— goard & Competitive Exams Holoalkanes and Haloarenes S00, 7 > alede! ——> Products tn products number of gaseous product(s) is/are (1) Two (2) Three @) One (4) Four HYSICAL PROPERTIES _ z Pe boing pons of aly halides are higher than those of jdrocarbons havin Tre We tue to polarty of alkyl halides which resis in ‘Songer intermolecular acs ase sae ca Ts oup. the Boling points of alkyl halides decrease in the order Rol > R-Br> RCI > RF pehehied als erocpoe in ize and mass of halogen atom, the magnitude oF Fn der Waal forces docresses Wrong Fe ound, the Boling pint depend pen molecular mass and varies a= CCl, > CH ne ints of isomeric haloalkanes decrease with the increase in the fared cans > CH,CI. The boiling P* js gwen below. CH, i CH,CH,CH,CH,—Cl_ > CH,CH.CH—Cl > ory -E—Cl CH, CH, 351 341 324 Boiling Point (K) me. However, para isomers having more have higher es are nearly the sat get packed more compactly and hence Boling points of isomeric dihalobenzen gymmetrcal structure than ortho and meta isomers, rmetting points. MP. (K) ue 5 olychloroalkanes are higher while those of fluoro and chloroalkanes are lover Densities of bromo, iodo and p than the density of water as given below CH,| > CH,Br > H,0 > CHF and CCl, > insoluble in water as they are no CHCI, > CHCl, > H,0 7 CHF Haloalkanes are practically 3 able to form H-bonds. | CHEMICAL PROPERTIES ‘ tive charge oF The CX bond of haloalkanes is polar with partial positive charge con carbon and pari ae causing halogen. Any nucleophile stronger than halide ion can attack at the C-atom due to Pes naloakanes underg? nucleophilic substitution. Halide ions being weak bases ‘and are good leaving OVP. arming ae! oat elimination reaction with a strong base. Reactive metals cause cx compounds, ; Reactions of Haloalkanes i | Nucleophit ; Philic Substitution Reactions I nucleanhitie ever: pairol with 3 1m : tone atom rectors anotinne the Incoming nucieophie heving teen ip on