:duii.

11 (N) ü9 jlJJ d1i5 -6

m1(Fe2 0 3 ) = (1,8.10- 4 )(0,1)(160)
M(NH4 N03) ~ m(NH4 N03) 2
2M(N) ~ m(N)
m1(Fe2 0 3 ) = 1,44. 10- 3 g
_ 2M(N). m(NH4 N03) Q m1(Fe 2 0 3 ) = 1, 44mg @
m(N) - M(NH N03) 'J 4
:diµ) ~il.li cipllo -y
2(14)(5,6) @ JÎJ diµ) ~ln ~il.li
m(N) = 80
@ m1(Fe 2 0 3 ) < 10mg
m (N) = 1, 96g @ (j10) ~1111 J!JQi.11 .P
:(N) üqjl1.t cia liSII ciJg.ioJI dJ..wi.JI -7
-1
1 96
(§ :.li.w.ig J.! Ul1ü JUWJûlg i;:>mJI du Jci -1
P = m(N) 100 = ' 100 l L
m 6
P = 32, 6% * 34, 4 % (§ ~ .la.Ô ~JJLô ~~ ,l.JÎ! jS :l_P{UJI
v . .LlruS
_ _ J9-:lJ- Jlli r--
,·;·c..1 9 1 H+ v9J9J-J
· -
@ Olpo ~ cïiioWI ~ <i!li5JI a.iog ~

ylwlSI ~ Jll.ô ~~ lJÔ. jS :lJLllwÎJI

- II ~ .J~Jg.:ij "jlli _µS I gl H+ J9-J9J-!
:gi,lSiJl llC â.ûlwSJI ll@JI iplµ -1 ~ ~:~l.Üllg ôylœll J.cliü cibla> -2
@ [Ho- JE = [NHt]E = Omol. L- 1
'inf:(aq) + HO (aq ) = NH3(aq) + H20 (l)
Ca, Va (5,6. 10- 2 )(10) ( N H+/N H3 ) , ( H2 0/H o - ) :J!.J
· -LùwJI
[NH3] E= - - - = - - - - - 4 ..
Va + VbE 10 + 14 @ jÔDÎJI :gi,lSiJI .M dwllS.JI jgJ -3
@ [N H 3 ] E = 2, 3. 10- mol. l- 1
2
(§ :ôJ;!lcoJI J.cliü pliü ,Jgn -4
_ Ca. l'a (5,6.10- 2 ) (10) J,clA.i.JI 4.IJw .NH"tc11q) + H Oc,,qJ = N H J (aq) + H1.0cn
[N0 3 ] 8 =Va+VbE= 10+14
e [N03]E
+
= 2, 3 . 10- 2 mol. L- 1
_ cb . v bE _ (4.10- 2)(14)
4.1 W 1 .>.i..J 1 (mol) Jg..a.JL. ô.)WI ..:..l.!,a.S

~ a ]E - Va + vbE -10 + 14 :9 Î 9Jio g! 5 ! ï III c}-ljoJ I g.O lS.ïJ 11i.c

~ [Na+]E = 2, 3 . 10- 2 mol. l - 1 Ca, Va = cb. v bE
~ lJLll.!-è:4 ô».Lco.ll :dbl µSût ô µlœll -2 cb. vbE ( 4. 10-2 )(14)
' J~ èi.ygl.11ô».Lco.ll jU cibl JlSI ê4Ji>li.ll Ca= Va - 10
U .lÏ>g Jocïwoll JuùlSU ~gl.11 .J,!-éiJI ~
. éiiù,J 0~ .l.:Ü ~ Ca = 5, 6 . 10- 2 mol. l- 1 @
: CO ,_,JgoJI iéJiJI ul.u.ü - 5
:~ -l:! .lO.iJI j gjl..ë jO
C0 = F. Ca = (5)(5,6.10- 2 )
Co = 2, 8 . 10- 1 mol. L- 1 @
:ciüu.11
- . lJt ciliS
P9!-'90
o s Vb( m l)
= C0 . V.M(NH4 N03 )@
10 15 20 25
: <1 E ~gi.JI ci.Lli,WI CÏOJ.D -4 m(NH4 N0 3)

@ = ÀNo3 • [NOi ]E + ÀNa+ • [Na+]E

cre
m(NH4 N 0 3) = (2,8.10- 1 ) (0,25)(80)
@ <1E = 0, 23mS. m 2 . mol- 1 m ( NH 4 N0 3 ) = 5, 6g @
 '11111 ëÎ!! ci'i'III ë4,bl~.lJI ~JJI_P..Jl ëi.J_Jgmo?,H P,11 }D
-w L

<Ï!J..iillg.bci,~.o.pl!>I
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20 .... /20 .... :u-111IJ.lJI pwgoJI .9g..iû <Ï!-iû WJJ.J..11 :0 9ï1110H

j.Jjcil ~ ~j.CDÏgb ::llli.uùl .L.14-bl{Jg ~~ J.iü
,ü!+J_µj pglc :ëi!ci'i'III
Lw 2 :ôJ0.11 cl!,j~.}!.rul pg.lcil :ô)lo t.jl (1) ~WI J4-DUI è!loi
0, 5 =f9J!l1 Ô!éOi Il âülcoJI (j10) :JglJI JJaoi.11 ,P-
Mn04 + 8H + + se- = Mn 2+ + 4H2 O _I
: jlü.Hiill ~ -
~ .e- Li9.JiSJ! :iÏlil a..iÎJ ~JO :lJ.uJI -1
G
~
(Fe 3 +/Fe2 +), (Mn04-/Mn 2 +) ·
a..iU ê9Jl ~ ..:Û.D jn,mSglJI -2
•
:4i,lSiJI p.µ lJllÏQ 4i,lSiJI duJci -5 ~ .e- LigJiSJ! ,_111115 1
0 LÔ..ÛJISJI jg.J )!ci âfuJ 9fD :gôlSiJI :<i!J~PI ciblœ.llg Ô!ôOÎII LJllllœ.11 -3
·9JÏ.09! 5 !ï "' ~ joJI 9I Jocïwoll :ih1115ÙJ ô,6oill êihlcoJI
:gi>tsill p.:µ § 2x [Fe = Fe 2+ +-ze-]
@ VE = 25 - 16 ⇒ VE = 9ml :f 9JµJ ô!Ooi II êihlcoJI
:C &jgoJI iéJi.llg <\blSiJI .lie dfil1c - 6 § 02 + 4H+ + 4e- = 2H20
:9 Î ~ji.og ! S ! ï"' ~joJI j ~ gi,ISill .l.i.c § :ê9J 1-ô.l.WSi ô..!Jl.o.:"\UI éihlcoJ 1
~o
~
.s n 0 (Fe +) 2
= n 0 (Mn04 ) 2Fe(s)
, r+ 2
+ 02 + 4n(aq) = 2Fe(aq) + 2H2O(fJ
+
5 1
C.V -Il
- 5- = C2, VE _w>gi.J :jSJQJI ..::U_P.SJI tJ:uu cii>li>l -1
S(C2 .VE) 5(2.10- s)(9) lo.s\
"-.:,::J .j.clà.iJI üg.ll.l â.oillil
J H + ü l.inïg,1
-:r ~~ 1
11
. •

C= V = 5(10) :Jgb.oJI ~.lO'.i -

G C = 1, 8 . 10- 5
mol. L- 1 • C';\ ~l.i.)j uJilll-!g lfuüo J ~ I j ~ ~
"-:.::J 00 ~ ibL:uuJrUo .l.!ci u u,1w4
=~.l.OiJI j~Lo J.ô' g.61.SJ pp
0 - .L.11.JD éb..c
~ C0 = F. C = (10)(1,8. 10- )
5
J ~ l ..,O lJlg.w.11 â.pp jm.u.ü uü -
4 1
~ 0 = 1 , 8 . 10 - mo l . l -
C';\C • - .cii>) jiS
'• 1 <::"
:_u ·liiJ1 u';:t-A-'
' anC::.ïg

:ciiillcJI .:..Lûl -1- 7 JgboJI 00 J+SI ô..!,05 ,eumï III i U uü -

.D.0.JI j.cl.éüoJI tfl> ~.ll.11 l Jlgw j Î la.! ·a,j_hll.c.o l lJoll
- n1 (Fe +) = 0 :0µ>
2
CJPJ@I y.p.JiJlg ._,pJ@I JgSgj~I -2
Q : ~~
0 no(Fe 2 +) - 4 Xmax = 0
~ O_hllcoJI Ô!locJ â.ojllil LJlglÎJI JSS -
n 0 (Fe 2 +) = 4 Xmax v_
.lmp ljj9 ~ 9 â.ojllil J.!-lbo.11 JSS -
Co, Vo = 4Xmax
@ ~ .ô_hllcoJI ül9ffi JSS -
@ n1(Fe203) = 2 Xmax =o.PÎ ~ je . éio~
i ll 11 .:..Lit.u.JI rul.c I i 'I
- • - JlillJ -
Il"'\
~_)-;A.1..1
i 11 Ll.l.S
• - ~
C0 .V0 = 2ni(Fe 2 0 3 ) :aiog ~ 99 pu .&Jill :ôJ:!lœ.11 Jcliü tP:iLm -3
m 1 (Fe 2 0 3 ) ~ :0lwli111g â•Ooill LJllllœ.11 -4
Co, Vo = 2 M(Fe20 3)
:ô.l.WSÙJ Ô!6oill êiblcoJI
1
§ m 1 (Fe 2 0 3 ) = C0 . V0 . M ( Fe 2 0 3 ) § Fe 2 + = Fe 3 + + e-
2
2 ..:,0 1 ô.:uio
 :~ I JdiüoJI g..cD Fe 2 + 0i l.o.kg (1) â.blœll pw Jg~ ~ )~U~ -7
" . 1 .... •
. lmp,nl pJ .m(Fe2 O3)= ÏC .V
0 0 .M(Fe 0
2 3 ) :01 ~ -1
-,# •

Ci.4cJ I j.m .10mg ~ ..:, lclw 6 Jlli lm.J è go III oli be.JI éiliS Jµ, d.i.µI bgJW yJ.1.ll -y
~ J lo.ci.wliJ ébJ ln
.M(Fe) = 56g.mol- 1 ,M(O) = 16g.mol-1 :1.)l!bco
:~WI jJ..J,OlJI
ô~icil ruUlocïwll à.159 ë4,.j4_.op.JI ülclio.11 ._jJ ë..!,JgÎ ôJloS N H4 N03 p9,!io9ÎJI ü lJÏ-Ï ~
15! <Ï!.p üJlgS ~ •.'!IIIÏJ iô aJj J!.è .(êiµ J.JiiJI ô~ÎJI ~9 éiclio.11 ~ ,~l.i.cll ~ J?àio5)
~
...._ J
- .(2020 ci.i.w-:.9Jhl i.o~ Jbit.il)
. cï.iJ.c.o - . a.iJ~
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y.15 ü.µ y.lnJI N H4 N0 3 p~g.oUI ülJÏ-Ï ~ u,elio ~giio 6 ~ -1
Ammonium
- -
Nitrate :ë..!,JWI ëio glcoJ 1 ~ I cïiinU ~
34.4N
= 34,4 % ~9iioJI ~ (N) ..:,gjlJI jcici CÏ! IÏS II êi.J9ÏOJI éiµu.i.JI"
. 1000q
~
"P
.â.o9.lœll o~ cbo j.O .gluiJI u,11 s:F.JI 1~ d»~
jb.a.o.111tl.oJI 00 V = 250ml p.:µ ..,il m = 6mg lmilï5 u,elinJI ~gli.oJ I 00 cïil c ~ii
.(Sa ) Jgb.oJI ~ Jénïià ül.JO 5 o)).oj pj .(NHt + N03-) 00 (S0 ) J ~ ~ Jénïià
ojp_µ (Na++ HO-) p9pgn.JI ~9J1!-ID-! OJ.!lcj9 Sa Jgb.o.JI 00 Va= lOnil lo.:µ nli
. vbE = 14ml OJ).O p.:µ <iàl..o! ii.c g..àlS.iJI ~ Jn..i . c b = 4.10- 2 mol.l- 1 Jgo.JI

·9J91- liÛ1..i 9J.! yJ.1.ll L}U lwÎJI g lP{U-11 l.Ôje -1

. ..,....
'"Là.ï.JI ~. ~
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~g..àlS.ïJI Jµ, Cl.!-lc Jo1ïoJI Jg.JJI g.m Lo J90,!]g.og_wl ,9JjÎ J91.oJI ulwlSJI Jlocïwl pj 15! -3
Ca o-Jgo.JI jp_µJI ylw.) 00 1i iSoï u,ill èifül.c.JI ~ l g ÔJ.!lcoJI j.cl.à.iJ pw Jg~ t,JWÎ -4
.. - .o+illJÎ f{j .(Sa ) J9,boll
.è4filll p~g.oÙI clliS ~iii ml f{j (S 0 ) Jgholl C0 J9oJI jpjlJI l..;,lJ-lüÎ -5
.è4fü.J I êi.4ci1 ~ (N) ..:, gjlJ I éiliS l..;,1J-lü i -6
~è-!J-0 cïiinliJI ~ y.15 Lo Jm .Ci.4c-JI ~ (N) ..:,gjlli CÏ! IÏS II ~91.oJI èi.µu.i.JI ~ I -7
.M(NH4 N0 3 ) = 80g.mol- 1 ,M(N) = 14g.mol- 1 a-•l!bco
. I t _p..11 00 4 Jlgw.11) piëüJI Jg~ ~ J~Jj~ - Il

p l_µJI J?c Î -1
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n....-,11 ciJU.lJ. ëiJ.cni ll éi.ili>WI J.!CJ
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.g..àlS.iJI je ŒE CÏ!-C9,ÜI é4Jl>WI êio!,O ~ I -4

[À.Ho- = 20 , ÀN03" = 7,14. ÀNHt = 7,4, À.Na+ = 5,01 ]mS.1n 2 .1nol-1 :..-,l!bCO
2jn1~
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uô l:!.i.:ill 0~1 ~li.iUI j.0-20%, llioi> ... <Ï:!itÎJlg â:!9lÎJI pouü .b.à.ill jë.i Y!,;ILiÎ b!}hl
- - . jSlioJI l:! ll.11 J l:lµ.wU ~9:!
<Ï.!5,J.JOÎJ I o.uïoJI ü~U gJ 1
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Jliü.iU è4,wlio ~ Lco jlJD~ û.µ j!)111S9ÎJl9 tloJI l~9 ii.c 1}.llll Î.io .:::,~ - I
,l:!ll.11 JSÏÏ!Ï> 0!?111S9ÎJI gij 1Jll.11 jO üLigjiSJpl
.Jk ~ Îl.OJI <4Loc ~ ~JO pl .l.lllSgo l:! ll.11 jcD -1
~êl?JI pi o.l.WSÎ 0!?116gÎU ü.l.:l Lo jcD -2
loJ.c .:J lb.JI jclàill é4J~UI 0.b l.coJI _pj ·êl?J}.Ug oiw.SùJ j ! ï ! ào i Il J,!,.Ï.hl.coJI ½,1ÏS Î - 3
.(Fe 2 + / Fe) g (02 / H2 0 ) :lom jcl.à.iJI ~ 0-!-4,bl.l.ll 0!Ï!Î1ilil jÎ
~ olJlg Fe 3 + è!OÏé LigJiSJ! .l.èiiü 0 _pÎJI uID OISi'i"1ioll Fe 2+ l:!ll.11 lJlg.w - Il
- :Cl!,JWI Oh l.coJI .90 9 Fe2 0 3 Î.lC.JI l.m..i..o

4Fe(dq) + 0 2 (g) + 4H2 O(L) = 2Fe2 O3 <aq) + BH(aq) (1) ciblœ.11

Vo ruµ.) Fe 2+ 0ll u~ lmio ji:ujg <Ï..wgJ.l.OJI ëi.4,cil DLi .ül.clw (6) J9JO ~
jSJ0.11 Ll:!_µSJI t,Pro jO ü!J.bi> aJ •é! èllO ül.19 10 ol.irug 5ml a.io Dû p:} = 1001nl
(K + + MnO; ) p~üg.µl l'.Jlicioj.! J9bo ô.b.wl(}:J OJ:!lc..i pj ( 2H(aq) + sof(aq) )
.Cb = 2.10 - 5 mol.l- 1 Jgo.JI ojpji
.251nl !mïcw ~I cbb..w.JI lfl Vb = 16ml p.µ d.ë.-;1 ii.c g.OlS.iJI t,1c Jmj
: é4J wI cï.b l.coJ 4 ai? ioj ~ ë,J:! l.coJ I Je liü

SFeta~) + MnO4(aq) + BH(aq ) = SFe{dq) + Mnctq) + 4H2 Oco (2) ciblc.o.11

~ ë,J,!l.coJI Jµ:> Jg.hoJI l.W f j loJg ~jSJO.li w__µSJI LP0J ~ l.l loJ -1

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.o~l.coJI Jcliü lJ).Îlm JS.lÎ -3
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.. .jclô.iJI

. VbE g.OlS.iJI p.µ l il J)J .g.OlSïJI uljc -5

.C0 jpJill ~ l g l J.OOll Fe 2 + l:!ll.ll lJl9JÎJ jpji yuoÎ pj gi>lS.iJI cioll.c _i;)gÎ -6

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