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In searching for a method to correlate data for frictional theory, and the equations for potential %ow to develop an
pressure drop in two-phase flow it is of interest to examine equation for the density distribution, Levy solved the equa-
the approaches which have been used in the past on other tions of motion by numerical means. The resulting rela-
complex problems involving transport processes. When one tionships between shear stress and the operational vari-
eliminates the class of problems which have been solved ables show agreement only with very restricted data.
by the use of potential theory or those which have used the No significant attempts have been reported at correlat-
assumptions of laminar flow in situations of relatively ing the two-phase frictional pressure drop by the use of
simple geometry, there remains those problems for which dimensional analysis or similarity analysis. The use of di-
it has been necessary to develop design correlations with- mensionless groups for empirical correlations techniques
out the availability of rigorous methods. This is not an is widespread; however a correlation based primarily on
unusual assignment for the chemical engineer. Typically dimensional analysis has not appeared. For a process with
his analysis of a complex problem produces very imperfect the large number of variables involved in two-phase flow
correlations at first based on limited data. These correla- it is doubtful that the use of dimensional analysis alone can
tions improve as the problem receives further study and provide a fruitful approach. It is readily demonstrated
more sophisticated tools are used for its analysis. Between that four dimensionless groups are involved for each
the first approaches to correlation and the refined attacks phase. Thus a total of eight dimensionless groups must be
which usually appear many years later there appear to be considered, and in each of these the phase velocity is un-
a number of distinctly different approaches which have unknown. Therefore the use of experimental data to pro-
been employed. These can perhaps be classified as follows: vide the interrelating constants becomes a near impossible
1. Empirical correlation. task.
2. Correlations with dimensional analysis used. No approach to correlation using the principles of simi-
3. Correlations with similarity analysis and model larity in a formal manner has appeared in the literature. It
theory used. is the purpose of this paper to examine this method, to
4. Mathematical analysis of a simplified physical model develop the correlating parameters, and to test the ap-
and development of equations relating the variables. proach with the data.
5. Solutions to the energy, momentum, and conserva-
tion equations using empirical expressions for the turbu- SIMILARITY ANALYSIS
lent transport terms, approximations to the boundary con-
ditions, and assumptions as the relative magnitude of the In this section the parameters for two-phase flow cor-
various terms in the equations. Usually the resulting rela- responding to the Euler and Reynolds numbers for single-
tionship between variables is obtained by numerical solu- phase flow will be developed. If two flow systems in single-
tion of the complex equations. phase flow are dynamically similar, it can be shown that
On any problem which has resisted definitive solution the Reynolds number and the Euler number for the two
over the years examples can usually be found of the ap- systems must be equal. (Note that the Euler number is
plication of each of these approaches. twice the friction factor.) In itself this condition does not
Attempts to develop correlations between frictional provide a relationship between Reynolds number and fric-
pressure drop and the controlling variables during gas- tion factor. However once the relationship is found from
liquid flow in conduits have utilized only three of these experimental data for one system (the model), the condi-
methods. Many empirical correlations have appeared. tion of dynamic similarity require the same relationship to
Most of these can be used beyond the range of the data apply to all similar systems. The particular grouping of
from which they were constructed with poor reliability, as variables which are known as the Reynolds and Euler
has been shown in the first paper (1).Correlations of this numbers emerge naturally from this similarity analysis for
type for horizontal flow appear in references 2, 3, 4 , 5, 6, single-phase flow. In the work which follows the group-
7. Empirical correlations for vertical conduits are given in ings will be evolved for two-phase flow, and thus the need
reference 8, 9, 10, 11. The correlations which have dem- for the arbitrary definitions used in the ast is eliminated.
onstrated the greatest success have been those based on a ph
The relationships for single- and two-p ase flow will be
simplified physical model of the complex two-phase sys- developed in parallel to clearly demonstrate the analogy of
tem. The homogeneous model has received considerable treatment.
attention because it permits the two phases to be treated Consider two conduits of different size (see Figure 1)
as an equivalent single phase having mixture properties containing in the general case two different fluid systems.
( 1 2 , 13, 14, 1 5 ) . The annular flow model has produced Points m A and m~ are two typicaI points located at geo-
a number of correlations (16, 17, 18, 19). Recently an ap- metrically similar positions relative to the boundaries. The
proach through the solution of the equations of motion flows are assumed to be dynamically similar. The rules of
was presented ( 2 0 ) . Using the PrandtI mixing length dynamic similarity require that at all corresponding points,
(7b)
Two-phase flow:
B
[ ?(VLT avL
+-)+
~ V L
at Equations (6) and (7) result from the conditions of
kinetic and geometric similarity. It is now necessary to
relate the local quantities to space average ones. For this
purpose use is made of the requirement of kinematic
Viscous forces: similarity ( I d ) along with the assumption that the scale
Single-phase flow: quantities are independent of position. The resulting
--
a2v
dv transformations for single- and two-phase flow are shown
gc an2 in Figure 2. The transformations for single-phase flow
Two-phase flow: have been developed in a particularly lucid manner by
Shames (21) . Those presented here for two-phase flow
incorporate the additional assumption that kinematic simi-
larity applies to the individual phase velocities as it does
to the mixture velocities. The local liquid and gas volume
Pressure forces: fractions can be related to the average values by the re-
Single-phase flow: quirement of geometric similarity. That is, at correspond-
ap
-
az
dv ing points, the ratio of the local to average volume frac-
tion in system A must be equal to that in system B.
Vol. 10, No. 1 A.1.Ch.E. Journal Page 45
Single Phase Flaw RG
-
c2=---.-
RL VL d2VG/dn2
(11b)
RG RL TGd2VL/dn2
The ratio of the phase velocities to the mixture velocity
can be expressed in terms of the input volume fraction
liquid A and the in-place volume fractions RL and RG:
qGA
-"GA
- = -
"GI "GB
( 12b)
~ T P = ~ L X - I - ~ G( 1 - X ) C2 (14b)
The problem now comes down to finding values for the
C terms.
The same procedure can be followed for two-phase flow As in most problems of this type it is necessary to exer-
and the analogous expressions developed. AS this proce- cise intuitive judgment to complete the analysis. As a
dure is followed, it soon becomes clear that for two-phase basis for arriving at this judgment the equations resulting
flow all of the local quantities do not cancel as they con- from several assumptions for the values of the C terms are
veniently did for single-phase flow. The groups which re- presented.
sult after some rearrangement are: Case I: N o Slip and Homogeneous Flow
- -+ ~ G R G ( V G / V ~ ) ~
~ L R (LV L / V m ) z CI
Under these conditions
NRWP= Nm
[ pLRL (vL/vm) + pGRG(VG/Vm) c
2
C1 = c2 = 1.0
A = RL
( 1Sa)
( 15b)
(9a)
~--X=RG ( 1%)
Furthermore since these equations must produce the
single-phase groupings as the amount of either phase goes
where to zero, the characteristic length 1 for tube flow must be
1 the diameter D . This produces the following results:
- QL+QG
Vm = (10)
A dP/dZ
fNS =
Rc R r . 2GT~
c ---
21 - (1la)
Ro Rr, VI. dVr./dz g r ~ N 72
S
-=-
pNS
1 x
pG
+-I--xPL
(18c) --
PL gc D Z L ~
In these e uations x is the weight fraction vapor. Simi-
B
Iarly it has een suggested (8) that the density be weighted
by the in-place fraction liquid and gas:
The modification of Petrick ( 2 4 ) can be written as
4 WT
PNS = EL p t + RGpc ( 184
NReTP = -
W D ~ L
It is now quite clear that the definitions for mixture prop- dP/dz
erties are not arbitrary. For homogeneous, no slip flow the TP =
~ G (T l -~ ~ ) ~
proper definitions are given by Equations ( 1 7 4 and (17b) --
with the correct weighting factor being the flowing vol- P L ~ C D RL'
ume fraction of liquid.
The general equations for the Reynolds number and the The form suggested by Chisholm and Laird ( 2 5 ) is
friction factor can now be written in terms of the no slip
values:
xz (1-A)'
(PL/PNS) 7
RL
+ (PG/PNS)-c1 RG dP/dz
= NReNs =
NReTp
( ~ L / ~ N As )+ ( ~ G / ~ N (1
s )- A ) cz
fTP
2 GT' 0.8
- -
(19a) PL gc D R L ~ . ~ ~
1
f fNS (19b)
(1-A)' Other similar types of formulas have been noted by Isbin
A2
(pL/pNS) T + (pG/pNS) ~ c1 ( 2 2 ) . Note that the modification to the friction factor
RL RG equation which was investigated by Petrick is closest to
Cz are Assumed to be 1.O:
Case II: Slip Takes Place but C1 and this case and could be expected to be correct for situa-
If it is assumed that the ratio of each phase velocity to tions of relatively high values of RL. However none of
the average velocity remains constant over the cross sec- these methods appear to recognize that modifications to
tion, as was done by Levy (ZO),but if this ratio is per- the definitions of the friction factor must be accompanied
mitted to be different from 1.0, then by modifications to the definition of the Reynolds number
as well in order to meet requirements of similarity.
- -
Case IV: CI= CZ = VL/VG
If one assumes that the ratio of the gas velocity gradient
and the liquid velocity gradient are constant in the flow
direction and in the direction normal to flow, and that the
velocity ratios are constant over the cross section, as was
done in Case 11, then the relations for CI and Cz reduce
to -
Here both the flowing volume fraction and the in-place VL
Cr = cz = : (25)
volume fraction of each phase enter into the definition of VG
the mixture density.
Isbin et al. (22) have reviewed the various equations When the proper substitutions are made in Equations
proposed for friction factor and Reynolds number which ( 9 a ) and (gb), the equations which result are
include the fraction liquid and vapor holdup. Their review
demonstrates the totally empirical nature of the equa-
tions. Now it can be seen that the definition for f and Re
depend on the assumptions made about the C terms.
Cz are Assumed to be Zero:
Case 111: C1 and
Under conditions where RG is small, a case can be made
for assuming Ci and Cz to be near zero. Both the Reynolds
Vol. 10, No. 1 A.1.Ch.E. Journal Page 47
this correlation was
0.125
f = 0.00140 +-
(Re)0.32
Case I1
This correlation was constructed by using experimental
data to establish the graphical relationship between f and
Re, as defined by Equations (20a) and (20b). In this
instance it was necessary to have data which provided not
only the measured frictional pressure drop and the oper-
ating variables but experimentally determined values of
holdup as well. As discussed in Part A certain of the culled
data included information on fraction liquid holdup. Of a
total of approximately 2,400 data points holdup data were
reported for about 800 points. Data taken in small diam-
Fig. 3. Typical Case II correlating curves. eter lines were not usable because the pressure drops ob-
tained included large acceleration effects. Data which re-
It is interesting to note that the definition for the Reynolds ported holdup values less than 0.10 fraction volume of
number which emerges from this series of assumptions is the tube were eliminated as being of doubtful accuracy.
identical to that proposed by Hughmark ( 2 6 ) . However In all approximately 400 data points of the total 2,400
once again the definition which he used for the friction culled data points were used to construct the correlation.
factor is not consistent with the assumptions which lead to For each of these 400 experimental data points the fric-
the Reynolds number. tion factor and Reynolds number were calculated from
It is now quite clear that by properly selecting values Equations ( 2 0 ~ )and (20b). The results, when plotted,
for the two C terms it is possible to develop either the fric- revealed a distinct trend with flowing fraction volume
tion factor or the Reynolds number expression used by liquid. Some typical results are shown in Figure 3. When
many (if not all) of the previous investigators. It is like- these various curves were normalized with single-phase
wise evident that these earlier approaches were not con- friction factor calculated for the mixture Reynolds num-
sistent within themselves. ber, the various curves for narrow ranges of Reynolds
f -hh
.(A) =-=LO+ (28)
fo 1.281 - 0.478 (- In A) + 0.444 (-In A) - 0.094 (- In A ) + 0.00843 (- In A )
The problem now becomes that of determining which of numbers converged into essentially one curve (Figure 4 ) .
these assumptions leads to the most satisfactory correla- The equation for the normalized curve of Figure 4 is
tion. The method for calculating two-phase pressure drop by
this correlation can now be outlined. The Reynolds num-
ber for the mixture is determined from
CORRELATION FOR CASES I AND II
Cora \
The assumptions of homogeneous flow which underlie
this case permit the two-phase mixture to be treated as an
equivalent single fluid with the properties defined by
Equations (17a) and (17b). Data for single-phase flow
have already provided the relation between the friction
factor and Reynolds number for dynamically similar
single-phase systems. For dynamically similar homogene-
ous two-phase systems the same f-Re relation must apply, 0. I I. I) I I00 lil",,
( 1 6 b ) . The equation relating single-phase f-Re used for Fig. 4. Normalized f/fo curve.
NO U I N AL
TUBE
SIZE
Inches
3H
relations of Case I and Case 11. Deviations between cal- wave 38.4 85.7 42.5 9.0 33.5 30.0 11.5 22.b 20.5' 287
culated and measured values were calculated for each SlUP 2.9 31.2 17.5 -2.9 29.4 15.0. 9.5 21.1 15.b 974
point, the data grouped, and the results processed through Annular -12.8 35.6 30.0 -21.7 46.3 37.5 -11.2 2b.O 19.0' 261
an error distribution program to generate a histogram of Dlsperred 18.0 34.1 25.0 3.1 31.1 27.5 14.8 16.9 17.1, 111
d= (3
- (3
(dP/dZ)m
(36)
groups for Case 11. Martinelli produces values of u exceed-
ing 25% for eight of the twelve groups. Case I1 correla-
tion produces only two c's exceeding 25%.
A comparison of correlations on data grouped by ob-
served flow regime appear in Table 2. Each of the flow
(37) regime groups includes data at all line sizes and for vary-
ing fluid properties. It is seen that the Case I and Case I1
correlations are in all instances better than the Martinelli
correlation. As indicated by the asterisks, agreement is
better for three groups using Case I and for three groups
using Case 11 correlation.
Results for the one-component, steam-water data in
In addition the histogram for each group was counted to Table 3 show that the Martinelli correlation is most satis-
obtain the quantity +,
which defines width of the band factory for the low- and the high-pressure data, but Case
around the mean which includes approximately 68% of I is significantly better at the intermediate pressure level.
the data points in the group. Results of these calculations For all three groups the Case I1 correlation is poor. This
appear in Tables 1 to 3. poor agreement results from the fact that the Hughmark
In Table 1 all the two component data are grouped by correlation describes the experimental holdup for these
line size and the viscosity of the liquid phase. Included steam water tests with rather large deviations. These devi-
also are the statistical parameters for the Martinelli cor- ations reflect in the prediction of the pressure drop values.
relation, shown in the first part of this paper to be the It is of some interest to reflect on Case I. This correla-
best of those tested. In general the Case I Correlation is tion, based on the assumptions of homogenous flow with
superior to the Martinelli correlation, and the Case I1 cor- the definition of the mixture properties dictated by re-
relation is more accurate than Case I. For each data quirements of similarity, was constructed without the use
group an asterisk has been placed under the column of of any two-phase flow pressure drop data. Despite this
the correlation which gives the best agreement between fact it predicts the pressure drop with greater reliability
calculated and measured values. Of the twelve groups than does the Martinelli correlation for ten of the twelve
Case I1 correlation gives best agreement for eight groups, two-component groups and in many cases is almost as
the Case I correlation for two, and the Martinelli correla- good as Case 11. For the one-component, small tube-size
tion for two. The Martinelli correlation performed best for data it is likely that the larger errors are due primarily to
low viscosity liquids in small tube sizes, conditions which inaccuracies in the prediction of the acceleration compo-
produced most of the data used by Lockhart and Mar- nent.
tinelli to construct their correlation. In the second in-
stance where the Martinelli correlation performed best, SUMMARY AND CONCLUSIONS
the Case I1 correlation was almost as satisfactory.
The standard deviation u is consistently lower when Various correlating parameters for frictional pressure
the Case I1 correlation is used than when Case I is used. drop are developed, starting with the requirement for
Case I consistently produces lower values of u than dynamic similarity for two-phase flow. Two cases are ex-
Martinelli. This quantity, which is a measure of the scat- plored in detail and tested with the culled data. Statistical
ter about the mean, exceeds 35% for five groups with terms describing the deviation between the prediction of
the Martinelli correlation, two groups for Case I, and no the correlations and the measured data are compared. In
PRESSURE
RANGE
TUBE
DIAMETER
MARTINELLI CASE I CASE II
N POINTS
o.DATA I
PSlA Inches L o - \y d a- 'I' 2- c r 'I'
I
25 - 100
400 - 800
1000 - 1400
Page 50
1.06
0.484
0.48-1
39.5
63.6
-17.5
66.6
57.0
21.1
55.0'
52.5
17.5'
61.5
-10.2
-29.4
A.1.Ch.E. Journal
179
44.6
16.2
95.0
37.5.
10.0
132
71.0
32.6
153
70.0
29.6
-
-
25.1
January, 1964
"t 1
general the Case I1 correlation based on holdup gives p = viscosity, single-phase
better agreement with data than does earlier correlations. PL, PG = viscosity, liquid, gas
As methods for predicting holdup are improved, these ~ N S= viscosity of two-phase homogeneous mixture, de-
correlations should be even more satisfactory. fined by Equation (17b)
ACKNOWLEDGMENT
The authors wish to acknowledge with thanks the support of
p -
~ T P = viscosity of two-phase mixture
density, single phase
PL, PG = density of liquid, gas
the American Gas Association and the American Petroleum In- PNS = density of two-phase homogeneous mixture, de-
stitute, who have supported this work. In particular the advice, fined by Equation (17a)
encouragement, and sympathetic council of Ovid Baker, Chair- PTP = density of two-phase mixture
man of the advisory committee representing these two organiza- u = standard deviation
tions, was invaluable. Use of the computing facilities of the 4~ = ratio of the two-phase pressure gradient to the
University of Houston Computing Center is appreciated. pressure gradient if liquid flowed alone in the
conduit
NOTATION LO = ratio of the two-phase pressure gradient to the
gradient if both phases flowed as a liquid
A = conduit cross-sectional area ~ L M= ratio of the two-phase pressure gradient to the
CI, C2 = grouping of variables defined by Equations qradient if both phases flowed as a liquid at the
( l l a ) and ( l l b ) mixture Reynolds number
d = percentage . deviation between calculated and
measured pressure gradient LITERATURE CITED
- 1. Dukler, A. E., Moye Wicks, 111, and R. G. Cleveland,
d = mean deviation for j data points
D = tube diameter A.l.Ch.E. Journal, 10, No. 1, p. 38 (1964).
2. Chenoweth, J. M., and M. W. Martin, Petrol. Refiner, 34,
Fs = local scale of force 151 (1955).
f = friction factor, single-phase flow 3. Hoogendoorn, C. J., Chem. Eng. Sci., 9,205 (1959).
fNS = friction factor, two-phase flow based on condi- 4. Isbin, H. S., R. H. Moen, R. 0. Wickey, D. R. Mosher, and
tions of no slip and homogeneous flow, Equation H. C . Larson, Chem. Eng. Progr. Symposium Ser. No. 23,
(16b) 55,75 (1959).
fo = friction factor for single phase flow evaluated at 5. Sobocinski, D. P., M.S. thesis, Univ. Oklahoma, Norman,
the mixture Reynolds number, Equation (30) Oklahoma ( 1955).
fTP = friction factor, two-phase flow 6. White, D. P., Ph.D. thesis, Univ. Oklahoma, Norman,
gc = dimensional constant of Newton’s equation of Oklahoma ( 1954).
motion 7. Yagi, S., Chem. Eng. (Japan),18,2 (1954).
GT = mass velocity based on total flow rate of liquid 8. Calvert, S., and B. Williams, A.1.Ch.E. Journal, 1, 78
(1955).
plus gas 9. Govier, G. W., and L. W. Short, Can. J . Chem. Eng., 36,
i = number of data points in a test group 195 (1958).
I = local scale for length 10. Hughmark, G. A., and B. S . Pressburg, A.1.Ch.E. Journal,
n = normal to the flow direction 7,677 (1961).
N E ~= Euler number 11. Yagi, S., T. Shirad, and T. Sasaki, Chem. Eng. (Japan),
N R e = Revnolds number.‘ sindeahase Q L
flow 15, 317 (1957).
N R e N S = Reynolds number, two-phase flow under con- 12. Owens, W. L., Paper presented at Second International
ditions of no slip, Equation (16a) Heat Transfer Conference, Boulder, Colorado ( 1961 ).
N R ~ T= P Reynolds number, two-phase flow 13. McAdams, W. H., W. K. Wood, and L. C. Heroman, Trans.
Am. SOC. Mech. Engrs., 64, 193 (1942).
n = distance measured normal to the flow direction
14. Adorni, N., I. Casagrande, L. Cravaralo, A. Hassid, M. Sil-
(dP/dz) = pressure gradient due to friction vestri, and S . Villani, Centro Informazioni Studi Esperienze
( a P / d ~= ) ~total pressure gradient due to friction and Rept. R 41, Milan, Italy (June, 1961).
acceleration 15. Bankoff, S. G., Trans. Am. SOC. Mech. Engrs., 82, 265
P- = local pressure (1960).
P = average pressure 16. Lockhart, R. W., and R. C. Martinelli, Chem. Eng. Progr.,
QL, QG = volumetric flow rate of liquid, gas 45,39 (1949).
EL, _ RG = local volume faction liquid or gas in place 17. Levy, S., “Proceedings Second Midwest Conference on
_ Fluid Mechanics,” p. 337, Ohio State University, Colum-
RL, RG = average, in place volume faction liquid, gas bus, Ohio (1952).
t = time 18. Lottes, P. A., and W. S . Flinn, Nuclear Sci. Eng., 1, 461
o = volume (1956).
V-
= local velocity, single-phase flow 19. Jacowitz, L. A., and R. S . Brodkey, Paper presented at the
V = average velocity, single-phase flow 55th Annual Am. Inst. Chem. Engrs. - Meeting, - Chicago,
- IN-
VL, VG = local velocity, liquid, gas nois (December, 1962).
- 20. Levy, S., Am. SOC. Mech. Engrs., Paper 62-HT-6 (1962).
VL,
- VG = average velocity of liquid, gas 21. Shames, I., “Mechanics of Fluids,” McGraw-Hill, New York
V, = average velocity of gas-liquid mixture, defined ( 1962).
by Equation (10) 22. Isbin, H. S., H. A. Rodriquez, H. C. Larson, and B. D.
V, = local scale of velocity Pattie, A.1.Ch.E. Journal, 5, 427 (1959).
WT = total mass flow rate of liquid and gas 23. Lottes, P. A., and W. S . Flinn, Nuclear Sci. Eng., 1, 461
WL,W G = mass flow rate of liquid, gas (1950).
x = ratio of weight of vapor flowing 24. Petrick, M., Argonne Natl. Lab. Rept. 5787 (March, 1958).
25. Chisholm, D., and A. D. K. Laird, Trans. Am. SOC. Mech.
z = direction of flow Engrs., 80,276 (1958).
26. Hughmark, G. A., Paper presented at the 55th Annual Am.
Greek Letters Inst. Chem. Engrs. Meeting, Chicago, Illinois (December,
/3 = dimensionless group defined by Equation (30) 1962).
k = ratio of the volumetric flow rate of liquid to the Manuscript received January 22 1963. revipiOn received May 16
1963; paper accepted June 10, 1’963. gaper presated at A.1.Ch.E.
total volumetric flow rate, Equation (12c) Chicago meeting.