Exercise 6.2b Name: Calorimetry Dae: me AP Chemistry DIRECTIONS: Answer the following in the space provided. 1, The specific heat capacity of aluminum is 0,900 J°C-g. ‘8. Calculate the energy needed to raise the temperature ofa 8.50 « 10% block of aluminum from 22.8°C to 94.6°C. b. Calculate the molar heat capacity of aluminum, seen eta d GFrees g.= Ssoniaty- oso = (AM.ue-22.8%) 2 sears ( stsc05 (4803 o.R003 | .48¢a\ xy T | : = 2.282 Soper | 24.3 Yooi-e Ko Ves at Frode | frck- °c 2. The specific heat capacity of graphite is 0,71 J/°C-g, Calculate the energy required 10 Qrash re = ie a.” Raise the temperature of 10 mol of graphite by LOSC. Grate = carton (0) b, Raise the temperature of 850. g of graphite by 150.°C. Nmol = 12.91 ©. Raise the temperature of 75 kg of graphite from 294 K to 348 K. S qememt ge (2org- 0 W3/re-4- 0% 28.527 6.55 b> qe meat ye BOY OMTAne - 150% 2 hess [atooos (as) Be ace, Seana CS pemeter gz Hoag: 0.NT 4 -(HOK-Z4) = 28358005 2.4410 | c 2.9 x03 ET 3, takes 782 J to asthe emperatur of 456g lead by 133°. ean iste eae eTHLE| : capacity of lead. A Seat < cz t. 2 Lemcar mer” hee aeT olor o.ay, . y rt Vol Be ee eae, (204 Src 2c 4. Ietakes 585 J of energy to raise the temperature of 125.6 g mercury froni[20.0°C 10 53.5°C. Waleulate the specific heat ‘capacity and molar heat capacity of mercury. Oxr= 33,5°O Fmese ex o> BSS L z . Lis mar © (28.69 -31.5% 010% we (oni34 is A 2.1395" [200.59 = 2798), [Bahl Came fi sat Teel 8B Lowi te | FEI Yrol 0c 5. 428.2 g sample of nickel i heated to 99.8°C and placed ina coffee-cup calorimeter containing 150.0 g water at 23.5°C. Aer the metal cools, the final temperature of metal and water is 25.0°C. Caleulate the specific heat capacity of nickel, assyming no hegt escapes to the surroundings ois wansferred to the calorimeter. ey s waker YS = 15008 48d 5% = GYIT a Cateece Gamer BY WwaTeR “ 50 qui 2 - FIT, = 0.12894 Thee 0.118 Hany s. ~ © or ait» - WSs 182q-%- (15.0% -94.0%) Kz OMG Soe, \OMs pe Revise: 2019-01-07 fmm De SAUTE ATTRA TOE ACERT Hoe PCA CTT TTA 018s. 1-104 20a DPE HH TOT IDM) -eeokima TPEExercise 6.2b ee Calorimetry Date:_ Per AP Chemistry 6. 4.46.2 g sample of copper is heated to 95.4°C and then placed in calorimeter containing 70.0 g water at 19.6°C. After the metal cools, the final temperature of metal and water is 21.8°C. Caleulae the specific heat capacity of copper, assuming that ll the heat lost by the copper is gained by the water, meee eee Hl sl neegy gurnch by wah wake 9 We = Moog NienTng« (8% HRD =O 3S Seis sor I Uy Re YF Men Cont Men GST 2 Heda: + (aBe-AeHre) 7 O-BUAGe [Oie For ( 7. A coffee-cup calorimeter intially contains 125 g water at 24.2°C. Potassium bromide (10.5 g) also at 24.2°C, is added to the water, and after the KBr dissolves the final temperature is 21.1°C. Calculate the enthalpy change for dissolving the salt in J/g and kimol, Assume thatthe specific heat capacity ofthe solution is 4.18 J/g:°C and that no heat is transferred to the surroundings or to the calorimeter. Gpolia = Msc + Coola AT solve GF BEEK HAG Tore (uate - tray 2 -1769.0T AWh, 2 -SHOS/0.5e KBr = ~ lee Yq [EO% \ 2 7 NSOF [6.2 (> wy =20¥%S/ ones = “Rerut saat ue = Wet (-20k at | 8, Camphor (C\cH,,0) has a Hat of combustion of 5903.6 kilmol. When a sample of camphor with mass 0.1204 g is burned ina bomb calorimeter, the temperature increases by 2.28°C. Calculate the heat capacity of the calorimeter in 1°C. O.w4, wcetGintiso | 5403.65] 1009S = 4.9.26" 52.20Bglabelimet — VS HOot.te 2 AAS s 20449 Cus = See oe 9. Comite extn ( 2250 %e\ 2HClfaq) + Ba(OH),(aq) > BaCl,(aq) +2H,0() AH =—118 kd Cleat he heat when 10.0 maf 500 AF CIs mited with 30.0 oF 5004 B4COH Assuming ta te temperature of both solutions was initially 25,0°C and that the final mixture has.a masggf 400.0 g and a specific heat Cincy oF 138°C salon ha enpeetre tena ee cack (= Qtooorncilosoomol Atl| —USKS 17 A5uT| arorny of BG mee GR jae mente Balor), = 0.30001 SaLot Se iyaly Deering Herr Aebotper By: are Bebe Tek ate Ge meAT PPE 2RET =" 00.04" HIBHIGeue (x- 250%) %* ZOHO 268°C! 10, A300 g sample of water at 280 Kis mixed with $0.0 g of water a 330 K. Caleulate the final temperature ofthe mixture asouming no beat oss othe surroundings 30.03 4B Sq-rc.> (X- 280% = = (s.0g- dae Tere- (x -3500)> N25HX — 3512 = - 20% + CBO BUM = loose X = Seon Bel i Bue Revised: 2019-01-07 Fae TART STIR De TST TCR a CP OTT Shussuyee. lly a0 Rima 8) OIFC IEC HST) Me a)-eelmal DHPC walvedeAP Chemistry Exercise 6.2b Names Calorimetry ane Ga qe) Date: Per 11. A 5.00 g sample of aluminum pellets (specific heat capacity = 0.89 J/°C'g) and 10.00sample of iron pellets (specific heat capacity = 0.45 J/°C-g) are heated to 100.0°C, ‘The mixture of hot iron and aluminunt is then dropped into 97°3 g of water at 22,0°C, Calculate the final temperature of the metal and water mixture, assuming no heat loss to the surroundings, ~ (B05 + 0.88% 0, + (x. wookd + 10.004: 04S Hore (100%) = FH.Sg+ HT (Q-22.08) “NASH + HHS - HS © X50 = HOU — BAdT ~ 8.25% + B95 = Hobe - 8% Four = 4A Treo T K = 28-42% (2a.tec | 12, Ina coffge-cup calorimeter, 0.0 mi. of 0.100 M AgNO; and 50.0 ml. of 0,100 M HCI are mixed to yield the following rea O.00%0eel © C08 e| > O:COSe0 mol Mylo ‘Ag (aq) + CI (aq) = ABCs) * ‘The two solutions were initially at 22.60°C, and the final temperature is 23.40°C. Calculate the heat that accompanies this reaction in kifmol of AgCl formed, Assume that the combined solution has a mass of 100.0 ¢ and a specific heat capacity of 4.18 IPC. Aig® 0.05001. Aghtt3 (0.100 mel M8803 — © Cos.0. meh Agios = d-cosDo mel Aah 7 Vabigise 2 0,00 500 mol CL~ Gime PDL et [oO mol Kel 2.00500 mol KCI ee Gisele = 100.046 MIBRa + (Z54r%- 22.40%) = ZHAT|AWS 2 vs woes “S eascanel 13, Consider the dissolution of CaCl: Nicer CaCl(s) + Ca®*(aq) + 2CI(aq) AH = -81.5 kd 1 es ea 2 G4 Xo ‘An 11.0 g sample of CaCl i dissolved in 125 g water, with both substances at 250°C. Calculate the final em the solution assuming no heat loss othe surroundings and assuming the solution has specie eat capac) of 18 eee WOg Cae |leeiGatle [-BUST 2 Borger < hear onleD NO. ABQCatiz| wor Calle 36 ‘BY Disouoriee! Gp0\0 = Mb0he * Csoln- BTearn SOIST = 12e,0q + WG ce + (x- 2500 KR = 34.20°% [a 2° ~ 14. Ifa student performs an endothermic reaction in a calorimeter, how does the calculated value of AH differ from the actual value if the heat exchanged with the calorimeter is not taken into account? 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