by the public.’’
Most materials engineers are aware, at least to some
VI. SUMMARY AND CONCLUSIONS extent, of the principles of corrosion. Therefore, the only
conclusion that can be made of the overall cause of the
In summary, corrosion takes many forms and is costly huge numbers of corrosion-related failures and the
on many fronts. Although rare, catastrophic failures due exorbitant associated costs is that materials scientists
to corrosion have cost many lives and, unfortunately, and engineers are not doing enough to educate and
will do so in the future because considerations of inform those whose responsibility it is to design and
environmental degradation of materials frequently take produce engineering components, i.e., the mechanical
lower priority to other property requirements. engineers, chemical engineers, civil engineers, and elec-
However, corrosion-induced pollution of the environ- trical engineers. Qualification in these disciplines usually
ment is much more common and can affect the health of requires, at most, a one term or semester course in
crops and drinking water and, therefore, of wildlife and materials and rarely is corrosion mentioned in these
humans. Then there is the ‘‘everyday corrosion,’’ which courses.
makes items, from household objects to production
machinery to highway infrastructure, dysfunctional,
aesthetically displeasing, and potentially dangerous. REFERENCES
The financial cost of all of this is enormous, constituting
a significant percentage of the gross domestic products 1. D.A. Jones: Principles and Prevention of Corrosion, 2nd ed., Pre-
ntice Hall, Upper Saddle River, NJ, 1996.
of industrial countries and, possibly, of developing 2. M. Pourbaix: Atlas of Electrochemical Equilibria in Aqueous
countries too, although this has not been documented. Solutions, National Association of Corrosion Engineers, Paris,
To quote Reference 34: ‘‘Corrosion research has, over 1974, vol. 1.
the years, suffered from inadequate industry and gov- 3. T.E. Graedel and R.P. Frankenthal: J. Electrochem. Soc., 1990,
vol. 137 (8), pp. 2385–94.
ernment funding, especially given the cost and inconve- 4. R. Baboian and S.L. Pohlman: in ASM Handbook, Corrosion,
nience associated with corrosion of water mains, bridge M.B. Ives, ed., American Society for Metals International,
structures, automobiles, airplanes, and pipelines. In Materials Park, OH, 1996, vol. 13, pp. 83–87.
contrast, physicists and biologists have captured the 5. B.D. Craig: J. Failure Analysis Prevention, 2006, vol. 7 (2),
attention of the public and Congress by describing the pp. 12–19.
6. G.S. Frankel: J. Electrochem. Soc., 1998, vol. 145 (6), pp. 2186–98.
dynamics of high-energy physics and biotechnology. 7. R. Sooknah, S. Papavinasam, and R.W. Revie: in Corrosion 2007,
While not as noteworthy to the popular press as some National Association of Corrosion Engineers, Nashville, TN, 2007.

METALLURGICAL AND MATERIALS TRANSACTIONS A VOLUME 42A, OCTOBER 2011—2961


8. J.F.D. Stott: Corr. Sci., 1993, vol. 35 (1–4), pp. 667–73. 23. NTSB: Aircraft Accident Report—Aloha Airlines Flight 243, Boe-
9. N. de Belie, J.J. Lenehan, C.R. Braam, B. Svennerstedt, M. Richardson, ing 737-200, National Transportation Safety Board Bureau of
and B. Snock: J. Agric. Eng. Res., 2000, vol. 76, pp. 3–16. Accident Investigation, Washington, DC, 1989.
10. W. de Muynck, N. de Belie, and W. Verstraete: Cement Concrete 24. J. Assaad Abdelmseeh, J.C. Jofriet, and G.L. Hayward: Biosys-
Compos., 2009, vol. 31 (1), pp. 163–70. tems Eng, 2008, vol. 99 (3), pp. 382–89.
11. R.A. Lane: J. Failure Analysis Prevention, 2005, vol. 5 (5), pp. 10–12. 25. L.M. Safley, Jr., P.W. Westerman, M.M. Kim, and D.S. Carr:
12. A.M. Olszewski: J. Failure Analysis Prevention, 2007, vol. 7 (4), Bioresource Technol., 1992, vol. 40 (1), pp. 53–61.
pp. 239–46. 26. OMAFRA: Corrosion of Roof Truss Gusset Plates in Farm Build-
13. B.M. Carrillo, S.B. Valdez, L. Vevela, L.T. Pérez, O.L. Vargos, ings [cited 20 July 2010]; available from: http://www.omafra.gov.
and W.M. Schorr: Anti-Corrosion Methods Mater., 2004, vol. 51 on.ca/english/engineer/facts/94-035.htm#Intro.
(5), pp. 331–38. 27. OMAFRA: Barn Fires: An Increasing Problem for Ontario Farmers
14. M.R. Louthan, G.R. Caskey, Jr., J.A. Donovan, and D.E. Rawl, [cited 20 July 2010]; available from: http://www.omafra.gov.on.ca/
Jr.: Mater. Sci. Eng., 1972, vol. 10, pp. 357–68. english/engineer/facts/barn_fire.pdf.
15. I. Eckerman: J. Loss Prevention Process Industry, 2005, vol. 18 (2), 28. S. Papavinasam, R.W. Revie, and A.M. Doiron: in Corrosion
pp. 213–17. 2006, National Association of Corrosion Engineers, San Diego,
16. S. Kumar: The Lancet, 1993, vol. 341 (8854), pp. 1205–06. CA, 2006.
17. M. Brown: Bhopal Gas Disaster Legacy Lives on 25 Years Later, 29. G. Korbin: in Microbially Influenced Corrosion, G. Korbin, ed.,
2009 [cited 18 July 2010]; available from: http://www.telegraph. NACE International, Houston, TX, 1993, pp. 90–100.
co.uk/news/worldnews/asia/india/5978266/Bhopal-gas-disasters- 30. Stories in the News: Stories in the News, Mary Kauffman,
legacy-lives-on-25-years-later.html. Ketchikan, AK, 2006.
18. M.J. Peterson: Bhopal Plant Disaster, International Dimensions of 31. E. Meggert and L. Giguere: GC-2 Oil Transit Line Release, Alaska
Ethics Education in Science and Engineering, 2009, available Department of Environmental Conservation, Unalaska, AK,
from: www.umass.edu/sts/ethics. 2008, p. 2.
19. W. Andrew, R. James, and M Handfield: Royal Commission of 32. EGCA Magazine: Vadnais Crews Repair Carlsbad’s Headline-
Inquiry into the Sinking of Mv Princess Ashika, Nuku’alofa, Making Ruptured Pipeline, Engineering and General Contractors
Kingdom of Tonga, 2010, p. 629. Association, San Diego, CA, 2007.
20. C.M. Hansson: Metall. Mater. Trans. A, 1995, vol. 26A, pp. 1321–41. 33. B. Henry: North County Times, North County Times, San Diego,
21. A. Rosenberg, C.M. Hansson, and C. Andrade: in The Materials CA, April 11, 2007.
Science of Concrete, J. Skalny, ed., The American Ceramic Society, 34. G.H. Koch, M.P.H. Brongers, N.G. Thompson, Y.P. Virmani,
Cleveland, OH, 1989, pp. 285–313. and J.H. Payer: Corrosion Costs and Prevention Strategies in the
22. B. Isecke: in Corrosion of Reinforcement in Concrete Construction, United States, Federal Highway Administration, McLean, VA,
C. Page, ed., The Concrete Society, London, 1983, pp. 79–89. 2002.

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