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Lectura - The Impact of Corrosion On Society
Lectura - The Impact of Corrosion On Society
Lectura - The Impact of Corrosion On Society
C.M. HANSSON
Almost all metals and alloys are unstable in the Earth’s atmosphere and will always be sus-
ceptible to corrosion. The basic principles of corrosion are briefly described in order to explain
the observations of corrosion, which render our personal items as well as industrial machinery
and public property dysfunctional, aesthetically displeasing, and potentially dangerous. This is
followed by a discussion, with case study examples, of three aspects of the impact of corrosion
on society: (1) direct effects resulting in injury or death, (2) contamination of the environment,
and (3) the financial costs.
DOI: 10.1007/s11661-011-0703-2
The Minerals, Metals & Materials Society and ASM International 2011
C. Pitting Corrosion
Pitting usually occurs in passivated metals and alloys
and is often associated with saline environments. Chlo-
rides cause local breakdown of the passive film, the actual
mechanisms of breakdown being a matter of debate. The
various theories[6] include (1) penetration through the
point defects in the passive oxide film by chlorides and
Fig. 2—(a) Refugee ship from China. (b) Close up of the corrosion
of the ship in (a), showing general corrosion with additional local-
subsequent aggressive dissolution,[6] (2) competitive
ized corrosion below the water line, attributable to the chlorides in absorption of chloride and oxygen ions, and (3) dynamic
sea water. depassivation-repassivation. However, what is agreed is
Fig. 3—Galvanic corrosion-induced perforation of the copper skin on the statue of Liberty.[4]
D. Crevice Corrosion
Local stagnant conditions often develop in confined
spaces, such as under a lap joint or a washer, and can lead
to that area becoming anodic with respect to the remain-
ing area of the metal, which remains exposed to aerobic
conditions and becomes cathodic. Since the number of
electrons consumed by the cathodic reaction (Eq. [3])
Fig. 4—Schematic diagram of cathodic protection of a buried pipe must, at all times, equal those released by the anodic
using magnesium as a sacrificial anode. reaction (Eq. [1]), and the area in the confined space is
usually significantly smaller than the rest of the part, the
result is more rapid corrosion of the metal in the confined
space, illustrated schematically in Figure 6. An example,
in practice, is shown in Figure 1(b) in which corrosion was
initiated between a cast iron bathroom washbasin and the
metal straps supporting it. The electrolyte, in this case,
was just the moist air in the bathroom.
Stainless steels seem to be particularly susceptible to
crevice corrosion, because when oxygen becomes
depleted in the crevice, the passive film of Cr2O3 cannot
be maintained. Molybdenum in the stainless steel
enhances the resistance to crevice corrosion as it does
to pitting corrosion.
III. CORROSION RESULTING IN INJURY B. Sinking of the Tongan Inter-Island Ferry ‘‘Princess
AND LOSS OF LIFE Ashika’’
Barely a month after being commissioned in 2009, the
A. Chemical Plant Explosion, Bhopal India, 1984
ferry ‘‘Princess Ashika’’ sank, resulting in the death of
There are many cases of injuries and deaths (of both all passengers and crew (a total of 74) (Figure 9). During
humans and animals) related to corrosion. By far the the Royal Commission established to investigate the
worst corrosion-related disaster, in terms of human cause of the disaster, a marine engineer who inspected
death, injury, and subsequent health problems was the the vessel prior to its sailing presented photos showing
explosion at a chemical plant in Bhopal, India in 1984 doors and entrances on the Ashika unable to fully close
(Figure 8). This plant was part of India’s ‘‘Green due to corrosion and had advised against the sailing.[19]
Revolution’’ intended to provide fertilizer and pesticides
to boost grain production. However, a number of design
flaws and management problems converged to cause a C. Berlin Congress Hall Collapse, 1980
catastrophic explosion. It is reported that, when steel In 1957, the Berlin Congress Hall, shown in
pipes corroded and water leaked into tanks containing Figure 10(a), was hailed as a spectacular building with
corrosion, leading to stress corrosion cracking. Small Fig. 15—Remains of farm buildings after fire initiated at corroded
electrical wiring (#921).
cracks formed at several adjacent rivet joints and
propagated by fatigue to form one large critical crack.
Fig. 19—Buena Vista Lagoon. Fig. 21—Direct costs of corrosion in the five major sectors.[27]
Fig. 20—(a) Damaged pipeline and (b) close up of the 25-cm (10-in.) hole in the 61-cm (24-in.) diameter pipe.[3,5]
research laboratories have significantly reduced their other technologies, corrosion research has much to
corrosion research staff or even have closed down their contribute to delivering social services more efficiently
research facilities.’’[34] and more reliably while lowering the costs of many of
the products and services purchased by the public.’’
Most materials engineers are aware, at least to some
VI. SUMMARY AND CONCLUSIONS extent, of the principles of corrosion. Therefore, the only
conclusion that can be made of the overall cause of the
In summary, corrosion takes many forms and is costly huge numbers of corrosion-related failures and the
on many fronts. Although rare, catastrophic failures due exorbitant associated costs is that materials scientists
to corrosion have cost many lives and, unfortunately, and engineers are not doing enough to educate and
will do so in the future because considerations of inform those whose responsibility it is to design and
environmental degradation of materials frequently take produce engineering components, i.e., the mechanical
lower priority to other property requirements. engineers, chemical engineers, civil engineers, and elec-
However, corrosion-induced pollution of the environ- trical engineers. Qualification in these disciplines usually
ment is much more common and can affect the health of requires, at most, a one term or semester course in
crops and drinking water and, therefore, of wildlife and materials and rarely is corrosion mentioned in these
humans. Then there is the ‘‘everyday corrosion,’’ which courses.
makes items, from household objects to production
machinery to highway infrastructure, dysfunctional,
aesthetically displeasing, and potentially dangerous. REFERENCES
The financial cost of all of this is enormous, constituting
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ntice Hall, Upper Saddle River, NJ, 1996.
of industrial countries and, possibly, of developing 2. M. Pourbaix: Atlas of Electrochemical Equilibria in Aqueous
countries too, although this has not been documented. Solutions, National Association of Corrosion Engineers, Paris,
To quote Reference 34: ‘‘Corrosion research has, over 1974, vol. 1.
the years, suffered from inadequate industry and gov- 3. T.E. Graedel and R.P. Frankenthal: J. Electrochem. Soc., 1990,
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contrast, physicists and biologists have captured the 5. B.D. Craig: J. Failure Analysis Prevention, 2006, vol. 7 (2),
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6. G.S. Frankel: J. Electrochem. Soc., 1998, vol. 145 (6), pp. 2186–98.
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