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    wSaral Exercise - 1 Chemical Bonding Concept Builder Each question has FOUR options for correct answer. ONLY ONE of these four options is correct option. For each question, choose the correct option to answer the question. Introduction When two atoms combine to form a molecule :~ a. (A) Energy is released (B) Energy is absorbed (C) Energy is neither released nor absorbed (D) Energy may either released o absorbed An electrovalent bond or ionic bond is formed between ? (A) Two electronegative atoms (B) Two metals (C) Electropositive and electronegative atoms (D) Two electropositive atoms Anatom with atomic number 20 is most likely to combine chemically with the atom whose atomic number is ? (AI (B) 16 (O18 (D) 10 @. Bismuth does not form stable pentahalide because of ? (A) Its higher electronegativity (B) Its smaller size (C) Inert pair effect (D) Non availability of d-orbitals An ionic compound A’ B- is most likely to be formed when ? (A) Ionization energy of A is low (B) Electron affinity of B is high (©) Electron affinity of B is low (D) Both (A) and (B) Properties of lonic Compound & Solul ity Q6. Which of the following is not a correct statement about an ionic compound ? (A) Higher the lattice energy, higher is melting point (B) Higher the dipole moment of solvent, ‘more the solubility (©) Higher the lattice energy, more the solubility (D) More difference in electronegativity, more is the ionic nature Electrovalent compounds or ionic com- pounds do not show stereoisomerism. The reason is? (A) Presence of ions (B) Strong electro statie force ofattraction (© Brittleness (D) Non- directional nature of ionic bond Q8. Capacity of solvent to neutralise charge onan ionic compound is given by ? (A) Solvation energy (B) Dielectric constant (©) Dipole moment (D) Solubility In which of the following solvents, KI has highest solubility ? The dielectric constant (£) of each liquid is given in parentheses :- (A) CH, (€=0) (B) (CH,),CO(€= 21) (©) CH,OH («=32) (D) CCI, (<=0) QUO. Solid NaClis a bad conductor of electricity because ? (A) In solid NaCI there are no ions (B) Solid NaC! is covalent (©) Insolid NaCl there is no mobility of ions (D) In solid NaCI there are no electrons wSaral & at wa gear B1 wSaral Chemical Bonding Qu. Select correct order out of given options : (A) Na,CO, > BaCO, : Lattice Energy (B) BeO > SrO : lattice energy (©) Be < Li (D) Be*(aq.) > Li'(aq,) : Ionic mobility ydration energy Fajans Rule Qu. Qi. Which pair in the following has maximum and minimum ionic character respectively? (A) LiCl, RBC! (B) RCI, BeCl, (©) BeCl,, RbCl (D) AgCl, RbCI According to Fajans rules favorable condition to form covalent bond is ? (A) small cation and large anion (B) small cation and small anion (©) large cation and large anion (D) large cation and small anion The polarizibility of the following com- pounds is ? (A) F> Br> Cr> F ()P> Br>F>Cl (Q3>2 (C)1>2>3 (D)2>1>3 Chemical Bonding Q27. Carbon has a Covalency of 2 in CO and 4 in CO, and CH, Its valeney in C,H, is : (ay3 (B)4 2 (p)1 Q28. Which is not an exception to octet rule ? (A) BF, (B) SnCl, (©) Bel, (D) Clo, VSEPR 29. Which following set of compound/ion has linear geometry ? (A) CH, NH;, BH, (B)CO? , NO, ,BF, (©) NO}, CO, Nj (D) BeC, BCL, CH, Q30. The species [I(CN),] is ? (A) Linear (B) Bent (©) Pyramidal (D) none of these Q31. Which of the following has a square planar structure ? (A) NH; (B) BF, (©) Xe, (p) CCl, Q32. Ac bonded molecule MX, is T-shaped. The number of non-bonding pairs of electrons is? (ayo (B)2 ©! (D) Can be predicted only ifatomic number of M is known, Q33. Select the correct matching List 1 List I A: 1. Pyramidal B: 2. T-shape C:XeO, 3. Distorted octahedral D:XeOF, 4. Square planar vSaral & a aa wea a1 ge 3 wSaral Chemical Bonding Qu. Q36. Q37. Q38. Q39. A BC »D (A) 4 3 1 2 @) 1 2 3 4 © 2 1 3004 @) 4 1 32 In which following set of compound/ion has linear shape (A) CH, NH;, BH; (B) CO;, NO;, BF, (©) NOs, CO,, XeF, (D)BeCl,, BCL, CH, Which of the following set is not correc (A)SO,, 0,, NH, ‘all have coordinate bonds (B) H,O, NO,, ClO;, all are 'V’ shape molecules IC);, NO} ; all are linear molecules iF, XeF, are tetrahedral in shape Shape of a molecule having 4 bond pairs and two lone pairs of electrons, will be :~ (A) Square planar (B) Tetra hedral (©) Linear (D) Octa hedral Hybridisation in XeOF,, XeOF, i shape will be respectively:~ (A) T,'V'shape (B)T shape, (See-Saw) (C) Both have T shape (D) T shape, irregular octahedral The shape of IF; will be :- (A) Square planar (B) Tetranedral (C) Pentagonal bipyramidal (D) Distorted tetrahedral Amongst CO,", AsO, XeO, , CIO; , BO} and SO,* the non-planar species are - (A) XeO, , CIO, , SO,’ AsO} (B) AsO,* , XeO, , CO, (©) BO, , CO, (D) AsO,” , BO,” , VBT Q40. 42, A sigma bond is formed by the overlapping of (A) s-s orbital alone (B) sand p orbitals alone (©) ss, s-p or p-p orbitals internuclear axis (D) p-p orbital along the sides long Which of the following leads to bonding ? s-orbital p-orbital s-orbital p-orbital orbital d-orbital (D) __ orbital p-orbital © The strength of bonds by 2s - 2s, 2 and 2p -2s overlapping has the order :~ (A)s-s>p-p>s—p (B)s—s>p-s>p-p (©)p-p>s—p>s-s (D) p-p>s-s>p-s t™ bond is formed :- (A) By overlapping of hybridised orbitals (B) Overlapping of s - s orbitals (C) Head on overlapping of p -p orbitals (D) By p- p collateral overlapping Fluorine molecule is formed by : (A) the axial p-p orbital overlap (B) the sideways p-p orbital overlap (C) the s-s orbital overlap (D) the s-p orbital overlap the following statements : 1A sigma (6) bond is formed when two s-orbitals overlap I A pi(x) bond is formed when two p-orbitals axially overlap II. Ao - bond is weaker than x - bond Which ofthe above statements is /are correct? (A) Land I (B) land Ill (©) Talone (D) 1 alone wSaral Q46. Q47. Number of and x bonds present in CH, — CH == CH — CH are ? (A) 108,3p (B) 10s,2p (©) 9, 2p (D) 8s, 3p Which of the following statements regarding covalent bond is not true ? (A) The electrons are shared between atoms (B) The bond is always non-directional (C) The strength of the bond depends upon the extent of overlapping, (D) The bond formed may or may not be polar Hybridisation Qa8, Q49. Q50. Qs. Overlapping of 2 hybrid orbitals can lead to the formation of (A) None (B) o-bond (C) n-bond (D) (B) and (©) both Inthe compound 123, 4 8 6 CH=CH—CH-CH—-C=CH.the C bond is formed by the overlapping of : (A) sp—sp* (B) sp'—sp’ (C)sp~sp° (D) sp*=sp* Which of the set of species have same hybridisation state but different shapes? (A) NO,', NO, , NO; (B) ClO, SF,, XeF, (C) NH,’ HO’, OF. 2 (D) SO?, PO}, ClO; Which compound has four sigma bond and one lone pair? (A) NH, (sr, (B) IC, (D) XeF, Q52. Q53. Q54. Q55. Q56. Q57. Q58. Chemical Bonding Descending order of electronegativity of sp’, sp* & sp hybridised orbitals is ? (A) sp*, sp, sp> (B) sp’, sp*, sp. (©) sp, sp. sp (D) sp, sp’, sp? In the protonation of HO, change occurs in (A) Hybridisation state of oxygen (B) Shape of molecule (C) Hybridisation and shape both (D) None The d- orbitals involved in sp'd hybridisation is:- (A) 4pye (B) dp © dy (D) 4, In which of the hybridisation state different quantum No. are used: (A) sp (B) sp'd (esp (D)sp Which of the following species are expected to be planar: (a) NH (b) NHG (©) CHy (d) PCly ‘The correct answer is:~ (A) bande (B) cand d (©) band d (D) and d Which order of decreasing bond angle is correct:~ (A) CCl, > BF; > NO; (B) NH; > NCI, > NBry (©) Br,0 > Cl,0 > OF; (D) PCL; > PBr;> Pls ‘A molecule is square planar with no lone pair, What type of hybridization is associated with it ? (A) sp'd (©) dsp’ (B) sp’? (D) dsp? vSaral @ a aa wea al wSaral Chemical Bonding Q59. Hybridisation state of | in ICL," is (A) dsp? (B) sp (C) sp* (D) sp? Q60. The hybrid states of central atom in diaborane, diamond and graphite are respectively : (A) sp’ sp’, sp” (BY sp’, sp’, sp" (C) sp’, sp’, sp’ (D) sp, sp’, sp" Q61. The change in the state of hybridization of asterisked carbon in the following reaction CH,CN —“© CH,CONH, (B) sp* to sp (D) sp’ to sp’ Bond Parameters 62. Which of the following has been arranged in order of decreasing bond length ? (A) P-O0 > CLO > S-0 (B) P-O>S-0>CLO (C)S-O> CLO > P-O (D) CLO > S-O > P-O 63. When the hybridization state of carbon atom changes from sp’, sp* and sp, the angle between the hybridized orbitals? (A) decrease considerably (B) increase progressively (C) decrease gradually (D) all of these Q64. Which is correct statement ? As the s-character of a hybrid orbital decreases (J) The bond angle decreases (11) The bond strength increases (LIN) The bond length increases (IV) Size of orbital increases (A) (D, (HID) and (LY) (B) (1D), (ITD) and (Iv) (©) (D and 1) (D) All are correct RE TeR NUL ee 522A) AR ARSE Gaia ae Cer Q65. The order of Bond Angle in CH, (A) and CCL, (B) is? (A)A>B (B)A BCI, > BBr, > BI, (B) BI, > BBr, > BCI, > BF, (©) BF, > BI, > BCl, > BBr, (D) BF, > BCI, > BI, > BBr, Select species which is planar at nitrogen : (A) (CH).N (B) (SiH,).N (C) NF, (D) NH, Which of the following compounds has a 3-centred, 2 electron bond :— (A) BF, (B) NH, (©) BH, (D) Co, Which of the following option w.r.t. increas- ing bond order is correct ? (A)NO NO > NO’ (B) NO’ Googie Play wSaral Q93. 6. Q97. BeF; has zero dipole moment where as HO has a dipole moment because (A) Water is linear (B) H,0 is bent © (D) Hydrogen bonding is present in HO more electronegative than O Which of the following species are symmetrical := (a) XeF, (b) Xek, (c) SO, (d) NHY Correct answer is:- (A) aandb (B) bande (C)eandd (D)aandd Inthe compounds CH,OH, CH,, CF,, CO,, which has maximum dipole moment: (A) CHOH (B)CE, (CCH, (D) CB, and CO, have equally more The dipole moment of NH, is:~ (A) Less than dipole moment of NCI, (B) Higher than dipole moment of NCI, (C) Equal to the diple moment of NCI, (D) None of these PCI, is non polar because (A) P- Cl bond is non-polar (B) Its dipole moment is zero (C) PC bond is polar (D) P & Cl have equal electronegativity Which contains both polar and non-polar bonds ? (A) NH,CI (B) HCN OHO. (D) cH, Chemical Bonding 9%. Which of the following molecule does not possess a permanent dipole moment : (HS (B) So, (C)s0,? (pycs, Hydrogen Bond and Weak Bonds Q100. The hydrogen bond is strongest in :- (A)O-H---S — (B)S-H---0 (QF-H---F — (D)O-H---O QIO1. Which of the following has strongest intra molecular hydrogen bonding ? OH OCH, “ oo ®) om 1H Hy © () COOH COOH Q102. The correct order of volatility is:- (A) NH,CH,-0-CI (D) HF > HCI Q103. Pure phosphoric acid very viscous. The reason is? (A) strong acid (B) It is tribasie acid (©) Itis hygroscopic (D) It has PO} groups which are bonded by many hydrogen bonds Q104. Acetic acid exists as dimer in benzene due to? (A) Condensation reaction (B) Hydrogen bonding (©) Presence of carboxyl group (D) None of the above vSaral @ a aa wea al ge 9 wSaral Chemical Bonding Q105. Density of ice is less than that of water because of ? Q106. In dry ice the bond present between two molecules is ? (A) presence of hydrogen bonding (A) Ionic bond (B) Covalent bond (B) crystal modification of ice (C) Hydrogen bond (D) Vander Waal (©) open porous structure of ice due to hydrogen bonding (D) different physical states of these Exercise - 1A Concept Builder MORE THAN O) CORRECT TYPE Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are) correct option(s). For each question, choose the correct option(s) to answer the question. Qi. @. Q@. Most ionic compounds have: (A) high melting points and low boiling points (B) high melting points and nondirectional bonds (©) high solubilities in polar solvents and low solubilities in nonpolar solvents (D) three-dimentional network structures, and are good conductors of electricity in the molten state Which of the following is/are correct ? (A) An ionic solute will dissolve in water if hydration energy of the ions is greater than the lattice energy (B) Greater the size of the ions greater is the lattice energy (C) Correct order of solubilities of the alkali metal fluorides is Lif < NaF < KF (D) The correct order of the solubilities of the alkali metal nitrate is LiNO, > NaNO, > KNO, Polarization may be called the distortion of the shape of an anion by an adjacently placed is/are incorrect ? Ranks in IIT-JEE/NEET with eSaral APP (A) Minimum polarization is brought about by a cation of low radius (B) A large cation is likely to bring about a large degree of polarization (©) Maximum polarization is brought about by a cation of high charge (D) Assmall anion is likely to undergo a large degree of polarization Which of the following statements is/are true for BaO and MgO ? (A) BaO is more ionie than MgO. (B) MgO is more ionic than BaO. (C) BaO has a higher melting point than MgO. (D) MgO has a higher melting point than Ba. Choose the correct order for the given properties. (A) MgSO, < SSO, < BaSO, : Thermal stability order (B) BeC,0, < CaCO, < BaC,0,: Solubility in water (©) Licl > NaCl > KCI Melting point order (D) Bek, > CaF, > StF, : Covalent character order Choose the correct order for the given properties. (A) Nak MgF, > Al power of cation, order of polarising Which of the following compounds contain’ s both ionic and covalent bonds ? (A) NHCI (B) KCN (C) CuSO,5H,O — (D) NaOH The octet rule is not obeyed in ? (a) CO, (B) BC (©) Pcl, (D) SiF, Which of the following species contain coordinate bond ? (A) AICL, (C) NOF, (B) CO. (D)N, The linear structure is assumed by ? (A) SnCl, (B) NCO («cs, (D) No Shape of NH, is very similar to ? (A) Se0? (B) CH, (©) BH, (D) CH, Which of the following species are isoelectronic with CO, ? (A) Ny (B) (CNO) (©) eneny: (D) NO, A r-bond may form between two p, orbitals containing one unpaired electron each when they approach each other appropriately along ? (A) axis (C) z-axis (B) y-axis (D) any direction Which combination of the compounds and their geometry! shape are correct ? + linear square pyramidal (C) CIF, - T-shaped (D) ICI, square-planar Qis. Q16. Qi7. Qis. Qu. Q20. Qu. Chemical Bonding Select the correct statement for following molecules : @ PFKCH),; GD PFYCF,), (A) Both have trigonal bipyramidal struc- ture with respect to P. (B) P-F bond length is longer in PF(CH,), than in PE(CF,), (©) F-atoms occupy axial position in both (D) None of these Molecules in which bond angle is changed due to back bonding war. B/O/N ? (A) HBO, (B) B(OMe), (© BF, (D) N(SiH,), 34,-2p, type back bonding is observed in ? (A) N(SiH,), (B) CCl, (©) S(CH), (D) BC, Three centre - two electron bonds exist in : A BH, (B) AY(CH,), (C) BeH(s) (D) BeCl(s) Select correct about NO, (A) It is odd electron species (B) N-O bond order = 1.5 (C) Paramagnatic speci (D) Isoelectronic with CO, Which of the following statements are CORRECT ? (A) The fiee electron of CIO, molecule is present in d-orbital of Cl-atom (B) The free electron of CF, is present in sp’ hybrid orbital (© NO is polar (D) The free electron of C10, molecule is present in d-orbital of Clatom Which of the following do not exist ? (A) SH, (B) HFO, (© Fel, (D) HCIO, vSaral @ a aa wear al P: wSaral Q22. order ? (A) 0," (C) CN Q23. Which of the following have identical bond Given the species : N,, CO, CN’ and NO’. Which of the following statements are true for these: (A) All species are paramagnetic (B) The species are isoelectronic (C) All the species have dipole moment (D) All the species are linear Q24. Which of the following is/are correct ? (A) During N', formation, one electron is removed from the bonding molecular orbital (B) During 0°, formation, one electron removed from the antibonding molec lar orbital (©) During O”, formation, one electron added to the an orbital (D) During CN~ formation, one electron is is onding molecular is added to the bonding molecular orbital Qs. (B) CHCl, () at Y-ci ASSERTION AND REASON Q26. Statement-1 : C,O, has linear structure. Statement-2 : Each C atom in C. sp-hybridised. Which has (have) zero value of dipole moment? (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1, (B) Statement-1 is true, statement-2 is true and statement explanation for statement-1 (©) Statement-1 is tru (D) Statement-1 is false, statement a is NOT the correct tatement.2 is false. Q27. Q28. Qu. Ranks in IIT-JEE/NEET with eSaral APP Chemical Bonding Statement-1 : Boron does not show univalent nature but unipositive nature of thallium is quite stable. Statement-2 : Inert pair effect predominates in thallium, (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. tatement-2 is true (B) Statement-1 is true, and statement-2 is NOT the correct explanation for statement-1. (C) Statement-1 is true, statement-2 is false. (D) Statement-1 is false, statement-2 is true. Statement-1 : Among alkali metal cations, Li‘(aq.) has highest electrical conductance. Statement-2 : Li'(aq.) is largest alkali metal cation because of greater degree of hydration, (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1 (C) Statement-1 is true, statement? is false. (D) Statement-1 is false, statement-2 is true, Statement-1: H, molecule is more stable than He-H molecule. Statement-2 : The antibonding electron in He-H molecule decreases the bond order and there by the stability (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1 (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1 (C) Statement-1 is true, statement-2 is false. (D) Statement-1 is false, statement-2 is true. Cry i wSaral PARAGRAPH TYPE This section contains PARAGRAPHS. Based on each paragraph, there are questions. Each question has FOUR options. ONLY ONE of these four options corresponds to the correct answer: For each question, choose the option corresponding to the correct answer, Paragraph # 1 (Ques. 30 to 32) Hydridisation helps to determine the shape of a molecule but shape of a molecule is mainly defined by VSEPR theory According to this theory Lp-Lp > Lp~ b.p > bp — bp repulsion. Q30. _Inwhich of the following pairs hybridisation of the central atom is not same? (A) CIE,, CIE,O, (B) CIF,O, CIF,O. (C) [CIF,O}" [CIF,O} (D) [CIE,OF [XeOF,] Q31. Correct structure of CIF, is ? f NN “ ®) AN ; F (Cc) L N (D) All of the above Q32. Which one is the only V-shaped molecule or ion? (Al, (B) Ny (sy (DCS Paragraph # 2 (Q. 33 to 35) Molecular orbital theory is based on linear combination of atomic orbitals (LCAO). According to LCAO when respective atomic orbitals of the atoms interact, they undergo constructive and destructive interference giving two types of molecular orbital i.e, bonding and antibonding molecular orbitals respectively. Chemical Bonding Q33. Which of the following species is paramagnetic ? (A) No (©) CN Q34. Bond order of Be, 1 ©3 (Do Q35. Number of anti bonding electrons in N. wa (B) 10 (© 12 (D) 14 Paragraph # 3 (Q. 36 to 38) Bond angles can be explained by the electro negativity or by the size. Species with larger difference in electronegativity values between central and outer atoms have smaller bond angles. ‘As the size of outer atom inereases ,the angle increases. The size of central atom can also be used to determine the bond angles in the series. Q36. Consider the following molecules HO HS HSe H,Te @ (dy (di) (lv) the increasing order of bond angles is - (A)I

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