/ PHYSICAL CHEMISTRY SURFALE PHENOMENA AND ADSORPTION Sofa gen dion, ~ he hifu . Yuy 3 oO — dyyind > argu, (5) radtcl fo seated of ray Liguid ed intejaual area, Spontanenn + cubtant . doreo 3 dS of Vande Waals © = 0; (1- LY" mite ne Te ierqanie compound n= 4] 9 Phase snachare Wetting, phenomena Oty oo Oy = Oy + Fig » cos 0 6: cntad aura lt : Fy = Sucjaw Aenbion 9) Aiquid Oe inberfactatl tun Ory 2 Supa ek energy of BoldWetng | 3 ~ Adhesion fore > Cohwsve forue Nena welttng > — Cobevive fore > Adhere forw 4 > — Higuid motoule fend 40 interact — Liquid molrulo fend to interact Avoid than Liquid Aiquid thon Added = a¢ 40° ' ~ «240° = Anya phitee (a avile D | . Araydre pho dic (An yu’e) ED Thomson — kelvin equation BY v (mer rentsua (650) Concave musa (r=-7’ <0) | Pe y {rm . ; ) ey Ge ae [R ae ees a Pr . 4 2 — o ~ - P*. * dat bet Ado hot Ath GE mit phaiig (ta) Pes ap audt Ad Add Roa ain AP matt cong (fa) wt a =k, 5 } . i a aie meng phan wa over wget) ah z ae, Ww — 9 me Py Corn moras 2 te Adsorption 2 Adsorbet - udsorphor ovuurs : Adsorbate. attach upSedsorbent's su Chemisorption vs. PS one! oF 5 sutpace - [__Chemisorption Physisorption | aaa ene Ra ses ier cl ML Phy Sorption AdsTomp. | adsorbates (Xe: T- 100 K: COT 200K) | al Catelyst . both 40 $00k/mol 540 kJ mol, low enthalpy | tow i> -10 kcal’ mot) Lana roxir ASOTK tn Van der Waals force Sienteal bon ro days Soe Weak interaction force mono Layer Propertic Treveibie weces forming multi-layers, ‘reversible process eae | ee non-selectivity Fround lich isothoren Mono layer 7 walt! —Layer rash = AO 1a ‘ i 1Lowney usc ote qa Liquid * — Une form Sapa - Mono haar adsorp tion, = — mare -— No Antvaction betwuw adsor bel speded and no movenent o adturbedl _ a spewed - _ KP | iE Be bina jae: Gry fad oO 4 m Vv, . : — [Mop + sain: [erin vain of aided ga ater (22) = ke Sire aye HA) km + tapavihy Jax tapacthy (2) © P dew (KP ee4>) > Vin propurhimnad te P ( Ve Vin eke P 2?) 2 Po drigh (KP >A VE Vin Freundlich ssotherm >. gah— Aolid/ Jiqui deli — badd’ = ~b.P% * | linear fm @* 4 AE 1 Gorn dn by | Xs adiorpson capachy ad | Aokid vel : 4 Ps grin oj goh om tHe odert gar Aabid adsorphion: 0.1<4¢0.5 at equedibiumn quid | actid adsorption: 0.9¢4 ¢ 4 yin constr (replat P by t) eT - Physical adsorp Kor fom § vwlti — oe ’ - | OT ce) | i —_ ae v(a- = Vint Vf Ee eae PoSpeutpic Ausya ON e 5 = Ven. aNv A (5) ; 2 Ver] MA Vor: Vola o4 First adsorbed Spee (=) Lay fe phioh hi uy Ain a) Anh N 6.022 107> A. oss section area of vdlsorhecl specced (m*) Ny. 0.462 « Aom®(m?) Vi molar velune at adlsoption condition ( thing Ja Aatm, oc) Pye PT sam R FV= nFT > ea ae V= (4) = (dm?) mm. adsorbent vaight Ts bela (ni dé dro doh ot Vda ue > wet) Surpactont Electroly 14 — Soll palubitty | — yk dai — Fous m a iE Counvated Jin bulk phae > = Adsorption on The pnleryacr | wigative adsoiphon ~ Orgtutin X Ont vent oe Oyotutiom > Ost ewnt= PRY SICAL CHEAWSTRY : CHEMICAL KINETICS ws Factors ayyect veachion vate : cnwntratior temperature Cex bs Rat Law uy [aA + b& —-—s dd + eE | > R= -4 ATA) oa atey a ato -44 ale) ar Dai >) tee a) en ee “ >» R= kfaAj* fey? Ke rate costar’t overcll } inetie reeuttion 12 feaction oreler respeck to A war: why 4 = teachin orale raped & B oder] Rackow | Rate Law Ament tegresstar Tala a R= ke Cay = Kt + Cao tay - Ge k= [ mote 4x at e% (A [4A ped [R= Kyla [ney =—kyt 4th Cao ee 1 5 x dfa) 1A > prod R= a ve Anly == + Anlyo Wipe 402 = Key ¥ sD) ky 2 a 5 “ spred [Raw Cq | = bt + 7 ba = 2 famomed JR= Meow fee BES te | = Ee Ar8 oped. With Cog = Cgo aa [ret el t] ri lon & “Yy(Go~Cre) Asbo ped ifn = = K (Cp - Cao) + Tua (Go Se 1446 >pted] oy Cra c Zao = Gas meee acre Rake ln mare An 2 bao = TAe_Rearhion rae op cumphix yea thon @ Reersibte reactor : ¥ aA + bb == cl + ad Ye pe -4 MAL 4 a0) gk ape), a afd a at par te Geeta Se = kLAy* ceye R= — 4 ate] 4 apo) 4 d atc) ajo] 4 dpe) d_ ala Coded ae eS elt ae = kfey poy A-A errsote aA 48 At test: G, = Cao Cy = Gy +¥ -y? 6 = “no R= Co-ey ao Ki Coy + Yor C | cc aa Xa-X% , Ki reer Caney | E So =-(hak)t - [-2 and aa er oe ; ; —_ Ke, Yop, CoXa +X (to Xo) Aa Bt | = aa Xe) tol Xe-X) _ Co Kor -\ = he fy, Xoo te Akal Mol o- Ke) t © Xoo -— % Gre —HeCpo “Ha Et a ky + er Ky Gy kee Leo AY eq: Ca-eg = Cp - Xc0 ke Coo ake Co ee aa \y 4 kr = t @ Uy ke) a 4 ly Coo t by Or Fr tee + Erii} @ Pura tll reactor ‘a Re = aCe, =Kla Re= ae = HCA A i ay , -_ a. fi Wg | Ber Mh ee tee Ue HDG Redan 4 ‘of = Ana — (et Ht a Ce le (er RA) E Ce : ()= ek Cue (ise ? , ty et Q)= Hg Ue ME) © Ke + be Ya : : A te Ca = Ca - Cpe p+ En Ai® &, p . ® Seves A keg be, kal oC F20: Cy =Cy = 0 = Oo = Cyt Car Ce _ dita _ dte ate Wy av Ala; ae 7 Kila Egy ae = hr na y. -k,t ats te = ¢ ee n= Cp Cy een le e ) a ne oe ba Cano , Small : SF ordur Hor + tray = aoe \ Me byl Ka ul Aasye 1G © a a m\ 4 cee —(eY wR] Nie Co, max ~ Tae i "Z yoo by Coma 2 Op Ke Fy Se a ® be stable fae» Step 2 ale deeming See Syep 4: vale seks Steady Stake approrximahion > » became A ay 12 (faeg! A+ 85> 2b dave LG A> aM (ha) Das | oy “ae 2 >” became Aas | | Mr 8 a t+ M (ky ay (Ca C mea Ce io M+A 5 ta M (i M 7 bas) 4 3) A, \ AS Antormecliate SS fat M+ M aA Ua day a de] dt aie j ACua =O Hae © dab trong rd =p \, Falun Ce + be Cu, C— Ci, =O. & a =0 ~> lu ly —& Cu Ca =O ® in Way ta = ly Gy 20 > Gm = fea Ca kK ar Bae =Ry =O > kyty— MY => —Nyla Vlas Cr tke Oy = Ky Cay Cg os ae - (kD = R= — dla ede = bly Cc =| ka Vo duny ay =O cho ar sep ( fale- det sep) be ya ‘e Duxrminahon of odir réochon, 4 1 Trteg ration Assume 0 (=-* WD lao ~> chick R (Linton vagy >) Assume 1: Unty = = efi) ttn ap > cheek Assume 2. kf + « > duce R he AO UsTO . Aue Setup 652 ve t beh te or ' ee ya , wh Ra 0-42 Avot hn > aay nba ea Joe phan re ? ihn SP ate hp Cua the dai é Aone AD fu Nw 1 sro K “Pr na cho P > DOE nani ae theo rae -= oe ) \. yV= hl = clinHaly — hie Aint _muthod Ant yg = (n> dn Coy — dn iosae q=2 > Tp = Z Co AME” dro howe ac! fds — He oe a © hora A Bie WE a3 at cm am <<“ rae ' a “tn (mE 5 pal Ai boas! wv ( teachin order) va kK qr ty Flooding mith od 1B voy high Cos cmt Ri V’G™ | ple Kec | xt = ke Rae Cry — as Avey high Caz cost R= k" Cg” Roa (ol the’ cho 2 dang 42’ fide feng do d mci AP cao heh tin Lav a Ai ques Auyin’ Anh <— Ata, (46.36 # \ Ase we [0] \ ; m , tin 2802 \ \ cho rls Ke Cg — 2 pahuicra, Aras ha ool ive om (re, . Y The, (cho sain) vas K gn \ TE rm, Cryo (thor logarithm’e yethe dl — \eep B cowl, change A 2 ae Pa . B= KCroa Co > ne fn (%) > In is pp n> i+ : R= KOgo,a Cgo An co) ™ Le, it Gor eo Woe gy 4 An (Veo “Vidz —\kt 4 Lin ( Vee VoD)Eygect oh ‘yet Vout tpg: | Bitrate? Am | ant Hay cole | ky | te . ; or Kg 440) aa —T TAC, vention rok FT g-4 fi . nel ‘ira 10) Ave hunius equator: > boc TY K - =ER 4 ka __ fa AA Ke ~nt =| Unk = Ea gedna | Me > Re \h Ay unbtant oe va K R= €344 rs yTT>*k Eu: arhivation entra ( Tlimet > T. plyn dank Lin Ae git Van t Pat va Archinivd NN Qe T40 2 Th dive An S14 4050 | nas The’ vio Var't Mot) 25 v. Ln, iM M AIT Nov 1, V+ 502 n=5 Modtudar linerie paceieetls —{— winber of collexien > 2 A A = || Ere = dy Me ngf inet (Aas A - | -as'va cham [ ae] Ane, > [om 1 Ta thy CO ieee Da Ng > Qnoteuales) /4 umn’ aS \ tis ain > mole x 02, 4923 KIL phre nicl >%S i W344 oe. Bg _ R= Z - RT —y KE ky xP ee MM 1* 245 q = Pee a ers tory ) Transition sae theo 2 pat dsp GY ge : ABC 2 Amy ay 8 a ost.) Stow fur = kee ie e * au ‘J kr ¢ St (Tran Hor sfakt _ k = RT RY k=X yom Kea =X See =e Ay Planck caslant = 6.62 wag 34ARH, Chain reaction Ty Pe Aneanint 4 Exomplt anit lH, Tivtiation, stnuewe yunber O% He vadi cals +ty +0, «H+ HO * Sable species s more frat radicals 4 HO, + Hy -H + Hh Oz ps i Propagation ‘rial wher gra vadieats remain | op th > oH 0 AML dome | Termination | 1 deat umber of gree radical |2.HO, —H, 0 + Op | | Jr fadicals —> fos active vadtealk | +H > wall | +H +0, +Ms+HQ 4M | (+H stable than Oa > mawh —5 wit Onbrarcheel ee hae aie - Avodinl +5 a radical Reaction rate = om Yn, It 2 a = rat d-e 7 ns prher of vadecals in a volume at + motte) Ny 2 ramber of rads’ eeilA gprerateal per Aime (A) per volume (4), const T: Aipe-hee op rack cal (4) bp: poswbe Lihy oy chain Arrmination Brandecl = 3 We op branihin 4 rt . Mina y Sana) Pena i a “yl v \ it | ho ( Dt b-s light absorp hon energy: Remcenttcticed ( met/o ) A- mE = Ra Bot) | ot d-e7 “) Riactio sat ve small: g*sf4u (uo) —y — a = kc (AS eur) | | Cc dorge: gp FCe_ Q _. dt | = ia aE = 4 (0 ody) Photo chunnieat (xa tation ” | AE =&- he |, [— é 6 a Ate pot: fs Be aw, | fT) = Hea spell) an Agee Rathi) i] ae) pu Cc ght's ran ™) Ay Planck ((. 626 11074 eo ) shit} 341 > a eile wh Mage (e260 Highs frequnuy ys F DPATIUIRO DEL gna teas of ho chumistry ( phofp dunt eal cy dow ) 4:[T) We A = Number of absorbed photos : ae : — Number Op en Ge te t= Na = 4 rol y 6.020 107 \ Real lye ne o> Aa Quan-hun gids y », Pp =Dge ee“Trem BT ToT preprtionl (dip aa aise) RT > cf Dat. increase (deg rhurg khéig #2) Rema b imverse CA" UP aghioh > eee a proper Bon ak CATA LY SIS van fags Aowet athvuken dnt gay IN don't chowge equilibrium content selbetivisy Homo gent ous cata lyAt E — At same phae as Au pactants Cadet (Kuro ke) | Cae 2 (k29 late] = ABK +: Archania comple” —— ASK + Van't Hopp tampe a ee ee pag . = R= bpTaee) -ky [a1 resTely | Akt ke, 0+) eal p-ninrl. eran © Lonear veep von ae A ++_ i) Ke Keg PF. (3) f(s \, [a1] C6) wry Aigh @ = FT ! AIC 8) sly R= ky keqlA)L6). fk] 9 4 ka ka = 45He tere gentous catadyst — Te dierent phose ad te veattantA — GEN i pecan Aolidh ~ 3% shepard \ N nm= porous 5 prep. 4. Dipgurien (external 5 . 1 2. Dijguaven ( tusernal 75 3. Adsoiptiay jot (reg Yonperatyre) 4. Sutjae reaction — rate AL wining akp S. Pesorphon fort b. Dippunton, (internat 4 +. Diypumon (external J” = Slowuat skp Ms nue — dterminin g Ap Vang muir —Hinshl wor ob Ely — Redeal — Poth adsorp | =p dort 4 adwyp A classification of metals according 10 their abilities in chemisorption Ges (0 pans ad Sep ‘Group Metals 0; CH; CH, CO Hy CO, Nz FZ (mans weak ad Sorp + + CC + ° Sk ~ there catalyst thet Bs # t GY 2 Fz weactants aelsorp, product iS fF FFT pet alse E 1 = @® Gta HS Oh [e imeans that strong chemisorption occurs; = means tat itis weak; ~means cat: A, By, Be bi” f A . - > men B.7 - . wnotsenatle) (nin cher at Aft Ad onidlt evn Leai dh anlidt aver, Kher by -4.% utae. at 0 ow hod de dang, al > Abyss} odscrphev \ \ Iwo cal Shen nly brand ¢ phyorel » wedkly odd scip hin Saphon,> Lan grunt C Asother my, lo k - AtS — AS B= kp, (4-84) K B= 0, Pn 4-6, * on Kn PA At equi byte KA = aderplin consieny = (K ~ Ta kaPa | mE® ‘ > parhaul presure of A ke & i a S suyaw Wouragt Of fret Si2e A nN 8 2 Dp ApS Ee ea Cee ne - Z Ax¥paPa + Ke Py Rate of reaction 2 Ha que ao Als [ee tkePa | A adiorbet ‘adverbed not A Kaka s kin PA | al: not adsorbed adsorbe (weal in jable) Adsorption rate Condit ov RW Reactant > weak 155 ka Pat Ka Pe REREAD (a ade ) Peder: weak | 1 mI part Bachata skater Kaha R= Ela (comet acy ah Product. weak A+ Kp PA He | | RochnE: Seng Oy da kg Oy | R= (0 ob > Product: weak Reactant. weak rot Ka PA, >> Ky Pa - Aka Pa Product. Shion “ “ R wa ( predoct A TAENZYME = lok and ty medel Kale is apseced hy Ni temperahore 5 sen wet Hod Aart intensen vath S nt ange a (s} M tunes’ howe a v Mos k 4 = Soe Conve ak e ES a E 4P q we => main this cep R= ¥,fesj= & [ETSI | pr Pr aR 1% fe, | _ ; [3] + Km ge kee tS] | eneaynt BETS | Be = EE ard satya eae Giax dvan | Gd lide R AH, tonpeahrs- oe : days poh | [SVC< Km | ge Reon PS) eee | Kw etm Mee Red Bae vd at J ( khng Angi’ Nek Ah ) tae pha thudt | va 19) vila) Linewearer ~ Burk aura yrs : [a +a tm |Z ft dite time rs] rs = ree + 4 | R~ Rinwe Rmax [S| alt Waing thir _ . V24yme . ) opens v~ — Dineweare’ uno Kena Maze AK 7 | = ¥ j [Pm = TEM Bron Riva hy aki -————> oen yd => wtetaciny shenger do (Spud cmatl aunt to Haves — Wolf plot: ESV _ km OS) km 18 R Rmaw Rak — Ky [E]y ele]; Eadie ~ Hopske > R= Rw ~ky Bo 4eh ae See Twhibction Of enayme aban : ts} co Leh | ma (ange danyptoek.) | Nowm eampel tive | Uncam pep tine Todubrter ond pubdate “Tle inhibitor dots not bind on [The iphibiter bind on the Compete with gach otter the ace sites, but its branching, eae mp —tubstake cumple jo Vind on the active ied Ot notion oie apfeds the" pod stabilind thon Alt son Oy Confer roa bon So THe tuutd not break te products Of the drayine in aun oaginally achive Files > iwactive iba) ae! CT AY TD MR / Ek potty prs). 7 a a | ZT}, Het L mM th THIEL), an, - ; { 27m! NTF aT, ot Ah IID yf 1/ki fentestt pecs) >, Afloa (A WD fy Ayn (14 093/46) a. km], HI\4 4. km (y,)E 4 _ kw 4d 1 a ea ( . ois R rea i dA R Rot atta 2) “f= | + cel MM D Kmat Krak kr Rae: Ro * Ems Vy Van * Kn svEyyect op ph: fe}, (8) ve eT (te Bee TH k nh . oA" ta” . = * ray EH +S a> ENS —t> EAP : 7 et Te Kym = Ks 4a bee Ba Enrymt activation Wy mab dant : km tm ee Fem ~ en koe em EM 4S Ms es Ms Ex? 1M Me petal don Ka Km + kmP) + £5) [tke Application L Sulfa dimeys Yeniadlin, Colfinien theory | an wv vy? Ts tan hi a chara ung Am ae = and (ae [ ee - MN Ps Pa | ww S . n= RT nogodro i ~ &.44 > ® votalty A = ee ee pep , mt (Met) Sones AUK sTT: od Ny Add ely cholate olution > O's < Add fwyjaciant > Opbutin < O'ndee Zor o, reather PO