: a Redox Reaction 2 Ee Z - a a: O Ns 18 eSaral.comwSaral Contents 1 Module Description 2 Homework Index 3 Exercise 1 4, Exercise 1A 5. Exercise 2 6 Exercise 2A 7 Answer Key Note Page - ii Page - ii Page - 1 Page - 5 Page - 10 Page - 14 Page - 17 Detailed solutions are available on the eSaral App. Redox Reaction wWSaral & at wae area SlwSaral Redox Rea Module Description For mastering the concepts only learning is not sufficient. We have to practice and apply those concepts in problem solving. This sheet does just that. It contains a collection of problems segregated in the following exercises to help you master the concepts in a systematic and organized way, “Practice makes a man perfect” 1. Concept builder—1& 1A As soon as you have finished learning the concept do the problems from these exercises first. These exercises contains easy level questions to help you build your concepts. 1 —+ Contains Single Correct Type questions 1A —» Contains pattern based questions incorporating the latest JEE Advanced based patterns like more than one correct, matching list, match the column, ete. 2. Brain Booster— 2 & 2A Now that you have built your concepts it’s time to master them by solving Brain Boosting problems, Don’t hurry through these problems. Take time to solve & learn from them. These exercises contains Medium & Tough level problems. Do questions from 2 & 2A after attempting I & 1A 2 —+ Single Correct Type questions. 2A ——» Pattern Based questions. 3. Simulator — JM & JA Contains questions from previous year JEE Mains & JEE Advanced questions in exercise JM & exercise JA respectively. Get the real taste & feel of the type of questions being asked in JEE. It’s a great tool for simulating your mind with JEE problems. These exercises are not included in the module but are provided separately. JM —» JEE Mains previous years topic wise questions. JA —+ IEE Advance previous years topic wise questions. crn noone Page ii (rodwSaral Home Work Index Problem solving is an integral part of learning, Find questions to solve after each video in the homework Index, Make sure that you attempt all the problems (in Ex 1 to 2A) after learning a topic from the videos. For example if you have finished topic 8, first attempt all the problems listed in the index corresponding to topic 8 before proceeding to the video Redox Reaction of topic 9. Sr. No, Topics Ex-1_ | Ex-lA | Ex-2 | Ex-2A 1 Introduction to Redox Reactions 1 wy 1-4, 10-18, 1,2,16,17, 2 (Oxidation and Reduction 2-17 20,21,27.28| 1-20 19 3 | Types of Redox Reactions 18-21 | 5,6,22,23 3 12,13, 4 [Balancing of Redox reaction 22-24 24 21-27 | “59 5 _ |lometectron Method ofbaancing redox] 45 46 | 9509 | 2909 | o12 reactions 6 [Equivalent Weight 27-36 26 30-39 7 |Normality And It's Applications 37-41 7,19 78,18 8 Titration, lodometry, lodimetry 42-45 89 40,41 15,9-11,15 9 |acc 46 - 53 42-45 | 46,14 wWSaral & at wae area SlwSaral Exercise - 1 Redox Reaction Concept Builder iG (ORRECT TYPE Q6. Each question has FOUR options for correct answer. ONLY ONE of these four options is correct option. For each question, choose the correct option 10 answer the question. Introduction to Redox Rea qr. QI. Redox Means- (A) Oxidation (B) Reduction (©) Oxidation + Reduction (D) None of These Qs. Oxidation and Reduction Q2. IF HO, the oxidation state of oxygen is ? A2 BH ©-1 wi |e Q3. Which of the following is a reducing agent in the given reaction :- HgCl, + Sn —> SnCl, + Hg (A) Sn (B) Hg joc (D) Both (A) & (B) Q4. Oxidation number of Cl in CaOCl, (bleaching powder is) (A) Zero, since it contains Cl, (B) -1, since it contains Ct (C) +1, since it contains C1O- (D) +1 and -1 since it contains CIO- and Ct QS. Which of the following groups of molecu- les act both as oxidising agent as well as reducing agent:- (A) KMn0,, 0,, SO, an. (B) HCIO,, HNO, HY (©) HNO,, SO,, Hy (D) HNO, SO,, H,SO, Quo. Qu. Which of following statement are correct :- (A) Oxidation number of Os in OsO, is +8 (B) Oxidation number of $ in H,SO, is +6 (C) Oxidation number of sulphur in H,S,0, is +6 (D) Alll of these The oxidation states of S-atoms in Caro's and Marshell's acids are :- (A) +6, +6 (B) +6, +4 (C) +6, -6 (D) +4, +6 The oxidation no. of oxygen atom in is @- (B)2 3 (D)-s Which of these substances is a good reducing agent:- (A) NaOCl (B) HI (©) FeCl, (D) KBr The oxidation state of S in Na,S,O, is (A) #25 (B) +2 and +3 (two S have +2 and other two have +3) (C) +2 and +3 (three S have +2 and one $ has +3) (D) +5 and 0 (two $ have +5 and the other two S have 0) Oxidation number of oxygen in F,O is : (Ay (By +2 ©-l (D) -2 An element, which never has a positive oxidation state in any of its compounds, is: (A) Boron, (B) Oxygen (C) Chlorine (D) Fluorine wWSaral & at we area SlwSaral Qu3. Qi. as. Que. Qi7. The compound which could not act both as oxidising as well as reducing agent is:- (A) So, (B) M0, (C) ALO, (D) HNO, In the reaction, Cl, + OH > Cl + ClO, + H,0, chlorine is (A) Oxidised (B) Reduced (C) Oxidised as well as reduced (D) Neither oxidised nor reduced When P reacts with caustic soda, the products are PH, and NaH,PO,, The reaction is an example of (A) Oxidation (B) Reduction (C) Both oxidation and reduction (D) Neutralisation The oxidation number of Pt in [Pt (C,H,)CL} is- (A+ (B22 (+3 (D)+4 Consider the following oxyacids of phosphorus (A) Orthophosphoric acid (B) Hypophosphoric acid (C) Orthophosphorous acid (D) phosphine In which of these acids, P is not present in +4 oxidation state ? (A) 2 and 3 (C) 3 and 4 (B) 2,3 and 4 (D) 1, 3 and 4 Types of Redox Reactions as. Which of the following is not a redox reaction? (A) Cu + > Cus (B) Cur + S* > Cus (C) Zn + CuSO, > + ZnSO, + Cu (D) All of these Qi. Q20. Qu. Redox Reaction Which of the following process represents, disproportionation ? (A) Cu + 4HNO, > Cu(NO,), + 2NO, + 2H,0 (B) 31, + 6OH > 10, + SI + 3H,0 (D) Zn + 2HCI— ZnCl, + H, The metals which can undergo dispropor- tionation are - aSn b Na c.Cu d. Ca (Aa (B)ad Cab (D) All of above A,B, Cand D are four metals. A.can displace D from its salt solution, but B and C cannot displace D. B can displace hydrogen (H) for a dilute solution of a mineral acid, but C cannot. The reduction potentials ofA, B, C, D and H (ie., hydrogen) are in the order : (A) C>H>B>D>A (B)A>B>C>D>H (C)A>D>B>H>C (D) H>A>C>D>B Balancing of Redox Reaction Q22. Q23. In the balanced reaction; xBrO3 +yCr*} +zH,0 —> aBr, +bHCr0j +cH™ the coefficients x, y and z are:- (A) 6,8, 22 (B) 6, 10, 22 (©) 6,7, 14 (D) 7, 10, 20 For the redox reaction MnO, +C,02 +H > Mn®* + CO, + H,O, the correct coefficients of the reactants for the balanced equation are MnO, C02 Ht A 2 5 16 (®) 6 5 2 © 5s 6 © 2 6wSaral Q24, In the redox reaction : x KmnO, + y NH,» KNO, + MnO, + KOH +H (A) 4, y=6 (B)x=8, y=6 (C)x=3, y=8 (D)x=8, y=3 Jon - electron Method of Balancing Redox Reactions Q25. The reaction of KMnO, and HCI results in:- (A) Oxidation of Mn and production of Cl, (B) Reduction of Mn and production of H, (C) Oxidation of Mn and production of H, (D) Reduction of Mn and production of Cl, Q26. In the balanced chemical reaction, 10, +aT + bi’ > cH0 + dl, a, b, ¢ and d respectively correspond to :- (A) 5, 6, 3,3 (B) 5,3,6,.3 (C)3, 5,3, 6 (D) 5,6, 5,5 Equivalent Weight Q27. The number of Fe* ion oxidised by one mole of MnO; ion is :- yt @w2 os we A; BF OS WF Q28. Number of moles of MnO; required to oxidise one mole of ferrous oxalate comple- tely in acid medium will be - (A) 7.5 moles (B) 0.2 moles (©) 0.6 moles (D) 0.4 moles Q9. The equivalent mass of H,PO, in the following reaction is : HPO, + Ca(OH), —> CaHPO, + 2H,0 [P =31] (A) 98 (B) 49 (©) 32.66 (D) 40 Q30. Qa. Q32. Q33. Q34. Redox Reaction Equivalent weight of FeS, in the half reaction, FeS, > Fe,0, + SO, is : (a) M10 (B) M/11 (©) M6 (DM The equivalent weight of an element is 4. Its chloride has a vapour density 59.25. The valency of the element is :- (Ay4 (B)3 ©2 (D)1 Hydrazine reacts with KIO, in presence of HCl as; NH, +10, + 2H + Cl —+ ICl+N, + 3H,0 ‘The equivalent masses of N,H, and KIO, respectively are :- (A) 8, 87 (©) 16, 53.5 (B) 8, 35.6 (D) 8, 53.5 Equivalent weight of H,PO, when it disproportionate in to PH, and HPO, is :- (A)M (B) M/2 (C) M4 (D) 3M/4 When potassium permagnate is titrated against ferrous ammonium sulphate in acidic medium the equivalent weight of potassium permagnate is Molecular weight (A) 3 Molecular weight 5 Molecular weight 2 ) 10 M (A) 3 wWSaral & at we area SlwSaral Q36. In the standarization of Na,S,O, using , by iodometry the equivalent mass ‘ay Memass py Memass Ay B)— | M. mass. (Cc) 3 (D) Same as M. mass Normality and Eq lent Concept Q37. How many moles of hydrazine can be £ oxidized into N, using 3 mole of bromate ions (BrO, — Br ):- ayt B) 1 AW; (B) 2 (us OF 3 Q38. 6 « 10° mole K,Cr,0, reacts completely with 9 x 10° mole x" to give XO, and Cr”. The value of nis :~ (A)l (B)2 (©3 (D)4 39, If0.5 g ofa metal on oxidation formed 0.79 £ of its oxide, then equivalent weight of the metal is = (A) 10 (B) 14 18 (D) 22 Q40. Three solutions of HCI having normality 12 N, 6N and 2N are mixed to obtain a solution of 4N normality which among the following, volume ratio is correct for above three components ? (A) 1:2 (B)2:1:9 (C)1:2:4 (D) 1:5 QAI. How muchof NaOH is required to neutralise 1500 em’ of 0.1 N HCI (At. wt. of Na =23), (4g (B) 6g (©) 40g (D) 60g Redox Reaction ‘ation, lodometry, lodimetry Qa. KMn0, reacts with ferrous ammonium sulphate according to the equation MnOj +5Fe** +8H* > Mn?* +5Fe** +410, here 10 ml of 0.1 M KMn0, is equivalent to- (A) 20 ml of 0.1 M FeSO, (B) 30 ml of 0.1 M_ FeSO, (©) 40 ml of 0.1 M_ FeSO, (D) 50 ml of 0.1 M_ FeSO, Q43. 100 ml of 0.1 N hypo decolourised iodine by the addition of z g of crystalline copper sulphate to excess of KI. The value of ' is, (molecular wt. of CuSO,.5H,O is 250). (A) 5.02 (B) 1.25 g (C)25¢ (D) 4g Q44, 1.575 g of (COOH), . XH,O are dissolved in water and the volume is made upto 250 mi, On titration 16.68 ml of this solution are required for the neutralisation of 25 ml of N js NaOH. Caleulate the value of X :- (A)3 (2 (B)1 (D)5 Q45. 5 ml of N HCI, 20 ml of N/2 H.SO, and 30 ml of N/3 HNO, are mixed together and volume made to one litre. The normally of the resulting solution N N N N AZ By On OD ACC Q46. Fe shows an oxidation state of +1 in + (A) Fe(CO), (B) [Fe(H,0),NO]SO, (©) Fe{Fe(CN),], (D) FeCl,wSaral Q47. Oxidation of Na is ? (A) Addition of hydrogen to sodium (B) Addition of oxygen to sodium (C) Addition of chlorine to sodium Qsi. (D) All the above Q48. Acompound contains atoms A, Band C. The oxidation number of A is + 2, of B is + 5 and C is -2. the possible formula of the | Q52, compound (A) ABC. (B) B(AC.), (C) AYBC), (D) A(B,C), Q49, Equivalent mass of oxidising agent in the reaction, SO, +2H,S > 3S +2H,O is - Redox Reaction (A) 0.5 mole (B) 0.9 mole (©) 1.2 mole (D) 4.5 mole Oxidising product of substance Na,AsO, would be (A) As," (B) AsO,? (©) AsO, * (D) AsO, Bleaching a (A) Reduction (B) Oxidation (©) Hydrolysis (D) Acidic nature : Q53. In alkaline medium CIO, oxidises H,O, to (A)32 (B64 (O16 (DB O, and itself gets reduced to Cr. How many moles of H,O, are oxidised by 1 mole of Q50. 1 mole of equimolar mixture of ferric clo, ? oxalate and ferrous oxalate will require x (Al (B) 1s mole of KMnO, in acidie medium for 25 (035 complete oxidation, x is = Exercise - 1A Concept Builder ONE OR MORE THAN Q3. Which of the following compounds is/are ONE CORRECT TYPE Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are) correct option(s). For each | eg, question, choose the correct option(s) to answer the question. QI. Which molecule have underlined atoms in their highest oxidation state’ (A) Hy820s (B) P,Ojo (©0, (D) Mn30, QZ. Inwhich ofthe following compounds further oxidation is possible? (A) Feo (B) FeO, (C) So, (D) Cro, oxidising agent? (A) KMn0, (B) KI (© Kr, (D) K.C.0, In which of the following species the O.S. of the carbon is/are equal to + 2 only (AH N (B)H-NSC © (D) 0=C=C=C-O Which of the following are disproportionation reaction (A) HO ——> Hg +0, (B) KC]. KCI + 0, (C) KClo, —> KCIO, + KCI (D) Cl, + OH” ——> ClO-+ CF + HO example of wWSaral & at wae area SlSa ral Which of the following is (are) not the redox reaction (s) ? (A) NaBr + HCL—> NaCl + HBr (B) HBr + AgNO, —> AgBr + HNO, (C)H, + Br, —> 2HBr (D) Na,O + HSO, —> Na,SO, + H,O Which of the following statements is/are correct? (A) molar ratio = — tor ratio (B) no, of equivalents = moles * n-fuctor (C) nefactor of H,PO, is 3 (D) n-factor of HBO, is 3 For the reaction H,PO, + Ba(OH), —> BaHPO, + 2H,0 The correct statement (s) is/are (A) The equivalent mass of HPO, is 41 (B) BaHPO, is the acid salt (C) BaHPO, is normal salt (D) 1 mole of H,PO, is completely neutrali- sed by 1.5 moles of Ba(OH), Choose the correct statements — (A) Copper sulphate sol ina zine ve mn can be stored (B) Copper sulphate solution can be stored ina nickel vessel. (C) Copper sulphate solution can be stored ina silver vessel. (D) Copper sulphate solution can be stored in a gold vessel. PARAGRAPH TYPE This section contains PARAGRAPHS. Based on each paragraph, there are questions. Each question has FOUR options. ONLY ONE of these four options corresponds to the correct answer. For each question, choose the option corresponding to the correct answer: Redox Reaction Paragraph For Q. 10 to 14 Oxidation reduction reaction are those in which oxidation reduction take place simultaneously. Oxidation and reduction are determined by the oxidation number, The oxidation state of any element can never be fractional, if oxidation number of any element comes out be in fraction, it is the average oxidation number of that element which is present in different oxidation states. Quo. The Fe,O, is the mixed oxides containing FeO & Fe,O,, therefore oxidation states of Fe in Fe,O, are- (A) #2 and +3 (B) +8/3 (+2 (D) +3 QIL. The structural formula of hydrazoie acid is, represented as > Non Therefore oxidation states of N', N° and N° respectively are - (A) 0, 0,3 (B) 0,0,-1 Oud (D)-3,— Q12. The equivalent weight of Na,$,O, in the following reaction is Na,$,O, + 2HC1— 2NaCl+H,0 +$ +80, Given : molar mass of Na,$,0, = M aw @* ot o™ “ Bz, OF OF QI3. Oxidation state of Cl in CaCI, is? (ayo (B)-1 (©) +1 and 1 (D) +1 Q14,_ In which of the following reactions H,0, acts as a reducing agent. (A) HO, + 2H? + 2e — 2H,0 (B) H,O,~2e° —, 0, + 2H" (C) H,0,+2e —+ 20H on (rodwSaral Paragraph for Q. 15 to 17 Observe the following reactions and answer the following questions. ()—_Zn(s)-+ PCI, (aq) —> Pb(s) + ZnCl (aq) (ii) 2Fe** (aq) + 21” (aq) —> 1 (aq) + 2Fe** (aq) (iii) 2Na(s)+Cl,(g)—>2NaC(s) (iv) Mg(s) + Clz(g) —> MgCl (s) (v)— Zn(s)+2H* (aq) —> Zn?* (aq) + H2(g), Q15. Which reactants are oxidising agents — (1) Pb* (2) Fe® (aq) @) CL) (4) Haq) Qi6. Qu. Redox Reaction (B) 1,23 (D) 1,2 (A) 1,234 OL34 Which reactants are reducing agents ~ () Zn (2)F (aq) G) Cig) (4) H (aq) (A) 1.2.3.4 (B)1,2,3 (13.4 (D) 1,2 Which of the following species can be oxidised ~ (1)Na Q)Mg yr (@)H (A) 1.2.3.4 (B) 1,2,3 (134 (D) 1,2 MATCHING LIST TYPE Each question has TWO (02) matching lists: LIST I and LIST Il. FOUR options are given representing matching of elements from LIST I and LIST H. ONLY ONE of these four options corresponds to a correct matching. For each question, choose the option corresponding to the correct matching. Q18. Compounds O.N. List-t (A) KMn0, (B) Ni(CO), (© [Pt(NH, CL ICI, (D) Na, Os List-II () +4 (2) +7 (3) 0 @) -1 The correct code for the O.N. of asterisked atom would be : A BC (a) 1 (B) 4 «© 2 4 2 3 3 (D) 1 D 304 2 1 1 4 2 3 wWSaral & at wae area SlwSaral Q19. Match the Column-I with Column-II — Column-1 (Redox process) (a) As,S; > As0; +80} (b) Lo +105 (©) H,PO, PH, +2H,P0, (d) H,PO, + NaOH + Nall,PO, +11,0 (A) as; b-p; e-q; der (Cas: bp en dq MATCH THE COLUMN TYPE Redox Reaction Column-IL (n-factor for underlined species) (p) 28 @ 43 1 ©) 53 (B) a-p; ber; e-g; des (D) ap; bs: eq; dr Following questions contain statements given in two columns, which have to be matched. The statements in Column-I are labelled as A, B, C and D while the statements in Column-II are labelled as (P), (Q), (R) and (S). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-II. Q20. Match the half-reactions (in column- I) with change in oxidation number (in column- II) : Column I (A) Cl —> Clo, (B) Ce —> Cr0, (C)H, —> 0, (D) Cr0,* —> Crt Q21. Match the column correctly Column I (A) Change of Cr,0? to CrO,* (B) Change of BrO, ' to BrO, (C) Change of $,0, (D) Change of Cu,0 to CuO Qn. Match the column correctly — Column 1 (A) 03? —> 0, +07> (B) CO} +H* —> (C) MnO4 +NO3 +H* —> (D) » (05 + HS, +Fe** —> Column I (P)2 @s (R)O (S)3 Column I (P) Oxidation (Q Reduetion (R) Neither reduction nor oxidation (S) loss/gain of 20~ Column IT (P) redox reaction (Q) One of the species undergoes only oxidation (R) One of the species undergoes only reduction (S) disproportionation, TeddwSaral Redox Reaction Q23. Column I Column I (A) (NH),Cr,0, > N, + Cr,0, + 41,0 (P) Intermolecular redox reaction (B) PbO, + H,O > PbO + (Q Disproportionation (©) Cr,0, + 2Al> (R) Intramolecular redox reaction (D) Cl, + 20H > ClO + Ch +H,0 (S) Metal displacement NUMERICAL TYPE Q27. Statement 1: The answer to each question is a NUMERICAL VALUE. For each question, find the correct numerical value (in decimal notation, truncated/ rounded-off to the second decimal place; e.g. 6.25, 7.00, -0.33, ~.30, 30.27, -127.30) Qua. 25. Q26. ASSERTION AND REAS¢ (a) (B) «) (D) How many electrons are involved in following reaction : Cr0F" + Fe"? +€,077 > 2Cr3 + Cr? +CO2 The value of n in the equation Cr,07? +14H* +ne~ — 2Cr3 +7H,0 is? Calculate equivalent weight of S in $037? Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. Statement-| is true, statement-2 is true and. statement-2 is NOT the correct explanation for statement-1 Statement-1 is true, statement-2 is false. Statement-I is false, statement-2 is true. Q29. Fluorine exists only in 1 oxidation state. Statement 2: Fluorine has 2s* 2p* configuration of valence shell Q28. Select the species acting as reductant and oxidant in the reaction given below (i) PCI, + Cl, —> PCI, (ii) AICI, + 3K — Al+ 3KCI (iii) SO, + 2H,S —> 38 + H,0 (iv) BaCl, + Na,SO, —> BaSO, + 2NaCI (¥) 31, + 6NaOH —> NalO, + SNal + 3H,0 Write complete balanced equation for the following in basic medium by ion-eleetron method: (a) H, + ReO, ——> Re0, + H,0 (b) Cu? +F —> cur +1, (©) KOH + K,Fe(CN), + Ce(NO.), —> Fe(OH), + Ce(OH), + K,CO, + KNO, +H,0 wWSaral & at we area SlwSaral Exercise - 2 Redox Reaction Brain Booster SINGLE CORRECT TYPE Each question has FOUR options for correct answer: ONLY ONE of these four options is correct option. For each question, choose the correct option 10 answer the question. Qi. Q. Q3. Qs. InS,, S,0?-and S.C, the oxidation state of sulphur is respectively :- (A)18, +641 (B)O, 46,42 (C)0, +8, +1 (D) 0, +6, +1 In the ethylene molecule, the two carbon atoms have the oxidation numbers :~ (A)-1-1 (B)-2,-2 (C)-1,-2 (D)+2,-2 Calculate the correct increasing order of average oxidation number of sulphur in : S,8,0,, $,0,°, $,0,%, 0,2 = (A) §, < §,0; <8,03 2 HI +S. (A) HS is reduced (B) H,S is oxidised OL (D) |, is acting as reducing agent oxidised One mole of iron [55.8 gm], when oxidised to +2 oxidation state gives up : (A) IN, electron (B) 2N, electron (©) 3N, electron (D) 0.5 mole of electron Inwhich of the following reaction H,O, does not act. as an oxidising agent- (A) 2FeSO, + H,SO, + H,0, + Fe(SO,), + 2H,0 (B) 2Cr(OH), + 4NaOH + 31,0, > 2Na,CrO, + 8H,O (©) 2K [Fe(CN),] + 2KOH + H,0,> 2K, [Fe(CN),] + 2H,0 + 0, (D) 2KI + H,O, > 2KOH +1, The number of electrons required to balance the following equation, NO, + 4H +e ——» 2H,O + NO is - (A) 5 (B)4 (3 (D)2 What is the value of » in the following equation CH(OH); + OH > CrO2-+H,0 + ne? (A)3 (B)6 (5 (D)2 wWSaral & at wae area a1wSaral Q23. Qa, Q26. Qa. Q28, Q29. In the reaction, xVO + yFe,0, > FeO + What is the value of x and y spectively :- (A) 1,1 2) 3,2 (B) 2,3 (D) 4,2 In the reaction, xBrO, + yCr°* + 2H,0 > Br, + HCrO, +H’, the coefficients x, y and zare: (A) 6, 8, 22 (B) 6, 10, 22 (©) 6, 10, 11 (D) 6, 10, 20 The balanced form for an equation K,Cr,0, + HCI» KCI + CrCl, + H,0 + Cl, will involve = (A) 14 HCI and 7 H,O (B) 2 KCl and 2 CrCl, (C) K,Cr,0, and 3 Cl, (D) All of these Number of moles of KMnQ, required to oxidize one mole of Fe,(C,O,), in acidic medium is- (Ay 12 (©) 0.2 (B) 0.167 (D) 0.4 KMnO, + HCl MnCl, + Cl, + KC1+ 1,0 In the above reaction how many moles of 11,0 would be formed for each mole C liberated. A (©) 58 (B) 45 (D) 8/5 How many electrons should X,H, liberate so that in the new compound X shows I oxidation number of > [E.N. X > H] (A)2 (C4 (B)3 (D)6 Dichromate ion in acidic medium oxidizes stannous ion as xSn" + yCr,0,7 cH,O Q30. Q31. Q32. Q33. Qa. Redox Reaction (1) The value of x : yis 1:3 (11) The value of x + y+ z may 18 (1D) a: bis 3:2 (IV) The value of z-c is 7 The correct code is - (A) LIL IV (B) 1, 11, 1V (LILIV (D)1, Equivalent weight of H,PO, when it dispropertinate into PH, and H,PO, is-- (AyM (B) M2 (©) 3M4 (D) 2M/3 In the reaction, 2S. , the eq. wt. of Na, (A) Mol. wt. (C) 2.x Mol. wt. 2 +1,98,02 +21 ,0, is equal to its : (B) Mol. wt./2 (D) Mol. wt./6 What is the equivalent weight of C,H.,O,, in the following reaction C,,H,,0,, + 36HNO, —> 6H,C.O, + 23 HO 3a (8) 55 © 2 Dp) 2 © a OF What would be the equivalent weight of the reductant in the reaction 2[Fe(CN),}* + H,0, + OH 2[Fe(CN),}* + 2H,0 + 0, (A) 17 (©) 34 (B) 212, (D) 32 w,g of metal combines with w,g of oxygen forming it's oxide. The equivalent weight of metal is 8w, 8w Ay, Bw, & © Va-w TeddwSaral Q35. Q36, Q37. Q38. Q40, Equivalent weight of KMnO, in acidic medium and neutral (M= molecular wt.) medium respectively- ay MM p) MM AF B>>5 oc MM p MM OSS Os 1.25 g of a solid dibasic acid is completely neutralised by 25 mL of 0.25 molar Ba(OH), solution, Molecular mass of the acid is = (A) 100 (B) 150 (©) 120 (D) 200 The equiv. wt. of hypo in the reaction .S,0, + Cl, +H,0 __, Na,SO,+ 1,80, + HCl is- ‘ay Molt, py Mokwt AZ 8) Fy Mol. wt Mol. wt. OF Os The equivalent wt. of the salt KHC,O, H,C,O,, 4H,O (to be used as a reducing agent) is- Mol. wt. Mol. wt. aw eas ,, Mol. Mol. wt. ors Ory How many moles of stannous oxalate can be oxidised into Sn'* and CO, using 1 mole of K,Cr,0, (A) 0.5 (B) 1 us (D)2 Calculate the number of milli moles of SO,. If in the following reaction 10 ml of 0.1 M KMn0, solution are required for titration. SO, + MnO~, = SO;2 + Mn? (A) 2.5 (B) 0.5 (©) 1.25 (D) None of these Qa. Q42. Redox Reaction A solution of Na,S,0, is standardized iodometrically against 0.167 g of KBrO, where BrO, changes to Br. This process requires 45 mL of the Na,S,O, solution, What is the strength of the Na,$,O, ? IMw. of KBrO, = 167] 2 2 2n ca (A i5 ®B) 39 1 5) PH, +NaHPO, (A) P is oxidised only (B) P is reduced only (C) P is oxidized as well as reduced (D) Na is reduced Sulphur forms the chlorides $,Cl, and SC\, If the equivalent weight of sulphur in SCl, is 16, then the equivalent weight of sulphur is S,Cl, is = (ays (B) 16 (C32 (D) 64 Ratio of moles of Fe(II) oxidised by equal volumes of equimolar KMnO, and K,Cr,0, solutions in acidic medium will be :- (A) 523 (BI (©) 1:2 (D) 5:6 wWSaral & at wa ae SIwSaral Exercise - 2A Redox Reaction Brain Booster ONE OR MORE THAN ONE CORRECT TYPE Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are) correct option(s). For each question, choose the correct option(s) to answer the question. QU. Which of the following can be used both as reductant and oxidant? (A) HNO, (B) SO, (0, (D) co Q2. No reaction occurs in which of following equations (A) P+ Fe? 5, (B) F, + 2NaCl_, (C) Cl, + 2NaF_—_, (D) 1, + 2NaBr—> Q3. Identify the disproportionation reaction (s)- (A) KIO, + 8 KI + 3H,SO, —> 3KI, + 3K,$0, + 3H,0 (B) Cu,0 + 2H*—> Cu+ Cu*+H1,0 (©) 2H,0, —> 2H,0 + 0, (D) 3Mn0; +2H,O—+ MnO, + 2Mn0; + 40H Excess of KI reacts with CuSO, solution and then Na,$,0, solution is added to it. Which of the statements is/are correct for this reaction ? (A) Cu, (B) Evolved 1, is reduced (C) Na§.0, is oxidised (D) Cul, is formed 20 volumes of Qs. 0, is equal to - (A) 20 % HO, by mass % HO, by mass (©) 1.764 (D) 3.528N Which of the following compounds have n- factor equals to 2? (A) H,S0, (C) HPO, (B) HPO, (D) NH, PARAGRAPH TYPE This section contains PARAGRAPHS. Based on each paragraph, there are questions. Each question has FOUR options, ONLY ONE of these four options corresponds to the correct answer: For each question, choose the option corresponding to the correct answer: Paragraph for Q. 7 to 8 The concentration of solution can be expressed in number of ways such that normality, molarity, mole friction, strength % by weight, % by volume and % by strength. the molarity of Ionic compound is usually expressed as formality because we use formula weight of ionic compound. Q7. Number of oxalite ions in 100 ml of 0.1N, Na Na “ 100 ®) 20 Na Na © 00 ©) {000 Q8. The normality of 0.3 M H,BO, is =~ (A) 03 N (B) 0.15N (©) 0.6N (D) 0.9 NwSaral Paragraph For Q. 9 to 11 KMno0, solution is to be standardized by titration against As,O,(s). A 0.1097 g sample of As,O, requires 26.10 ml of the KMnO, solution for its titration, The concentration of Mn* can be determined by titration with KMnO, solution in neutral medium resulting in formation of MnO,. A 15.00 ml solution of Mn** requires 20.06 ml of the KMno0, solution. (As = 75, Mn = 55) Redox Reaction Q9. What is the normality of the KMnO, solution? (A) 0.085 (B) 0.85 (C) 1.085 (D) 5.032 QUO. What is the molarity ofthe KMnO, solution? (A) 0.017M. (B)0.17M (LIM (D)2.34M QUI. Calculate the concentration of Mn". (A) 0.0341 M (B)0.341M (©) 1.231M (D) 5.124M MATCH THE COLUMN TYPE Following questions contain statements given in two columns, which have to be matched. The statements in Column-1 are labelled as A, B, Cand D while the statements in Column-II are labelled as (P), (Q). (R) and (S). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-II. Q12. Column- 1 (A) 2 mole electrons transfer (B) 3 mole of electrons transfer (C) 4 mole of electrons transfer (D) Reduction reactions QI. Match the following = Column 1 (A) Change of NO to NO, (B) Change of P, to H,PO, (C) Change of ClO" to Ct (D) Change of $,0,* to $ Q14, Column-t (A) SCN’ > so? + HCN (B) KCIO, > KCIO, + KCI (©) K,cr,0, 1 cr(80), + Cr,0, (D) FeS, —> Fe + SO, () co; +00, (Q) Fe,0,-> Fe* (R) coe > Ce (S) MnO, > MnF, Column I (P) gain of 2e (Q gain of 4e (R) Loss of 4e (S) loss of 3e Column-I1 (P) Disproportionation reaction (Q) rfactor = 6 (R) Equivalent mass = T2leeularmass (S) Two elements show change in oxidation state wWSaral & at wae area SlwSaral Redox Reaction TRIPLE MATCH TYPE This section contains ONE table having 3 columns and 4 rows. Based on the table each question has FOUR options [4], [B], [C] AND [D]. ONLY ONE of these four is correct. Q15. Column I Column ID Column-HI Compound Oxidation No. underlined atom (A) KC, (+7 (P) Mohr's salt (B) KMn0, (2)+2 (Q) n-factor = 2 (C) Fe(SO,)(NH,),30,.6H,0 3) +6 (R) underlined atom in heigl oxidation state (D) K.cr0, (4) +3 (S) organe colour solution Codes : A BC D (A) 4,P LR 38 2,Q () 4Q 1R 2P 3,8 © 3Q 28 4P LR (D) 2,8 1,P 3,.Q 4R NUMERICAL TYPE ASSERTION AND REASON The answer to each question is a NUMERICAL | (A) _ Statement-1 is true, statement-2 is true and VALUE. For each question, find the correct statement-2 is correct explanation for numerical value (in decimal notation, truncated/ statement-| rounded-off to the second decimal place; e.g. 6.25, | (B) Statement-1 is true, statement-2 is true and 7.00, -0.33, -.30, 30.27, -127.30) statement-2 is NOT the correct explanation for statement-1 Q16. Find oxidation number of Fe in FeS, - (©) Statement-1 is true, statement-2 is false. (D) _Statement-1 is false, statement-2 is true. QUT. The oxidation number of Mn in the produet of alkaline oxidative fusion of MnO, is- | Q19, Statement 1 : Li is the strongest reducing agent, and Li’ is the weakest oxidising agent. QI8. The normality of 2M phosphorus acid Statement 2 : F, is the strongest oxidising (H,PO,) is - agent, and F is the weakest reducing agent. Get Top Ranks in IIT-JEE/NEET/10"/9"/8" with eSaral APP Get it on Page 16 (rodwSaral Redox Reaction SUBJECTIVE TYPE Q20, Complete the following redox equations and balance them.: (a) KnO, + KI + HCI——> + -~ (b) NaS + HCI+ $0, —> + ~ (©) As,S,+NHO, (Cone)+ H,O— + ~ (d) [Fe(CN),}* + H,0, + OH + — --+ H,O+ NO oe Q21. Write complete balanced equation for the following in acidic medium by ion-electron method: (a) 8,0,? + Sb,0, —~ SbO + 1,80, (b) 107+ r+ H > 1, + H,.0 (¢) Mn0,*——> MnO! + MnO, Q22. Balance the following redox reactions by ion ~ electron method : (a) MnO, (aq) + Faq) » MnO(s) + 1,6) (in basic medium) (b) MnO,-(aq) + SO,(g) > Mn*"(aq) + HSO,(aq) (in acidic solution) (c) H,O,(aq) + Fe"(aq) > Fe*(aq) + H,0() (in acidic solution) (d) Cr,0} + SO,(g) > Crag) + $0," (aq) (in acidic solution) Answer Key wWSaral & at wae area Sl EawSaral Redox Reaction Ex-1A 1.A,B,D 2A, C 3.A,C 4.4, B,C 5.C,D 6. A,B, D 1.B B.A, C 9.C,D 10.4 11. B 12.B 13. 14. B, D 15. 16. D 17.B 18.C 19.D 20. (A) > Q; (B) > S;(C) > P; (D) >R 21. (A) > R; (B) > P, 8; (©) > QS; (D) > PS 22. (A) > PS 3(B) > R;(C)OPR QR OVOP QR 23. (A) > Rs (B) > Ps (C)9P,S3(D) >Q 24.6 25.6 26.8 27.B Ex-2A 1.A,B,C,D 2A,C,D 3.B,C,D 4.4, B,C 5. B, D 6.A,C,D 1c BA 9A 10. A TA 12. (A) > PQ; (B) > R: ©) > $;D) + QRS 13.(A) > S;(B)>R:(©>P; M)>Q 14.(A) 9 Q,S8;B)9P;O>Q; MOR S 15.B 16.2 17.6 18. 4N 19.B Get Top Ranks in IIT-JEE/NEET/10' rea Get it on (rod