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1 Preliminaries 2
1.1 Current Density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
1.2 Lorentz Force . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
2 Maxwell’s Equations 3
2.1 Maxwell’s Equations in (2+1) Dimensions . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
2.2 Longitudinal and Transverse Fields . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1
1 Preliminaries
1.1 Current Density
Let n̂ be the local unit normal to an element of surface dS, such that dS = n̂ dS (see (a) in the Figure
below). We define a current density j so that dI = j · dS is the rate at which charge passes through dS.
The total current that passes through a surface S is then given by
Z
I= j · dS
S
When a velocity field v characterizes the motion of a charge density ρ, the current density is given by
j = ρv
If the charge is entirely confined to a two-dimensional surface, we define instead a surface current
density in terms of the surface charge density σ:
K = σv
The current which flows past a curve C on a surface (see (b) in the Figure below) can then be expressed
in terms of the local surface normal n̂ using
Z Z
I= (K × n̂) · dl = K · (n̂ × dl)
C C
2
The first term on the LHS vanishes identically, and the second term on the RHS is also zero since v1 and
v2 are mutually perpendicular. Rearranging then gives
v1 · (F2 × v2 )
k1 v12 =
qv22
Substituting for k1 thus obtained in the first of the original expressions for B then yields
F1 × v 1 v1 · (F2 × v2 )
B= + v1
qv12 qv12 v22
which explicitly shows that two distinct measurements are sufficient to uniquely determine B.
2 Maxwell’s Equations
We begin with the inhomogeneous form of Maxwell’s equations, from which it is apparent that all elec-
tromagnetic fields are ultimately attributable to charges and currents:
∇·E=ρ
1 ∂E
∇×B= J+
c ∂t
∇·B=0
1 ∂B
∇×E=−
c ∂t
The first two of these equations are consistent with the observation of charge conservation, expressed by
the continuity equation:
∂ρ
+∇·J=0
∂t
If we further postulate that ρ and J make up a contravariant four-vector field j µ = (cρ, J), then the
continuity equation takes the Lorentz-covariant form
∂µ j µ = 0
where ∂µ = (c−1 ∂/∂t, ∂/∂x, ∂/∂y, ∂/∂z) and ∂ µ = (c−1 ∂/∂t, −∂/∂x, −∂/∂y, −∂/∂z).
We now introduce a scalar potential ϕ and a vector potential A that satisfy the last two Maxwell
equations identically with
1 ∂A
E = −∇ϕ −
c ∂t
B=∇×A
We can postulate that these potentials also make up a four-vector Aµ = (ϕ, A), or Aµ = (ϕ, −A), so that
the above two equations can be encapsulated as
∂ µ Aµ = 0
E1 E2 E3
0 0 Ex Ey Ez
−E 1 0 −B 3 B 2
−Ex 0 −Bz By
Fµν ≡ ∂µ Aν − ∂ν Aµ = −E 2 B3
=
0 −B1 −Ey Bz 0 −Bx
−E 3 −B2 B1 0 −Ez −By Bx 0
3
where µ, ν = 0, 1, 2, 3, or alternatively
−E 1 −E 2 −E 3
0 0 −Ex −Ey −Ez
1
E 0 −B 3 B2 Ex 0 −Bz By
F µν ≡ ∂ µ Aν − ∂ ν Aµ =
=
E 2 B3 0 −B 1 Ey Bz 0 −Bx
E3 −B 2 B1 0 Ez −By Bx 0
From the above, we find that the components of the electric field are given by
Ex ≡ E 1 = ∂0 A1 − ∂1 A0 = ∂ 1 A0 − ∂ 0 A1
Ey ≡ E 2 = ∂0 A2 − ∂2 A0 = ∂ 2 A0 − ∂ 0 A2 =⇒ E i = ∂0 Ai − ∂i A0 = ∂ i A0 − ∂ 0 Ai (i = 1, 2, 3)
Ez ≡ E 3 = ∂0 A3 − ∂3 A0 = ∂ 3 A0 − ∂ 0 A3
The first two of Maxwell’s equations above can now be expressed in compact form using F µν :
Jν
∂µ F µν =
c
To see this, we first note that ∂µ = ((1/c)∂/∂t, ∂/∂x, ∂/∂y, ∂/∂z) and J ν = (ρc, J). The LHS of the first
Maxwell equation results from operating with each element of the row vector ∂µ on the corresponding
elements of the first column of F µν and summing the result, while the RHS results from multiplying the
first element of the row vector J ν by 1/c. The LHS of the second Maxwell equation results from operating
with each element of the row vector ∂µ on the second, third and fourth columns of F µν with the resulting
sum for each column forming the components of a vector, while the RHS results from multiplying the
second, third and fourth elements of the row vector J ν by 1/c to form another vector.
The second two of Maxwell’s equations can be obtained from the Bianchi identity
∂λ Fµν + ∂µ Fνλ + ∂ν Fλµ = 0
where λ, µ, ν must be different from one another for LHS to be nonzero. The third Maxwell equation is
obtained from λ = 1, 2, 3, while the fourth Maxwell equation is obtained from λ = 0.
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2.2 Longitudinal and Transverse Fields
Maxwell’s equations of classical electromagnetism can be expressed in modified Heaviside-Lorentz units
as follows:
1 ∂B(r, t)
∇ · E(r, t) = ρtot (r, t), ∇ × E(r, t) + =0
c ∂t
1 ∂E(r, t) 1
∇ · B(r, t) = 0, ∇ × B(r, t) − = Jtot (r, t)
c ∂t c
where E(r, t) and B(r, t) are the self-consistent local fields, determined in part by the charges and currents
they induce, and ρtot (r, t) and Jtot (r, t) are the total charge and current densities, which are comprised
of the external charge and current densities of the sources that give rise to the external fields and the
charge and current densities induced in the system by these sources/fields, i.e.
ρtot (r, t) ≡ ρex (r, t) + ρ(r, t), Jtot (r, t) ≡ Jex (r, t) + J(r, t)
∇2 ϕ = −ρtot
1 ∂2A 1
2 ∂ϕ 1
∇ A− 2 2 − ∇ = − Jtot
c ∂t c ∂t c
The first equation is simply Poisson’s equation, while the second is a wave equation for A - the electromag-
netic field has therefore been split into an electrostatic potential (described by ϕ) and an electromagnetic
wave (described by A).
A fundamental result of vector calculus says that any vector field can be split into longitudinal and
transverse components, so that we have, for example:
E = ET + EL
where by definition
∇ × EL = 0 and ∇ · ET = 0
tot
and similarly, B = BT + BL , J = Jtot
T + Jtot
L and A = AT + Atot
L . Applying the Coulomb gauge
condition to the latter gives
∇ · A = ∇ · (AT + AL ) = 0
and because ∇ · AT = 0 by definition, we must also have ∇ · AL = 0, so that in the Coulomb gauge
A only has a transverse component (hence the alternative name, transverse gauge). Note that we could
have chosen an alternative gauge, in which case A would have had both longitudinal and transverse
components.
Decomposing the current density allows us to use the continuity equation to obtain
∂ρtot
− = ∇ · Jtot = ∇ · (Jtot tot tot
T + JL ) = ∇ · J L
∂t
5
Differentiating Poisson’s equation with respect to time gives
∂ρtot
∂ ∂ ∂ϕ
(∇2 ϕ) = (∇ · ∇ϕ) = ∇ · ∇ =−
∂t ∂t ∂t ∂t
The rearrangement of the internal charge of a dielectric resulting from the application of an external
field is characterized by the polarization P(r), and it is traditionally defined as the electric dipole moment
per unit volume, so that the integral of the polarization over the volume of a dielectric is equal to the
total dipole moment of the dielectric, i.e.
Z
d3 r P(r) = p
V
The source of the electric field EP (r) arising from polarization of the medium is referred to as bound
charge or polarization charge, with volume density ρP (r) = −∇ · P(r). On the other hand, the source of
the external electric field Eext (r) is referred to as free charge, with volume density ρf (r). Examples of free
charge include the charge on the surface of capacitor plates and point charges placed inside or outside
the body of a dielectric. The total charge density that enters Maxwell’s theory is the sum of the free and
bound charge densities, i.e.
ρ(r) = ρf (r) + ρP (r)
Applying Gauss’s law then yields
We can define a new vector field D(r), traditionally known as the electric displacement, as follows:
∇×E=0
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The above three equations therefore imply that
∇ · D = ρf
and
∇×D=∇×P
The above set of equations is insufficient to determine all the unknown quantities, and must be
supplemented by a so-called constitutive relation that relates P(r) to E(r) (or equivalently, D(r) to
E(r)) obtained from experiment, theory or phenomenology. For the vast majority of systems, which are
unpolarized in the absence of a field but acquire a uniform macroscopic polarization in the presence of a
uniform external electric field, the general rule revealed by experiment is
(2)
Pi = ε0 χij Ej + ε0 χijk Ej Ek + . . .
(2)
where the tensor nature of the constants χij and χij allows for the possibility that P is not parallel to
E, as is the case in spatially anisotropic matter. The second- and higher-order terms in the expansion
allow for the possibility that the polarization depends non-linearly on the field, which occurs in all matter
when the electric field strength is large enough.
If a dielectric is linear, it can be described by just the first term on the right-hand side of the expansion;
if it is also isotropic, then the tensor χij can be replaced by a scalar and the constitutive relation written
simply as
P = ε0 χE
The constant χ is called the electric susceptibility. We also introduce the (dimensionless) relative permit-
tivity εr ≡ 1 + χ (sometimes also known as the dielectric constant, κ) via
P = ε0 (εr − 1)E
In a linear, isotropic medium the electric displacement D defined earlier can therefore be expressed as
D = εr ε0 E = ε0 (1 + χ)E
p = αElocal
The polarization will then be given in terms of the number of dipoles per unit volume, n, by
P = nαElocal
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However, we already have an expression for the polarization in terms of the dielectric constant and
macroscopic field, i.e. P = ε0 (εr − 1)E, and eliminating P therefore yields
nα Elocal
κ=1+
ε0 E
The question now is how to determine the local field. Lorentz suggested imagining a macroscopically
small sphere centred on the atom in question - all the material outside the sphere then contributes the
field E + P/3ϵ0 calculated earlier, while all the dipoles within the sphere must be treated individually and
their effect added to the latter field. For a material with a cubic lattice, he showed that the contribution
of the dipoles within the sphere would be zero, and hence
P
Elocal = E +
3ε0
All magnetic phenomena are due to electric charges in motion. At the atomic scale, a piece of magnetic
material contains microscopic currents due to electrons orbiting around nuclei and spinning on their own
axes. On a macroscopic scale, these current loops are so small that we can treat them as tiny magnetic
dipoles. Usually, these dipoles cancel each other out due to the random orientation of the atoms, but
when the material is placed in an external magnetic field, there is a net alignment of the dipoles and
the material becomes magnetically polarized, or magnetized. For a magnetized material, we define the
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magnetization M(r) as the magnetic dipole moment per unit volume, such that the total magnetic dipole
moment of the material is given by Z
m= d3 r M
V
A magnetic dipole experiences a torque in a magnetic field, and this is the origin of both paramagnetism
and diamagnetism. In the case of paramagnetism, it is the dipole formed by the electron spinning about
its axis that experiences the torque, which acts to align the dipole with the field. However, since the Pauli
exclusion principle dictates that electrons in a given atom form pairs with opposing spins, this effectively
neutralizes the torque on the pair, and hence paramagnetism normally occurs in atoms (and molecules)
with an odd number of electrons. In the case of diamagnetism, it is the dipole formed by an electron
orbiting about the nucleus that experiences the torque, which acts to align the dipole antiparallel to the
applied field. Diamagnetism is a universal phenomenon affecting all atoms, but is typically much weaker
than paramagnetism, and is therefore usually observed in atoms with an even number of electrons, where
paramagnetism is normally absent.
The source of BM is therefore the bound current or magnetization current that results from the
combination of all the tiny atomic dipoles or current loops in the material, and we use the symbols
jM and KM for its volume and surface densities, respectively. These can be expressed in terms of the
magnetization as follows:
Similarly, we can view the source of the external applied field that initiates the magnetization process as
free current, such as that flowing through a coil or solenoid, and use the symbol jf for its density. The
total current density that enters Maxwell’s theory is then given by the sum
If we assign a point dipole moment dm(r′ ) = M(r′ )d3 r′ to every element of the sample volume V ,
then summing their contributions gives
r − r′
Z Z
3 ′ ′ ′ µ0
BM (r) = µ0 d r M(r )δ(r − r ) − ∇ d3 r′ M(r′ ) ·
V 4π V |r − r′ |3
Z Z
µ0 1
= µ0 d3 r′ M(r′ )δ(r − r′ ) − ∇ d3 r′ M(r′ ) · ∇′
V 4π V |r − r′ |
where we note that the first term is only non-zero for r ∈ V (r = r′ ), and in the second line we have used
the fact that
r − r′ 1 1
′
= −∇ ′
= ∇′
|r − r | 3 |r − r | |r − r′ |
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If we now define the magnetic scalar potential of a volume distribution of point magnetic dipoles with
density M(r) via Z
1 3 ′ ′ ′ 1
ψM (r) ≡ d r M(r ) · ∇
4π V |r − r′ |
(N.B. for proof of convergence of electromagnetism integrals of this type, see Electromagnetic Theory,
Stratton, p.171) we can write
(
µ0 M(r′ ) − µ0 ∇ψM (r) r∈V
BM (r) =
−µ0 ∇ψM (r) r∈/ V (since M = 0)
We now define an auxiliary field HM (r) ≡ −∇ψM (r), and since M = 0 outside the magnetized volume,
the above relations can be summarized as the fundamental relation of magnetic matter:
Comparing with E = −∇ϕ(r), we can interpret HM (r) as a field produced by a fictitious magnetic
’charge’ with volume density ρ∗ (r) = −∇ · M(r) and surface density σ ∗ (rS ) = M(r)S · n̂(rS ), such that
r − r′ r − rS
Z Z
1 1
HM (r) = d3 r′ ρ∗ (r) ′ 3
+ dS σ ∗ (rS )
4π V |r − r | 4π S |r − rS |3
Note that HM inside V is often called the demagnetization field as it tends to point opposite to M. This
is because the surface charge density σ ∗ = M · n̂ is the source of the field HM .
where θ is the angle that the radius makes with the z-axis. Using HM (r) ≡ −∇ψM (r) we find that
(
− 31 hM r<R
HM (r) = R3 3(r̂·M)r̂−M
i
3 r3 r>R
10
The field lines for both BM (r) and HM (r) are shown in the Figure below. Outside the volume of the
sphere, BM = µ0 HM is identical to the expression for the magnetic field of a point magnetic dipole at
the centre of the sphere:
µ0 3(r̂ · m)r̂ − m
BM (r) =
4π r3
4 3
with dipole moment m = V M = 3 πR M.
Inside the sphere, BM (r) and HM (r) are uniform and anti-parallel, which is because the lines of
BM (r) must form closed loops, while the lines of HM (r) must point away from (or towards) the surface
depending on the sign of the magnetic charge shown in the previous Figure.
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Hence, on further application of the Halmholtz theorem we may write H(r) in the form
jf (r′ ) jf (r′ )
Z Z
1 1
H(r) = −∇ψM (r) + ∇× d3 r′ ′
= −∇ψM (r) + d3 r′ ∇ ×
4π V |r − r | 4π V |r − r′ |
∇ × jf (r′ )
Z Z
1 3 ′ 1 1
H(r) = −∇ψM (r) + d r ∇ × jf (r′ ) + d3 r ′
4π V |r − r′ | 4π V |r − r′ |
The last term is zero because jf (r′ ) is not a function of the unprimed coordinates, and so the curl is zero.
Using the relation from earlier we may rewrite the second term to yield the following:
′ ′
3 ′ jf (r ) × (r − r )
Z Z
1 3 ′ ′ 1 1
H(r) = −∇ψM (r) − d r jf (r ) × ∇ = −∇ψM (r) + d r
4π V |r − r′ | 4π V |r − r′ |3
M = χm H
where the (dimensionless) constant χm is known as the magnetic susceptibility of the material, and is
positive for paramagnets and negative for diamagnets. Materials that obey the above relation are known
as linear media. From the definition of H, we obtain the constitutive relation
B = µ0 (H + M) = µ0 (1 + χm )H = µH
µ ≡ µ0 (1 + χm )
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