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Tim Edwards*
Air Force Research Laboratory, Propulsion Directorate
Wright-Patterson AFB, OH
military jet fuels JP-5,7,8 and T-6, commercial jet fuels became apparent that several fuel properties were key
Jet A, Jet A-1 and TS-1, and kerosene rocket to bounding the envelope of jet fuel characteristics.
propellants RP-1 and RG-1. Chemical class High altitude operation (with ambient temperatures on
composition will be discussed, as well as pertinent the order of -65 F) meant fuel freeze point required
physical properties. Sources of physical property data attention. However, the lower the freeze point the
and modeling approaches will also be discussed. lower the fraction of crude oil that was suitable, so
freeze point had to be balanced against availability.
Atomization and altitude relight were aided by higher
INTRODUCTION fuel volatility (vapor pressure), which had to be traded
The discussion of kerosene fuels divides fairly against boiloff and entrainment losses from fuel tanks at
naturally into two applications: turbine engines and altitude (as well as safety concerns from explosive
liquid rockets. The term kerosene is used to describe a mixtures in tank vapor spaces) [Maurice et al, 2001a].
distillate fraction of petroleum boiling between Two fuels emerged in the late 40’s and early 50’s from
(roughly) 150-300 C (300-570 F). An illustration of the this chaotic situation: a “wide-cut” gasoline/kerosene
resulting distribution of the hydrocarbons in various mixture called JP-4 in the U.S. (MIL-F-5624 in 1950)
fuels is shown in Figure 1. and a kerosene fuel with a -50 C (-58 F) freeze point
specified as DERD-2494 in England and Jet A-1 in the
Turbine Engine Fuels U.S. ASTM D-1655 specification. This freeze point
The early pioneers in gas turbine development, was arrived at through a significant research effort.
Whittle in England and Von Ohain in Germany, faced a ASTM D-1655 also specified Jet A with a -40 C (-40 F)
wide variety of options in choosing a fuel for gas freeze point. Civil aviation currently uses Jet A-1 (or
turbines. Whittle had considered diesel fuel, but ended its equivalent) throughout the world, except for
up choosing kerosene because of an expected domestic carriers in the U.S., who use Jet A. Military
requirement for a lower freeze point than that available aircraft used JP-4 until converting to JP-8 in the 1980s.
with diesel [Martel, 1987]. In contrast, Von Ohain JP-8 (MIL-T-83133) is essentially Jet A-1 with a three
originally decided to use hydrogen, but combustor military-specified additives-fuel system icing inhibitor,
developmental difficulties led to a switch to liquid fuel corrosion inhibitor/lubricity improver, and static
[Dukek et al, 1969]. The world’s first turbojet-powered dissipater. The conversion to JP-8 occurred primarily
flight was made on August 27, 1939 in a Heinkel 178 to improve the safety of aircraft, although the “single
aircraft burning aviation gasoline. The first flight of the fuel for the battlefield” concept (and the similarity of jet
Whittle engine occurred on May 15, 1941 in a Gloster fuel to diesel fuel) is centered on the use of aviation
Meteor aircraft using kerosene as the fuel. Despite their kerosene in all Air Force and Army aircraft and ground
head start in turbojet engine development, Germany did vehicles. The history of the evolution of conventional,
not decide until 1943 to produce jet-powered aircraft. widely available jet fuels from the late 1950s to the
________________________ present is mainly the story of the evolution of test
*Associate Fellow, AIAA methods and fuel additives to maintain the integrity of
the jet fuel supply and to improve safety and correct
operational problems.
1
American Institute of Aeronautics and Astronautics
This material is declared a work of the U.S. Government and is not subject to copyright protection in the United States.
Specialty fuels were developed for various specification was published in the absence of user
applications throughout the second half of the 20th requirements.
century. JP-5 (included in MIL-F-5624) is a high-flash Beyond Mach 5, flight speeds are considered
(140 F) kerosene used on-board U.S. Navy ships to hypersonic (vs supersonic). The high heat loads
enhance safety. The development of higher Mach encountered by vehicles in hypersonic flight leads
aircraft led to several specialty fuels. As flight velocity inevitably to regenerative cooling of (at least) the
increases, aerodynamic heating leads to larger amounts combustor. The heat loads and fuel flows are such that
of heat being rejected to the fuel, both in the tanks and high levels of fuel heat sink are required. This heat sink
in the engine, leading to vapor pressure and thermal can be obtained from sensible heating of high heat
stability concerns. The cutoff point between the use of capacity fuels such as liquid hydrogen or the use of
conventional Jet A-1/JP-8 fuels and specially-produced endothermic (hydrocarbon) fuels. For many
fuels is between Mach 2.2 and 3. Thus, the Mach 2.2 applications, hydrocarbon fuels are preferred due to
Concorde uses Jet A-1, while the Mach 3 XB-70 and their greater density [Lewis and Gupta, 1997] and ease
SR-71 used specialty fuels. JP-6 (MIL-F-25656) was a of handling. Endothermic fuels achieve heat sink by
low-volatility kerosene developed for the Mach 2+ XB- deliberate reactions of the bulk fuel, such as
70 [Freschl and Steele, 1965]. The Mach 3 SR-71 dehydrogenation or cracking [Maurice et al, 2001b;
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required JP-7 (MIL-T-38219), a low-volatility/high- Lander and Nixon, 1971; Sobel and Spadaccini, 1997;
thermal-stability, highly-processed (low sulfur and Ianovski, 1993]. Engine concepts for hypersonic
aromatics) kerosene [Martel, 1987]. The U-2 high- aircraft are currently under development in several
altitude reconnaissance aircraft required both improved programs.
thermal stability and lower freeze point in its fuel (JP- World-wide jet fuel consumption was 177
TS, MIL-T-25524) because of its high altitude, long million gallons/day in 1997, with about 40% of the
duration cruise. These specialty fuels gave higher consumption in the United States [Bacha, 2000].
performance than conventional aviation kerosenes, at
the expense of higher fuel and logistical costs (JP-7 and Kerosene Rocket Propellants
JP-TS are roughly 3X the cost of JP-8/Jet A-1). The
Oxygen/hydrogen is the highest performing
temperature limits of these various fuels are
operational propellant family. Of course, the low
approximately 325 F for Jet A/Jet A-1/JP-8, 425 F for
temperatures (20 K) and explosion hazards of hydrogen
JP-TS, and 550 F for JP-7 [Croswell and Biddle, 1992].
impose significant launch cost penalties. The low
Just for completeness, it should be noted that JP-9 and
density of liquid hydrogen (4 lb/ft3) is also a drawback.
JP-10 are high density missile fuels, not kerosene fuels,
For these reasons, Russian launch vehicles and many
and consist of one (JP-10) and three (JP-9)
U.S. vehicles have used various types of liquid
hydrocarbons. Typical kerosene fuel properties are
hydrocarbons as a fuel. Although Goddard’s initial
shown in Table 1.
1926 flight test used gasoline, operational hydrocarbon-
Russian jet fuels underwent a parallel
fueled rockets since then have used kerosene. Jet fuels,
evolution throughout this period [Ragozin, 1961;
as described earlier, are kerosenes; naturally, jet fuels
Pustyrev, 1993]. In most properties, current Russian
like JP-4 were the initial kerosenes used in rocket tests
fuels TS-1 and RT and Russian specifications (GOST
(although JP-4 does not strictly fit the definition of a
10227) are interchangeable with Jet A-1/JP-8. The
kerosene because of its low initial boiling point).
main difference between fuels TS-1 and RT is in the
However, it was found that jet fuel did not have tight
area of thermal stability: TS-1 is a straight run fuel,
enough specification properties to serve as an effective
while RT is hydrotreated. By comparison with Jet A-
propellant. The U.S. developed Rocket Propellant 1
1/JP-8, TS-1 and RT are “lighter” (have a lower initial
(RP-1) in the mid 1950s as MIL-P-25576. In
boiling point and 10% recovery point in distillation)
comparison to jet fuel, RP-1 has a much narrower
and have a correspondingly lower flash point and freeze
allowable density range, and lower limits on fuel
point. For example, recent unpublished surveys of
components that were thought to cause deposits during
Russian jet fuel at Moscow airport have shown an
regenerative cooling, such as sulfur, olefins, and
average flash point of 97 F (vs 127 F for Jet A-1 shown
aromatics [Sutton, 1992]. Deposit formation (“coking”)
in Table 1). Pustyrev discusses two specialty Russian
led to a maximum fuel-wetted surface temperature limit
fuels specified in GOST 12308: T-8V, a higher
quoted as 600 F [Cook and Quentmeyer, 1980], 600-
density/higher flash kerosene and T-6, a high density
700 F [Wagner and Shoji, 1975], 580 F [Rosenberg and
kerosene (specific gravity 0.84 vs 0.8 for Jet A-1/JP-8)
Gage, 1991], 710 F [Liang et al, 1998], and 850 F [Van
which has no commercial or military counterpart in
Huff, 1972]. The amount of coking is very dependent
Europe or the U.S. [Pustyrev, 1993]. U. S. Air Force
upon the fuel-wetted surface, with copper causing more
programs in the 1980s demonstrated the production of
deposition than steel. Russian kerosene (“RG-1”,
fuels similar to T-6 [Hanson, 1989; Smits, 1986], but no
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American Institute of Aeronautics and Astronautics
“naphthyl”) is somewhat different from RP-1, notably the RD-180, RD-170, and NK-33. Aircraft fuel T-6 has
with a higher density (0.832 vs 0.806 at 22 C) [Mehta et been used in engine tests in place of RG-1 because of
al, 1995]. RG-1 has been chilled before use to increase its similar physical properties and greater availability.
its density (and thus the mass of propellant that can be Typical kerosene propellant properties are shown in
loaded onto the rocket). Engine applications include Table 2.
60
Avgas
RP-1
50 JP-7
Jet A
diesel
40
Weight %
30
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20
10
0
4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Carbon number
Figure 1. Carbon number distribution for several kerosene fuels [Edwards, 2001], diesel [Briker
et al, 2001] and avgas [Bacha et al, 2000].
Table 1. Typical aviation fuel properties [Coordinating Research Council, 1983; Martel,
1988; Martel, 1978; ; Goodger and Vere, 1985; Sobel and Spadaccini, 1997; Yu and Eser, 1995;
Mehta et al, 1995; Defense Energy Supply Center, 1997; Wood et al, 1989; Hanson, 1989;
Favorskii and Kurziner, 1990]
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American Institute of Aeronautics and Astronautics
Table 2. Typical kerosene propellant properties [Mehta et al, 1995]
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American Institute of Aeronautics and Astronautics
400
90-96 (18.2±3.1 vol%)
Millions of gallons
99 (17.7 ±3.1 vol %)
350
JP-8
300
250
200
150
100
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50
0
9 11 13 15 17 19 21 23 25
Aromatics, vol%
250
200
Frequency
150
100
50
0
-58 -56 -54 -52 -50 -48 -46 -44 -42 -40
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American Institute of Aeronautics and Astronautics
Table 3: Hydrocarbon classification ASTM D2784
Jet A-1 JP-8 JP-8 JP-5 Jet A
Paraffins 38.3 44.0 46.3 50.7 49.4 (avg
C # = 12)
Cycloparaffins 41.6 36.2 39.5 20.9 34.2 (12)
Alkyl benzenes 12.6 16.5 7.5 17.7 12.7 (10.7)
Indans/tetralins 4.4 2.3 3.9 9.3 2.1 (11)
Indenes/dihydrona 0.9 0 0.5 (10)
phthalenes
Naphthalenes 3.0 0.5 1.9 1.1 0.7 (11.5)
Average carbon 10.6
number
Reference AFWAL- unk AFAPL- AFAPL- AFAPL-
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American Institute of Aeronautics and Astronautics
Table 5. RP-1 composition by GC-FIMS
1-ring 2-ring 3-ring Benzo- Benzo-
Isoparaffins n-Paraffins cycloparaffins cycloparaffins cycloparaffins Alkylbenzenes cycloalkanes dicycloalkanes Naphthalenes
c7 0.000 0.000 0.004 0.000 0.000 0.021 0.000 0.000 0.000
c8 0.000 0.011 0.030 0.002 0.002 0.350 0.000 0.000 0.000
c9 0.044 0.063 0.697 0.135 0.013 1.149 0.009 0.000 0.000
c10 0.590 0.244 4.154 2.372 0.113 1.848 0.132 0.000 0.003
c11 4.810 0.817 11.525 7.590 0.607 1.807 0.372 0.005 0.327
c12 8.058 0.687 10.637 6.514 1.167 1.205 0.496 0.014 0.041
c13 7.902 0.052 5.855 3.427 1.117 0.372 0.180 0.006 0.011
c14 4.465 0.136 2.580 1.585 0.608 0.048 0.018 0.000 0.000
c15 1.099 0.039 0.736 0.651 0.150 0.005 0.003 0.000 0.000
c16 0.158 0.016 0.056 0.041 0.002 0.000 0.000 0.000 0.000
sum 27.127 2.064 36.274 22.316 3.778 6.806 1.210 0.025 0.384
Table 7. Typical fuel compositions. JP-7 composition uncertain (see text above).
7
American Institute of Aeronautics and Astronautics
modeling surrogate would match real aviation fuels 2002]. Whether these changes would improve the
more accurately if (1) the fraction of aromatics was accuracy of the model prediction for aviation kerosene
increased to about 18 vol%, (2) the aromatic was a C10 combustion is certainly debatable given the scarcity of
alkyl benzene, and (3) the non-aromatic component was experimental data. Surrogates for specialty kerosenes
an iso-paraffin and/or naphthene, as opposed to a n- like JP-7, RP-1, and RG-1 should be based primarily on
paraffin. A recent kinetic modeling effort for JP-8 used C11-C12 naphthenes and isoparaffins to match the real
butyl benzene as the aromatic component, consistent fuels as closely as possible.
with the data shown in Figure 4 [Montgomery et al,
7
Jet A 3219
Jet A-1 3136
6
alkyl benzenes
5
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Weight %
0
c7 c8 c9 c10 c11 c12 c13 c14 c15 c16
Carbon number
HEAT OF FORMATION
Heat of combustion calculation (lower
Unlike pure compounds, the heat of formation value) (∆Hc ):
of petroleum distillates is not well-defined. For
example, the heat of formation is usually given in
a(∆Hf CO2) + (b/2)(∆Hf H2O (gas)) - (∆Hf
kcal/mole; what is a mole of “kerosene”? If one fuel) – (a+(b/4))(∆Hf O2) = Heat of
requires the heat of formation (for an Isp calculation, combustion, in (typically) kcal/mole fuel,
for example), usually the heat of formation has to be ∆Hc Eq 2
back-calculated from the heat of combustion and the
fuel H/C ratio. If the heat of formation is required per
mole, one must be careful to define what the reference where ∆Hf = molar heat of formation {CO2=-94.05
“mole” is. Often, the kerosene fuels are defined as (for kcal/mole, H2O (gas)=-57.80 kcal/mol, O2=zero
example) C12H24 or CH.1.9. Table 8 provides the heat of (definition)}. The only unknown in Equation 2 is the
formation (in mass units) for kerosene fuels as heat of formation of the fuel. The molar heat of
calculated from the following equations: formation can be obtained using the overall formulas
from Table 5, or using another user-defined “mole”.
Table 8 includes two values of hydrogen content for JP-
Stoichiometry [molar basis] for complete 8, to show the sensitivity of heat of formation to
combustion: hydrogen content. The higher value of hydrogen
CaHb + (a+ (b/4)) O2 Æ a CO2 + (b/2) H2O content is consistent with the most recent JP-8 data
(13.81% in 1999 and 2000). The data in Table 8 was
Eq 1 iterated with Mike Zehe of NASA/GRC to compare to
8
American Institute of Aeronautics and Astronautics
existing kerosene fuel data in the NASA CEA code batch-specific heat of combustion and H/C ratio. Don
[McBride and Gordon, 1996]. Penn of AFRL/PRSE did such a calculation several
If one is interested in the variation in heat of years ago using 1997 data, with the result shown in
formation from lot-to-lot, say for the variable JP-8, the Figure 5. Note that fuels such as JP-7 and RP-1 are
DESC database could be used to calculate heat of much less variable than JP-8 (Jet A/Jet A-1).
formation for each batch of fuel delivered, using the
140.0
120.0
100.0
JP-8, M Ga
80.0
60.0
40.0
20.0
0.0
5
5
2.
3.
4.
5.
6.
7.
8.
9.
0.
1.
2.
3.
4.
5.
HF
-3
-3
-3
-3
-3
-3
-3
-3
-4
-4
-4
-4
-4
-4
H eatofForm ation,kcal/100g
9
American Institute of Aeronautics and Astronautics
SUMMARY Favorskii, O. N., and Kurziner, R. I., “Development of
Almost 200 million gallons of kerosene Air-Breathing Engines for High-Speed Aviation
aviation fuels are burned each day world-wide. This By Combining Advances in various Areas of
paper has summarized the characteristics and Science and Engineering,” High Temperature, Vol.
composition of these fuels to a limited extent, and has 28(4), pp. 606 613, 1990 (translation of Teplofizika
discussed some of the simplifications that are used to Vysokikh Temperatur Vol 28(4) 793-803, 1990).
approximate these fuels for various purposes. Freschl, E., Steele, E. S., “Development of the XB-70A
Propulsion System,” AIAA Paper 65-571, June
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Maybury, J., Morris, J., “Aviation Fuels Technical Hanson, F. V., “Production of High Density Aviation
Review,” Chevron Products Company,, 2000. Fuels via Novel Zeolite Catalyst Routes,” WRDC-
Bergsten, B., “Concise History of Aviation Fuel TR-89-2097, October 1989.
Development in the United States,” unpublished, Hazlett, R. N., Thermal Oxidation Stability of Aviation
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Martel, C. R., "Molecular Weight and Average
Composition of JP-4, JP-5, JP-8, and Jet A,"
unpublished results, 15 July 1988
McBride, B. J., Gordon, S., “Computer Program for
Calculation of Complex Chemical Equilibrium
Compositions and Applications. II. Users Manual
and Program Description,” NASA Reference
Publication 1311, pp. 84-85, June 1996.
Mehta, G., Stone, W., Ingram, C., Bai, S. D., Sanders,
T., “Comparative Testing of Russian Kerosene and
RP-1,” AIAA 95-2962, July 1995.
Pustyrev, O., “Aviation Fuel in the Russian
Federation,” Proceedings of the Second
International Symposium on Aviation Turbine Fuel
Specifications, May 1993.
Ragozin, N. A., “Jet Propulsion Fuels,” Pergamon
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American Institute of Aeronautics and Astronautics
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