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Article history: Mushrooms (Paris variety) were dehydrated in a hybrid solar dryer (HSD) provided with a 3 m2 solar
Received 3 December 2012 panel and electric resistances. Mushrooms were cut in 8 mm or 4 mm thickness slices. At the outlet of
Accepted 23 January 2013 the tray dryer 80–90% air was recycled and the air temperature was adjusted to the pre-defined levels
Available online 19 March 2013
(50 or 60 °C). At the outlet of the solar panel the air temperature raised between 2 and 20 °C above
the ambient temperature, depending mainly of solar radiation level.
Keywords: Temperature, slices thickness and air recycle level had statistically significant effects on critical mois-
Effective diffusivity
ture content (Xc), as well as on the time necessary to reach a moisture content of 0.1 (wb).
Color
Thickness effect
The color parameters of dehydrated mushroom indicate a notorious darkening, in all runs. Rehydration
Drying assays at 35 °C showed that in less than 30 min rehydrated mushrooms reached a moisture content of 0.8
Solar energy (wb).
Effective diffusivity (Deff) was estimated by the Simplified Constant Diffusivity Model (SCDM), and it
ranged between 6E10 and 40E10 m2/s, with R2 higher than 0.98, agreeing with literature. The adjust-
ment of experimental drying kinetics with the empirical Page’s model resulted in R2 higher than 0.997.
Finally, the input of solar energy resulted in 3.5–12.5% energy saving. These values could even be
improved by increasing the agro-product load in the HSD.
Ó 2013 Elsevier Ltd. All rights reserved.
1.1. Generalities Chile belongs to the southwest hemisphere, located to the west
form Greenwich meridian, between 17°300 and 90° south latitude.
Drying is one of the most energy-intensive processes in the food Chile is 4270 km length and its maximum width is 445 km. This
industry [1–3]. Traditionally the required energy comes from fossil geographical location shows marked irradiation differences along
fuels, which show continuously growing prices and negative im- the country. Thus, in the north zone there is a high irradiation level
pact on the environment [4,5]. In search for new energy sources, that gradually diminishes when moving towards the south zone.
solar energy is an attractive non-polluting alternative to be used On the other hand, most agricultural production in Chile is ob-
in drying processes [1,6,7]. The duration of the sunshine as well tained in the central zone. In this sense, the Metropolitan region,
as its intensity depends on the season, weather conditions and where the capital Santiago is found, exhibits an irradiation level
the geographical location. The partial (or total) replacement of tra- similar to the average of the central zone of Chile. In addition, en-
ditional fuels by solar energy in drying processes will result in con- ergy consumption projections in Chile indicate a serious energy
siderable energy savings, thus reducing the CO2 emission deficit for the next decade, and therefore solar energy constitutes
responsible for global heating [6]. However, the daily and seasonal an interesting alternative.
fluctuations in the irradiation level represent an important draw-
back, that makes it necessary to use additional energy sources
and/or energy accumulators that allow the operation during the
1.3. Solar dryers
low or null irradiation periods.
0196-8904/$ - see front matter Ó 2013 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.enconman.2013.01.032
32 A. Reyes et al. / Energy Conversion and Management 70 (2013) 31–39
Nomenclature
cultural products in order to keep quality, i.e. vitamins, color, fla- 1.4. Drying of mushrooms
vor, etc. [3].
Drying by solar radiation can be divided into two categories: Mushrooms are edible fungi that exhibit high nutritional value,
(a) direct or open sun drying; and (b) indirect or convective solar and therefore their commercial importance and consumption have
drying. Open sun drying may be an efficient and cheap process, increased. They show high content of some vitamins, minerals,
but it has some disadvantages such as contamination by dirt, in- essential amino acids and fiber. From the almost 2000 mushroom
sects and bacteria, and loss due to wetting by rain squalls [5,8]. In species, only about 20 are grown for commercial purposes [20].
order to avoid the previous disadvantages, indirect solar dryers In Chile its consumption has increased in the last 5 years up to
have been developed, in which the foodstuff is kept inside a an average annual consumption of 0.4 kg per capita, however it
chamber. is still low with respect to other countries such as Taiwan (7.3 kg
In past years, the use of solar dryers was encouraged in high per capita) and Netherlands (6.5 kg per capita). Unfortunately
radiation zones, especially in rural communities, aiming to exploit mushrooms are extremely perishable and their shelf life is about
solar energy potential for foodstuff dehydration, using simple dry- 24 h at ambient temperature and it can be extended to 7–10 days
ers [3,9–12]. However, the energy crisis and global heating prob- when refrigerated. As a consequence, mushrooms are usually dried
lems have resulted in an increase of the use of solar energy, even to extend their shelf-life. Since mushrooms are thermo-labile,
in moderate radiation zones, by means of more sophisticated choosing the right drying conditions is relevant [21].
dryers. Usually the consumption of dehydrated mushrooms requires
In order to allow using the solar dryer in low or null radiation rehydration, which is influenced by the processing conditions,
periods, hybrid solar dryers have been designed that consider the sample composition, sample preparation and extent of the struc-
use of additional energy sources (biomass, hydrocarbons or elec- tural and chemical disruptions induced by drying [22].
tricity), which is employed in such periods [13,14]. These systems
consist of three main components: (a) solar energy capture panel 1.5. Objectives
(flat plate collectors), (b) additional energy generator or accumula-
tor, and (c) convective drying chamber [2,5,15,16]. The objective of this work was quantifying some quality param-
Several studies evaluated the technical and economical feasi- eters (color and rehydration) and the solar energy fraction that can
bility of hybrid solar dryers (HSDs): Boughali et al. [5] evaluated be used in a hybrid solar dryer (pilot level) for mushroom dehydra-
a HSD for tomato slices dehydration, informing that the solar en- tion, under different operating conditions. In this dryer the com-
ergy input fluctuated between 13% and 25% as complement to plementary energy source was electric, because of its availability
electric energy. Amer et al. [8] dried ripe banana slices in a dryer and convenience, even though at industrial level the preferred en-
which was operated during normal sunny days as a solar dryer, ergy source is methane or biomass.
during cloudy days as a HSD, and using the energy stored in
water during the night, which was collected during the time of 2. Mathematical modeling
sunshine and with electric heaters. Bhattacharya et al. [17] dried
banana and chili (16 kg each) in a dryer that could be operated The drying processes consist of the constant rate drying period
during normal sunny days as a solar dryer, during cloudy days and the falling rate drying period. An approach to describe food
as a hybrid solar/biomass dryer, and at night with energy pro- dehydration process during the falling rate period is based on the
vided only by biomass combustion. Pangavhane and Sawhney concept of effective diffusivity (Deff), which allows describing the
[18] showed the evolution of solar dryers for grapes, including diffusion of moisture by Fick’s second law. This equation can be
traditional solar dryers and HSD. Bennamoun and Belhamri [19] integrated for different geometries, boundary/initial conditions
used a solar batch dryer with a 3 m2 surface collector and an elec- and special physical and mathematical considerations [23]. The
trical heater. analytical solution of the Fick’s second law is well known for
A. Reyes et al. / Energy Conversion and Management 70 (2013) 31–39 33
one-dimensional geometries (infinite slab, infinite cylinder and (HSD) was designed and built, with a maximum load of 15 kg (Figs.
sphere), although the mathematical solution for finite regular sol- 1 and 2). The HSD was equipped with temperature, pressure,
ids can be obtained as the product between two or three one- humidity and solar radiation sensors. The solar panel was located
dimensional solutions [23,24]. On the other hand, during convec- on the roof of the 4-floors building, while the drying chamber
tive drying of agro-products the solid shrinks, resulting in possible and control devices were located in the 4th floor, immediately be-
variation of Deff along the drying process [25,26]. low the solar panel.
A simplified approach considers that diffusivity remains con- The hybrid solar dryer (HSD) consists of a 3 m2 (3 m length and
stant, that there is no shrinkage, the conditions of the drying air 1 m width) solar panel composed by a glass sheet (5 mm thickness)
do not vary and that the external resistance to mass transfer is neg- and a black wavy zinc plate. Below this zinc plate a thermal insu-
ligible. Besides, it must be taken into account that usually the equi- lating material was located (50 mm thickness of mineral wool).
librium moisture content of mushroom is relatively small at drying The air passes through the free space (30–50 mm height) between
conditions. With these assumptions, for an infinite slab of thick- the glass and the zinc plate until reaching the mixing point with
ness 2L and diffusion in the x direction, the Constant Diffusivity the recycled air. This air mixture enters the electric heating system
Model (CDM) is obtained [24]: composed by 5 kW electric resistances where the air temperature
is adjusted to the desired level (50 or 60 °C). After that, the air en-
XðtÞ X eq XðtÞ
/x ¼ ffi ters the drying chamber (0.5 m 0.5 m 1.2 m), where it distrib-
X o X eq Xo utes to pass over 10 perforated plate trays made of stainless steel
X
8 1 p2 Deff t (0.45 m 0.5 m), located in two sections of five trays each one.
¼ exp ð2n 1Þ2 ð1Þ
p 2
n¼1 ð2n 1Þ
2 4L L The air flow rate through the trays varied between 0.8 and
1.0 m/s.
By omitting the factor 8/p2, and considering only the first term The air is sucked through a 3 KW blower and directed to the
of the series, Eq. (2) is obtained that corresponds to the Simplified electric resistances zone, although a 10–20% fraction is removed
Constant Diffusivity Model (SCDM) for an infinite slab of thickness from the system through valve V2.
2L, which allows a semi empirical estimation of Deff: The HSD is provided with a data acquisition system OPTO 22
(model SNAP-PAC-R1), which allows registering air temperature
XðtÞ p2
/x ¼ ¼ exp Deff t ð2Þ at the outlet of the solar panel (Tsp), temperature and relative
Xo 4 L2
humidity at the inlet of the drying chamber (T1 and RH1) [Hanna
Rahman and Kumar [25] reported Deff values in the order of 30% Instruments, HI 8666, RH/°C transmitter] and temperature and rel-
higher when considering one-dimensional (infinite cylinder) with ative humidity at the outlet of the chamber (T2 and RH2). Pressure
respect to finite cylinder. Besides, when shrinkage is neglected, Deff drop was registered through two Pitot tubes located at the outlet of
values resulted about 30% higher than considering shrinkage. the centrifugal fan and the outlet of valve V2, in order to determine
Reyes et al. [26] for regular particles of carrots (parallelepipeds) ad- the air rate. The solar radiation was determined by a Pyranometer
justed Deff in terms of shrinkage, temperature and air velocity. (Li-200SA) located at one side of the solar panel on the roof of the
Besides, many empirical models have been used to adjust the building. This information was stored in a PC. Air pass valves open-
dehydration curves [27–29]. The most common model for agricul- ing was controlled from a PC.
tural products is the empirical Page model, given by Eq. (3), where
k (min1) is a dimensionless value and t (min) is the drying time 3.2. Materials
[30].
Drying runs were performed using mushrooms (Paris variety)
XðtÞ
¼ expðk t n Þ ð3Þ purchased in the local market. Mushrooms were soaked for
X0 5 min in a disinfectant solution (10% benzalkonium chloride),
which was diluted 600 times in water. After that mushrooms were
3. Equipment, materials and methods thoroughly rinsed. Then, mushrooms were cut in 4 mm or 8 mm
slices.
3.1. Equipment
3.3. Experimental procedure
In the Unit Operations Laboratory (Department of Chemical
Engineering, Universidad de Santiago) the hybrid solar dryer 3.3.1. Drying kinetics
About 6.5 kg of mushrooms were put in the dryer, distributing
0.650 kg in each tray (0.48 m 0.58 m). Additionally 0.050 kg
was loaded in two wire baskets, which were located in Sections
1 and 2, respectively, and were weighed every half hour. The initial
mass was measured with a balance (Boeco BBL62, Boecktel Co.,
Germany). After 30 min, the wire baskets were taken out from
the dryer, weighed and then put back. This procedure was repeated
until moisture content was below 10% (wb).
To obtain the drying curves, samples of the solids were removed
of two sector of the dryer and their moisture content was deter-
mined by measuring the difference in weight between their wet
state and after drying exhaustively at 85 °C on a digital balance
with a sensitivity of 0.01 g.
A. Solar panel; B. Electrical heater; C. Chamber drying;
3.3.2. Color
D. Centrifugal fan; E. Exit air. Vi. Valves.
The color of the samples was measured with a colorimeter
Fig. 1. Scheme of the hybrid-solar dryer. (A) Solar panel; (B) electrical heater; (C) (Minolta Chromo Meter CR 200b) using the Lab color scale, which
chamber drying; (D) centrifugal fan; and (E) exit air. Vi. valves. is an international standard for color measurements, adopted by
34 A. Reyes et al. / Energy Conversion and Management 70 (2013) 31–39
Fig. 2. Pictures of the hybrid solar dryer. (A) Drying chamber; (B) drying chamber containing mushrooms; (C) solar panel before installation; (D) solar panel installed on the
roof of the building; and (E) general sight of the solar panel.
ments were made under a CIE D65 illuminant which simulates dif- Run Air recycle (%) Temperature (°C) Thickness (103 m)
fused daylight. Color measurements of mushrooms were made on C1 90 50 4
a Petri dish over a white plate and replicated ten times after mixing C2 90 50 8
the dried samples, and the average values of L⁄, a⁄ and b⁄ were re- C3 90 60 4
ported. Mixing of samples was done primarily to account for color C4 80 60 4
C5 80 60 8
variation among dehydrated mushroom slices.
C6 80 50 8
Color variation between fresh (denoted by the subscript ‘0’) and C7 80 50 4
dehydrated mushrooms, was used to describe the total color C8 90 60 8
change DE after drying by means of the following equation:
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
DE ¼ ðL0 L Þ2 þ ða0 a Þ2 þ ðb0 b Þ2 ð4Þ was measured by the procedure given previously in the description
of the drying procedure.
4. Results
Fig. 3. Ambient and solar panel temperatures and solar radiation. (A) Run C2, (B) Run C8, (C) Run C4, and (D) Run C7.
36 A. Reyes et al. / Energy Conversion and Management 70 (2013) 31–39
Fig. 5. Temperature and relative humidity at the inlet and outlet of the drying chamber. (A) Run C2, (B) Run C8, (C) Run C4, and (D) Run C7.
Air temperature (T1 and T2) and relative air humidity (RH1 and
RH2) at the inlet and outlet of the drying chamber were also regis-
tered, which are presented for some runs in Fig. 5. Fig. 5A shows a
special situation that corresponds to run C2, where inlet tempera-
ture could be maintained at 50 °C only during the first 3 h of dry-
ing. After that this temperature gradually raised up to 58 °C, even
when electric resistances were turned off. This agrees with the so-
lar radiation peak. In other words, in high radiation days drying
could be performed using mostly solar energy. Fig. 5 shows that,
for all runs, the relative humidity at the inlet of the dryer (RH1)
fluctuated between 25% and 35%, rising drastically at the outlet
of the dryer (RH2) up to 55–75% during the first hour drying. This
can be attributed to the quick removal of unbound water. As the
process went on, RH2 gradually decreased, coming near to RH1
after 5 h drying. Additionally Fig. 5 shows that most of the drying
period, the relative air humidity at the outlet of the drying cham-
ber was below 40%, i.e. still having a high drying potential. As a
consequence, the foodstuff load could be increased.
Fig. 6. Drying kinetics of mushroom slices (%R = air recycling; T = air temperature;
4.2. Experimental drying curves and E: slice thickness).
inlet air temperature. The drying curves (Fig. 6) exhibit the ex-
pected behavior: a linear decrease of moisture content in the initial
period, until reaching the critical moisture content, which was
0.45 ± 0.12, where the non-bound moisture was removed; and
after that the bound moisture was removed following an exponen-
tial trend in terms of time. As expected, the lower drying rates
were achieved with thicker particles and at lower temperatures.
An unexpected behavior was observed in run C8 (in both replicate
runs), which was very similar to results of run C4, probably due to
the higher air recycling ratio that compensates the larger thickness
of the particles used in C8.
However, the statistical analysis showed the opposite. A possible C1 0.50 0.44
explanation of this behavior is that increasing the air recycling re- C2 0.55 0.57
C3 0.45 0.48
sults in an increased air humidity, which in turn reduces the col-
C4 0.32 0.35
lapse of the superficial cellular structures thus facilitating C5 0.43 0.50
moisture removal. C6 0.54 0.55
Fig. 8 shows the fluctuation of the estimated effects of the C7 0.42 0.40
C8 0.45 0.50
experimental factors on moisture content of mushroom in time.
During the first hour of drying, the factor thickness had no signif-
icant effect on drying rate, agreeing with the removal of unbound
water from the particles surface. Slice thickness had a positive ef- Table 3
fect (higher thickness implies longer drying time) on moisture con- Color parameters.
tent from the minute 90 onwards, which agrees with the beginning Run DE DL Da⁄ Db⁄
of the bound water release. On the other side, both air temperature
C1 32.70 31.32 5.66 7.53
and air recycle had significant negative effects on moisture C2 37.05 36.08 4.65 7.03
content. C3 38.71 38.32 3.09 4.54
C4 49.99 49.82 4.16 0.10
C5 32.65 31.59 3.60 7.40
C6 26.34 25.78 2.23 4.93
4.2.2. Critical moisture content
C7 31.27 29.84 5.50 7.55
The slope change in moisture content versus time plots allowed C8 34.89 33.41 4.07 9.20
determining critical moisture content for the eight runs and their
replicates. The values obtained from drying rate versus moisture
content graphs were similar, but showed higher variability. Tem-
4.3. Color
perature, slice thickness and air recycle percentage showed statis-
tically significant effects on Xc and time required to reach moisture
The color parameters (a⁄, b⁄, DE, and L⁄) of dehydrated mush-
content of 0.1. Xc diminished with temperature increase, and it in-
room indicate a notorious darkening, in all runs (Table 3), which
creased with slice thickness and air recycle percentage. Drying
agrees with the results informed by Kotwaliwale et al. [31] for dry-
time decreases proportionally to Xc, since higher values of Xc result
ing of Oyster mushroom. The statistical analyses of the color
in shorter constant drying rate periods (highest drying rate). For
parameters were not affected by the experimental factors. A possi-
this reason, it is recommendable selecting operating conditions
ble explanation could be that temperature was expected to affect
that reduce the critical moisture content (see Table 2).
them, but the temperature range studied could have been too nar-
row (10 °C). Another possible explanation is that the color of each
particle was uneven, exhibiting evident differences in color param-
eters. As a consequence, despite random sampling, color measure-
ments could have a high variability.
Table 5
Absorbed solar energy/electric energy input [Qsp/Qe].
between 0.1 and 0.8, depending on solar radiation level and oper-
ating conditions. The average efficiencies (given in Table 5) ranged
between 0.035 and 0.117. Even though these values are not very
high, they result in considerable energy saving and also in a reduc-
tion of CO2 emission. These values could probably be improved by
Fig. 9. Rehydration profiles of mushroom slices. increasing the mushroom load in the HSD, since in this work only
40% maximum capacity (15 kg) of the dryer was used. Amer et al.
The time required to reach this moisture content was shorter for the [8] used solar dryer containing solar reflectors with holders to
thinnest slices due to the shorter diffusional path of water. move them according to the sun angles during the day. They re-
ported that the instant efficiency of the dryer rose up to 75% by
4.5. Adjustment of experimental drying curves recycling about 65% the drying air.
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