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  • ORGAnic CHEMiStry Class 11

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    Prateek Pranjal
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    The document discusses organic chemistry concepts including: - The structures, properties and stability of cis-2-butene and trans-2-butene. Cis-2-butene is less stable with a dipole moment while trans-2-butene is more stable and without a dipole moment. - The structures, properties and acidity of maleic acid and fumaric acid. Maleic acid has a higher dipole moment and lower pKa values than fumaric acid. - Three homework questions are presented on naming organic compounds and determining R/S configuration around stereocenters. The answers to the homework are then provided.

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    ORGAnic CHEMiStry class 11

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    The document discusses organic chemistry concepts including: - The structures, properties and stability of cis-2-butene and trans-2-butene. Cis-2-butene is less stable with a dipole moment while trans-2-butene is more stable and without a dipole moment. - The structures, properties and acidity of maleic acid and fumaric acid. Maleic acid has a higher dipole moment and lower pKa values than fumaric acid. - Three homework questions are presented on naming organic compounds and determining R/S configuration around stereocenters. The answers to the homework are then provided.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    4 views27 pages

    ORGAnic CHEMiStry Class 11

    Uploaded by

    Prateek Pranjal
    The document discusses organic chemistry concepts including: - The structures, properties and stability of cis-2-butene and trans-2-butene. Cis-2-butene is less stable with a dipole moment while trans-2-butene is more stable and without a dipole moment. - The structures, properties and acidity of maleic acid and fumaric acid. Maleic acid has a higher dipole moment and lower pKa values than fumaric acid. - Three homework questions are presented on naming organic compounds and determining R/S configuration around stereocenters. The answers to the homework are then provided.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 27

    Introduction To Organic Chemistry-(Section-4 and 5)-Class-10

    IOC-JEE-2024 Page 1
    IOC-JEE-2024 Page 2
    Cis-2-Butene Trans-2-Butene
    Structure

    Dipole Moment 0.3D 0.0D


    Boiling point 276.7K 273.9K
    Melting point K K
    Stability Less More
    f 7kJ/mol 11kJ/mol
    comb 2685kJ/mol 2682kJ/mol
    Hydrogenation 120 kJ/mol 116 kJ/mol

    Cis-But-2-ene-1,4-dioic acid Trans-But-2-ene-1,4-dioic acid


    Structure

    IOC-JEE-2024 Page 3
    Trivial Name Maleic acid Fumaric acid
    Dipole Moment More Less
    Melting point 1◦C 287◦C
    Solubility 788 g/L at 25◦C 7 g/L at 25◦C
    pKa1 Lower(1.92) Higher(3.02)
    pKa2 Higher(6.23) Lower(4.38)
    H-Bond Intramolecular Intermolecular
    Anhydride formation Form cyclic anhydride on Do not form cyclic anhydride
    heating on heating

    IOC-JEE-2024 Page 4
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    Homework-2

    IOC-JEE-2024 Page 15
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    IOC-JEE-2024 Page 17
    Answers-Homework-2

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    Homework-3

    IOC-JEE-2024 Page 22
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    Answers

    IOC-JEE-2024 Page 24
    IOC-JEE-2024 Page 25
    IOC-JEE-2024 Page 26
    IOC-JEE-2024 Page 27

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