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Chi-Chun Liu, Jed Pitera, Neal Lafferty, Kafai Lai, Charles Rettner, Melia Tjio,
Noel Arellano, Joy Cheng, "Progress towards the integration of optical
proximity correction and directed self-assembly of block copolymers with
graphoepitaxy," Proc. SPIE 8323, Alternative Lithographic Technologies IV,
83230X (21 March 2012); doi: 10.1117/12.916525
Event: SPIE Advanced Lithography, 2012, San Jose, California, United States
ABSTRACT
A photomask design flow for generating guiding patterns used in graphoepitaxial DSA processes is
proposed and tested. In this flow, a new fast DSA model is employed for DSA structure verification.
The execution speed and accuracy of the fast model were benchmarked with our previously reported
Monte Carlo method. We demonstrated the process window verification using the OPC/DSA flow
with the fast DSA model and compared this with experimental results in the guiding patterns
simulated by e-beam lithography.
Keywords: Directed self-assembly, DSA, block copolymer, BCP, OPC, fast model
1. INTRODUCTION
The economics of semiconductor fabrication dictates that devices need to be scaled by
approximately 70% in linear dimensions every 18-24 months in order to maintain cost effectiveness.
Optical lithography has been the key driving force to support this scaling in the past few decades.
However, state-of-the-art 193 nm immersion lithography (193i) has reached its physical resolution
limit at the 22nm node while the potential technological successors of 193i haven’t matured enough
to be implemented in high-volume manufacturing (HVM). Double patterning, which decomposes
one layer of dense patterns into several less dense layers and employs multiple processes to achieve
the target patterns, is the interim solution for printing smaller features and tighter pitches beyond the
resolution limit, at the expense of significantly increased process complexity and cost of ownership.
Directed self-assembly (DSA) of block copolymers (BCPs) is an alternative approach to extend
optical lithography, which utilizes a topographical or chemical guiding pattern to direct the BCPs
into a desired morphology at a pre-determined location while the material properties of the BCPs
control the feature size and uniformity of the resulting structures. Such a technique has drawn great
attention due to its capability for pattern density multiplication and defect rectification.[1, 2] Recent
studies on 193i/HVM compatibility and defectivity of DSA further reinforce its role as a potential
candidate for lithography extension rather than merely a lab-scale nanofabrication method.[3-5]
Current applications of interest of DSA in the semiconductor industry range from periodic lines (for
gate or metal layers), periodic holes/posts, to aperiodic holes with various densities (for via or
contact layers).
Alternative Lithographic Technologies IV, edited by William M. Tong, Douglas J. Resnick, Proc. of SPIE
Vol. 8323, 83230X · © 2012 SPIE · CCC code: 0277-786X/12/$18 · doi: 10.1117/12.916525
DSA
Better CD uniformity Rectified Via patterns
Fig. 1: An example of the DSA via process for CD uniformity improvement and pattern rectification. (Presentation
by IBM in 2010 SPIE Advanced Lithography)
Target Mask
Pass
Accept
check the
dose
design!
Fail
Target Pattern Mask/OPC/SRAF
Fig. 2: A design flow for a photomask which can generate a DSA guiding pattern that results in DSA via
structures at the desired locations.
The major difference between the design-for-DSA flow demonstrated here and a typical
photomask design flow is that an additional DSA model/simulation is needed for verifying the
resulting structures. Two types of DSA model are employed in this work: (1) the Monte Carlo (MC)
method[6, 7] and (2) a newly developed fast DSA model.
When benchmarking the two DSA models, we would like to focus on the execution time and the
computational accuracy/discrepancy. Eleven different guiding pattern designs, which are basically
composed of 2 merged circles with various center-to-center distances and different level of corner
rounding, were chosen for the benchmark test. The MC method was performed on the guiding
patterns and the equilibrium morphologies were obtained, as shown in Fig. 3. Centroids of the DSA
via domains were extracted afterward using MATLAB Image Processing Toolbox. In addition, 8
MC numerical experiments were repeated on each of the 11 guiding pattern designs to obtain
statistics about the DSA structures. Fig. 4a illustrates the execution time of the MC method and the
fast DSA model on one single run. Each of the MC simulations takes ~100 CPU hours while the fast
DSA model takes ~1.5sec in average. Fig. 4b shows the histogram of the distances between the
3D Monte Carlo DSA Model Image resolution = 1 nm/pixel. fast DSA Model
different MC simulation
different GP design
Fig. 3: Examples of the two DSA models used in this work: Monte Carlo and the fast DSA model.
(a) CPU time comparison of DSA models (b) Positional difference between MC and
(log scale) the new model (histogram)
1000000 12
Average error ~0.644nm
100000 10
Computation time (sec)
10000
> 105 improvement 8
count
6
1000
4
100
2
10
0
0.5 1 1.5 2 2.5 3
1
|rMC - rfast| (nm)
Monte carlo new model
Fig. 4: The performance comparison between the two models used in this work in terms of (a) computational
speed and (b) positional accuracy.
Fig. 5: The “placing-circle” method for guiding pattern design (left) and the predicted DSA results by the fast
DSA model (right).
The variations in the photomask fabrication process and the fluctuations in lithography process
conditions such as exposure dose and focus will result in resist contours, and therefore variations, in
the guiding patterns that cause deviations from the target design. Extreme conditions, such as those
listed in Table 1, are often used to study the reliability of a lithography process.[8] For an OPC/DSA
process, it would be important to check if the DSA structures can form correctly under the extreme
conditions, so that one can further fine-tune the mask design if needed. Typically, the OPC software
can also predict the smallest (inner condition) and the largest (outer condition) possible resist
contours if a proper resist model is provided. Then one can apply the MC or the fast DSA model to
the resist contours and evaluate via placement for the nominal and the extreme cases. Fig. 6 top row
shows the prediction by the fast DSA model in the extreme resist contours. One can see that the
same number of the DSA vias formed correctly under all 3 conditions, even though some vias were
predicted to have larger positional fluctuations than others. We used e-beam lithography to simulate
4. CO
ONCLUSIO
ON
A scheeme for integ
grating grapphoepitaxial DSA via prrocess guidinng pattern design
d with OPC
O is
demonstratted. The keyy componennt in this floow is the use of a DSA A model to verify
v the reesulting
DSA structures, as wee demonstratted that a strraightforwarrd “placing-ccircles” guidding pattern design
method caannot guaran ntee the positional acccuracy. Besiides the connventional Monte
M Carloo DSA
model, a newly
n develooped fast DS SA model iss reported annd compared to the MC C model. Thhis new
fast DSA model achiieves orderss-of-magnituude higher computation
c nal efficiency while prooviding
nearly the same resultss in terms off positional accuracy. An
A example where
w e-beaam lithographhy was
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