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pH & Conductivity Meter

Operation Manual

Please read and adhere to all recommendations in this manual to ensure the best experience and to
maintain your Meter in good working order. The manual is for the model P713.

1. Features

● 6.5-inch LED screen with concise and friendly-use interface.


● Built-in microprocessor chip has Intelligent functions such as automatic calibration, ATC, data storage, clock display,
USB output, function settings, wireless printing, and self-diagnosis information, etc.
● Auto recognition of 25 buffers with three kinds of options: Europe & USA, NIST and China. Support 1, 2, 3 point calibration.
● Adopt advanced conductivity measurement technology, with conductivity electrode (K=1), it can meet measuring
accuracy requirement for range of 0.5μS/cm ~ 200mS/cm.
● Can switch among conductivity, TDS, salinity and resistivity. Multinomial calculation for TDS and salinity to ensure the
conversion precision of the full scale.
● Auto recognition of 8 conductivity standard solution with 2 kinds of options: Europe & USA, and China.
● It supports wireless bluetooth printing. Real-time data transfer to mobile phone via bluetooth is optional.
● Smart electrode status display to ensure accurate use.
● Omron long lasting and light touch key can be used more than 100,000 times.
● Can store 1000 sets of test data, which can be saved and transferred to USB memory stick and opened with Excel.

2. Technical Parameters

2.1. pH

Measuring Range (-2.00 - 19.990) pH


Resolution 0.1/0.01 pH
Accuracy Meter:±0.01pH; Complete Kit: ±0.02pH
Input Current ≤2×10-12 A
Input Impedance ≥1×1012 Ω
Stability ±0.02 pH/3h
Temp. Compensation (0 - 100) ℃ (Auto/Manual)

2.2. mV
Measuring Range -1999 mV - 0 - 1999mV

Resolution 0.1mV

Accuracy Meter:±0.03% FS

2.3 Cond.
Conductivity:
(0.00~20.00)μS/cm, (20.0~200.0)μS/cm
(200~2000)μS/cm, (2.00~20.00)mS/cm
(20.0~200.0)mS/cm,
Measuring range
(200~2000)mS/cm (K=10)
TDS:(0 ~ 100)g/L
Salinity:(0 ~ 100)ppt
Resistivity:(0 ~ 100)MΩ·cm
Resolution 0.01/0.1/1μS/cm; 0.01/0.1mS/cm
Accuracy Meter: ±1.0% FS, Complete Kit: ±1.5% FS
Temp. compensation (0 ~ 100)℃, Auto/Manual
Electrode constant 0.1 / 1 / 10 cm-1
Reference Temp. 25℃,20℃,18℃

2.4 Temp.
Measuring range (0 ~ 100)℃
Resolution 0.1℃
Accuracy 5 ~ 60℃:±0.4℃, Others: ±0.8℃

2.5 Others
Display 6.5-inch LED screen
Data storage 1000 sets
Power 12V
Output USB, Bluetooth
Ambient Temp. 5 ~ 35 ℃
Ambient Humidity ≤85%
IP grade IP54
Dimensions/N.W. 215×170×37mm/600g
Quality & Safety Certification ISO9001, CE

3. Instrument Structure

3.1. LCD display

①---Parameter mode
②---Measuring value
③---Time
④---Measurement unit
⑤---Temp. measuring value
⑥---Tips
⑦---Stable icon
3.2. Operation Keys
【ON/OFF】Switch key
【CAL】Calibration key, Left direction key
a) In measuring status, press this key to enter into calibration mode.
b) In system time & manual temperature compensation state, the key is a Left direction key.
【SAVE】Record save, Record query, Right direction key
a) Under measurement status, short press the key can store measuring data in the corresponding mode (the
lower right corner of screen will display serial number M+, time length 1s).
b) In measuring state, long press the key can search stored data in the corresponding mode (RM and serial number
will be displayed in search operation).
c) Under system time and manual temperature compensation mode, it is used as the right direction key.
【ESC/PRN】Print, Return key
a) Under measurement mode, it is used as printing key and can be printed directly through bluetooth printer.
b) In non-measuring mode, it is used as a return key.
【SET】System setting
In measurement mode, system setting interface can be entered through the key.
【UP】Upwards key
Under system time and manual temperature compensation mode, it is used as the upwards key.
【DOWN】Switching mode, Downward key
a) Under measurement status, the key is used as switching mode: pH-mV-pH, COND-RES-TDS-SAL-COND.
b) In system time and manual temperature compensation mode, it is used as the downwards direction key.
【OK】confirm key

3.3. Interface diagram

① Temperature probe
② Conductivity electrode
③ pH electrode
④ USB
⑤ Data cable
⑥ Power

4. pH measurement

4.1. Preparation work


4.1.1.Press【ON/OFF】key to turn on, then warm up for 10 minutes.
4.1.2. Check pH electrode glass bulb is kept wet or not, if the glass bulb is damaged, then the electrode will not work
properly; if glass bulb’s surface too dry, it needs to be immersed into a potassium chloride solution for 24 hours.
4.1.3. Insert the pH electrode.

4.2. Instrument Calibration


4.2.1. Press【CAL】to enter into calibration mode, LCD displays “ C1 ”, indicating to enter the 1st point calibration.
4.2.2. Wash the pH electrode & temperature probe in purified water and dry it, then immerse them into the
PH6.86 buffer solution, shake the electrode and place stable, then wait for the data stable. when appear stable icon,
then press【OK】, LCD will display 6.86 PH, then press【OK】, LCD will display “C2”and enter into the 2nd calibration,
or press【ESC/PRN】to exit calibration mode.
4.2.3. Wash the pH electrode & temp. probe in purified water and dry it, then immerse them into the pH4.00 buffer
solution, rock the the electrode and place stable, then wait for the data stable. when appear stable icon, then press
【OK】, LCD will display 4.00pH, press【OK】again, ”C3”will appear in the upper right corner and enter into the 3rd
point calibration, or press【ESC/PRN】to exit calibration mode.
4.2.4. Wash the pH electrode & temp. probe in purified water and dry it, then immerse them into the pH9.18 buffer
solution, rock the the electrode and place stable, then wait for the data stable. when appear stable icon, then press
【OK】, LCD will display 9.18pH, then press【OK】again to confirm the 3rd point, meanwhile exit calibration mode to
enter into measuring mode, then the lower right corner of LCD screen will show “ L M H ” at the same time, which
means the meter finish three point calibration.
4.2.5. Calibration attention
a) This meter can adopt random one-point, two-point or three-point automatic calibration, after the 1st point
calibration (see item 4.2.2.), press 【 ESC/PRN 】 to exit calibration mode and enters into measuring mode. The
calibration icon “L” for one-point calibration will appear on the lower left corner of LCD. When the measuring
accuracy is ≤±0.1pH, user just need to choose one kind buffer solution to do one-point calibration as per measuring
range.
b) After the 2nd point calibration, (see item 4.2.3.), press 【 ESC/PRN 】 to exit calibration mode and enter into
measuring mode. The calibration icon “L M” for two-point calibration will appear on the lower left corner of LCD.
User can choose pH4.00 and pH6.86 to calibrate if only measuring acidity range; choose pH6.86 and pH9.18 to
calibrate if only measuring alkalinity range.
c) Three-point calibration should be selected to reach a more accurate measurement, if the measuring range is wide,
or if the electrode has been used for long time and have ageing phenomenon. if the electrode be used for the 1st
time, it must be calibrated by three-point calibration to adjust meter slope in accordance with pH electrode.

4.3. pH solution measurement


Immerse pH electrode & temperature probe into the sample solution after washing and dry it, rock the electrode and
place stable, when the measurement value is stable and LCD appears the stable icon, then read it out which is
sample pH value.
Note: According to the pH isothermal measurement principle: the closer the temperature of the sample solution
with the calibration solution, the more accurate the measuring value will be acquired. So please comply with this
principle.

4.4. Parameter Setting


Press【SET】to enter into setting mode, press【UP】or【DOWN】to choose P1-P12, press【OK】to enter the selected
setting mode. Press【ESC/PRN】to return to measuring mode.

Prompt Parameter setting Remark

When USB drive is connected, press【OK】to export data.


P1 Export data to excel
If not, an error will be prompted.
P2 System date setting

P3 Clear record setting

P4 Temperature unit setting ℃, ℉


P5 Check machine code The displaying code on screen is the machine code.

P6 APP Authorization code setting


When displaying 8888 on screen, press【OK】to restore to
P7 Restore to factory setting
factory setting.
P8 Manual temperature compensation setting

P9 Bluetooth mode setting

P10 pH resolution setting

CH (China series) : 1.68, 4.00, 6.86, 9.18, 12.46 pH


P11 pH standard buffer solution selection USA (Europe & U.S.A series) : 1.68, 4.00, 7.00, 10.01, 12.45 pH
NIS (NIST series) : 1.68, 4.01, 6.86, 9.18, 12.45 pH

“OFF” No compensation. “H2O” Purified water pH


P12 Ammonia pure water compensation setup
compensation. “nH3”Ammonia pure water compensation.

4.5. Attentions
4.5.1.Calibration times of meter depends on the sample,electrode performance and required accuracy. For high
accurate measurement (≤±0.02pH), which should be calibrated immediately with high accurate standard buffer
solution, for general accuracy measuring (≥±0.1pH), which can be used almost one week or long time o after be
calibrated.
4.5.2. The meter must be recalibrated in the following situations
a) New changed or unused electrode for a long time;
b) After measuring acid (pH<3) or alkaline (pH>10) solution;
c) After measuring solution which contains fluoride and concentrated organic solution;
d) The solution’s temperature is much different with calibration temperature.
4.5.3. There is an electrode soaking solution in the protective bottle at the front of the pH electrode,which can
protect the glass blub, when measuring,open the bottle cap,pull out the electrode and wash it with pure water,insert
the electrode into the bottle and tighten the cap to prevent the exudation of the solution.If the soaking liquid in the
protection bottle is found to be turbid or mildewed, clean it in time and replace the new soaking liquid.
4.5.4. It is not allowed to soak in pure water, protein solution and acid fluoride solution for a long time, and prevent
getting touch with organic grease.
4.5.5. When the meter is calibrated with a standard buffer solution of known PH value, the buffer solution PH value
should be reliable in order to improve the measurement accuracy.The buffer solution should be changed in time
after repeated use.
4.5.6. Always keep the meter clean and dry; especially for the socket of meter and electrode, otherwise it may lead
to measurement error or failure.
4.5.7. The sensitive glass bulb at the front of combination electrode should not touch with hard things, and any
broken and friction will make the electrode invalid. Before and after measuring, the electrode should be washed with
purified water, and dry electrode after washing, Do not wipe glass bulb with paper towel,it will effect stability of
electrode potential and enlarge response time. After the measurement in the viscous sample, the electrode shall be
repeatedly washed with pure water for several times to remove the sample stuck on the glass film, or first cleaned
with appropriate solvent.
4.5.8. If the electrode is used for a long time, or the solution under test contains substances that are likely to
contaminate sensitive glass bulb or block the liquid interface, the electrode will be passivated. The phenomenon is
that the sensitivity gradient is reduced, the response is slow, and the reading is inaccurate. The following measures
can be taken according to different situations:
a) The glass bulb is contaminated and aging: soak the electrode in 0.1mol/L diluted hydrochloric acid for 24h, clean it
with pure water, and then soak it with electrode soaking solution for 24h. If the passivation is serious, soak the
electrode bulb in 4%HF (hydrofluoric acid) solution for (3~5) s, clean it with pure water, and then soak it in electrode
soaking solution for 24h to make it new.
b) Cleaning of glass bulb and liquid interface contamination: (for reference)
Contamination Abluent
Inorganic metal oxide Diluted acid less than 1mol/L
Organic lipidic matter Dilute detergent (weakly alkaline)
Resin macromolecule matter Dilute alcohol, acetone, ether
Protein blood deposit Acidic enzyme solution (such as dried yeast)
pigments substance Dilute bleach solution, peroxide

4.5.9.The service life of pH electrode is about one year,but if the service condition is bad or the maintenance is
improper, the service time will be shortened, and the electrode should be replaced in time after aging or failure.
4.5.10. When the meter is abnormal,please set P7 to restore the meter to factory settings state, and then to do
calibrate and measure again.

5. MV Measurement
5.1. Press【ON/OFF】to turn on, press【DOWN】, choose MV measurement mode.
5.2.Connect the ORP combination electrode or the ion combination electrode (optional), wash the electrode in pure
water and keep it dry, and immerse it in the measured solution. slowly stir and then place stable. When
measurement value is stable and appear stable icon, then read the MV value.

6. Conductivity measurement

6.1 Preparation Work


6.1.1. Press【ON/OFF】key to turn on,and warm up for 10 minutes.
6.1.2. Check whether the DJS-1.0 platinum black electrode plate is intact, if the electrode plate is damaged, platinum
black electrode rust,electrode can not be used normally, the new electrode should be replaced.
6.1.3. Insert the platinum black electrode and the temp. electrode into the corresponding interface of the meter.

6.2 Instrument calibration (standard solution calibration method)


6.2.1.Press 【 CAL 】 to enter the calibration mode, displays "CAL" on the screen, indicating to enter the calibration
mode.
6.2.2.Wash the conductivity & temperature electrode in pure water and dry it, then immerse them into the 1408
Us/cm calibration solution, shake the electrode and place stable, when the measurement value is stable and show
stable icon, then press【OK】, display 1408 Us/cm,confirm the calibration is correct then press the【OK】to complete
the calibration, save the data ,then press【OK】to exit the calibration mode, The icon "L M" will appear on the screen.
Note:
a) The Meter has been calibrated when it is out of factory, and can be used directly under normal circumstances.
b) The standard solution method is aimed at the inaccuracy of the conductivity constant caused by the long time use
of the conductivity electrode. The new conductivity electrode has been calibrated before leaving the factory, and its
constant is marked on the electrode, and the input constant before use.
c) The input method of electrode constant, firstly, to determine the type of electrode constant, then input the
constant coefficient. For example, the constant is 10.5, select 10 electrode types first, and then set the constant to
1.05. That is: 10.5 = 10*1.05.

6.3. Conductivity solution measurement


6.3.1. Clean the conductivity electrode and dry it, put it in solution with the temperature electrode, stir it and place
stable, when the measurement value is stable and LCD appears the stable icon, then read it out, which is the
measurement value of the conductivity solution.
6.3.2. Short press【 DOWN】 to circularly display resistivity values, TDS values and salinity values corresponding to
conductivity values.
6.4. Important explanation
6.4.1. The meter has two series of calibration solutions, please set it in parameter setting P12.
Chinese series:
146.6 mu s/cm, 1408 mu s/cm,12.85ms/cm, 111.3 ms/cm.

The European and American Series:


84 mu s/cm, 1413 mu s/cm,12.88ms/cm, 111.9 ms/cm.

6.4.2. The Meter has a unique one point calibration function. Users can select a solution for calibration according to
the principle that the conductivity of the water sample and the calibration solution is as close as possible. The
commonly used calibration solution is 1408 mu s/cm, using the DJS-1 platinum black electrode (K=1), and using the
1408 mu s/cm calibration solution, it can be used in measurement range less than 100 ms /cm. Please refer to the
table for selection.

Measuring range 0.05~20μs/cm 0.5μs/cm~200ms/cm


Electrode constant K=0.1cm-1(Flow test) K=1.0cm-1
Calibrated solution 146.6 μs/cm 146.6 μs/cm 1408μs/cm 12.85ms/cm, 111.3 ms/cm
Indicator icon L L L M L M H

6.4.3 The calibration method of conductivity electrode set in the instrument includes standard solution calibration
method and constant setting method. The article 4.2 "electrode calibration" refer to the standard solution calibration
method. As long as the standard solution is accurate, it can ensure the best accuracy. Therefore, the standard
solution calibration method is preferred. If the user is used to use constant setting method, user can set it according
to the constant on the conductivity electrode (New conductivity electrode constant manufacturer has marked it
accurately, customer can rest assured to use, if not used for a long time or stained, in order to ensure accuracy, clean
the electrode first then calibrated with standard solution).
6.4.4 The temperature compensation coefficient of the instrument setting is 2.00%/ C, but the conductivity
temperature coefficient of various kinds of different kinds of different concentration solutions is different. The user
can refer to the table (4-2) or the data obtained by the user in the experiment to setting in parameter setting P13. In
high purity water below 10 s/cm,the instrument automatically performs nonlinear temperature compensation.
Note: When the temperature compensation coefficient is set to 0.00,that is: there is no temperature compensation
when the instrument is tested. The measured value of the instrument is the conductivity value at that time.

Solution Temperature compensation coefficient

NaCl Salt solution 2.12%/℃


5%NaOH solution 1.72%/℃
Dilute ammonia solution 1.88%/℃
10% Hydrochloric acid solution 1.32%/℃
5% Sulfuric acid solution 0.96%/℃

6.5. Parameter settings


Press【SET】to enter into setting mode, press【UP】or【DOWN】to choose P1-P14, press【OK】to enter the selected
setting mode. Press【ESC/PRN】to return to measuring mode.
Prompt parameter setting item Remark
P1 Export data to excel When USB drive is connected, press【OK】to export data.
If not, an error will be prompted.
P2 System date setting
P3 Clean record setting
P4 Temperature unit setting ℃, ℉
P5 Check machine code The displaying code on screen is the machine code.
P6 APP Authorization code setting
P7 Restore to factory setting When displaying 8888 on screen, press【OK】to restore
to factory setting.
P8 Manual temp. compensation setting
P9 Bluetooth mode setting Bluetooth or APP
P10 Electrode coefficient setting
P11 Electrode constant level setting 0.1, 1.0, 10
P12 Standard solution setting CH or USA mode
P13 Temp. compensation coefficient setting
P14 Reference temperature setting 18℃, 20℃, 25℃

6.6. Attention
6.6.1.When the instrument is out of factory, the conductivity electrode has been calibrated. Its constant value is
marked on the electrode. The customer can set the constant value directly. It can use directly,does not need to be
recalibrated.
6.6.2. Normally recommends that the customer be calibrated once a month, and that the conductance electrode
after a period of time needs to be calibrated once.
6.6.3. Keeps the conductivity electrode clean. Before and after measurement, it needs to be cleaned with pure water
and dry it.
6.6.4.DJS series platinum black conductivity electrode is plated with a layer of metal platinum black to reduce
electrode polarization and expand the range. Therefore, the platinum black electrode can not be wiped out, so it can
only be washed in water to avoid damaging the platinum black coating. With the warm water containing detergent,
the organic components of the electrode surface can be cleaned and the alcohol can be used to wash.
6.6.5. Conductivity electrode can be immersed in pure water before use, in order to prevent platinum black. If
platinum black electrode is found out of failure,immerse into 10% nitric acid solution or 10% hydrochloric acid
solution, measure it after rinse with pure water. If the condition is not improved, then platinum black needs to be
re-electroplated, or new conductivity electrode should be replaced.
6.6.6. When the meter is abnormal, please set P7 to restore the meter to factory settings state, and then to do
calibrate and measure again.

6.Meter’s Complete Kit


pH & Conductivity Meter
E-201-9 pH electrode
DJS-1 Platinum black electrode
T-10-Q Temperature probe
Standard buffer solution (3 bottle)
Adapter (12V 1000mA)
Manual
Appendix A

Conductivity Standard solution concentration and conductivity value

Solution Reference Reference Conductivity/(S.cm-1)


number solution solution
KCLg/1000g KCLg/1000m
solution L solution 15℃ 18℃ 20℃ 25℃ 35℃
(In vacuum) (20℃room
temperature)
1 71.1352 74.2457 0.09212 0.09780 0.10170 0.11131 0.13110

2 7.41913 7.4365 0.010455 0.011163 0.011644 0.012852 0.015353

3 0.745263 0.7440 0.0011414 0.0012200 0.0012737 0.0014083 0.0016876

4 0.074528 Dilute the 0.0001185 0.0001267 0.0001322 0.0001465 0.0001765


number 3
100ml to
1000ml
Notes: The following conditions must be observed in the application of the above standard solution
1. The standard values listed in the table deduct the water conductivity of the standard solution.
2. The standard solution of the solid standard substance of electrical conductivity can be prepared by
baking 4h at 110℃.
3. Configuration of standard substances according to the environmental conditions specified in Table 2.
4. It is recommended to use a first class 1L capacity bottle and a balance of 0.1mg.

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