wf. pate 210 June 2021 Date — : pee Nessa Rajkumoy “Gude Number: 219003070 - eee Practical # + Proctlcal 3 + Pytnometuy * him: oa Pawlal wolav yolumes. of methanol and“ water by “To determine the partic) molar volumes. of wethorel and wate shy pytnonetey ond Wethed of intevceptS oud: 4 eamine the deosity of water « sng ?. Flow chart: & i, Va ond Ug from Plot Vaewwin Ve Xe > —> nN cha athb ne ross from ply | vO mewred quewt ities <—— Pret, Pol k \ ( v, paleroneden from p= “he i badle + Scanned with CamScanner7 Yolumes for methanol ond soter e = — HOH 19: Wo 19 1 Teta 19 re 25-3 94-0122. 104 3g : ao 5o- 6 SE-4418 109.04, Bo as.) 34-2322 WAR zo low 18 -Jeraey 120 ag Joo 6-4 °. Re-an, Dersity of Sater = Ug Tint Mass of empty pykne= 33 38709 “ Density of metharol = o ta3gini Feble 2: The determined mass *y, Preset im pycnometa asec. > Pgtromete 19 : 49-4284 ge2z0+ | 43.9285 | | 43.2485 Table 3: mass of Woler i thass empty tytwo 19: 34-3870 38 3370 38-3579 46. 9438 20 100 48.3094 49 1355 4 8954 Methanol Solution m) Tet [ macgrite ig: | Avg Mass of Solution 19 Poasity lgimt lo-0214 | 0.3039 a.4529 | 02893 9.00482 0 6l 8.4445 oot Oat 1092 Hee! sy water ony Lg Scanned with CamScannerCalculations : For the Solution with 20> — methanol the fle Faas Ve 12.66 And watew ene ip. Y= .43aq-[ 4 Ve a4i9qq mI __ Table 4: The results of aif Pyenometer ast Pongal Pesta! Solution Volume is Solutias in different Samples Scanned with CamScannerass oF ated safest site Baageneg: of ay gontesed mass of Wetlew = Wass of soln. x mass of adjusted tte~ 9:319499 x10 ‘oom g FO-Oleg . corrected MOSS For 26%. Methanol mass BF Sol. =o) Toyor ~ Ne = mT nam . waaset ='-Mdss 20°. Solw.~ O-onaeg: = le-o414g - o-0naeg i = to 0296 g ang 2, OS [32.04 g-mot™ 20-313 mol. x wole fraction 2+ O-313 mol x O2 = 0-0626 mol ee Iig.02g Imo} 20-554 moa Y wole Fraction. ° =: oO SEImol 4 08 : Ass mol Scanned with CamScannertoble below - All calculations _ Gre summarized in the tb Sys a ‘oh-vanter, andithaoles OF «nmin — Table 5+ The corrected mass of watey an i methanol 0445 O:3i Oo 454e Ong Sa 0-114 ae © -0143) Bvotume = [Nests 10 meena + Dio x M0 a —Reterel x MM mechan) Die 1 mye Pmethauo} a ~ 9.7199 O-3q3 : maya “Toe = Oso%e yy Bo) ee es heey BRR cd 2556 SHES! sat Fat Scanned with CamScannervy / _ = Mmethanol - = 6.0620 mej = 081230 fees eee - I —————_ Se ee e _ 7 Neoted ©°SOAS mol ; ee - OC = a ee 7 / a i Glladeted Xe values and AVmixln values for pte eae solutions . i j s ee ee nMetrousl [mal] Totes [ul : Xe: 0.0626 d- 5045 ; wees O14as7 o-454¢ o0-2498 a taa2 indie 2 O-42u Batea8, 2SI6e 0-2e6@3¢ 6 -255S © 2449 — Pure molor Volume Hip = -\ 9.02 Qlmol | Iglmo| 4 Veng% = 18:09 ml fmol Pure molar Volume Wethauel = 32.04 g lwol | o-4a¢ ginal = 40-40 mi Iwol — Scanned with CamScanner[momo AVmix ln moor fraction CHs0H , Xe Figure | 1 BVnixtn 0D function OF te molar fraction of Methar Scanned with CamScannerPortia) molar volume of X methanol Fromy-int: 0-25 2 Vy - Va a® O28 2. Vy ots .00 Vn = 18-24 mL mol 5 x [From iintesection 2 J-2 = Vp iy & re a 46 bes Ve -— tO -4 Vg = 44-60 ml-[mel. Discussion : The expenmental results Dbtatned were used to deternbe the Partiad Moles! Volumes of methonal and - Bate by wing a: Polmometer. The pyknometer was weighed m1 oun onely tice * balenee sand Instrumentes error Could have Yesulted th Precidon exvors. The metho! Substouce Was used to determine the Partial nioler volume of methanol ond water. Trp adjutrent for density of miv prowded a suiteble OM eration to bie reading of masses tootlowed for Accuraay The increas, i © Intemperate Served as q cotedyot «Pe | iM uartrect op Vor és thet Veluwe, increases with a decrease op Wwrethans!. The partlol woter Yolames Vin Stand Ving® ee fouud fo b, ' Be ae < 1823 and alco mI I mot, Feo pectlv Studied wos the bina. i heb “J Mixture of Lote, ond wethone| OE Whiee bol, ists ina single Phase . Scanned with CamScannera [Te Gxpertvendnl proceluve of pyuonetiy was done, riherrafe’ the hoults in the form of uate were used bo colenloke mule, ~~ Preettow aod densities af -eack “Solution wh lon on used in te “meted of Intencepts be aatibe the Patial wolav volumes. The. oe r cetled molar Volume of Sthauol is te rate-ab which Ux volume ofthe 7 Syste Cheeses: ob tonstont tempeotire ond: prrgiuiewith methana{ added cody Lime. The density A methanol 0-943 gimtond at a hater is 1 gl md ot 25°C therefore it wap observed that the Solutions With a Wit percentage af hethanel hed < len mats. This tegutted the overall censities of -the Solution to decroase With a decreate im Weklane| = Wrcersinge, Te tether of tntewcepts rere used to. fina tle poatial islar Volumes of Ons two Component Systm oy Lis Wore accurate. Te gimph oe BVinix [ay VS Xp 09 ptled ond Barough Ue noe of x dougent bie at 0.5 Yep Be povtled molar Volume wey Laud. M limiting Value sp observedon the jrogle ond thie Wao che 4 ages Solute molede surrounded by Solvext Wolecules. The puse molav Volunto ot tata amet bey Mx Ghent Woncus, Calle Tl in aes ReneS allied, Tespectivey - : ‘Troblems ASS0Gated with ebtadning Qcurate mass values wet av bobble in the pyknometer, solution hot Up to Gredusted mark water ‘Lope tstde #4 pybwonede~ oy droplets Xe Contamination of the Syringe by - ‘otler Soustions | Ty Anrity thuncitter Colatloted toy Joo, hetlurad) 01 [rot ecaeett A be especie! tore ; | | = i | Scanned with CamScannerConiusion + “The purpose of the ‘experihemt was toackine the particl mata, Volume ef ethers! and wot worhg ble pyknonete. This woe ® Success The di feverce fai) parbial moter Volumes being sina, Bon -Be-pare Wolor Volumts is become of the "ntenvlete, Gorey heme, okdn cud brkhenr Chyclreg ex bord ing } hs References : Jos cd Prichad, Prodral: Passi Cuealy ) 3¥d chitin Sp. 2eas At bins Phy slouf Chaarict y yivth ed, Be ap Stas Scanned with CamScanner