Professional Documents
Culture Documents
TUDALEN 65
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Hazard statements
May cause cancer.
Suspected of damaging the unborn child.
Causes damage to organs through prolonged or repeated exposure.
Precautionary statements
Obtain special instructions before use.
Do not breathe dust/fume/gas/mist/vapours/spray.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
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IF exposed or concerned: Get medical advice/attention.
Store locked up.
Dispose of waste according to applicable legislation.
Special labelling of certain mixtures
Repeated exposure may cause skin dryness or cracking.
Restricted to professional users.
2.3. Other hazards
No information available.
Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article 59
(REACH)
3.2. Mixtures
Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
GHS Classification
64742-04-7 Extracts (petroleum), heavy paraffinic distillate solvent 100 %
265-103-7 649-002-00-9 01-2119488173-34
Carc. 1B, Repr. 2, STOT RE 1, Aquatic Chronic 2; H350 H361d H372 H412
Full text of H and EUH statements: see section 16.
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Never use gasoline, kerosene or other solvents for washing of contaminated skin.
Seek medical attention in all cases of serious burns.
Wash affected area with soap and water.
May cause burn in case of contact with product at high temperature.
Symptoms: dry skin, irritation in case of repeated or prolonged exposure.
After ingestion
Do not give anything by mouth to an unconscious person.
Always assume that aspiration has occurred. Seek immediate medical attention. Do not wait for symptoms to
develop.
Do not induce vomiting. Ask for medical advice.
Symptoms: few or no symptoms expected. If any, nausea and diarrhoea might occur.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation of fumes or oil mists produced at high temperatures may cause irritation of the respiratory tract.
Individuals with pre-existing lung disorders may have increased susceptibility of the effects of exposure.
When using high-pressure equipment, injection of product can occur.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
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Additional information:
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Recommended measures are based on the most likely spillage scenarios for this material.
Local conditions (wind, air temperature, wave/current direction and speed) may significantly influence the choice of
appropriate actions.
For this reason, local experts should be consulted when necessary. Local regulations may also prescribe or limit
actions to be taken.
Concentration of H2S in tank headspaces may reach hazardous values, especially in case of prolonged storage.
This situation is especially relevant for those operations which involve direct exposure to the vapours in the tank.
Spillages of limited amounts of product, especially in the open air when vapours will be usually quickly dispersed,
are dynamic situations, which will presumably limit the exposure to dangerous concentrations.
As H2S has a density greater than ambient air, a possible exception may regard the build-up of dangerous
concentrations in specific spots, like trenches, depressions or confined spaces.
In all these circumstances, however, the correct actions should be assessed on a case-by-case basis.
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Store in a well-ventilated place. Keep containers tightly closed and properly labelled.
Storage area layout, tank design, equipment and operating procedures must comply with the relevant European,
national or local legislation.
Hints on joint storage
Do not store together with: Oxidising agent, strong.
Further information on storage conditions
Empty containers may contain combustible product residues. Do not weld, solder, drill, cut or incinerate empty
containers, unless they have been properly cleaned.
Fire class: B
7.3. Specific end use(s)
Recommendation:
Ensure that proper housekeeping measures are in place.
Do not eat, drink or smoke when using this product.
Contaminated materials should not be allowed to accumulate in the workplaces and should never be kept inside the
pockets.
Keep away from food and beverages.
Wash the hands thoroughly after handling.
Change contaminated clothes at the end of working shift.
In case the substance is transported to other sites for further processing, the substance should be handled at these
sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor
and Downstream Processor/User of the Registrant’s intermediate.
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Wash hands and face before breaks and after work and take a shower if necessary. Apply skin care products after
work. When using do not eat, drink or smoke. Keep away from food and beverages. Use of personal protective
equipment must be consistent with good occupational hygiene practices.
Eye/face protection
Goggles and /or face shield, if splashes or contact with eyes is possible or anticipated.
If splashing is likely, full head and face protection (protective shield and/or safety goggles) should be used.
Hand protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four
control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific
working place concentration and quantity of hazardous substances. For special purposes, it is recommended to
check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these
gloves.
Suitable material: NBR (Nitrile rubber), CR (polychloroprene, chloroprene rubber), FKM (fluoro rubber) INDEX No.:
5-6, Category 2 (EN 388)
Heat resistant gloves with long cuffs, or gauntlets.
Gloves must be periodically inspected and changed in case of wear, perforations or contaminations.
Skin protection
Protective clothing: Not readily flammable.
Wear protective clothing for operations with hot material: heat resistant coveralls (with trousers legs over boots and
sleeves over cuffs of gloves), heat resistant heavy duty antiskid boots (e. g. leather).
Coveralls should be changed at the end of the work shift and cleaned as necessary to avoid transfer of product to
clothes or underwear.
For loading/unloading operations: wear safety helmet with integrated full face visor and neck protection.
Respiratory protection
generation/formation of aerosols:
Filtering device (full mask or mouthpiece) with filter: A2, A2/P2, ABEK
Approved respiratory protection equipment shall be used in spaces where hydrogen sulphide may accumulate: full
face mask with cartridge/filter type “B” (grey for inorganic vapours including H2S) or self-contained breathing
apparatus (SCBA).
If exposure levels cannot be determined or estimated with adequate confidence, or an oxygen deficiency is
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10.1. Reactivity
No information available.
Revision No: 2,2 GB - EN Print date: 05.06.2020
H&R ChemPharm (Thailand) LTD
Safety Data Sheet
according to Regulation (EC) No 1907/2006
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Further information
Decompostion takes place from temperatures above: > 350 °C
This substance is stable under all ordinary circumstances at ambient temperatures, and if released into the
environment.
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Aspiration hazard
Based on available data, the classification criteria are not met.
Additional information on tests
Substance related information: health hazard properties, Special hazards arising from the substance or mixture,
Classification according to Regulation (EC) No 1272/2008 [CLP]
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according to local regulations.
This substance can be burned or incinerated, subject to national/local authorizations, relevant contamination limits,
safety regulations and air quality legislation.
These codes can be given only as a suggestion, according to the original composition of the product, and its
intended (foreseeable) use(s).
The final user has the responsibility for the attribution of the most suitable code, according to the actual use(s) of the
material, contaminations or alterations.
Other national or local legislation may require additional identification or other measures for this product, may also
limit or exclude the use of generic (n.o.s.) codes.
General information:
In the absence of relevant alterations to the material or presence of contaminants, disposal of this substance as
surplus (unused) or off-spec material, or waste resulting from the foreseeable use(s), does not present a specific
hazard, or require special handling measures other than those indicated in Sect 7.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
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ENVIRONMENTALLY HAZARDOUS: no
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Restrictions on use (REACH, annex XVII):
Entry 28: Extracts (petroleum), heavy paraffinic distillate solvent
Employment restrictions: Observe restrictions to employment for juvenils according to the 'juvenile work
protection guideline' (94/33/EC). Observe employment restrictions under the
Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Additional information
none
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Changes
This data sheet contains changes from the previous version in section(s): 2,3,14,15.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our present -day
knowledge. The information is intended to give you advice about the safe handling of the product named in this
safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of processing, the
information on this safety data sheet is not necessarily valid for the new made-up material.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data
sheet.)