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3rd IASME/WSEAS Int. Conf. on Energy & Environment, University of Cambridge, UK, February 23-25, 2008

A Concise Review of Exergy-Based Economic Methods


MARC A. ROSEN
Faculty of Engineering and Applied Science
University of Ontario Institute of Technology
2000 Simcoe Street North, Oshawa, Ontario, L1H 7K4
CANADA

Abstract: In the analysis and design of energy systems, techniques are often used which combine scientific
disciplines (mainly thermodynamics) with economic disciplines (mainly cost accounting) to achieve optimum
designs. For energy conversion devices, cost accounting conventionally considers unit costs based on energy. Costs
are better distributed among outputs if cost accounting is based on the thermodynamic quantity exergy, partly
because exergy, but not energy, is often a consistent measure of economic value. In this article, we critically review
relations between exergy and economics, and exergy-based economic methods (exergoeconomics,
thermoeconomics, exergy-based pricing, EXCEM analysis, analysis based on the ratio of thermodynamic loss to
capital cost). Most such methods aim to determine appropriate allocations of economic resources for optimal
design and operation, and/or economic feasibility and profitability.

Key-Words: energy, exergy, economics, thermoeconomics, exergoeconomics, costing, prices, environment.

1 Introduction The exergy of an energy or material quantity


Although the merit of a system or process is usually measures its usefulness or quality. Although energy
based on such varied factors as technical performance, cannot be destroyed, exergy can. Energy efficiencies
efficiency, resource availability, environmental impact, do not always assess how nearly performance
health, safety and societal acceptance, economics is a approaches ideality and do not properly describe
central consideration. Analysis, design and factors that cause performance to deviate from ideality.
optimization often utilize techniques that combine Exergy analysis (e.g., [2-6]) overcomes many of the
technical disciplines like thermodynamics with shortcomings of energy analysis, yielding efficiencies
economics. Cost accounting applied to energy systems which provide a true measure of approach to ideality,
normally considers unit costs based on energy. and identifying properly the causes, locations and
Many authors suggest the second law of magnitudes of inefficiencies. Exergy indicates
thermodynamics, which embodies entropy concepts, theoretical and practical limitations imposed on a
has significant implications for economics. A system, which show that a real system can not
thermodynamic theory of economics sought, for conserve exergy as only a portion of input exergy can
instance, considering the first and second laws [1]. be recovered. Through its illuminating, rational and
Relations between utility and the law of diminishing meaningful approach, exergy analysis can help
marginal utility and a thermodynamic model of a improve and optimize designs. Applications of exergy
money system and thermodynamic-based measures for have been reported for power generation, cogeneration,
economic value were developed. geothermal plants, thermal, chemical, and
Some researchers note that the thermodynamic metallurgical processes, transportation and countries
quantity exergy, which stems from the second law, is (e.g., Canada, United States, United Kingdom,
often a consistent measure of economic value, while Sweden, Italy, Turkey, Saudi Arabia, Japan) [2-6].
energy is not. Many recommend that cost accounting Several exergy-based economic analysis methods
and pricing are better based on exergy than energy. For have been developed. Their goal is usually to
instance, costs based on exergy are more rationally determine economic feasibility and profitability, or
distributed among outputs, since exergy-based unit appropriate allocations for economic resources for
costs are more meaningful than energy-based ones. achieving optimal or improved designs. Here, we
critically review relations between exergy and

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economics and many analysis methods which integrate commodity flow as a quasi-thermodynamic irreversible
exergy and economics. This article is an abbreviated process [16]. In that work, which supposes
version of a much longer chapter [7]. thermodynamics can explain commodity diffusion, a
coupling relation between commodity price and quality
is derived.
2 Exergy and Economics A cost balance can be written for a system as
Exergy is a useful concept in economics [8,9] and
crucial to cost accounting and economic analyses [10]. cost input + cost generation − cost output
Costs should reflect value, and since value is not = cost accumulation
generally associated with energy but with exergy,
assignments of cost to energy lead to Cost input and output represent respectively the cost
misappropriations, which are common and often associated with all inputs and outputs. Cost
significant [10]. It has been further pointed out that accumulation represents build-up of cost, while cost
exergy possesses an intrinsic and direct correlation generation corresponds to the capital and other costs
with economic values [11]. On the one hand, therefore, associated with the creation and maintenance of the
exergy allows rational evaluation of efficiencies and system. The cost generation term emphasizes that cost
inefficiencies (including internal exergy consumptions is a non-conserved quantity.
due to irreversibilities and waste exergy emissions), as Although cost and thermodynamic balances appear
well as the value of fuels and resources. On the other similar, they exhibit several significant differences:
hand, exergy facilitates the determination of the costs • Energy is conserved but economic cost is not.
associated with thermodynamic losses and the values • Both cost and exergy are not conserved, with cost
and costs of the outputs and accumulated quantities for generated due to the cost of devices and exergy
processes and devices. Consequently, using exergy as a consumed due to irreversibilities associated with
basis for cost accounting can help determine the real their operation.
costs of producing commodities and in pricing such • In energy and exergy balances, the values
products. Also, exergy can help evaluate economic associated with all quantities are defined by
viability and profitability. thermodynamics. Only cost input and generation are
Exergy can interface broadly with economics. In defined for the cost balance, however, as the
microeconomics, exergy can be combined with cost- distribution of costs over outputs and accumulations
benefit analyses to improve designs. In is subjective. If costs are not allocated
macroeconomics, exergy provides a basis for appropriately, it is difficult to gauge the cost-
increasing efficiency, reducing resource utilization and effectiveness of a device and to set prices for
losses, and reducing environmental damage. These salable commodities, especially when there are
objectives can be accomplished with, for example, multiple products.
exergy-based incentives or exergy taxes. Exergy more Exergy is also useful in understanding and
broadly can help in optimizing designs and making assessing environmental impact, non-renewable
operating decisions. Exergy-based concepts and resource depletion, ecology and sustainable
methods for analyzing and optimizing energy systems development [2-6]. The ties between exergy and
including life cycle exergy analysis have been economics can be extended to environmental and
described [10], as has the relation between exergy ecological aspects in several ways:
destructions and investment costs in thermal systems • The potential of exergy to be an indicator of
[12]. environmental impact can be incorporated in
Thermodynamics, including exergy and entropy, exergy-based economic assessments.
has been linked to economic systems [13]. Related • The costs associated with environmental impact and
work involved modelling the economic order quantity protection can be included in the economic portion
based on the second law [14], and using entropy cost to of an exergy-based economic assessment.
evaluate the economic order quantity for repair and Extending exergy and economics to account for
waste disposal [15]. Diffusion-like economic environmental effects permit one to minimize life
commodity flows were considered from a cycle costs and thereby find the most appropriate
thermodynamic perspective, by modelling a device or process. This can be accomplished while

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reducing environmental effects, for prevailing approach is proposed which was tested using US data
economic conditions. over 25 years. The effect of energy and exergy values
on fuel pricing has been examined, including how
3 Exergy-based Economic Methods energy and exergy values and their differences affect
Methods integrating exergy and economics have been energy commodity prices [10].
developed over the last several decades. Georgescu- The characteristics of different fuels and energy
Roegen [17] is often cited as a pioneer in the field of forms vary. Energy and exergy prices are equal for
the thermodynamics of economics. Details on exergy- electricity and for work, and are approximately equal
based economic methods are reported in books (e.g., for hydrocarbons. Energy and exergy costs for heat and
[2,4]) and reviews and comparisons (e.g., [2,18,19]). for cold usually differ, with the exergy cost
Most exergy-based economic methods have several significantly dependent on temperature, which
commonalities: they combine exergy and economics to determines the quality of thermal energy.
help achieve thermodynamic and economic objectives, The energy-conversion technology used can
and they recognize that exergy, not energy, is the significantly affect price. For example, heat and
commodity of value in a system and consequently electricity can be produced independently, or
assign costs and/or prices to exergy-related variables. simultaneously via cogeneration. Determining the
These methods assess economic feasibility and portion of the cost that should be allocated to each
profitability, in part by determining actual costs of product is important to the commercial success of
products and appropriate prices; and/or determine cogeneration, yet there is no widely accepted
appropriate allocations of economic resources to allocation method. If costs are not allocated
facilitate design and operation optimization. appropriately, one product may be overpriced (and
Four main categories of exergy-based economic thus unlikely to be purchased) and one under-priced
methodologies have been identified, depending on (and thus unable to recover costs even if in great
which of the following forms the basis [18]: 1) exergy- demand).
economic cost accounting, 2) exergy-economic
calculus analysis, 3) exergy-economic similarity 3.2 EXCEM analysis
number, and 4) product/cost efficiency diagrams. EXCEM (exergy, cost, energy and mass) analysis
Available energy costing methods were developed focuses on the four key parameters represented by its
[20], while thermoeconomics has been investigated name [24], and can help assess and improve systems
often [21]. Optimization is a particularly important and processes. EXCEM analysis is intended as a
application of exergy-based economic techniques [22]. unified aid for thermodynamic, economic and
environmental decisions and design.
3.1 Exergy-based pricing and cost allocation EXCEM analysis presumes an understanding of
The selection of energy sources for residential, system or process performance requires examination of
commercial, transportation, industrial and other uses is all flows of exergy, cost, energy and mass through a
primarily based on prices, so it is important to system. Balances can be written for each EXCEM
determine prices appropriately. Incorrect pricing can quantity. Mass and energy are conserved. Exergy and
lead to problems, e.g., businesses can be uncompetitive cost are not conserved, as exergy can not increase
when prices are too high, and unable to cover costs while cost can not decrease. The exergy-related aspects
they are too low. of EXCEM are often the most informative.
Exergy-based prices can foster resource savings and EXCEM analyses of processes have demonstrated
efficient technology. Prices for a commodity based on that the method provides valuable insights into
exergy usually parallel its physical value, while prices efficiency, economics and environmental impact.
based on energy do not. Prices of physical resources EXCEM analyses can yield results not obtainable
can thus be more rationally set based on exergy. The conventionally, and can sometimes find results
use of exergy in economic valuations and the obtainable with conventional analyses more directly.
correlation of exergy with money have been
considered [23]. Exergy-based production expenses are 3.3 Loss-cost ratio analysis
shown to lead to natural price determination, and a Loss-cost ratio analysis focuses on the ratio of
corresponding general macroeconomic dynamics thermodynamic loss rate to capital cost. The insights
provided with this exergy-based economic method can

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assist in analysis and design [25,26]. Loss-cost ratio good. Costs must be properly formed to understand
analysis identifies correlations between capital costs and evaluate exergy costs and resource degradation, as
and specific second-law-based thermodynamic losses well as cost and irreversibility relations. Numerous
(i.e., total and internal exergy losses). applications are described of exergy cost accounting
The approach has been applied to mature devices, and thermoeconomics, explaining thermoeconomic
with the relations between energy losses and capital costs, thermoeconomic analyses of complex systems
costs generally observed as not useful. Correlations are and operation diagnosis and optimization [34,35].
observed between capital costs and exergy-based Uncertainty has been included in thermoeconomics
thermodynamic losses for systems and their [36]. Such fuzzy thermoeconomic analysis considers
components, suggesting that designers incorporate fuzzy nonlinear programming where local criteria like
exergy-based economic recommendations into designs, maximum efficiency and minimum total cost rate as
overtly or unknowingly [9,19,25,26]. The ratio of loss well as constraints in an ill-structured situation can be
rate to cost based on total and internal exergy loss rates represented by fuzzy sets. Structural theory in
are normally the most useful. A correlation also is thermoeconomics has been examined [37], as has
observed between the mean thermodynamic-loss-rate- malfunction and dysfunction analysis using structural
to-capital-cost ratio for all system devices and the ratio theory within thermoeconomics [38].
for the overall system, when the ratio is based on total
or internal exergy losses, but not when it is based on 3.5 Exergy and environmental economics
energy losses. Designing efficient and cost-effective systems, which
meet environmental requirements, is can be
3.4 Thermoeconomics and exergoeconomics challenging. Mass and energy conservation indicate
Exergoeconomics and thermoeconomics are exergy- that raw material inputs to economic processes are not
based economic methods that have evolved over consumed, but instead ultimately return to the
several decades [11,27,28]. Exergy and environment as wastes. If the Earth is treated as a
microeconomics forms the basis of thermoeconomics, closed system, the concepts of exergy and entropy
also called exergoeconomics and exergonomics [27]. yield different economic implications, suggesting that
Utility is a central concept in macroeconomics and is constraints are imposed on economic growth because
closely related to exergy. An exergy tax is an example economic processes utilize high-exergy (or low-
of how exergy can be introduced into entropy) raw materials such as fuels and high-grade
macroeconomics. minerals, and discard low-exergy (or high-entropy)
With thermoeconomics, exergy efficiencies are wastes. Since the Earth is an open system that receives
determined, while non-energy expenditures such as large quantities of high-exergy (or low-entropy) solar
financial and labour costs are related to the technical radiation, energy resources may be adequate to sustain
parameters of the device under consideration. In economic activity over time, although non-renewable
thermoeconomic optimization [29,30], the optimal natural resources like metal ores and fossil fuels may
design point and operating conditions are determined eventually be exhausted.
by minimising the total economic cost under financial, Several researchers have investigated exergy and
technical, environmental and other constraints. A environmental economics [39]. Economics and the
systematic and general method for evaluating costs in second law have been linked via eco-thermodynamics,
thermal systems is described [31]. which assumes the economic significance of the
Multi-objective energy and economic optimization second law is that exergy is not conserved and is a
algorithms exist for thermal designs [32]. It is observed useful measure of resource quality and quantity [40].
that considering only economic minima may not Exergy is treated as a factor of production like labor
provide sound decisions, and that more efficient and capital, with strong implications on economic
solutions may yield preferred designs due to changes growth theory, especially in assessing the role of
in energy market prices or energy policies, despite technical progress.
small increases in total costs. Exergy accounting and thermoeconomics have been
Exergy accounting utilizes exergy costs and is extended with environmental factors [11]. The
useful for diagnosing energy systems and accounting approach allows direct quantitative comparisons of
for natural exergy resources [33]. The method factors like labour, environmental impact and
measures the amount of exergy resources to produce a externalities. The approach is seen to be a natural

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development of the economic theory of commodity described [47]. The ecological function is represented
production, which it extends by accounting for the by the ratio of power output to entropy generation rate,
unavoidable exergy consumption in the production and the economic function by the ratio of power output
chain. Extended Exergy Accounting exploits the to total cost. Some authors extend exergy-based
correlation between exergy and economics to develop economic methods encompassing environmental
a theory of value based on exergy or monetary metrics. factors to sustainability. For instance, thermodynamics
The premise is that, while exergy and monetary costs and economics are integrated to obtain exergy-based
both represent the resources to be consumed for a indicators of sustainable development [48]. Exergy and
given output, their structures differ and yield different entropy are applied to the steady-state economy to
optimal designs. Extended Exergy Accounting has also develop a model for sustainable development at the
been proposed as a cost analysis method using a macro-economic level [49]. The approach combines
resource-based quantifier (extended exergy rather than resource depletion with pollution and focuses
money) [41,42]. This quantifier links labour and environmental protection on reducing degradation.
financial costs to an equivalent resource consumption, Industries are thus able to seek alternatives for
expressing the total exergy consumption required to environmentally sound processes and products. The
produce one person-hour of work or one monetary unit method permits companies to set environmental goals
of currency circulation. Environmental remediation and programs.
costs are accounted for by determining the equivalent
cumulative exergy expenditure for zero impact.
Extended Exergy Accounting thus evaluates the 4 Applications
resource-based value of a commodity (not necessarily
monetary cost), enabling more comprehensive and 4.1 Thermal processes
meaningful energy planning. The method complements EXCEM analysis has been applied to many thermal
such tools as life-cycle assessment, environmental systems and processes [24,34].
footprint analysis, cumulative exergy analysis and Several exergy-based economic assessments of
emergy analysis, incorporating some of their elements. heating systems have been reported, such as
A comprehensive method is proposed based on optimizations of hot water piping systems using
energy, exergy, economic and environmental factors thermoeconomics and considering simultaneous
[43]. Environmental emissions are considered and optimization of pipe diameter and insulation thickness
performance indicators developed, providing useful based on maximization of exergy efficiency and cost
information about performance and possible minimization [50]. Exergoeconomic analyses have
improvements. Energy-system designs can be been reported of ground-source heat pump systems for
optimized using separate objectives relating to energy, buildings [51] and geothermal district heating [52]. A
economics and the environment [44]. This multi- greenhouse heating system using a solar-assisted
criterion optimization is argued to be advantageous to ground-source heat pump was assessed using EXCEM
single-objective thermoeconomic optimization and and loss-cost ratio analyses [53]. The latter
two-objective energy and economic optimization. An demonstrated devices in successful air conditioning are
environmental impact objective function is expressed configured to achieve an overall optimal design by
in cost terms by weighting carbon dioxide and nitrogen appropriately balancing exergy and economic
oxide emissions according to their unit damage costs. behaviour of the overall system and its devices.
A thermoeconomic method to increase exergy- Exergy-based economic analyses have been
resource utilization efficiency based on a carbon undertaken for cooling, refrigeration and air
exergy tax is proposed to promote efficient exergy use conditioning. An exergoeconomic optimisation was
[45]. The author feels that the method, which evaluates reported of aqua-ammonia absorption refrigeration for
the cost of exergy destroyed and rejected in a system, air conditioning, by minimizing the overall operation
and which is connected with the CO2 emissions, and amortization cost and utilizing exergetic costs
improves system economic suitability by permitting [54]. A small capital cost increase (2%) yielded a
better use of exergy. Exergoeconomics provides a significant product cost reduction (15%). An
thermodynamic foundation for rational resource use exergoeconomic analysis of cold thermal storage using
[46]. A method for performance evaluation under a glycol working fluid was performed [53].
maximum ecological and economic conditions is

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Exergoeconomic optimization was used to investigate economic and environmental factors [43], and a
the effect of matrix thermal conductivity on an air- thermoeconomic analysis was reported of a residential
conditioning rotary regenerator [56]. The optimum photovoltaic-hydrogen system [65].
rotary regenerator geometry was determined using the Several exergy-based economic investigations have
unit exergy cost of the warm air delivered as the been carried out of processes for multiple products,
objective. The operating cost was determined using including cogeneration, including an exergy cost
different unit costs for the pressure and thermal minimisation of gas turbine-based cogeneration [66]
components of exergy. The geometry of a precooling and a thermoeconomic analysis of institutional
air reheater for air conditioning was also cogeneration using a gas turbine and waste boiler [67].
thermoeconomically optimized, with the total cost The most advantageous systems were found based on
given by the precooler capital cost and the operating pay-back period and maximum savings in ten years.
cost attributable to precooler irreversibility [57]. An Several combined-cycle cogeneration configurations
exergoeconomic optimisation of the geometry of were thermoeconomically compared using specific-
continuous fins on an array of tubes of a refrigeration exergy costing [68]. Cost balances of the subsystems
air-cooled condenser was performed [58]. The exergy and unit exergy costs were found. Combined-cycle
destruction was investigated by varying condenser tube cogeneration with condensing extraction steam
diameter. An optimum heat exchanger area was found turbines was found to be thermoeconomically
by optimally balancing exergy destruction advantageous to those with back-pressure steam
components, and the total cost was based on annual turbines. Methods extending exergy accounting and
capital cost and compensation cost for irreversibilities. thermoeconomics with environmental factors were
applied to cogeneration based on a gas turbine,
4.2 Power generation and cogeneration yielding an optimal design [11,41]. For gas turbine-
Numerous exergy-based economic investigations based power generation and desalination,
have been undertaken of power generation, including thermoeconomic analyses were carried out [69], and
exergoeconomic analyses of nuclear, oil and coal exergy costs determined [70].
plants [19.59]. Thermoeconomics was applied to a
power plant using structural theory with malfunction 4.3 Chemical processes
and dysfunction analysis [60,61]. A Brayton cycle was Chemical processes vary widely [4]. Desalination was
investigated considering ecological and economic examined with thermoeconomics [69,70] and a method
conditions [47], defining the economic function as the based on exergetic, economic and environmental
ratio of power output to total cost and the ecological parameters was applied to bioethanol production [43].
function as the ratio of power output to entropy High-purity product generation from air separators was
generation rate. The cycle was maximized for thermoeconomically analyzed [71]. A thermoeconomic
economic and ecological objectives while minimizing investigation was carried out of multi-effect
entropy generation rate. An exergoeconomic evaporation and multi-stage flash [72], showing that
optimisation of a Kalina power cycle, as a bottoming operating cost decreases with increasing module
application for cogeneration, was carried out [63]. The number, and the combined system is more economic
objective was the exergoeconomic unit cost of than stand-alone systems.
electricity produced by both cogeneration and the
absorption cycle. An exergoeconomic analysis of a
PEM fuel cell was undertaken for various operating 5 Conclusions
conditions [64]. The effects of varying parameters on Useful relations exist between exergy and economics,
the fuel-cell exergy cost were determined; a significant different from those between energy and economics,
reduction in exergy cost was possible with lower fuel which provide the basis for exergy-based economic
cell capital costs, annual operation and maintenance methods. Such methods are useful in analysis and
costs and hydrogen costs. A power plant combining a improvement activities. The methods generally
solid oxide fuel cell and gas turbine was assessed using combine thermodynamics with economics to achieve
a thermoeconomic method based on a carbon exergy advantageous designs, acknowledging that costs are
tax aimed at increasing the efficient use of exergy better distributed among outputs if costs are based on
resources [45]. Hydroelectric and thermoelectric power exergy rather than energy, and that a consistent
generation were analyzed based on exergetic,

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measure of economic value is provided by exergy but Conversion and Management, 43, 2002, 1259-
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the Natural Sciences and Engineering Research [15] Jaber, M. Y., and Rosen, M. A. The economic
Council of Canada is gratefully acknowledged. order quantity repair and waste disposal model
with entropy cost. European Journal of
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