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Groundwater

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Edwin Brands R. Rajagopal


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G RO U N DWAT E R

Research and GIS.” In Qualitative GIS: A Mixed important role in the hydrologic cycle, in plant
Methods Approach, edited by Meghan Cope and growth and soil formation, and in providing
Sarah Elwood, 113–135. Thousand Oaks, CA: water for human activities. Since groundwater is

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SAGE. difficult to observe and track directly, monitor-
Knigge, LaDona, and Meghan Cope. 2006. ing, mapping, and modeling efforts are crucial to
“Grounded Visualization: Integrating the Analysis
the understanding of its storage, distribution, and
of Qualitative and Quantitative Data through
patterns in flow through the subsurface, how it
Grounded Theory and Visualization.” Environment
and Planning A, 38(11): 2021–2037. DOI:10.
may be sustainably used, and how it may become
1068/a37327. contaminated. Humans have used groundwater

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Pavlovskaya, Marianna. 2002. “Mapping Urban throughout history, but the demand for it and
Change and Changing GIS: Other Views the societal ability to consume and contaminate
of Economic Restructuring.” Gender, Place it have all increased exponentially over the past
and Culture, 9(3): 281–289. DOI:10.1080/ century. Uneven distribution of human popu-
0966369022000003897. lations combined with variations in availability
Strauss, Anselm, and Juliet Corbin. 1998. Basics of and accessibility to groundwater have resulted
Qualitative Research: Techniques and Procedures for in overexploitation of several major aquifers

Oaks, CA: SAGE.


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Developing Grounded Theory, 2nd edn. Thousand serving population and agricultural produc-
tion centers in China, India, and the United
States. Significant current and future threats to
groundwater quantity and quality that require
attention from policy and planning perspectives
 Groundwater include climate change, fossil fuel exploration 
and extraction, natural contaminants such as
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radium and arsenic, underground storage tanks


Edwin Brands
and industrial contaminants, and agricultural use
University of Minnesota, Morris, USA
and pollution.
Raj Rajagopal
University of Iowa, USA
Groundwater: natural and physical
Usha Eleswarapu science perspectives
Rutgers University, USA
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Peter Li Groundwater’s place in the water cycle


Tennessee Technological University, USA
More than 68% of fresh water is found in
Groundwater is water that exists mainly in polar ice caps and glaciers and is thus largely
subsurface pore spaces but also in defined chan- unavailable for societal use (Shiklomanov 1993).
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nels, such as those found in karst formations, Approximately 30% of global fresh water is
which are created by dissolution of soluble groundwater, whereas only 1.2% is found in
rocks such as limestone. After the polar ice streams and lakes. Geologic formations that
caps, groundwater is the next largest reservoir yield a significant amount of water to wells or
of freshwater on Earth, containing more than springs are called aquifers. An aquifer consists of
100 times the volume of streams and freshwater two or more permeable layers in the subsurface
lakes (Shiklomanov 1993). Groundwater plays an separated at least locally by intervening layers

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that impede groundwater movement but do not rocks, while another 18% of the subsurface is
significantly affect the regional hydraulic con- dominated by aquifers of more complex and
nectivity of the system. With the exception of heterogeneous geology (Richts, Struckmeier,

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fossil aquifers, groundwater is replenished mainly and Zaepke 2011, WHYMAP, Table 1). The
by precipitation falling within the recharge area remaining approximately 47% of the land surface
of an aquifer. Precipitation on land flows hor- is underlain by local and shallow aquifers along
izontally across the surface or infiltrates into stream valleys and lowlands. There are significant
soil and moves either horizontally or vertically regional variations in the distribution of aquifers.
within the subsurface. Groundwater consists For example, shallow local aquifers dominate

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both of water that remains in the unsaturated or much of North America, whereas major regional
vadose zone (also often termed “soil water”) and aquifers spanning thousands of square kilometers
of water that reaches the saturated zone (aquifer) are the predominant aquifer type throughout
where pore spaces are completely filled. much of continental Europe (Table 1).
Currently, approximately 24% of global
aquifers are highly overexploited; the major
Global distribution of groundwater
Groundwater may be found almost anywhere
on Earth if one digs deep enough, but most
accessible groundwater is generally found within
PR driving factor is irrigated agriculture for feed-
ing human and livestock populations (Gleeson
et al. 2012). Pumping from the most exploited
aquifers (Upper Ganges, North and South
1 km of Earth’s surface (Hess 2014). Beyond Arabian, Persian, Western Mexico, and High
 this depth, groundwater availability decreases Plains or Ogallala) is on the order of tens of 
gradually and quality is often poor due to high times the natural recharge rate, and may also
salinity and mineral concentrations. World- act as a limiting factor in future agricultural
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wide, approximately 36% of the land surface output (Figure 1). Although 76% of aquifers
(excluding Antarctica) is underlain by major are not being significantly exploited, overex-
aquifers, primarily composed of sedimentary ploitation of a few large aquifers has led to a

Table 1 Groundwater basins and aquifers by continent.


Major groundwater Complex hydrogeological Local and shallow
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basins structures aquifers


Continent (million km2 ) (%) (million km2 ) (%) (million km2 ) (%)
Africa 13.5 44.9 3.3 11.0 13.2 44.1
Asia 14.5 32.0 7.8 17.3 23.0 50.7
Australia, New Zealand 2.6 32.5 2.9 36.3 2.5 31.1
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Europe 5.2 53.0 1.8 18.8 2.7 28.2


Central/South America 8.4 45.0 2.0 10.9 8.2 44.1
North America 3.2 15.0 5.8 26.9 12.4 58.1
World (excl. Antarctica) 47.3 35.6 23.6 17.8 62.0 46.6
Source: Richts, Struckmeier, and Zaepke 2011. Date of the source data is 2008. With permission from WHYMAP, BGR,
Stilleweg 2, 30655 Hannover, Germany.

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G RO U N DWAT E R

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600

Aquifers
400

200

0–
0. .5
1– 1
5–
10 0
> 2 20
5–
0

5
1

0
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GF/AA

GF/AA
Groundwater

>20
10–20
stress

5–10
1–5
<1

Aquifer
area (AA)
Groundwater
footprint (GF)
Western
Mexico
High plains
PR
North
Arabian
Persian Upper Ganges
North
China
plain

Figure 1 Groundwater footprints of aquifers. Source: Gleeson et al. 2012. Reproduced by permission of
 Nature. 
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total groundwater footprint of more than 3.4 influence on the composite average of the global
times the global area of aquifers (Gleeson et al. groundwater footprint. In contrast, the median
2012, Table 2). If 1 and 2% of the largest pristine of the global groundwater footprint of 0.11
or unexploited aquifers (7 and 15 observations is robust and is not significantly impacted by
from 748 considered in Table 2) are removed the extreme outlying values of aquifer areas or
from consideration, the composite average of groundwater footprints.
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the groundwater footprint rises to 4.81 and 6.34 Exploitation of aquifers also varies significantly
(39 and 84% increase, respectively) indicating within aquifers. For example, the average water
that a few outlying pristine aquifers have undue level in the High Plains (or Ogallala) aquifer of
influence on the composite average of the global the central United States has declined by more
groundwater footprint. Similarly, if 1 and 2% of than 4 m since before World War II. However,
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the aquifers representing the largest footprints this includes some areas where water levels have
(7 and 15 observations from 748 considered in increased by up to 20 m and others that have
Table 2) are removed from consideration, the decreased more than 70 m (McGuire 2013).
composite average of the groundwater footprint Total water storage in the High Plains aquifer
falls to 1.52 and 0.93 (56 and 73% decrease, has decreased by approximately 8%, but storage
respectively) indicating that a few outlying in 5% of the aquifer area decreased by over 50%
aquifers with large footprints also have undue (McGuire 2013).

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Table 2 Properties of aquifers with the largest groundwater footprints.


Aquifer Country GF (106 km2 ) AA (106 km2 ) GF/AA
Upper Ganges India, Pakistan 26.1 ± 7.5 0.48 54.2 ± 15.6

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North Arabian Saudi Arabia 17.3 ± 4.7 0.36 48.3 ± 13.5
South Arabian Saudi Arabia 9.5 ± 3.6 0.25 38.5 ± 14.7
Persian Iran 8.4 ± 3.7 0.42 19.7 ± 8.6
South Caspian Iran 5.9 ± 2.0 0.06 98.3 ± 32.6
Western Mexico Mexico 5.5 ± 2.0 0.21 26.6 ± 9.4

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High Plains USA 4.5 ± 1.2 0.5 9.0 ± 2.4
Lower Indus India, Pakistan 4.2 ± 1.5 0.23 18.4 ± 6.5
Nile Delta Egypt 3.1 ± 0.8 0.1 31.7 ± 7.9
Danube basin Hungary, Austria, Romania 2.4 ± 0.8 0.32 7.4 ± 2.6
Central Mexico Mexico 1.8 ± 0.5 0.2 9.1 ± 2.6
North China plain China 1.8 ± 0.6 0.23 7.9 ± 2.8
Northern China
North Africa
Central Valley
China
PR
Algeria, Tunisia, Libya
USA
1.4 ± 0.6
0.9 ± 0.3
0.4 ± 0.2
0.31
0.36
0.07
4.5 ± 1.8
2.6 ± 0.9
6.4 ± 2.4
Other aquifers 38.6 ± 0.8 34.17 1.1 ± 0.3
All aquifers 131.8 ± 24.9 38.27 3.45 ± 1.06
 
GF = groundwater footprint;
AA = aquifer area.
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Source: Gleeson et al. 2012. Reproduced with permission from Nature.

Types of aquifers have not been cemented together, and where


water fills up spaces between the particles. In
The unsaturated zone of an aquifer is immedi- contrast, water-bearing formations that have
ately below the land surface where the soil/rock been cemented together are termed consoli-
pores contain both water and air, but are not
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dated aquifers. Relatively large pore spaces in


totally saturated with water. It differs from unconsolidated aquifers and solution channels in
the zone below which is saturated with water. carbonate aquifers can hold significant amounts
The top of the saturated zone is referred to as of groundwater with high hydraulic conductiv-
the water table (USGS 2014a). Aquifers may ity. In contrast, only the presence of fractures and
be classified by whether they are confined or joints in igneous and metamorphic rocks allow
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unconfined and by their geologic composition. water to enter and move through the formations.
Confined aquifers exist between two impermeable Sand and gravel aquifers are generally uncon-
layers, often comprised of clay or clay-derived fined, and can be several hundred feet thick.
rock. Unconfined aquifers lack a confining layer They are comprised of alluvial or glacial deposits
above the water table, and are thus vulnerable to and found in valleys, depressions, and lowlands.
pollution from the surface. Unconsolidated aquifers Alluvial aquifers were formed over hundreds to
consist of sand, gravel, and other materials that thousands of years by water deposition of sand,

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G RO U N DWAT E R

silt, and clay particles. These alluvial deposits Land


surface
can contain large groundwater reserves that are
fairly accessible and easy to withdraw. Sand and

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gravel aquifers of glacial origin may also have
large reserves of groundwater that are fairly easy Well
Potentiometric
to withdraw, but hydraulic conductivity in such surface Water level Cone of
in well depression
aquifers may be quite variable due to lack of (water table)

sorting in glacial till. Aquifer


Carbonate rock aquifers are comprised primarily

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of limestone or dolostone formed in ancient
marine environments. Weak carbonic acid Figure 2 A schematic representation of aquifers,
wells, and drawdown. Drawing by Edwin Brands.
in rainwater dissolves carbonate rock and over
thousands of years has in many areas formed karst
landscapes characterized by numerous solution cases, a well or a spring located at a point where
cavities, caverns, and sinkholes through which the potentiometric surface (or water table) is higher
water can move rapidly. Where carbonate layers
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are exposed to the surface, runoff from precipita-
tion or entire streams may connect directly with
groundwater, resulting in significant contamina-
than the land surface will flow freely without
the need for pumping; such wells or springs are
termed artesian.
Wells drilled into unconfined aquifers or con-
tion potential. Sandstone aquifers and igneous fined aquifers with insufficient pressure to flow
 and metamorphic rock aquifers typically store naturally require pumping to bring water to the 
and transmit water only along bedding planes, surface. Some level of drawdown (or reduction in
joints, and other cracks and fractures. Hydraulic the height of the potentiometric surface) occurs
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conductivity in such aquifers is low, but large with pumping of water from aquifers. During
regional aquifers can yield high total volumes of pumping, a cone of depression (Figure 2) forms
groundwater. around wells – the shape, size, and depth of the
cone of depression as well as the rate at which
the well water level recovers depend upon the
Groundwater flow and wells
pumping rate and duration, aquifer character-
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The geology of the aquifer influences water istics such as hydraulic conductivity, and the
storage capacity as well as hydraulic conductivity, or presence or absence of nearby wells. Pumping
the ability of aquifer materials to transmit water. tests are done to determine whether the aquifer
Factors affecting hydraulic conductivity and stor- will provide an adequate yield (measured in
age capacity include porosity (proportion of pore gallons or liters per minute) for the intended
space) and permeability (connectedness) of the purpose of the well.
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pore spaces. Groundwater flow is down-gradient


from high to low pressure, which often corre-
sponds with moving from high to low elevation.
Soil formation
An exception to this occurs in the case of As it moves through soil, water dissolves
confined aquifers contained within tilted rock chemicals and sometimes deposits them at lower
formations where considerable pressure builds levels. This leaching process can deplete the
up in the lower reaches of the aquifer. In such topsoil of essential nutrients (Hess 2014). Fine

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particles such as clay are picked up by water and most common chemical constituents in ground-
carried in suspension and deposited elsewhere at water include sodium, calcium, magnesium,
greater depths. Water, thus, constantly changes potassium, chloride, and sulfate. However,

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the physical, chemical, and biological makeup of depending on mineral composition of the
the soil as it moves downward due to gravity, or subsurface and on length of exposure, high
sideways depending on available openings. When levels of arsenic, fluoride, iron, manganese, or
silica is removed by dissolution leaving behind radionuclides may also be found.
the more insoluble iron compounds, reddish col-
ored soils such as latosols are produced in tropical

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and subtropical regions of the world. In mid- Modeling and visualizing groundwater
and high latitudes, water removes minerals like
oxides of aluminum and clays and forms shallow The importance of modeling groundwater
acidic soils like podzols. Gley soils are acidic
and oxygen-poor and develop in waterlogged Because of its intractability, understanding the
conditions in cool climates. In the more arid and processes associated with groundwater is more
semiarid regions, capillary action brings up soil complicated relative to those associated with
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moisture, which evaporates leaving behind salts
like chlorides and sulfates. Soil salinization is
exacerbated by inadequate drainage and low pre-
surface water. Hence, monitoring, mapping, and
modeling efforts are crucial for this purpose.
As in any area of inquiry, however, the appli-
cipitation rates, resulting in calcic and other salt cability and accuracy of groundwater models
hardpans. is highly dependent upon (i) the quality of the
 
input data (i.e., knowledge of initial conditions
and the existence of adequate hydrogeological
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Groundwater chemistry data) and (ii) the “fit” between the model-
Groundwater quality may be affected by contam- ing approach (assumptions and equations) and
inants of both natural and human origin. Factors the scope and purpose of the problem being
that determine groundwater quality include explored.
the thickness of the aquifer, aquifer structure, Many groundwater models in one, two, or
mineral composition of the aquifer, presence or three dimensions rely at least to some degree
upon Darcy’s Law (Henry Philibert Gaspard
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absence of a confining layer, presence of direct


conduits (e.g., abandoned wells or sinkholes) Darcy, 1803–1858), which among other things
to the aquifer, and in the case of unconfined allows for estimating water velocity in an aquifer
aquifers, presence of pollutants on the overlying as well as time required for water to travel
land surface. Unconfined aquifers are more sus- between points within the aquifer, and which
ceptible to contamination from human activities holds for nearly all hydrogeological condi-
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because of their proximity to pollution sources. tions. In brief, Darcy’s Law provides that water
The age or residence time of water in the aquifer flows only when there is a gradient, that water
is also a significant factor affecting groundwater flows down-gradient from high to low head
quality as longer residence times provide more (pressure), that flow velocity is proportional
opportunity for dissolving minerals. to head loss, and that velocity is modified
Many substances may be dissolved by ground- by the hydraulic conductivity of the aquifer
water as it moves through the subsurface. The materials.

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Modeling approaches and data needs Software use in groundwater modeling


There are three types of groundwater models: Many commercial and open-source software
analytical element, finite element, and finite dif- packages exist for purposes of modeling and

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ference. The latter two are data driven and are displaying various aspects of groundwater
calibrated or fitted with extensive field data. The quantity and quality, including flow, transport,
simplicity of the analytical element method is in and geochemical reactions. A selected list of
its assumptions. It uses points, lines, and polygons open-source software for groundwater models is
to spatially represent contaminant sources, rivers, provided by the US Geological Survey (USGS

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flow barriers, and groundwater zones. Assump- 2014b).
tions such as flat water tables, uniform aquifer MODFLOW is the USGS’s three-dimensional
thickness, and constant conductivity are typical (3-D) finite-difference groundwater model
in such modeling efforts. However, such models (USGS 2013) that is considered an interna-
may not accurately represent the complex geom- tional standard for simulating and predicting
etry and heterogeneity of the real world of sub- groundwater conditions and the interactions that
surface groundwater (Bennett 2014). take place between ground and surface water.
Depending on the scope and purpose of
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modeling efforts, data of varying quality at com-
patible scales may be required. Generally, the data
required includes hydrologic measurements (e.g.,
Originally developed and released in 1984 as
a computer code for simulating groundwater
flow, its modular structure provides a robust
framework for integrating additional features.
precipitation, infiltration, evapotranspiration), Current capabilities include simulations of cou-
 initial and boundary conditions (e.g., poten- pled groundwater and surface-water systems, 
tiometric surface height, presence of confining solute transport, variable-density flow (includ-
layers), subsurface characteristics (e.g., thick- ing saltwater), aquifer-system compaction and
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ness, composition, hydraulic conductivity), and land subsidence, parameter estimation, and
human conditions (e.g., presence and pumping groundwater management (USGS 2013).
rate of wells, surface modifications). There is To enable users to make appropriate soft-
much more detailed hydrologic and subsurface ware selections, Kumar (2012) has provided
data available in developed nations than in a review of the capabilities and limitations of
developing nations. For example, in the United available groundwater modeling software. 3-D
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States, vast amounts of hydrologic data may be groundwater computer software uses borehole
obtained from federal government agencies such stratigraphy, geologic layers, cross sections,
as the US Geological Survey and the National and terrain data (for example, digital elevation
Oceanic and Atmospheric Administration and models) to construct 3-D models of the sub-
most states require submission of well boring surface (Strassberg, Maidment, and Jones 2014).
logs to permitting authorities for every well that With its ability to provide preprocessing data
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is drilled, resulting in a slowly increasing store of input to MODFLOW, and store results from
knowledge of the subsurface. In recent decades, MODFLOW, the Arc Hydro Groundwater data
satellite technology has also been employed to model of the flagship software company ESRI
search for signs of groundwater (e.g., landforms of California (Strassberg, Maidment, and Jones
such as ancient lake beds) or overexploitation of 2014) has created a very rich and comprehensive
groundwater (e.g., changes in surface elevation) environment for groundwater modeling and
over time. visualization.

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Discharging
playa Dry playa Dry playa Discharging

FA
UL
playa

T
Springs
Local
Water Table
Basin fill
Local Basin fill
Basin fill Intermediate

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Low-permeability rock Permeable rock Low-permeability rock
Regional
Undrained Partly drained Drained Partly drained
Sink
Closed basin Closed basin Closed basin Tributary area

Single-valley system Regional system

Phreatophytes
PR
Approximate location of local,
intermediate, and regional systems
Groundwater flow

Faults

Figure 3 Schematic block diagram of Death Valley and other basins illustrating the structural relations between
mountain blocks, valleys, and groundwater flow. Source: Faunt, D’Agnese, and O’Brien 2010. Reproduced by
 permission of USGS. 
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Groundwater models and geovisualization, (e.g., tracing historical contamination to its


selected examples source) scales. Two examples of 3-D ground-
water modeling efforts are provided below and
Hydrogeologists often use diagrammatic repre-
include predicting the migration of a uranium
sentations (Figure 3) to characterize and visualize
plume (Figure 4) and assessing risk of encounter-
the subsurface flow systems and the influence
ing high arsenic concentrations at various depths
of geology and climate on such systems over
(Figure 5).
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time. The movement of groundwater in the


subsurface of the Death Valley Regional Flow To construct 3-D images for visualizing
System (DVRFS) is captured and depicted in concentrated plumes of contaminants such
Figure 3 (Faunt, D’Agnese, and O’Brien 2010). as uranium in subsurface sediments of waste
It shows the flow paths of groundwater move- sites, as shown in Figure 4, scientists at the US
ment under the influence of hydraulic gradient Department of Energy (2009) have developed
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through varying zones of permeability, from groundwater models. Such models enable the
recharge to discharge areas in a regional context. prediction of movement of contaminants such
In addition to testing local aquifers to deter- as uranium over tens to hundreds of meters on
mine well or aquifer yields, and using well data temporal scales ranging from hours to years.
to describe subsurface flow patterns, models are Arsenic contamination of shallow groundwater
also used to understand groundwater both at and its impact on the health of affected popula-
spatial (local to regional aquifers) and temporal tions is one of the most serious environmental

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UO22+ concentration (M)


Saturation: 0.05 0.25 0.45 0.65 0.85
5E-07

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1E-07
8E-08 N

110

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105

Z (m)
100

95

1000
PR 600
800

0
)
200 400 (m
Y
 
400
200
X (m 600
)
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800 0 Time: 0.42 y (May)

Pressure (Pa): 10 000 50000 90000 130000 170000 210000

Figure 4 Three-dimensional plot of the uranium plume in groundwater beneath a portion of the Hanford
300 Area (a nuclear reservation site in Washington, USA), using PFLOTRAN model. Source: US Department
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of Energy 2009.

problems in developing countries. In Figure 5, Social, political, and planning aspects of


the authors of a study (Winkel et al. 2011) groundwater
on groundwater contamination of the Red
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River Delta in Vietnam show the probability of


Arsenic (As) concentration exceeding 10 μg/l
Historical access to and use of groundwater
at 10 m depth intervals. Such analyses resulting Throughout history, humans have accessed
from models enable us to study the connections groundwater in several different ways, likely
between large-scale pumping of groundwater beginning with locations where seeps or artesian
and the resulting vertical migration of arsenic in upwellings occurred, progressing to hand-dug
the subsurface. wells and wells accessed via windlass and bucket,

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GRO UN DWATE R

Hanoi
N
Haiphong

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Thaibinh

0m
Depth

0–1

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m
20
10–

m
30
Probability 20–
As >10 μgL−1
0.8–0.9 m
40
0.7–0.8 30–
0.6–0.7
0.5–0.6
0.4–0.5
0.3–0.4
PR 40–
50
m

m
0.2–0.3 60
0.1–0.2
50–
 
Figure 5 Risk of arsenic pollution of groundwater in Vietnam plotted in three dimensions and at 10m depth
intervals. Source: Winkel et al. 2011. Reproduced by permission of the Proceedings of the National Academy of
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Sciences.

and finally tube wells with electric or fossil demanded a cohesive community to successfully
fuel-powered pumps. maintain channels. Flow in qanats varies with
Qanats, or hand-dug tunnels with numerous the level of the water table in the aquifer, which
vertical shafts that access groundwater and deliver ensured sustainable use of the aquifer but also
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water by gravity for irrigation or domestic use, may have limited use for crops (and therefore
have been in use for more than eleven centuries crop yields) or other uses during periods of low
throughout much of the Middle East, western recharge. Although qanats are still in use in many
Asia, southern Europe, northern Africa, and regions, their importance for domestic supply
Central America. This technology is believed and irrigation has decreased due to increasing
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to have originated in Persia and spread via use of the same aquifers by powered pumps
trade routes and expansion of Arab and Roman or other hydrological modifications that may
empires. Water from qanats was historically have reduced recharge (e.g., as in the case of
viewed as a community resource to be shared, Morocco’s Tafilalet oasis and aquifer system).
and the maintenance and cleaning of qanats was Rapidly growing urban populations with
also a laborious and challenging exercise. Thus increasing water use and consumption during
the use of qanats for accessing water in effect the twentieth and twenty-first centuries have

3246




G RO U N DWAT E R

stressed aquifers with relatively high withdrawal groundwater (e.g., as in a sandstone aquifer) and
rates. In the case of coastal megalopolises such as groundwater flowing as a subterranean stream in
Houston, New York, and Chennai, the increas- a defined channel (e.g., as in a karst formation).

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ing water use rates have outstripped recharge
rates, thus enabling saltwater intrusion into Groundwater, conflict, and transboundary
coastal aquifers. Human population and agricul- aquifers
tural centers have not all been developed in close
proximity to locations with ample surface or The destruction, deliberate draining, or poison-
groundwater resources. Major river systems or ing of wells has been a feature of many conflicts

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throughout history; instances include Assyria’s
areas of significant precipitation often give rise to
use of rye ergot to poison enemy wells in the
the highest yielding alluvial freshwater aquifers.
sixth century BCE, Saladin’s sanding of wells in the
Large human settlements in arid and semiarid
defeat of the Crusaders in the twelfth century CE,
regions and areas overlying saline groundwater
poisoning of wells in German Southwest Africa
have long been water stressed.
by retreating German troops in 1915, Japan’s
use of biological weapons to contaminate wells
Groundwater rights
Modern groundwater rights are most often
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determined by ownership of overlying land, or,
in China in 1939–1942, Serbian cut-off of well
water to Bosnians in Sarajevo in 1992, Botswana
troops’ destruction of Khoisan (Bushmen) wells
in 2002, and intentional contamination of Darfur
where legally permissible, by leasing or purchas- wells in 2004 (Gleick et al. 2012).
 ing the rights to groundwater residing beneath There are numerous transboundary aquifers 
lands owned by others. The pumping or abstrac- worldwide, some of which are shared by more
tion rate may be determined by principles such than two nations. The nature of aquifer sharing
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as absolute ownership (pumping without regard includes several different types of situations, for
to depletion or conflict with others), correlative example:
rights (considering the rights of other users), or
a permit that specifies a maximum pumping rate. • two or more nations overlie an unconfined
Historically, groundwater pumping rates have aquifer;
not been of significant concern, except in water • two or more nations overlie a fossil aquifer
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scarce regions. with no meaningful recharge;


In recent decades, with increasing ground- • one nation has the recharge zone and part
water consumption for irrigation and other of an unconfined aquifer within its territory,
purposes, and with more complete information whereas down-basin nations have access only
about aquifer extents, capacities, and depletion to the water in the aquifer (Eckstein and
rates, pumping has become increasingly reg- Eckstein 2005).
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ulated in semiarid regions. In some situations


(e.g., Texas, United States), groundwater rights With some exceptions, and despite the
may be separated from the overlying lands and catastrophic potential impacts of aquifer contam-
may be purchased or leased and exploited by ination and depletion, there has been relatively
individuals or entities who do not own the land. little progress on the international management
Groundwater rights in some locations are also of groundwater. In 2008, the United Nations
affected by the distinction between percolating adopted Resolution A/RES/63/124 on the Law

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of Transboundary Aquifers, which provides a important ways: (i) groundwater may become a
set of guidelines and recommendations to assist more valuable resource in a changing climate,
nations in establishing bilateral and multilateral where precipitation becomes less predictable

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agreements. More recently, the UN has discussed and more “flashy,” and (ii) aquifer recharge
establishing a more formalized convention on may also be altered by changes in precipitation
transboundary aquifers. Key issues in the man- patterns and evaporation rates. Climate change
agement of transboundary aquifers include prior impacts on groundwater resources may be most
use patterns, military conflict, economic growth, significant in areas that have scarce precipitation
population growth, irrigated agriculture in arid or which already are water stressed, as well as in

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or semiarid lands, land use, climate change, and monsoon regions.
the proportion of overlying land or recharge area
controlled.
There are several notable regional conflicts Water quantity: over abstraction
in which groundwater plays an important In addition to the 15 highly overexploited
role. Groundwater is interwoven into the aquifers of the world (shown in Table 2),
Israeli–Palestine conflict because the Mountain over-abstraction or mining of groundwater for
PR
Aquifer provides a significant proportion of the
domestic and agricultural water to Israeli terri-
tory, but the recharge zone lies nearly entirely
agriculture (e.g., San Joaquin Valley, California,
United States), industrial use, and drinking water
supply (e.g., Osaka City, Japan) has occurred in
within the West Bank. The lack of stable and numerous other aquifers worldwide. In many
durable peace in the region makes it difficult locations, such overuse has caused permanent
 
to manage and use the resource efficiently and compaction and aquifer capacity reduction and
also construct and operate water and wastewater accelerated sinkhole formation in karst regions.
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treatment facilities in the West Bank so as to Resulting land subsidence of several tens of
protect the highly vulnerable aquifer. meters in some cases (e.g., Houston, Texas,
The Nubian sandstone aquifer is a fossil United States) have increased the vulnerability
aquifer in northern Africa shared by Libya, of such areas to flooding. Due to approximately
Egypt, Sudan, and Chad. In 2013, these four 8 m of subsidence in the last century, numerous
nations adopted the Regional Strategic Action buildings in Mexico City have been damaged
Plan on the Nubian Sandstone Aquifer in
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and significant repairs have been necessary to


response to declining water levels, increased much of the subsurface infrastructure, including
salinization in the Post-Nubian System (north of subways, sewers, and potable water pipes.
the Nubian System), and the declining health of
dependent ecosystems.
Groundwater quality issues
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Key issues related to planning and future Arsenic (arsenicosis), fluoride (fluorosis), and
sustainability of groundwater resources radionuclides (mutations, cancer) are all found
in groundwater in some regions and have sig-
nificant human health impacts. For example,
Water quantity: climate change
relatively low concentrations of arsenic can be
Climate change is already impacting groundwa- found in groundwater in many regions; how-
ter and will continue to impact it in at least two ever, the highest concentrations consumed as

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G RO U N DWAT E R

potable water appear to be found in the southern Significant and growing threats to
Asian nations of Bangladesh, India, and Vietnam groundwater: agriculture
(Mukherjee et al. 2006; Winkel et al. 2011).
Agricultural productivity has increased signifi-

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Other groundwater constituents tend to have
cantly over the past several decades. Yields have
impacts that are less health-related but significant
risen due to increased use of pesticides, fertilizers,
nonetheless. For example, the main impacts of
and irrigation (often from groundwater sources),
calcium and magnesium are the formation of
as well as to expansion of cultivated areas. But
scaly deposits on pipes and reduced performance
gains in productivity have been accompanied by
of soaps and detergents. Sulfur compounds typi-

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increasing groundwater degradation and deple-
cally affect the smell and taste of water, whereas
tion. For example, herbicides such as atrazine and
high levels of iron can leave reddish stains on
alachlor (used respectively on cereals and fruit
fabrics washed with groundwater. trees) have been extensively detected in ground-
Groundwater contaminants of human origin water in Europe and North America; and in
include industrial discharge, landfills and legacy South Asia, commonly used insecticides includ-
waste disposal sites, agriculture, toxic chem- ing carbofuran and lindane have been widely
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ical spills, leaking underground storage tanks
(LUSTs), and domestic sewage discharge. The
behavior and toxicity of contaminants varies
widely, as does the ability to remediate and
detected in groundwater (Mateo-Sagasta and
Burke 2011). Elevated nitrate levels, sometimes
exceeding the US Environmental Protection
Agency (EPA) maximum contaminant level of
restore groundwater quality. Nitrate, the most 10 mg/L are nearly ubiquitous in unconfined
 common agricultural groundwater contaminant, 
shallow aquifers in major breadbaskets such as
is highly soluble in water, but its presence in the Midwestern United States.
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affected aquifers may be significantly reduced by


source reduction or prevention. Other contam-
inants that are less soluble and less mobile may Significant and growing threats to
be extremely difficult and expensive to remove groundwater: fossil fuel exploration and
from aquifers. Dense nonaqueous phase liquids extraction
(DNAPLs) such as trichloroethylene (TCE) Hydraulic fracturing or “fracking” is a drilling
tend to sink toward the bottom of aquifers technique used to obtain natural gas and oil
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where they may slowly degrade and release toxic from shale rock and other nonconventional
by-products. Gasoline from leaking underground sources (Bigham 2013). For every fracking well,
storage tanks is perhaps the most common light between 8 and 20 million liters of water along
nonaqueous phase liquid (LNAPL). Benzene, with sand and hundreds of compounds (e.g.,
toluene, ethylbenzene, and xylene (BTEX, four for lubricating, anticorrosion) are injected to
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of the major hydrocarbons found in petroleum fracture deep tight rock formations, releasing gas
products) spread in plumes at different rates and oil from small pores within them (Figure 6).
throughout the top of the aquifer. Microbial Groundwater contamination associated with
contaminants may be introduced to aquifers fracking operations appears to be associated
by improperly sited septic tanks as well as by mainly with (i) the disposal of “produced” water
untreated or inadequately treated municipal and infiltration into shallow unconfined aquifers,
discharges above unconfined surficial aquifers. and (ii) well barrier and integrity failures, which

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Fracking for fuel


Hydraulic fracturing is used to access oil and gas

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resources that are locked in nonporous rocks.

Water recovery tanks


Methane gas Polluted flowback water
escapes during the may be injected into a deep
mining process. storage well, recycled, or
sent to a treatment plant

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Blowouts
are possible.

Poorly treated

Water
table
Well
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Possible flow
Leakage of fracking
fluids from the pipe
has not been seen.
flowback water
has leaked into
drinking water.

of methane.

Leakage of
 fracking fluid 
Cement
Holes in the well from the
casing
casing allow fluid fracture zone
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to exit and gas to is highly


enter. unlikely.
Steel pipe

High-pressure fracturing fluid

High-pressure Gas flows


fracking fluid from the
opens networks fractures
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Shale of fractures in the into the


shale. Sand props pipe.
the fractures open.

Fissures
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Figure 6 Hydraulic fracturing. Source: Howarth, Ingraffea, and Engelder 2011. Reproduced by permission
of Nature.

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G RO U N DWAT E R

may allow migration of methane and fracking laws focused on groundwater in the United
fluids to aquifers used for drinking and irrigation. States. Much of the regulation of groundwater is
Davies et al. (2014) indicate well failure rates then left to individual states. But since aquifer and

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are highly variable (1.9–75%) depending upon state boundaries rarely coincide, this leads or has
when and where they have been drilled. Other the potential to lead to problems similar to those
recent studies indicate that groundwater in close faced with international aquifers. One major
proximity to fracking operations is much more policy need, therefore, is to “scale up” policy
likely to be contaminated with produced water related to protecting and conserving aquifers.
and methane, and that in some cases the chem- Numerous strategies have been proposed for

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ical composition of methane found in drinking situations in which aquifers are stressed due
water aquifers was quite similar to the gas found to over abstraction from irrigated agriculture,
in the much lower shale formations ( Jackson including substituting dryland-adapted crops
et al. 2013; Gordalla, Ewers, and Frimmel 2013). (e.g., wheat, sorghum, millet) in place of rice
To facilitate rapid exploration and recovery or maize, developing drought-tolerant strains
of crude oil and natural gas, changes have been of rice or maize, reducing tillage, reestablishing
made to existing legislation such as the United native grasslands, limiting drilling of new wells,
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States’ Safe Drinking Water Act to exclude
hydraulic fracturing from the definition of
underground injection, a practice that was until
and using moisture sensors and ultra-efficient
irrigation technologies. In urban areas where
aquifers are depleted, strategies such as aquifer
the early 2000s largely prohibited or tightly recharge via infiltration ponds or galleries and
regulated. Within the United States, fossil fuel injection of surface water or treated municipal
 exploration is mainly regulated at the state level, wastewater are being increasingly employed. 
but the US EPA has recently undertaken a
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nationwide study on fracking and may issue SEE ALSO: Aquifers; Environmental
nationwide regulations in the future. Hydraulic uncertainty; Hydrologic cycle; Soil water; Waste
fracturing is already being employed or planned and waste management; Water conflicts; Water:
in Germany, the United Kingdom, India, and drinking; Water and human rights; Water
China (Gleick et al. 2012), and numerous suit- quality; Water rights
able formations for exploration and extraction of
resources via hydraulic fracturing exist on every References
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populated continent.
Bennett, Ray R. 2014. “Analytic vs. Numeric
Ground Water Models.” Colorado Division of
Strategies for protecting and replenishing Water Resources. http://www.cwi.colostate.edu/
aquifers southplatte/files/Presentations/Glove-Modflow-
At least in part due to difficulties in directly SPDSS.pdf (accessed February 5, 2016).
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Bigham, R. 2013. “Fracking Features.” Pollution Engi-


observing groundwater, efforts to conserve and
neering, 45(6): 39–41.
protect the quality of groundwater resources have Davies, Richard J., Sam Almond, Robert Ward,
lagged behind such measures for surface water. In et al. 2014. “Oil and Gas Wells and Their
addition to international cases noted above, this is Integrity: Implications for Shale and Uncon-
also true at national scales. For example, whereas ventional Resource Exploitation.” Marine and
the Clean Water Act is aimed at protecting Petroleum Geology, 56: 239–254. DOI:10.1016/j.
surface water, there are no federal environmental marpetgeo.2014.03.001.

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Eckstein, Yoram, and Gabriel Eckstein. 2005. “Trans- Mateo-Sagasta, Javier, and Jacob Burke. 2011. “Agri-
boundary Aquifers: Conceptual Models for Devel- culture and Water Quality Interactions: A Global
opment of International Law.” Ground Water, Overview.” SOLAW Background Thematic

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43(5): 679–690. DOI:10.1111/j.1745-6584.2005. Report TR08. Food and Agriculture Organi-
00098.x. zation of the United Nations. http://www.fao.
Faunt, Claudia C., Frank A. D’Agnese, and Grady org/fileadmin/templates/solaw/files/thematic_
M. O’Brien. 2010. “Hydrology.” In Death Val- reports/TR_08.pdf (accessed February 21, 2016).
ley Regional Groundwater Flow System, Nevada and McGuire, Virginia. 2013. “Water-Level and Stor-
California – Hydrogeologic Framework and Transient age Changes in the High Plains Aquifer, Prede-
Groundwater Flow Model, edited by Wayne R.

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velopment to 2011 and 2009–11.” United States
Belcher and Donald S. Sweetkind. USGS Profes-
Geological Survey Scientific Investigations Report
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2012–5291. http://pubs.usgs.gov/sir/2012/5291/
(accessed February 5, 2016).
sir2012-5291.pdf (accessed February 5, 2016).
Gleeson, Tom, Yoshihide Wada, Marc F.P. Bierkens,
and Ludovicious P.H. van Beek. 2012. “Water Bal- Mukherjee, A., M.K. Sengupta, M.A. Hossain, et al.
ance of Global Aquifers Revealed by Groundwater 2006. “Arsenic Contamination in Groundwater: A
Footprint.” Nature, 488: 197–200. DOI:10.1038/ Global Perspective with Emphasis on the Asian.”
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Gleick, Peter, Lucy Allen, Michael Cohen, et al. 2012.
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142–163.
Richts, A., W.F. Struckmeier, and M. Zaepke. 2011.
“WHYMAP and the Groundwater Resources of
Gordalla, B.C., U. Ewers, and F.H. Frimmel. 2013. the World 1:25,000,000.” In Sustaining Ground-
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Hess, D. 2014. McKnight’s Physical Geography: A Land- World’s Fresh Water Resources, edited by Peter H.
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Publishers. Strassberg, G., D.R. Maidment, and N.L.
Howarth, Robert W., Anthony Ingraffea, and Terry Jones. 2014. “Arc Hydro Groundwater
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11250–11255. DOI:10.1073/pnas.1221635110.
Kumar, C.P. 2012. “Groundwater Modeling Soft- February 5, 2016).
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2050290/Groundwater_Modelling_Software_-_ USGS. 2014a. “Glossary of Hydrologic Terms.”
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USGS. 2014b. “Water Resources Groundwater the shortcomings of social scientific analysis of
Software.” http://water.usgs.gov/software/lists/ urban power structures in the USA.
groundwater/ (accessed February 5, 2016). Logan and Molotch (1987) suggested that

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Winkel, Lenny H.E., Pham Thi Kim Trang, Vi Mai the activities of rentiers – land development
Lan, et al. 2011. “Arsenic Pollution of Groundwater
interests – lie at the crux of understanding the
in Vietnam Exacerbated by Deep Aquifer Exploita-
tion for More Than a Century.” Proceedings of the
behavior of growth machines. Rentiers prepare
National Academy of Sciences, 108(4): 1246–1251. the ground for land-use intensification and
DOI:10.1073/pnas.1011915108. profit-making in the city. Often this is to the
benefit of a wide range of business interests

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Further reading and organizations, such as corporations, con-
tractors, the local media, universities, utilities,
Domenico, Patrick A., and Franklin W. Schwartz. sports franchises, chambers of commerce, trades
1997. Physical and Chemical Hydrogeology, 2nd edn. unions, and so forth. Local government is not
New York: John Wiley & Sons. a disinterested party in this process as it strives
Holden, Joseph, ed. 2014. Water Resources: An Inte- to influence land-use outcomes in ways that
grated Approach. New York: Routledge. enhance the local tax base and foster a sense of

Growth machines
PR community solidarity. Growth coalitions tend
to converge around those levels of government
having fiscal resources and land-use powers
necessary for delivering growth and jobs.
 For urban geographers, the growth machine 
Andrew E.G. Jonas thesis has provided fertile territory for critique
Hull University, UK
and further refinement (Jonas and Wilson 1999).
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The concept of the growth machine refers to Some critiques have highlighted how its focus
systemic properties operating within capitalist on the tension between use and exchange value
cities which generate growth around the inten- subverts knowledge of class tensions and progres-
sification of land use. This often happens despite sive urban politics. Others examine the discur-
pressures and political interests opposed to sive tools deployed by growth machines and their
such growth. The term “growth machine” can effects on marginalizing the voices of minorities
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also refer to coalitions of business and local in the city. Then there are those who have sought
government interests seeking to attract inward to apply the thesis to settings outside the USA,
investment, promote redevelopment, and market finding that the national state is a more powerful
the city. The growth machine concept was first driver of urban development than local growth
proposed by the American urban sociologist coalitions. However, the jury is still out in respect
Harvey Molotch in the 1970s (Molotch 1976). of whether the growth machine thesis is con-
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It was subsequently refined into a thesis about ducive to the international comparison of urban
the tensions between use and exchange value development politics.
arising from unregulated capitalist forms of Urban scholars today argue that knowledge
urban growth (Logan and Molotch 1987). By of power structures operating in cities requires
connecting urban political agency to certain a shift in focus away from territorial growth
systematic properties of capitalism, the growth coalitions and towards relational processes and
machine thesis was able to transcend some of networks operating beyond the city limits.

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