© CHEMISTRY | il Periodic Table S518 D eSaral.comwSaral Contents 1 Module Description 2 Homework Index 3 Exercise 1 4, Exercise 1A 5. Exercise 2 6 Exercise 2A 7 Answer Key Note Page - ii Page - ii Page - 1 Page - 6 Page - 11 Page - 15 Page - 19 Detailed solutions are available on the eSaral App. Periodic Table wWSaral & at wae area SlwSaral Periodic Table Module Description For mastering the concepts only learning is not sufficient. We have to practice and apply those concepts in problem solving. This sheet does just that. It contains a collection of problems segregated in the following exercises to help you master the concepts in a systematic and organized way. “Practice makes a man perfect” 1. Concept builder—1& 1A As soon as you have finished learning the concept do the problems from these exercises first These exercises contains easy level questions to help you build your concepts. 1 —+» Contains Single Correct Type questions 1A —» Contains pattern based questions incorporating the latest JEE Advanced based patterns like more than one correct, matching list, match the column, ete. 2. Brain Booster— 2 & 2A Now that you have built your concepts it’s time to master them by solving Brain Boosting problems, Don’t hurry through these problems. Take time to solve & learn from them. These exercises contains Medium & Tough level problems. Do questions from 2 & 2A after attempting I & 1A 2 —+ Single Correct Type questions. 2A ——» Pattern Based questions. 3. Simulator — JM & JA Contains questions from previous year JEE Mains & JEE Advanced questions in exercise JM & exercise JA respectively. Get the real taste & feel of the type of questions being asked in JEE. It’s a great tool for simulating your mind with JEE problems. These exercises are not included in the module but are provided separately. JM —» JEE Mains previous years topic wise questions. JA —+ IEE Advance previous years topic wise questions. Eee scat (rodwSaral Home Work Index Problem solving is an integral part of learning, Find questions to solve after each video in the homework Index. Make sure that you attempt all the problems (in Ex 1 to 2A) after learning a topic from the videos. For example if you have finished topic 8, first attempt all the problems listed in the index corresponding to topic 8 before proceeding to the video Periodic Table of topic 9. Sr.No.| Topic Name Ext Ex1A Ex2 Ex2A Introduction to Periodic 1 1-6 1,2 table 2 |Group, Period and Blocks | 7-16 |31,38,39,42,44] 1-68 | 6,23,25, 32 Periodicity,Effective Nuclear 3 |e and Atoms Reding | 1735.) 328,26 9,10 31 4 | Atomic Radius in Detail 4, 20-22 4,5,11-20] 1, 2, 28, 33, 34 5,7,9,17,18, |21,22,24,2 5 |Ionisation Energy 36-49 | 16 3s as. as 29 Applicatiopn of Tonisation 10, 14, 15, § Tenergy << 18-22, 35 7,.10-11, 14, 23, 3, 5, 8, 11, 16-17, 7 |Bkeetron gain Enthalpy 50°56 | 44,36,41,46. | 2926?9 | "24,07, 30, 36 12, 16, 27-30, 32, 4,7,9,12, 8 |Eleetronegativty 57-66 ee aan | 3032 16 9 lace 7,33 wWSaral & at wae area SlwSaral Exercise - 1 Periodic Table Concept Builder SINGLE CORRECT TYPE Q6. Each question has FOUR options for correct answer. ONLY ONE of these four options is correct option. For each question, choose the correct option 10 answer the question. Development of Pi ic Table a. @. Q3. Atomic wt. of P is 31 and Sb is 120. What will be the atomic wt. of As, as per Dobernier triad rule ? Q. (a) 151 (B) 75.5 (©) 89.5 (D) Unpredictable Which of the following set of elements follow Newland's octave rule ? (A) Be, Mg, Ca (B) Na, K, Rb Which are correctly matched ? (a) Eka silicon — Be (b) Eka aluminium — Ga (c) Eka mangenese ~ Te (d) Eka scandium ~ B (A) be (B) abd (Cad (D) All The places that were left empty by Mendeleev were for ? (A) Aluminium & Silicon (B) Galium and germinium (©) Arsenic and antimony (D) Molybdenum and tungstun The discovery of which of the following group of elements led to the failure of Rule of Octave? (A) Inert gases (B) Alkali metals (C) Transuranic element (D) Halogens (D) B, Al, Ga Q8. Quo. Qu. Atomic no. is the base of ? (a) Lother meyer curve (b) Newland octave rule () Modern periodic table (d) Doeberiener triad rule (Aa (B) ¢ @d (D)b Group, Period and Block Which of the following statement is wrong? (A) No inert gas is present in 7" period (B) 3” period contains 18 elements (C) 1" period contains two non metals (D) In p-block, metal, nonmetal and metalloids are present From the list given below, elements which belong to the same group or sub-group are? (A) Atomic number = 12, 20, 4, 88 (B) Atomic number = 8, 16, 34, 2 (©) Atomic number = 11, 18, 27, 5 (D) Atomic number = 24, 47, 42, 55 Which of the following set of elements belongs to same period ? (A)Zn,Cd,Hg (BY Fr, Ra, U (C) K, Ca, Ag (D) None There are 10 neutrons in the nucleus of the element ,M". It belongs to ? (A) block (B) s-block (C) &-block (D) p-block Elements upto atomic no. 118 have been discovered till now. What will be the electronic configuration of the element possessing atomic no.108 ? (A) [Rn]5f* 6° 7% (B) 6f% 7a* 78° (C) [Rn] Sf* 6a* 73° (D) [Xe] 4f* Se* 6s? wWSaral & at wae area a1wSaral Qu. For an element the quantum numbers of the last electron are : 1= 3, m =~ 2 and s = + 1/2. In which block of the periodic table is this element present ? (A) s-Block (B) p-Block (C) d-Block (D) £Block QI3. Elements with similar chemical properties? (A) Occur only within the same period (B) Have identical atomic mass (weight) (C) Have identical number of neutrons (D) Have the same number of electrons in the outer shell, QU4. As applied to periodic table, which of the following sets include only magie numbers? (A) 2, 8, 20, 28, 50, 82, 126 (B) 2, 8 & 18, 18, 32 (C) 2, 2, 8, 8, 18, 32 (D) 2, 8, 18, 18, 32, 32 QS. An clement recently discovered is Uub. Expected electronic configuration of the element is ? (A) [Kr] 584d" (B) [Xe] 6s°40"Sa* (C) [Rn] 785#%6d" (D) [Rn] 7s°Sf%a? QI6. Tendency of BrCl oxi and F to be ed is in order : (A) > Br > Cr > F (B) F >Cr >Br >t (© ch >F >Br >I (D) 1 =Br Na>K (C) Na> Li> K (B) K> Na> Li (D) Li< Na=K Which of the following has largest radius ? (A) 18%, 2s, 2p%, 3s? (B) Is*, 28°, 2p*, 38%, 3p! (C) 1s*, 28°, 2p*, 38%, 3p? (D) 1s, 28%, 2p, 38°, 3p" The ionic radii of N°, O° and F are respectively given by ? (A) 1.36, 1.40, 1.71 (B) 1.36, 1.71, 1.40 (©) 1.71, 1.40, 1.36 (D) 1.71, 1.36, 1.40 In which of the following compound, dlis- tance between two nuclei is maximum ? (A) CSE (B) KI (C) CsI (D) Lil Highest size will be of ? (A) Br (8) Br lr (I Which group of atoms have nearly same atomic radius ? (A) Na, K, Rb, Cs (C) Fe, Co, Ni (B) Li, Be, B, C (D) F, Cl, Br, I Arrange the elements in inereasing order of atomic radius Na, Rb, K, Mg ? (A) Na < K < Mg < Rb (B) K < Na M, (6) M, >M\, OM, > M% @) My 9M"y Minimum and maximum IP would be of ? (Aya, d (B) b, ¢ (C)e,d (D) da Which of the following electronic configura- tion belongs to least and most metallic character respectively ? (a) Is? 2s! (b) 5s? Sp* (c) 38° 3p* 4s! (d) 1s? 2s? aps (Aad (B) de Oda (Dyed The correct values of ionization energies (in kJ mol") of Be, Ne, He and N respectively are? (A) 786, 1012, 999, 1256 (B) 1012, 786, 999, 1256 (C) 786, 1012, 1256, 999 (D) 786, 999, 1012, 1256wSaral Electron Affinity Q50. Qsi. Qs2. Q53. Q54. Q55. 56. In the process Cl, + e&° —> Cl(g), AH is? (A) Positive (©) Zero (B) Negative (D) None In which ease the energy released is minimum ? (A) Cl > Ch (NN (B)P > P (D)C + C Which of the following is energy releasing process ? (A) Cl Cl(g) +e (B) O-(g) +¢# > O (O(g)> O'(@) +e (D)O@) +e > OL) Second electron affinity of an element is? (A) Always exothermic (B) Endothermic for few elements (©) Exothermie for few elements (D) Always endothermic Which of the following configuration will have lowest electron affinity ? (A) ns'np* (B) ns'np* (©) ns'np’ (D) ns'np* The electron affinity value for the halogens shows the following trend :— (A) CL> F> Br>T (B) FCl> Bro (D) Br> Cl> F > Which of the following element will form most stable bivalent anion? (A) Fluorine (B) Oxygen (©) Chlorine (D) Nitrogen Periodic Table Electronegativity Qs7. Q58. 59, Q60. Qot. Q02. Which of the following is affected by stable configuration of an atom :- (a) Electronegativity (b) Tonisation potential (©) Electron affinity Correct answer is (A) Only electronegativity (B) Only ionisation potential (C) Electron affinity and ionisation potential (D) Alll of the above The correct set of decreasing order of electronegativity is ? (A) Li, H, Na (C)H, Li, Na (B) Na, H, Li (D) Li, Na, H Outermost electronic configuration of the most electronegative clement is ? (A) ns'np? (B) ns'np* (©) as" (D) ns*np* On the Pauling’s electronegativity scale, which element is next to F ? cl (Bo (©) Br (D) Ne Which one of the following is incorrect ? (A) An element which has high electro- negativity always has high electron gain enthalpy (B) Electron gain enthalpy is the property of an isolated atom (C) Electronegativity is the property of a bonded atom (D) Both electronegativity and electron gain enthalpy are usually directly related to nuclear charge and inversely related to atomic size Select the group where EN increases down the group. = (A) Ca, Sr, Ba (©) FC, Br (B) Zn, Cd, Hg (D) Li, Na, K wWSaral & at wae area SlwSaral Periodic Table Q63. Calculate the bond length of C-X bond if | Q65. The lowest electronegativity of the e C~C bond length is 1.54 A and X-X bond from the following atomic number length is 1.2 A and electronegativities of C « is (A) 37 B) 55 and X are 2.0 and 3.0 respectively. i y @) 5 (A) 2.74 (B) 137A os (D) 35 (©) 146A (D) 1.28. A Q66, Select the correct order of acidie strength of Q64, The increasing order of acidie nature of oxic HAO, BO. B: (A) SO, > SO, > CO, (A) Li0 > BeO < BO, 2 2 (B) Li0 < Bed < BO, (B) Cs,0 > K,0 > Na, (© Li0 < BeO > BO, (©) CO, > N,0, > B,0, (D) Li,O > BeO > BO, (D) SO, > CO, > BO, Exercise - 1A Concept Builder ONE OR MORE THAN CORRECT | Q3. Which of the following represent the correct TYPE order (5) of effective nuclear charge ? (A)F>O>N>C (B)F Li (D)1>Br>F>Cl answer(s). ONE OR MORE THAN ONE of these four option(s) is (are) correct option(s). For cach | Q4, Which of the following represent the correct question, choose the correct option(s) to answer the order (5) of the radii? question. ee B) Atomic radii of Fe, Co, Ni - QI. The statements that are true for the long form itonigradii of Fe, Co, Niare approxi 2 mately equal of the Periodic table are (©) O>N>F (A) it reflects the sequence of filling the : electrons in the order of sub energy (D) Fe,’ < Fe,’ < Fe levels s, p,d & f (B) it helps to predict the stable valency | Q5. Considering the following ionisation steps: states of the elements A(g) > Ag) +e AH = 100 eV (©) it reflects trends in physical & chemical A(g) > A*(@) +e AH = 250 eV properties of elements Dyin helps t -, Select the correct statements : it helps to predict the relative ionicity ; " of the bond between any two elements. (A) IE, of A(g) is 100 eV (B) IE, of A°(g) is 150 eV Q2. Which of the following statements is/are (C) IE, of A(g) is 150 eV true about the long form of modern periodic (D) IB, of A(g) is 250 eV table? (A) Properties of the elements are the | 6, Which of the following are correct ? periodic function of their atomic number. (B) There are 7 periods. (C) There are 8 groups (D) Ithas separate position for the isotopes. (A) IE,(Mg) < IE, (Na) (B) IE (N) > IE (P) (C) Atomic size Mg"? >Atomic size(Mg") (D) IE of Na < Mg < AlwSaral Q7. Which of the following represent the correct, order of ionization energies ? (A)F>O>N>C_ (B)F>N>O>C (C)F>CI>Br>I (D) 1>Br>F>Cl Q8. Which of the following represent the correct, order of electron affinity ? (A)F>0 >C (B) Na>K>Rb (C) Cl>Br>1 (D) I> Br> F> Cl Process Na* > Na, —1> Na, (A) In (I) energy released (B) In (II) energy is absorbed (©) In (ID) energy is released (D) In (1) energy absorbed Q10. Which of the following ions is most unlikely to exist ? (A) Li Oe (B) F (D) Be” QUI. The electron affinity (A) Of carbon is greater than oxygen (B) Of fluorine is less than iodine (C) Of CI is less than Cl (D) OFS is more than oxygen Q12. Amongst the following statements, which is/ are correct? (A) Electronegativity of sulphur is greater than that of oxygen. (B) Electronegativity of oxygen is larger than that of sulphur. (©) Electron gain enthalpy of fluorine is most negative (D) Electron gain enthalpy of chlorine is most negative Q13. Which of the following statement is/are not correct? (A) LP. increases down the group (B) IP of s-block elements is less than corresponding d~ block elements Periodic Table (©) IFAIP >16 eV higher oxidation state is more stable (D) IP of halogen elements is maximum in their respective period QI4. Select equations having endothermic step - (A) S (g) > Sg) (B) Na’ (g) + Cl (g) > NaC) (C)N(Q)N (g) (D) AP’ (g) > AI (g) QUS. Diagonal relationship is shown by ? (A) Be and AL (B) Li and Mg (C) Mg and Al (D) B and P Q16. Two elements M and X (both from same period) form oxide M,O and X,O. If X,0 is acidic and M,O is basic then select CORRECT option(s) about M and X : (A) M> X (size) (B) (IE) X>M (©) (EN) M>X (D) (Acidic strength) MOH > XOH PARAGRAPH TYPE This section contains PARAGRAPHS, Based on each paragraph, there are questions. Each question has FOUR options. ONLY ONE of these four options corresponds to the correct answer: For each question, choose the option corresponding to the correct answer: Paragraph for (Ques. 17 to 19) The IE] and IEII in ki/mol of a few elements are given in the following table : Element | IE in kKJ/Mol | En in kJ/mol P an 5251 Q 520 7300 R 900 1760 Ss 1680 3380 wWSaral & at wae area SlwSaral QUT. Which of the above element is likely to be alkali metal ? (AVP (B)Q (OR (D)S QI8. Which of the above element is likely to be alkaline earth metal ? (A)P (B)Q (OR (@)s QU9. Which of the above element is likely to be noble gas ? (AyP (B)Q (OR (Ds Paragraph for (Ques. 20 to 22) A, Band C are hydroxy-compounds of the elements X, Y and Z respectively. X, Y and Z are in the same period of the periodic tabe. A gives an aqueous solution of pH less than seven, B reacts with both strong acids and strong alkalis. C gives an aqueous solution which is strongly alkaline. 20. Which of the following statements is/are true? 1. The three elements are metals. Il, The electronegativities decrease form X to YtoZ. IL. The atomic radius decreases in the order X, YandZ IV. X, Y and Z could be phosphorus, aluminium and sodium respectively. (A) 1, 1], Ml only correct (B) 1, Ml only correct (C) ILL, IV only correct (D) IL, IIL, IV only correct Q2I. Find out correct order of acedie strength in water. (A) HF > HCI> HBr > HI (B) HCI> HF > HBr > HI (©) HFO > HCIO > HBrO > HIO (D) HF < HCl < HBr < HI Periodic Table Q22, In the following hydroxy compounds which are present in paragraph. Find out maximum and minimum electronegativity of X, Y and Zz. (A) Zand X (B) Xand Y (©) Yand Z (D) All elements having same E.N. Paragraph for (Ques. 23 to 24) KI First electron gain enthalpy (in — of few elements are given below Elements ‘AHy i 60) iM a5 im 328 IV =295 Vv +48 Answer the following questions on the basis of above data: Q23. Which clement may be an inert gas ? @! Bl OV MV Qu. Which element is most non-metallic among all the elements ? (I (By om @iv Paragraph for (Ques. 25 to 27) According to I. C. slater effective nuclear charge , 2", due to screening , is not exactly equal to the actual nuclear charge Z of the nucleus of the atom. Z depends on the type of orbital in which the electron is housed , and on the ability of other electrons in more penetrating orbitals to screen the electron in question from the nucleus. The relative extent to which the various orbitals penetrate the electron clouds of other orbitals is s>p>d>f The effective nuclear charge Z° due to screening is given by , Z’ = Z —. Where Z is the atomic number and a is the slater screening constant values : 0< 0 < Z. on a (rodwSaral Q25, What is the value of Z’ for Rb (37) ? (A)1.7 (B13 (©)22 (D)348 26. What is 2° for last electron of Cu (29) ? (A)29 (B) 24.8 (©) 7.85 (42 Q27. In which of the following cases the concept of Z’ is applicable ? (A) lonisation energy increases as Z’ increases (B) Electronegativity of the atom increases as Z’ increases (C) Atomie size decreases along the period as Z" increases (D) All of the above Paragraph for (Ques. 28 to 30) The real meaning of the word periodic in any classification of elements is that when the elements are arranged in order of increasing atomic numbers in the same period or group there isa gradual change (ie. increase or decrease) in a particular pattern. In a period the gradual change of electronic Periodic Table configuration from member to member. Some of the properties which depends upon electronic configuration of elements such as screening effect, atomic radii, ionization potential, electron affinity ete, follow the general trend of periodicity, Q28, The correct order of ionic radii of the species Ny. O,, Na’ & Fis? (A) Na < F <0, 1> + (ByI> > (I> > b (D)I¥>L-> I MATCH THE COLUMN TYPE Following questions contain statements given in two columns, which have to be matched. The statements in Column-1 are labelled as A, B, Cand D while the statements in Column-II ave labelled as (P), (Q), (R) and (S). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-HI. Q31. Match Column-I (atomic number of elements) withColumn-II (position of element in periodic table) and select the correct answer using the codes given below : Column-I (A) 19 (B) 22 © 32 (D) 64 Column-II (P) p-block (Q fblock (R) d-block (S) s-block wWSaral & at wae area SlQ33. Q34. Q35. Q36. ‘Column-A. | Vertical column in periodic table A(g)+ Energy > A"(g) + Horizontal row in periodic {table A(g)te > A (g)+ Ener Periodic Table A(g)+ Energy |® [A (ye > A® ()+Enery, AZ(gye |) [FAL Column 1 Configuration Column-1 (A) Increasing ionisation potential (B) Increasing electronegativity (C) Decreasing 2.5 (D) Decreasing electron affinity Match the column Column-1 (aycl (B) F Oca (D) He Felectron gain enthalpy in kI/mol Column-1 (A) 66 (B) 333 © 99 (D) -348 Column-| (A) Increasing atomie size (B) Decreasing atomie radius (C) Increasing electronegativity (D) Increasing effective nuclear charge Column-Il Ionisation energy in k J/ mol (P) 2100 (Q) 1400 (R) 800 (S) 900 Column-I1 (P)Cl>S>P (QNC>N Column-I1 (P) Metal (Q Highest electron gain enthalpy (R) Most Electronegative element (S) Highest ionisation energy. Column-I1 @ cl QF (R) Be (Ss) Ne Column-I1 (P)C1O>FwSaral NUMERICAL TYPE Periodic Table IE, IE,, 1E,, IE,, IE,, IE,, EGE,, EGE, (IE = ionization energy, EGE = electron gain The answer to each question is a NUMERICAL enthalpy) VALUE. For each question, find the correct numerical value (in decimal notation, truncated/ | Q42. How many element belong to same group rounded-off to the second decimal place; e.g. 6.25, Na, Mg, K, Rb, N, O, C, Cs 7.00, -0.33, ~.30, 30.27, -127.30) Q43. Upto argon find the number of elements Q38. Find out the atomic number of element which have lower IE, as compared to He. whose IUPAC name is Unnilpentium. Q44,_ Element with atomic number 114, which . . : well known element would you expect it to Q39. A particular atom(not ion) having atomic resemble? Witte 4a siomic oumber number between 22 to 30 has magnetic (between Z=1 to 10). moment equal to 1.73 B.M. Then find the . atomic number of the element which is next to it in the periodic table. SUBJECTIVE TYPE Q40. Select total number of acidic compounds out | 245+ The Ist ionisation energy of potassium is of given below - less than that of Cu but the reverse is true for 2nd ionisat CsOH, OC(OH),, $0,(OH), , Sr(OH),, — _ Ca(OH), , Ba(OH), , BOH, NaOH, O,NOH 2(OH),, Ba(OH),, BOH, NAOH, O, Q46. Of the two elements given in each of the | following sets choose the element having a Q41. Total number of enthalpy(s) (out of given more negative electron gain enthalpy. eight) of A(g) which is/are not associated (A)Nando (B) Fand Cl with conversion of A. > A..*: Exercise - 2 Brain Booster SINGLE CORRECT TYPE Q2. Among the following, which species is/are paramagnetic ? Each question has FOUR options for correct @ sr @ Fe" answer: ONLY ONE of these four options is correct (iil) Co” (iv) S option. For each question, choose the correct option (v) Pb* 10 answer the question. (A) ii, v (B) i, i, ii (©) ii, ii (D) iv, v QL. The number of d- electrons in Mn** is equal to that of = Q3. The correct order of stability of Al’, AI®, (A) p-electrons in N (B) s-electron in Na (C) d-electrons in F (D) p-electrons in 07 Al is ? (A) AP? > AP? > AL (B) AI? > AIS > AL (©) Al? < AP > Ale (D) APS > AP > AL? wWSaral & at wa ae Sl¥S. 4. Qi. Qs. aral A transition element X has the configuration [Ar] 34° in its +3 oxidation state. Its atomic number is ? (A) 25 (2 (B) 26 (D) 19 Which of the following lanthanoid ions is diamagnetic? Ye = 58, Sm = 62, Yb =70) IfAufbau and Hund’s ru Incorrect statement is : are not used, then (A) K* would be coloured ion (B) Na will be in sume s-block (if these rules are true) (C) Cu would be s-block element (D) magnetic moment of Cr (24) would-be zero Which of the following arrangements shows the correct order of decreasing paramagne- tism ? (A) N>Al>O>Ca (B) N>O>Al>Ca Oo (D) O>N>Ca>Al N>AI>Ca Total number of p block elements among given atomic number 83, 79, 42, 64, 37, 54, 34 are? (ay3 (5 (B)4 (6 Rank the 4p, 4d and 4f orbitals of increas ing degree to which the electrons present in them are shielded by inner electrons ? (A) 4d>4f > 4p (B) 4f > 4d> 4p (C) 4p>4d> af (D) 4d>4p > 4f Quo. Qu. Qi2. Qu3. Qu. Periodic Table Which of the following option is correct ? [State T for true and F for false} () On moving from left to right in a pe- riod screening constant value increases (ii) Ins, p, d, orbitals the order of screen- ing effect is s > p > d> fina given shell (iii) In any period from left to right e! tive nuclear charge increases so elec- tronegativity also increases (iv) When increases, Z,,, also increase (A) TTTE (B) FFFT (©) FFTT (D) TTFF 0 Which of the following order is incorrect against the property indicated ? (A) Mg < Ar < Na 2nd LE.) (B) Be < F < C1 (AH.,) (C) Rb < Na < K < Ca (atomic radius) (D) P Be>C# (B) A?= B= Cc (D) B8< A2= C4 The radii of F, F,O and O* are in the order of? (A)? >F > F>0 (B)F >0>F>0 (C)O°>0>F->F (D) 0? >F >O>FwSaral Qs. Q16. ut. ais. Qis. Q20. Arrange the following in order of increasing atomic radii Na, Si, Al, Ar := (A)Na 2>3> 4. Species which are present at 1 and 4 position respectively are (A) Al, Mg (C) Mg’, Al (B) Mg, AP (D) Mg, AP* Reason of lanthanoid contraction is ? (A) Negligible screening effect of 'f orbitals (B) Increasing nuclear charge (C) Decreasing nuclear charge (D) Decreasing sereening effect For the element (X), student (A) measured its readius as 102 nm, student (B) as 103 nmand (C) as 100 nmusing same apparatus. Their teacher explained that measurements were correct by saying that recorded values by (A), (B) and (C) are (A) erystal, van der Waals and covalent radii (B) covalent, crystal and van der Waals radii (C) van der Waals, (D) none is correct nic and covalent Largest in size out of Na* , Ne and F> is: (A) Na® (B) Ne Or (D) all are equal ‘The single covalent radius of P is 0.11 nm. The single covalent radius of Cl will be : (A) smaller than P (B) greater than P (C) same as P (D) twice of P Qu. Q22. Q23. Qu. Qs. Q26. Periodic Table Amongst the following, the incorrect statement is ? (A) IE, (AD < IE, (Mg) (B) IE, (Na) < IE\(Mg) (C) IE, (Mg) > IE, (Na) (D) IE, (Mg) > IE, (Al) Four successive members of the first row transition elements are listed below with their atomic numbers. Which one of them is expected to have the highest third ionization enthalpy ? (A) Vanadium (2 = 23) (B) Manganese (Z = 25) (C) Chromium (Z = 24) (D) Iron (Z = 26) Electronegativity and electron affinity of an element A are X and Y respectively. Hence, ionisation potential of A is : wa (©2v-Y (B) 2X-Y (D) 2X +¥ Correct order of L.E. in Ni, Pd and Pt (A)Pt>Pd>Ni—(B) Pt> Ni> Pd (C)Ni>Pd> PL (D) Pd> PL> Ni Following the transition elements, (IE), drops abruptly in Ga, In and TI. This is due to: (A) decrease in effective nuclear charge (B) increases in atomic radius (C) removal of an electron from the singly occupied np orbitals of higher energy than the ns-orbitals of Zn, Cd and Hg. (D) none is correet The second electron gain enthalpies (in kJ mol) of oxygen and sulphur respectively are : (A) — 780, + 590 (C) +590, + 780 (B) - 590, +780 (D) +780, + 590 wWSaral & at wae area a1wSaral Qa7. Q28. Qs. Q30, Qi. Increasing order of Electron affinity for following configuration, (a) Is*, 2s? 2p* (b) Is", 2s* 2p! (©) Is, 2° 2p* 38° 3p" (d) 1s*, 2s? 2p%, 38° 3p? (A)d CuOF (N>P (D) C>N Q4. AB exists as Av B- if (A) (IP), < (IP), (B) (EA), < (BA), (©) (EN), < (EN), (D) Size of A < size of B QS. Select the correct statement(s). (A) The value of electron gain enthalpy of an element can be -ve or +ve. (B) In the periodic table, metallic character of the elements increases down the ‘group and decreases sacross the period. (C) The CI” & S* are isoelectronic species but first one is not smaller in size than the second. (D) Ionization enthalpy of an atom is equal to electron gain enthalpy of cation. Q6. IfAufbau’s principle and Hund’s rule were not followed. (A) K would have been a d-block element & a paramagnetic substance (B) Cu would have been a s-block element. (©) Cr would have been a diamagnetic substance (D) None of these Q7. Which of the following show amphoteric behaviour ? (A) Z(H), (© ALO, (B) BeO (D) Pb(OK), Electron affinify of the elements or ions shown correct are ? (A)S> 0 ()O>s (B)O>S (D)N >S Inhalogens, which of the following proper- ties increases from iodine to fluroine ? (A) Ionisation energy (B) Electronegativity (C) Bond length (D) Electron affinity Q10. Inwhich of the following set of elements 1" clement is more metallic than second ? (A) Ba, Ca (B) Sb, Sn (©) Ge, (D) Na, F QUI. Which of the following order is correct (A) P< Si < Be < Mg < Na (Metallic character) (B) Mg? < Na < F< 0 (lonie radius) (©) Li [X, — Xj then A-O-H_ shows basic nature (NaOH) IX, — X,| < |X, - X,/ then A-O-H shows acidic nature (H-O-Cl) With the help of EN values [EN, = 1.8, EN, = 2.6, EN, = 1.6, EN, = 2.8] answer the following questions for the compounds HAO, HBO, HCO, HDO. Q12. Compounds whose aqueous solution is acidic and order of their acidic strength is? (A) AOH, COH; AOH < COH (B) HDO, HBO; HDO > HBO (C) AOH, COH; AOH > COH (D) HDO, HBO; HDO < HBO Qu. Compounds whose aqueous solution is basic and order of their basic strength is ? (A) AOH, COH; AOH < COH (B) HDO, HBO ; HDO > HBO (C) AOH, COH ;AOH > COH (D) HDO, HBO ; HDO < HBO Paragraph for (Ques. 14 to 17) Four elements P, Q, R & S have ground state electronic configuration as: Periodic Table PIs! 2s! 2p 38° 3p? 3p* 3d" 4s* 4p" S Is? 2s? 2p% 3s? 3p* 3d'° 4s* 4p! Q14. Comment which of the following option represent the correct order of true (T) & false (F) statement I size of P < size of Q Il size of R < size of S III size of P < size of R (appreciable difference) IV size of Q < size of S (appreciable difference) (A)TITT (B) TTTE (C) FFTT. (D) TTFF QUIS. Order of IE, values among the following is? (A)P>R>SeQ — (B)PS>P>Q_ (D)P>S>R>Q Q16. Considering the elements F, Cl, O and S correct order of their electron affinity value is- (A)F>Cl>O>S (B)F>O>CI>S (C)\Cl>F>S>0 (D)O>F>s>Cl QI7. Which process involves maximum release of energy ? (A)O,+e +0, (COE, +e 98, (B)S, +e FS, (D) Cl te Ch, Paragraph for (Ques. 18 to 23) Ionization energies of five elements in keal’mol are given below : Atom I 1 M1 P 300 549 920 Q 99 734 1100 R 18 1091 1652 176 347 1848 T 497 947 1500 Get Top Ranks in IIT-JEE/NEET/10"wSaral QI8. Which element is a noble gas ? (AP (B)T (CR (D)S Q19. Which element form stable unipositive ion? (AP (B)Q (OR (D)s Q20. The element having most stable oxidation state +2 is ? (AQ (BR Os (D)T Periodic Table Q21. Which is a non-metal (excluding noble gas)? (A) P (B)Q OR (D)s Q22. If Q reacts with fluorine and oxygen, the molecular formula of fluoride and oxide will be respectively ? (A) QF, Q0, (B) QF, QO (©) QF, QO (D) None of these Q23. Which of the following pair represents elements of same group ? (AQR (B) P,Q (RS (D) QS MATCH THE COLUMN TYPE Following questions contain statements given in two columns, which have to be matched. The statements in Column-I are labelled as A, B, Cand D while the statements in Column-H ave labelled as (P), (Q), (R) and (S). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-II. Q24, Match the characteristics mentioned in Column II with the process in Column I. Column-I (A) 0 (g) +e +O (g) (B) O (g) +e + OF (g) (C) Na (g) > Na(g) +e (D) Mg" (g) + & — Mg (g) Column-II (P) Positve electron gain enthalpy (Q) Negative electron gain enthalpy (R) Exothermic (S) Endothermie Q25, Column-I Column-It (Consider elements of 4" period) (A) Number of elements which have ns' configuration (P) 4 (B) n + | for last electron of last element (Qs (C) Maximum unpaired electron in any of the element (R) 6 (D) (n+ 1) for outermost electron of 1" element (S)3 Q26, Column-I Column-II (A) Fe < Fe? < Fe® (B)O Cl for 6,023 x 10 atom (IP for Cl = 1250 kj mole! and EA = 350 KJ mole”) on P: (rodwSaral Answer Key Periodic Table Ex-1A 1, ABCD 2. AB 3. AC 4. ABD 5. ABC 6. AB 7. BC 8. ABC 9. AC 10. D 11. CD 12. BD 13. ACD 14. ACD 15. AB 16. A,B 17.B 18.C 19. A 20..C 21.D 2A 23.D 24,.C 25.C 26.C 21.D 28.A 29. 30.A 3L.A>S,B5R,C>PRD+Q 32. (A) > IV, (B) > I, (C) > II, (D) > VE) > VI(F) > IL 33. (A) > S, (B) > R, (©) + Q, (D) > PP 34. (A) > R, (B) > Q, (©) +P (D) > S 35.A5QBOR,C>RDOS 36.A3R,B>QC3S,D>P 37. (A) +R (B) + S(C) +P (D) +Q 38. 105, 39.30 40. 4 (OC(OH),, SO(OH),, BrOH, O,NOH), 41.3 (EGE,IE,, IE,,) 42. 4 (Na, K, Rb,Cs) 43. 017 44. 6 46. (A)-O (B)-Cl wWSaral & at wae area SlwSaral Periodic ‘Table Ex-2A 1. A,B,C.D 2. A,B,D 3.AB 4. A,B,C 5. A,B,D 6. A 7. ABCD 8.AB 9. A.B 10. A,C.D 1. A.B 12.B 13. 14. B 15,4 16. C 17.D 18. B 19. BC 20. C 2A 22.B 23.A 24. (A) > QR, (B) > PS, (C) > S, (D) > QR 25.A>S,B>Q,C3R,D>P 26. (A) > P.QR, (B) > R, (©) > S. (D) > PT 27.4 28.0 29.3 30.7 31.3 32. 101-Unu, 102-Unb, 103-Unt, 104-Ung, 105-Unp, 106-Unh, 107-Uns, 108-Uno, 109-Une 33. Mn"? < Vs < Ca" < K’ Ge Cs