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  • Gibbs Equations or T Ds Relations

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    Thangavel Sarujan
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    The document discusses several thermodynamic relationships involving temperature (T), internal energy (U), enthalpy (H), heat (Q), work (W), pressure (P), and volume (V). It presents equations relating the change in these quantities, such as dU = TdS - PdV, dH = TdS + VdP, and dQ = TdS. It also discusses using these relationships to derive equations involving changes in temperature, such as ΔU = ∫cudT, ΔH = ∫cpdT, and ΔS = ∫cv/TdT.

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    Derivation for the formula for 1st and 2nd T ds relations

    Original Title

    Gibbs equations or T ds relations

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    The document discusses several thermodynamic relationships involving temperature (T), internal energy (U), enthalpy (H), heat (Q), work (W), pressure (P), and volume (V). It presents equations relating the change in these quantities, such as dU = TdS - PdV, dH = TdS + VdP, and dQ = TdS. It also discusses using these relationships to derive equations involving changes in temperature, such as ΔU = ∫cudT, ΔH = ∫cpdT, and ΔS = ∫cv/TdT.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    5 views1 page

    Gibbs Equations or T Ds Relations

    Uploaded by

    Thangavel Sarujan
    The document discusses several thermodynamic relationships involving temperature (T), internal energy (U), enthalpy (H), heat (Q), work (W), pressure (P), and volume (V). It presents equations relating the change in these quantities, such as dU = TdS - PdV, dH = TdS + VdP, and dQ = TdS. It also discusses using these relationships to derive equations involving changes in temperature, such as ΔU = ∫cudT, ΔH = ∫cpdT, and ΔS = ∫cv/TdT.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 1

    Gi;b6s ~UQ¾ions or T ds r-e.

    lQl,ons

    11 E \ S8S = s~,n - 8Wou.±


    dV \s~s = 8Q,n -8Woll.t
    -J;
    Tds
    tFdV
    dV = Tds - Pdv
    t5-c -a:, reloJ-ion3: 1 ds - dV + Pdv
    knowira -tha.:b H= U.. + PV
    ll = H -PV
    dlt =clH-fdV-Vd.f
    t'J.TdS rel~ TotS =dH-Vdf

    Consik 11\Q..- I Bi, Tels r-e.l<A:t:tons: Td S -= + PdV


    d..V
    T~ == clv + pclv fUse ·fv =RT]
    -rd~ = cvdT +R1~
    .
    do =Cv dT
    T
    +-Rel~
    V

    ~-'11 "'c'J +~f


    I I

    -12--j1 = Cv In~}+ Rln(~)


    Consid...er 18L Tds r-e..lu!rons: I use.. fv = RT!

    \J cxrio..bon ·,n Tu+QXncJ.. ~t1: u.2 -u 1 -=- J Cu. dT


    \Jo..ria!f Oh in f=v-i-!J.,aJf~: h2-h1 =-J CpdT I

    I
    ~z<~, :::: cv In({,-)+ Rln (f)
    or 12 -~ 1 = Cp In ~)-Rlh ( ~z)

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